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By B. R. Mohal, F. F. Aplan, S. Chander

"Dust abatement by water sprays involves the subprocesses of 1) collision between dust particles and water droplets, 2) adhesion of particles to droplets, and 3) engulfment of particles by the droplets. A review of the fundamental aspects of these subprocesses shows that collisions between particles and droplets are determined by aerodynamics and the size and surface charge of the particles and of the droplets. However, the adhesion and engulfment subprocesses depend upon the wetting characteristics of the particles. Although wetting agents (also known as surfactants) have been used as dust suppressants in several investigations, conflicting results are available regarding their effectiveness. In this paper, we show that these results can be explained if the effects of coal rank on surfactant adsorption and wetting characteristics are taken into account.The influence of several nonionic surfactants containing polyethoxy adducts on the wetting behavior of coal is presented. The wetting was determined by a modified Walker Test method, and contact angle measurements. The results show that the wettability of coal depends upon coal rank, structure of the hydrocarbon chain of the surfactant, and the number of ethoxy groups in the molecule.IntroductionDue to the inherent nature of the mining process, a large number of particles are generated, a portion of which becomes airborne to create dust. Dust can be aesthetically and environmentally unacceptable and it can also be explosive. Fine particles in the respirable size range ( < 5 urn) are con-sidered to cause lung diseases, namely, silicosis, pneumoconiosis, etc.(1) Several approaches to reduce dust in mine environments are practiced throughout the mining industry. These include decrease in generation of dust through improvements in mine machinery, ventilation (in which lower dust levels are achieved by dilution of contaminated air with clean air), and dust removal methods. Water sprays are most commonly used to remove dust par-ticles. Recently, scrubbers are reported to have been installed on mining machines to remove dust,(2,3) which also make use of water sprays to reduce dust."

Mar 1, 1989

By C. A. Wilson

The Bureau of Mines started a continuing program to investigate and evaluate analytical techniques to assist governmental agencies to select simple, rapid, reliable methods for crude oil spill identification. Six crude oil samples were analyzed to evaluate gas-liquid chromatography, atomic absorption spectrophotometry, infrared spectoscopy, sulfur and nitrogren determinations, mass spectrometry, nuclear magnetic resonance spectroscopy, and ultraviolet spectrophotometry. Samples were studied from the following selected fields: El Morgan, Egypt; Duri, Indonesia; Minagish, Kuwait; Bachaquero, Venezuela; Gach Saran, Iran; and Prudhoe Bay, Alaska. These samples were chosen to represent high-production fields that are likely to be involved in oceanic transport. Over 50 years of Bureau of Mines analytical research on petroleum served as the basis for evaluation of the experimental results to determine which of the methods are effective techniques to identify crude oil spills. Gas-liquid chromatographic analysis, atomic absorption spectrophotometric analysis, and sulfur-nitrogen determinations are recommended as the most useful of the techniques investigated.

Jan 1, 1975

By Richard L. Lewis

This is a discussion of the application of the zonal harmonic series to problems involving dipole sources in the vicinity of spherical boundaries. The application of a formal zonal-harmonic series solution to directly obtain numerical results involves two distinct problems: namely, the convergence of the series solution and the accurate calculation of the special functions involved in the series solution. Some interesting techniques will be introduced which help to improve the convergence properties of the series solution.

Jan 1, 1973

By E. D. Gardner

A custom gold and silver plant is one that treats ores for a fee. Usually such plants are located in mining districts and treat local ores. Ores of milling grade generally can stand only moderate transportation charges. These plants are scattered throughout the West. Most plants now doing a custom business originally were built by mining companies to handle ores from their own mires. As excess mill capacity became available ores from neighboring properties were treated, vainly as an accommodation. Later, as their own ore bodies became depleted, the mills were operated entirely on a custom basis. A few plants pull ore from their own mines only when the supply of custom ore is insufficient to keep the mill operating. Some of the present custom plants were built for custom work alone. Although built originally to treat the ores of the Golden Cycle mine, the Golden Cycle plant at Colorado Springs, Colo., soon became a custom mill and has been operating successfully for many years. It is the largest gold mill in the Western States and. treats Cripple Creek ores, from which most of its tonnage still comes. The plant is equipped to treat a great variety of ores and receives shipments from a wide area. It competes with smelters in Colorado, as it has a roasting plant to prepare sulphide concentrates for treatment in its cyanide plant. Most custom mills, however, are not adapted for more than one or two kinds of ore. Gold occurs in its ores both in the metallic state (free) and locked up in sulphides. It also occurs in a few places, notably at Cripple Creek and a few other Colorado districts, as tellurides. Mien the gold occurs in the native state, the ores is said to be free-milling and can be recovered by amalgamation. Usually, however, some subsidiary treatment is required to make a satisfactory extraction. Amalgamation generally was followed by tabling in the earlier mills; at present, flotation has replaced tables at many places. As depth is reached in raining and the workings extend below the oxidized zone the character of the ore usually changes, or, as the miners say, "it gets base". Since the advent of flotation, the average recovery of gold in base ores has been improved-greatly. Cyanidation is applied to some types of both gold and silver ores. The recovery by cyanidation is in general considerably higher than by other methods in vogue and in addition has the advantage of making a finished product which can be sold directly to the mist, thus obviating smelting charges on concentrate and discounts

