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By Johanna van Deventer, Sean Scott, Rene du Preez, Steven R. Izatt

In order to meet the stringent specifications associated with the production of LME Grade A cobalt cathode, producers need to ensure that a number of impurities, including Cd, are removed from the advance electrolyte to ppb levels (~0.1 mg/L). Conventional options include ion exchange using amino methyl phosphonic acid resin and solvent extraction using D2EHPA. More recently a Cd-selective resin, employing Molecular Recognition Technology (MRT), became available from IBC Technologies, Inc. These three potential unit operations were evaluated in parallel at Mintek. MRT was identified as the most technically feasible option. Results obtained on a cobalt advance electrolyte, containing 55 g/L Co, 6 mg/L Cd and 60 g/L Na2SO4, are presented in this paper.

Jan 1, 2007

By O. O. Ogunmodimu, D. K. Weatherley, M. S. Powell

Discrete element methods (DEM) have provided the ability to resolve the complex phenomena experienced by ore within comminution devices such as tumbling mills. The new developments in DEM techniques and the corresponding increase in computational power have made it more feasible to study the movement of individual ore particles as they traverse a tumbling mill. A range of information can be extracted on individual particle impact histories, such as kinetic energy at the time of collision, velocities of individual particles, per-particle stress tensors, impulse, and collision energy. DEM codes have been modified to provide required information that can be analysed in associated software to investigate the impact of varied operational parameters on the resultant granular dynamics. This paper explores the reaction of individual ore particles to the breakage environment within a tumbling mill using DEM techniques and studies the stressing conditions that would lead to either impact or abrasive breakage. Keywords: DEM, comminution, tumbling mill, breakage

Jan 1, 2020

By M. E. Rossi, C. Badenhorst

Conditional bias occurs when the expected value of the true grade conditional on the estimated grade is not equal to the estimated grade. It is a quantification of how the average of estimates differs from the true value. Conditional bias is present in all resource estimates due to the unavoidable properties of kriging, and indeed all linear estimation (regression) methods. In a mining resource estimation context, the degree of conditional bias is dependent on the spacing of the conditioning data; more data leads to the expectation of less conditional bias This paper discusses conditional bias from two perspectives: 1. 2. Estimates seeking to eliminate, as much as possible, conditional bias; and Estimates that accept a larger amount of conditional bias in resource models, in order to achieve a specific outcome. The problem of conditional bias in estimation can only be fully appreciated if the objective or purpose of a resource model is understood. There are instances where conditional bias should be avoided because it is not reasonable to make decisions using estimates that are known to be wrong in expected value; for example, when making a final decision in grade control with respect to the destination of the material. In most instances in the mining resource estimation context, however, the estimated values will not be “final estimates”, but “interim estimates”, meaning that in the future more data will be obtained, and the ”interim estimate” will then be updated. In this context, the most useful resource model is an interim model that is able to predict the final model estimates, despite not having all the data available that will be collected in the future. This is the objective, for example, of a recoverable “long-term” model developed prior to operating a mine, for example at the feasibility stage. It attempts to predict the ore that a processing plant will receive, well into the future. In such cases, it can be unequivocally demonstrated that conditional bias is not only unavoidable, it is a necessity.

Sep 1, 2021

By P. N. Harris

The Colloquium on 'Recent Mining and Metallurgical Developments in the Orange Free State' was held at the Civic Centre in Welkom on the 4th and 5th May, 1983. The Chairman of the Orange Free StatejKlerksdorp Branch of the Institute and Acting General Manager of Unisel Gold Mining Company, Mr D. A. Parfitt, opened the proceedings, and Professor A. N. Brown gave the welcoming address. Mechanization of mining The South African Institute of Mining and Metallurgy is to hold a one-day colloquium on 'Developments in the Mechanization of Mining Operations' during September 1984. Surfac,e mining and quarrying The Second International Surface Mining and Quarrying Symposium is being organized by The Institution of Mining and Metallurgy in association with the Institute of Quarrying.