Jan 1, 1935

By Robert C. Gabler

The extraction of metals from coal ash was investigated by the Bureau of Mines in an effort to produce a more environmentally acceptable waste and offset waste disposal costs with recovered metal values. The research was conducted in two steps: determination of the parameters that affect extraction of metals from coal ash and development of extraction-recovery procedures. Data obtained indicate that the major parameter affecting the extraction of metals from coal ash is the calcium content of the ash. Other parameters such as furnace type and operating temperature had much smaller effects on metal extraction. Two procedures were studied for metal extraction: an acid leach procedure for high-calcium ashes and a lime sinter-acid leach procedure for low-calcium ashes. An alumina product was recovered that, with sufficient washing, meets Hall cell specifications. The leach residues pass the EPA EP Toxicity Test and are thus nonhazardous wastes available for a variety of uses.

Jan 1, 1983

Provide an instrument for continuous remote monitoring of carbon monoxide concentration in underground mines. Approach A carbon monoxide fixed? point continuous monitor consists of two modules. A line-powered control module is designed to power a remote transducer module; provide continuous readouts, visual and audible alarms, operational checks; and activate fans and equipment shutdown circuits if preset CO concentration levels are exceeded. How It Works The control module must be used in conjunction with a single transducer module. Developed under contract. the control module is a wall-mounted Instrument which contains a readout and alarm capability and power supply

Jan 1, 1981

By M. E. Tyrrell

The purpose of the work leading to this report was two-fold: (1) To determine the properties of cemented tungsten carbide modified by the addition of one, two, and five percent of titanium diboride, and (2) to compare the properties of these mixtures when sintered, hot-pressed, and flash-welded (resistance-sintered). Minor additions of titanium diboride to mixtures of 94 percent WC and 6 percent Co decrease mechanical strength but increase oxidation resistance in proportion to the amount of the addition. One percent of titanium diboride increased the hardness by 2 Rockwell A units. Hot-pressing produced compacts with the highest density and the best mechanical strength, but losses of cobalt were high and grain growth was pronounced.

Jan 1, 1962

By Fred Leighton

The Bureau of Mines monitored a rock-burst-prone pillar in a metallic ore vein, up to and through failure, to measure its reactions to increasing loads, as it was mined. Three parameters were monitored: the stress changes at chosen points within the pillar, the displacement characteristics of the drift above the pillar, and the micro-seismic activity in and around the pillar. In descending order of effectiveness, the microseismic technique, vibrating wire stress measurements, and displacement measurements reflected the pillar reactions, and all showed good correlation to one another. A major rock burst in the pillar, which destroyed about 100 feet of drift above the pillar, occurred at the end of this study. This burst was preceded by a large anomaly in the microseismic activity in the failure area.

Jan 1, 1982

To find solutions for common safety problems encountered in the handling of trailing cables, based on observations at many different surface mining operations. Approach Practices in handling trailing cables were Investigated through personal visits to over 40 mines, supplemented by visits to cable manufacturers and cable repair service companies. The most effective solutions to the safety problems en-countered were noted and are described In the project final report. Examples are given in this Technology News. Accident Experience Most cable-related injuries occur as a result of workers lifting, pulling, tripping, or being struck by the cable. The Table gives the frequency of occurrence for injuries reported during a recent 3 1/2 year period.