Jan 1, 1983

This report describes the investigational work on the development of a fire-assay method capable of concentrating, in a button of nickel sulphide, all six of the platinum-group metals present in samples of ores, concentrates, and mattes. In the method adopted, the sample is fused with a mixture of sodium carbonate, sodium tetraborate, nickel carbonate, and sulphur. The nickel sulphide formed during fusion collects the noble metals and carries them to the bottom of the crucible. The nickel sulphide button is dissolved, and the noble metals are isolated and determined. The coefficients of variation range between 1,0 and 4,9 per cent for the various platinum-group metals when they are present in concentrations between 0,3 and 75 p.p.m.

Oct 15, 1971

Mr R. C. J. Goode (President) was in the Chair. There were also present one hundred and thirty-six Members, including Messrs R. J. Adamson, Dr J. M. Bereza, Messrs M. Barcza, H. Britten, H. E. Cross, J. K. E. Douglas, G. W. Holl, Dr J. P. Hugo, Messrs C. J. Irving, P. Lambooy, Prof J. de V. Lambrechts, Mr D. G. Maxwell, Dr J. T. McIntyre, Prof R. P. Plewman, Messrs J. F. Reid, V. C. Robinson, H. Simon and P. W. J. van Rensburg (Council Members), G. Abdinor, C. B. Anderson, H. F. Allan, E. L. Atkinson, V. C. Barnes, J. F. Bennet, W. W. Bath, R. E. Barnes, C. L. Berrange, J. P. Buds, Dr W. Bleloch, Dr L. A. Bushell, Messrs D. L. Carson, D. D. Cornier, R. S. Cooke, R. R. M. Cousens, J. P. Coetzee, W. L. Cousens, J. Daniel, R. Daniel, D. G. Davies, S. K. de Kok, V. S. Dillon, B. S. Dykhouse, Dr H. G. Denkhaus, Dr R. S. J. du Toit, Messrs J. I. L. Edwards, R. C. Espley-Jones, J. C. Ferguson, D. T. Fourie, A. Frost, W. R. Flook, Dr N. P. Finkelstein, Messrs D. F. H. Grave, J. M. Gosnell, E. K. Gibson, R. W. Grout, E. W. Gray, J. S. Hay, F. G. Hill, H. N. Hepker, J. P. Hoffman, C. G. Hodges, D. M. Jamieson, Dr D. G. Krige, Dr N. P. Lategan, Messrs J. E. Laschinger, J. Levin, C. P. Linsell, J. O. Kempe, F. Q. P. Leiding, A. I. Lee, D. G. Malan, W. Malan, H. W. McCulloch, R. D. R. Munro, C. S. Macphail, Dr T. F. Muller, Dr A. J. Nel, Messrs S. C. Newman, G. G. Nicolson, G. Y. Nisbet, J. A. Papenfus, E. Pavitt, W. H. Pittie, P. C. Pirow, P. G. D. Pretorius, N. F. Peverett, R. P. Plaskett, M. P. Pearse, W. Pilkington, T. K. Prentice, Dr R. E. Robinson, Messrs R. B. Richardson, R. St. J. Rowland, R. J. Rouillard, F. O. Read, W. T. Ruhmer, D. Savile Davis, E. F. Statham, K. Smith, H. Simon, G. B. Stern, C. D. Storrar, Dr N. B. Strydom, Messrs J. H. Talbot, A. H. Taute, J. H. Taylor, G. W. Thiel, K. A. Tweedie, W. E. Vance, Dr H. J. van Eck, Messrs L. W. P. v. d. Bosch, P. A. von Wielligh, N. B. Vinson, S. J. Venning, W. M. Walker, D. T. Watt, Dr H. J. R. Way, W. T. L. Wayman, R. G. Williams, L. G. S. Wright and C. F. Ziervogel. Thirty Associate Members, including Messrs E. Collier, G. Douglas, D. H. Gray, H. G. Gericke, R. Hemp, N. M. Hayne, A. Hazell, P. M. Johnston, D. E. Love, Miss V. E. Marting, Messrs R. G. Matthews, P. Malpage, D. Nicolle, R. Pendreigh, J. J. Rosslee, R. W. Shearer, R. F. Taylor, G. C. Thompson and D. A. Viljoen. Three graduates, Messrs G. S. Giles, J. P. Hatfield and J. A. Jones. Five Affiliates, Messrs A. C. Collie, E. Collier, A. B. Cook, W. Jacobs and G. M. Thain. Two Students, Messrs C. J. Bircher and R. P. Henrard.

By E. J. Maunders

This paper describes briefly a computerised model of the South African electricity system which has been developed jointly by the Atomic Energy Board and the Electricity Supply Commission. The results of an analysis of this system have been subjected to a fairly extensive sensitivity analysis which reveals that up to the year 1990 between 680 and 700 million tons of coal will be required for electric power generation, together with between 7 000 and 10 000 tons of uranium. This result is fairly insensitive to data variations, but the prediction of a cumulative requirement up to the year 2000, of between 1 300 and 1 800 million tons of coal and 25000 to 70000 tons of uranium, proves to be very data-sensitive.

By M. Timucin

High-temperature phase relations and thermodynamics of the condensed phase region of the Pb-S-O system at 1473 K were analysed by use of the available information. The sub-regular solution models on Pb-PbS and PbO-PbSO4 continuous melts were used in conjunction to generate a consistent set of thermodynamic and phase equilibrium conditions for the Pb-S-O system. The directions and distributions of conjugation lines between melts of this system were derived with relevant activity and composition data. The calculations permitted the thermodynamic analysis of direct lead smelting and the construction of isothermal reaction diagrams for the system in terms of oxygen and sulphur partial pressures at 1473 K.

Jan 1, 1989

By I. Zh. Bunin, M. V. Ryazantseva, V. A. Chanturiya

The paper proposes a new method for selective calciferous separation. The effect was achieved through the application of the combination of high-power electromagnetic pulses (HPEMP) and a specific reagent regime of the flotation. The combined application of HPEMP with the special reagent regime allowed for the improvement of the scheelite floatability: the recovery of CaWO4 rises from 41.2 % (untreated sample) to 58.5 (sample treated at 103 pulses). In contrast, the floatability of calcite decreases significantly: the recovery of calcite drops from 74.7% (untreated sample) to 41.1 % (sample treated at 103 pulses). The conditions were found for the selective separation of the minerals with very close flotation properties. Keywords: Calcite, scheelite, flotation, high-power electromagnetic pulses, DRIFT, XPS

Jan 1, 2020

By J. A. Theron

"This paper provides guidelines on performing mass and energy balance modelling involving coal and coal derivatives. Usually, the inputs to a pyrometallurgical process would be specified in terms of elements and compounds. Reliable thermochemical data is more widely available for species involving uniquely defined, relatively smaller molecules. However, in the case of coal, the molecules are extremely large and not uniquely defined. Consequently, modelling processes involving coal and its derivatives have several potential pitfalls. These are outlined in the present paper. The main findings are as follows:•,Coal proximate analysis should not be regarded as absolute; it could vary with several parameters, including heating rate •,For modelling, the use of ultimate analyses should be considered a preferable option to proximate analyses, where, ‘fixed carbon’ and ‘volatiles’ are not defined in terms of chemical composition •,Significant errors could be made if the larger molecules are neglected during calculation of the calorific value (CV) of coal gas (the gas liberated when coal is heated in the absence of oxygen) •,For elemental analyses, the oxygen content (which is calculated by balance) should be checked to ensure it is within the expected range •,For representation of sulphur in coal, double-counting due to SO3 in the ash analysis should be avoided •,Potentially, oxygen in coal could be represented as O2, H2O, CO, or CO2; however, use of some of these species without considering the experimentally determined gross CV results in significant errors in the energy balance. If coal enthalpy is calculated from elemental analyses without correction, representation of coal oxygen as H2O(l) gives reasonable accuracy (up to 6.9% error for a set of South African coals). Coal volatiles could be represented by a complex mixture of compounds, even using different oxygen-containing species than the abovementioned four, provided the enthalpy is corrected •,It is recommended that an ‘enthalpy correction value’ is incorporated in energy balances involving combustion, devolatilization, or conversion of coal and coal derivatives, e.g. coke, char, or tar. That would imply that proximate analysis, elemental analysis, as well as the gross CV would be required for all solid or liquid coal-derived substances being modelled. No other correction due to the form of carbon being different than graphite should be used, as that would imply doublecounting some effects."