Jan 1, 1982

To minimize support costs and to improve ground control by improving wood-crib design and utilization through the development of engineering methods that will match the placement and performance of the wood cribs to the load conditions imposed by the mine environment. Background While wood cribs are used extensively to stabilize mine openings, their utilization is often based on historical practice or trial-and-error rather than on engineering design. This has led to conservative crib utilization where more capacity than is necessary is employed or inadequate capacity is provided when mine conditions worsen. Critical design parameters, such as the stiffness of the support structure, are often ignored. Optimum crib design and employment is becoming increasingly important as the utilization of wood cribs increase due to the growth of longwall mining, and as the cost of wood continues to rise. A single longwall operation will spend as much as a million dollars per year on the support of the gate roads.

Jan 1, 1994

By G. B. Atkinson

The Bureau of Mines, in cooperation with McDermitt Mine, investigated a method for recovering mercury metal from mercury sulfide flotation concentrate by a hydrometallurgical technique. This preliminary report shows the feasibility of leaching mercury with a cupric chloride solution and electrowinning mercury from the solution. Proposed chemical reactions are shown in equations 1 through 3: 2CuC12 + HgS + 2CuCl + HgC12 + S°; (1) electrolysis HgC12 ?Hg + C12; (2) 2CuC1 + C12 ? 2CuC12. (3) A bench-scale leaching-electrowinning apparatus capable of treating 2.36 kg of sulfide concentrate in 11 days was operated continuously. An acid chloride solution containing, in grams per liter, 70 Ca, 60 Cu, 30 Fe, and 80 Hg was used as both leachant and electrolyte; 99.5 pct of the mercury was solubilized from the sulfide concentrate. Electrolysis of the leaching solution recovered mercury metal at an average current efficiency of 32 pct and an average energy consumption of 1.2 kwhr/lb Hg. Results from a preliminary economic evaluation indicated that a plant producing 31,500 flasks of mercury per year would have a capital cost of $3.7 million and an operating cost of $62 per flask of mercury.

Jan 1, 1983

By Robert M. Becker

A thick-wall cylinder solution applicable to the evaluation of anisotropic elastic parameters is derived for the interpretation of stress relief data. For a restricted class of problems, a special relationship among certain orthotropic moduli yields stress distributions for the plane orthotropic problem that are identical to the corresponding isotropic case. A ring or hollow cylinder with these specialized anisotropic properties subjected to uniform radial loads is one of the problems in this class. Consequently, known stress solutions are used to develop the strains and displacements for a specialized orthotropic thick-wall cylinder under uniform pressures. The results are consistent with anisotropic equations used in the evaluation of in situ rock stresses.

Jan 1, 1968

Use instantaneous sampling to pinpoint dust sources and to Improve dust control on longwalls. Approach Use a dust monitor developed under a Bureau contract. How It Works Sampling can be done by either a moving or a stationary method. In the "moving&apos; method, the dust monitor is carried by a survey engineer walking at the midpoint of the shearer Dust levels and face position (support number) are taken during all phases of the mining cycle while the shearer is cutting. These measurements can show how changes in airflow along the face, face specific; (rock partings) and cutting sequence (cutting the wedge) variables affect dust levels. In the "stationary sampling" method, the survey engineer stands with the RAM at a fixed location on the face. As the shearer approaches, the dust level and the distance to the shearer are recorded at 10-second intervals. Typically measurements start when the shearer is 20 feet from the sampling position and continue as the shearer passes the position until it is 20 feet away on the other side. Dust profiles around the machine are obtained at several fixed locations along the face only while the shearer is cutting.

Jan 1, 1982

By Basil Dimitriades

Five recently developed methods for determining nitrogen oxides in automotive exhausts have been evaluated from the standpoint of accuracy and applicability in current exhaust studies. Results showed that methods requiring conversion of nitric oxide to nitrogen dioxide as a part of the analytical procedure are subject to errors introduced by the instability of NO2. The extent of some of these errors has been determined and procedures have been developed to minimize undesirable influences. On the basis of the results obtained from this study, recommendations are made regarding procedures for batch type or continuous measurement of nitrogen oxides in exhaust streams.

Jan 1, 1968

By R. W. Dalzell, Fred N. Kissell, J. L. Banfield, M. G. Zabetakis

Methane concentration peaks were measured by the Bureau of Mines at coal mine working faces during entry development. The statistical distribution of peaks was found to be normal or log normal depending on how well the methane was being mixed into the ventilation airstream. A normal distribution indicated good mixing, whereas a log-normal distribution indicated that mixing was poor. In addition, the "highest" peaks over selected intervals were found to fit a type I extreme-value distribution, a result similar to that obtained while mining longwall faces.