Jan 1, 2014

By John Freer

A colloquium on solid-liquid separation was held by The South African Institute of Mining and Metallurgy on 23rd September, 1982, at the State Pavilion Auditorium, Milner Park, Johannesburg, to co-incide with the Electra Mining Exhibition. It was attended by about 150 delegates. Eight papers were presented covering: Geostatistics The School of Earth Sciences of Stanford University, the Centre de Geostatistique ofthe Paris School of Mines, and the Department de Genie Mineral of the Ecole Polytechnique of Montreal are cosponsoring the organization of a 2nd NATO ASI (North Atlantic Treaty Organization Advanced Study Institute), under the name of 'GEOSTAT TAHOE 1983', to be held at South Lake Tahoe, California, on 4th to 17th September, 1983.

Jan 1, 1982

The AMIRA Code of Practice and Guidelines for Metal Accounting was developed in response to demand from a number of sponsor companies, including one major platinum producer. Since its publication in 2007, the Code has become widely accepted in the mining industry world-wide as a guide for best practice in metal accounting. With the changes in the structure of the platinum mining industry in South Africa over the last 10 ? 15 years, in particular, the starting up of a number of small platinum producers who must have their concentrate smelted and the contained valuable metals refined by third parties, the need for metal accounting systems that are accurate and have an acceptable level of precision has become even more critical to the success of a platinum-producing operation. The current state of metal accounting in the industry is discussed and possible areas for improved accounting and associated metallurgical efficiencies are identified.

Jan 1, 2012

By G. J. Krige

The extent of ground movements and stress concentrations in the vicinity of the reef in the deep mine-shafts used in the South 4frican gold-mining industry have led to the requirement that special tower structures be developed to span the reef intersection zone in several new shafts. So that structural engineers are able to design these towers, it is necessary to model the dynamic behavior of conveyances traversing them in some way, to provide a means to determine the magnitude of the forces generated. This paper describes the development of two such procedures. The first is a numerical method, utilizing a step by- step integration technique to track the motion of a conveyance through a tower. This technique has been implemented in a computer program, and some results are given.

Jan 1, 1995

Mr J. Meintjes (Chairman) was in the chair. There were also present: 7 Members: Messrs B. D. McNeice, A. Bain, G. E. Carlyon, C. H. Coxon, B. F. v. d. Merwe, A. C. Hofmeyer, H. J. R. Way. 4 Associate Members: Messrs E. J. Jackson, A. C. Melvill, W. Weber, R. E. Powell. 2 Visitors. It was decided to have the visit to ETC at Barberton on 20th March. A programme will be sent to all members who indicated that they wish to go on this visit. A talk on "Billet Casting of Ferrochrome" was given by Mr. B. F. van der Merwe. After question time the chairman thanked the speaker and asked for the talk to be forwarded for possible publication in the Journal. The meeting closed at 9.10 p.m.

By H. Karabulut, S. Gündüz, K. Karacif, M. A. Erden

The corrosion properties of iron-based composite materials containing graphite and silicon carbide (SiC) reinforcement were investigated. The effects of silicon carbide reinforcement were investigated by adding 0.5% graphite and 1%, 2%, and 4% SiC. A powder metallurgy method was used to produce the composite samples. Iron, graphite, and silicon carbide powders were blended for one hour with a threeaxis mixer and then unidirectionally pressed under a pressure of 750 MPa. After pressing, the composite materials were sintered at 1100°C for one hour. The corrosion properties and microstructure, density, and hardness properties of the composite materials that can affect the corrosion properties were also investigated. It was determined that the pore ratio and hardness of the composite material increased, and corrosion resistance decreased, with increasing silicon carbide content.

Jun 2, 2022

By D. Lunt

This paper describes and sets in context the commercially proven uranium extraction processes. It also discusses some of the technologies that are currently being pursued with the aim of reducing costs and overcoming a number of technical issues that are faced by process designers and operators. In doing so, opportunities for the transfer of extraction technology from other industries/commodities are identified. The key processing areas that are examined include: ?The influence of mineralogy. The type of uranium mineralization and the nature of its association within a particular deposit will have a major impact on process route selection. Uranium minerals are classified according to their influence on extractive metallurgy. As the uranium price has risen in recent times, so opportunities are increasing for the recovery of uranium from less conventional resources such as phosphates and fossil fuels. ?The opportunities for employing techniques aimed at reducing the capital and operating costs of the overall process such as heap leach and beneficiation. Preconcentration by screening, gravity separation and radiometric sorting can potentially reduce the mass flow to the downstream leach and recovery plants. ?Purification or separation of uranium in carbonate systems. While it is possible to directly precipitate uranium from clarified leachate, the presence of impurities such as vanadium, molybdenum and others may dictate that ion exchange or selective precipitation is employed. Advances have been made in other industries in terms of improved ion exchange equipment aimed at reducing resin inventories and hence costs. ?Separation in acid leach systems. Earlier developments included the use of combined SX-IX systems (Eluex or Bufflex) and the introduction of continuous countercurrention exchange (CCIX). Column SX has found a ready application to uranium in view of the rapid extraction kinetics. With the renewed interest in uranium processing, efforts are being redirected towards further development of resin-in-pulp (RIP) as a means of driving down capital and operating costs. ?Extraction in a chloride environment. Australia and Namibia are desert countries where good quality water comes at a cost. However, both have access to saline water from either the ocean or subterranean aquifers. The issues associated with operating a uranium extraction operation in such environments is discussed. ?Extraction from less conventional sources. Recent price increases for U3O8 have resulted in a number of companies examining the recovery of uranium from sources such as fossil fuels and phosphate deposits. Both of these areas were examined in the 1970s and 1980s and a number of approaches were commercialized. The paper reviews the extraction options.

Jan 1, 2007

By G. Mucsi, F. Kristály, R. Szabó

Kaolin is one of the most important ingredients in porcelain manufacturing. Its main phase is clay mineral containing aluminum hydrosilicate, namely kaolinite. Beside kaolinite it also contains quartz, illite and feldspars, which impair its applicability. Kaolin is a non-reactive material, but metakaolin can be produced by heat treatment (calcination) of kaolin, which is also used by the cement and concrete industry due to its latent hydraulic (pozzolanic) properties. Beside thermal activation, reactive materials can also be produced by mechanochemical activation in general. This paper deals with the mechanochemical activation of kaolin. The raw material was classified into various size fractions, then ground in a batch stirred media mill under varying circumstances (residence time, circumferential velocity). After grinding, the structural changes of the products were investigated by X-ray diffractometry (XRD) and Fourier Transform Infrared Spectroscopy (FTIR). In addition, the particle size distribution of the ground material was determined by laser scattering. As a result of the grinding experiments and analytical measurements of the products, it can be clearly seen that reactivity of kaolin can be improved significantly by mechanical activation in a stirred media mill, but due to its high energy density the circumstances were optimised carefully to avoid aggregation. Keywords: Kaolin, grinding, stirred media mill, mechanical activation, material structure

Jan 1, 2020

By G. M. Evans, S. Mitra, A. V. Nguyen

As an alternative to the conventional flotation method, there has been continual research in an effort to enhance base metal ores and combustibles recovery using ultrasonics. These studies however were largely limited to the pre-treatment of ores for the removal of surface contaminants while the effect of ultrasonics on the bubble and pulp-phase interactions remained somewhat unexplored. Noting this deficiency, this study aimed to investigate the mechanistic effect of an ultrasonic field in an impeller less flotation cell specifically focusing on the bubble-particle interaction dynamics. A lab-scale flotation cell (capacity 1 litre) was designed, involving a vertically oriented ultrasonic probe (20 kHz, rated at 1.2 kW) and operated in the output power range from 1 to 20% with continuous liquid recirculation. Particle suspension was achieved by the combined action of recirculation and ultrasonic pulses. Interactions of coarse size glass ballotini particles (D32 = 314 μm) with bubbles (< 1 mm diameter) in the presence of a surfactant were studied, using high-speed imaging. Application of an ultrasonic pulse in the aqueous medium resulted in the generation of numerous microbubbles which increased with increasing input power and duration of the ultrasonic pulse time. Such periodic pulses introduced at a high level of turbulence in the pulp phase facilitated adequate bubble-particle contacts. Microbubbles played a key role in forming particle clusters which were observed to be floatable even in the absence of any carrier bubbles. When carrier bubbles were introduced, some of these particle clusters attached to the bubble surface and conveniently floated. It was noted that a favourable state of bubble-particle interaction was achievable to produce stable bubble-particles aggregates by suitably controlling the input power and period of the applied ultrasonic pulse. Keywords: Flotation, bubble-particle interactions, collision, attachment, detachment, ultrasonic pulse