Jan 1, 1974

By John C. Edwards

The Bureau of Mines has developed a time-dependent droplet vaporization model (in the absence of forced convection) that can be applied to the vaporization of liquid Halon 1301 droplets (vapor pressure at 300 K = 14 atm) sprayed from an extinguisher. It was found that rapid surface vaporization quickly lowers the droplets&apos; surface temperature very near to the boiling temperature, and the vaporization becomes diffusion controlled. Although the lifetime of the droplet is proportional to the square of the initial radius of the droplet, the elapsed time prior to complete droplet vaporization is not proportional to the square of the droplet radius, as an equilibrium model would indicate.

Jan 1, 1982

By E. E. Remmenga

Often a collection of analytical data, which should reasonably be expected to follow the normal distribution, contains too many extreme values, which the experimenter is inclined to eliminate according to some arbitrary procedure. The stepwise computer procedure described for this purpose is similar to many other truncation procedures; however, because truncation of a basically normal distribution causes a downward bias in the estimated variance, this procedure provides a graphical method to compensate for the bias.

Jan 1, 1971

By E. J. Matson

The Little Castle Creek chromite deposit was examined in February and May 1941, respectively, by W. O. Vandenburg and O. H. Metzger, engineers of the Bureau of Mines. The Federal Geological Survey started a magnetometer survey of the area in November 1940 and completed its work during April and May 1941. Field work by the Bureau of Mines was conducted during May and June 1941. The purpose of the Bureau of Mines investigation was to search for a continuation of the chromite mineralization. The property at one time was the largest chromite producer in California.

Jan 1, 1949

By A. B. Hooker, J. W. Paul

"There was a time when any suggestion that the Davy flame (safety) lamp be discarded, would have evoked unlimited, criticism. However, that time is past.Investigations both here and abroad have shown conclusively that the Davy lamp does not have the necessary factor of safety against ignitions of mine gas, and England, the lost stronghold of the Davy lamp in Europe, has eliminated this lamp and substituted safer types.In the United States there are companies who still use the Davy lamp in spite of all that has been said and published as to the dangers connected with its use.Recently the purchasing agent of an anthracite coal company requested the Department of the Interior, Bureau of Mines, to pass upon the safety of some braise gauzes for use in a shielded Davy lamp. A shielded Davy lamp is an ordinary Davy safety lamp equipped with a circular brass shield that is attached to the lamp posts. This shield extends about one-half way around the gauze and one-half of the gauze height. The main purpose of the shield is to prevent the lamps being extinguished by a sudden increase in the velocity of the air current past the lamp.The brass gauzes submitted for this test represented two grades of brass - a yellow brass and a red brass. The analysis of these brasses was not determined. Two shielded Davy lamps that were submitted for the tests each had a steel gauze. These steel gauzes were also tested. Tests were made in horizontally moving mixtures of Pittsburgh natural gas and air at velocities of 400 to 1,000 feet per minute. The gas percentages used were 7%, 8.6%, and 11%. Tests were made with the lamp shield in two positions relative to the lamp and direction of flow of the gas-and-air mixture. In one position the shield was between the gauze and flow, as normally used. In the other position the shield was on the downstream side of the lamp. The tests were continued until one or more failures or gas explosions been obtained with each of the six gauzes. The results of these tests summarized as follows:"

Jun 1, 1923

By Ben A. Kornhauser

Petroleum production was the principal component of the mineral industry, followed by cement production and some salt output. The French Central Fund for Economics Cooperation loaned $9.15 million2 to the Communauté Electrique du Benin (CEB), which served Benin and Togo, toward financing the construction of a dam on the Mono River at Nangbeto, Togo. The dam was to supply hydroelectric power to reduce the energy dependence of the two countries and to irrigate crops. Nine other international financial organizations, including the International Bank for Reconstruction and Development (World Bank). the African Development Bank, the Arab Bank for African Economic Development, and the French Aid and Cooperation Fund, contributed to the estimated $140 million cost of the dam. The CEB also was to contribute to the financing. Contracts amounting to $60 million already had been awarded to West German and Canadian firms. The dam was expected to be completed in 1987.

Jan 1, 1986