Jan 1, 2020

On 23rd October, 1969, 54 members of the Institute set out at an early hour from Rand Airport in two chartered Dakota aircraft for a visit to the Hendrik Verwoerd Dam site. The weather was at the start rather unpromising but after passing Bloemfontein the overcast cleared and it turned into a glorious day for a most memorable visit. The Institute is indebted to U.C-Dumez-Borie Dams Limited, the main civil engineering contractors, and Mr J. D. McNamara their executive manager, for the very excellent arrangements made for this excursion. From the time the aircraft landed till a slightly belated departure the organisation of the extensive tours arranged for the parties was quite outstanding and a matter for congratulation to all concerned. At each of the many places visited there was a senior official to give an authoritative and comprehensive description of the work under his control. In addition the guides on the buses, loaned by the Department of Water Affairs, kept up an interesting running commentary throughout the day. A further much appreciated facet was the introduction of many of the experts on the site and a brief talk by each after an excellent lunch served at the recreation club. Each visitor also received a brochure with a progress report and a detailed site plan, with various sections highlighted in colour, and obviously prepared at the cost of much time and effort. The visit included tours of the large dolerite quarry, where some 150 000 tons of rock are removed each month, the 42 in. gyratory primary crusher, the secondary crushing and screening plant, the rod mill plant for sand production, and the automated blending and concrete batching plant. The transport of mixed concrete by &apos;silobuses&apos; to the 6 cu. yd buckets of four Blondin cableways, two of which are radially movable and two with buffing towers, and the placing of the concrete in the huge blocks of the wall was watched from a vantage point. The most interesting part of the visit was without a doubt the inspection of the wall itself and the explanations of the many intricasies of its design and care in construction, covering aspects such as positioning of galleys, interlocking of blocks, reinforcement, refrigeration, actual concrete placing, subsequent grouting, etc. Other points of interest were the very complicated design of the wall itself, the river diversion plans, with three stages of coffer dams, the spillways, and the very well cut penstock tunnels.

By H. Matsuoka, M. Kawata, K. Mitsuhashi, C. Tokoro, T. Kato

Copper sulfide minerals generally have high floatability, but their floatability decreases when surfaces are oxidised under some conditions. Sodium hydrosulfide, NaHS, is known both as an activator and as a depressant for copper minerals. NaHS at low concentrations activates copper oxides by sulfurising surfaces, but at high concentrations depresses copper sulfides by interfering with the adsorption of collectors. In this paper, we applied NaHS to activate oxidised chalcocite and bornite and focused on the conditions of NaHS treatments such as dosages and pH, and the effect of these conditions on the floatability of those minerals. The pure minerals treated with NaHS were analysed using zeta potential analyser and X-ray photoelectron spectroscopy. Analyses indicated that the reactions of NaHS and the products on the mineral surfaces after the reactions (i.e. oxidation, pH change) depended on whether NaHS reacted with copper or iron, and the reactions between NaHS and iron depend on NaHS concentration and pH. Flotation tests using a small column cell were performed with a single pure mineral, and using a Denver-type flotation machine with a copper sulfide ore. The results of each flotation test were utilised to clarify the floatability. The relation between flotation behaviours and analysis results were also discussed. Keywords: Chalcocite, bornite, NaHS activation, flotation, floatability

Jan 1, 2020