Search Documents

By K. E. Tame

The Bureau of Mines is studying possible modifications in conventional uranium ore-processing steps to confine and permit controlled disposal of radioactive wastes. Surveys of Ra226 contamination of liquid wastes from uranium mills indicated that the Vanadium Corporation of America plant at Durango, Colo., had one of the more urgent problems. A possible procedure for minimizing the waste disposal problem was to reuse the waste solution in the mill--in effect, erasing the need for disposal of liquid waste. In examining this possibility, interlocked bench-scale leaching and solvent extraction tests simulating the Durango flowsheet were made. The simulated reuse of barren raffinate for leaching and washing was carried through three separate campaigns of 9, 12, and 35 cycles each.

Jan 1, 1961

By G. W. Weems

The Bureau of Mines combined preconcentrating techniques and mass spectrometry to develop a parts-per-billion general analysis of impurities in helium. The impurities are preconcentrated using a Bureau trace-impurity analyzer; 35-mm Hg pressure of helium is left in the concentration trap to sweep the impurities into the mass spectrometry and provide a 10-mm Hg sample pressure.

Jan 1, 1966

By H. J. Heinen

This report summarizes preliminary research studies by the Bureau of Mines in electrowinning molybdenum directly from pure or impure molybdenum trioxide (MoO3) by fused-bath electrolysis in an open graphite cell without need of a protective inert atmosphere. A formulated electrolyte of the tertiary system containing 41.6 percent sodium pyrophosphate, 16.7 percent sodium tetraborat, 33.3 percent sodium chloride, and 8,4 percent molybdenum trioxide, by weight, electrolyzed at 1,000° C,, gave excellent results. Current density studies were made over a range from 20 to 260 amperes per square decimeter. Current efficiencies of 80 to 90 percent were obtained over the entire range. Yields up to 500 grams of molybdenum per kilowatt-hour were obtained. Higher current densities, however, reduced yields and produced a finer grained metal. The two most important facets in electrowinning molybdenum from MoO3, in an open cell, are temperature and electrode spacing to minimize or eliminate the formation of the suboxide MoO2, the major source of oxygen contamination. At temperatures of 1,000° C. and higher, together with the proper spacing of the electrodes, formation of oxides are practically eliminated. Molybdenum metal electrowon from pure MoO3 was 99.9 percent pure and contained 0,056 percent oxygen and 0,007 percent carbon. This metal, when arc-melted, had a Vickers hardness number of 175 and contained 50 parts per million oxygen and less than 10 parts per million carbon. Molybdenum metal electrowon directly from an impure MoO3 containing 90 percent MoO3 resulted in a metal of 99.8 percent purity.

Jan 1, 1961

By McHenry Mosier

Although local conditions at each mining property affect the percentage of increase in drilling speed for a given reduction in gage of bit, the results of drilling tests conducted at the Mount Weather testing adit show such a large advantage in favor of the smaller gages that they should be indicative of the possibilities at most mines. GENERAL DISCUSSION Although it is common knowledge among miners that drilling speed increases with reduction in gage of bit, the large amount o this increase is not so universally realized, A recent Bureau of Mines4/ survey of drilling practices in 28 metal mines showed that the maximum gage of starters is 3 inches and that at 50 percent of the mines starters are 2-1/4 inches or larger, Because this size appears too large for conditions at most mines where abrasion is moderate and where powder distribution permits, the use of smaller bits presents a favorable opportunity for reducing drilling costs.

Jan 1, 1939

By Eugene T. Sheridan

This report presents statistical data on individual plants in the fuel- briquet and packaged-fuel industries circularized by the Bureau of Mines, United States Department of the Interior, in its 1957 annual survey. This survey revealed that 17 briquet and 23 packaged-fuel plants were active part or throughout the year. The annual production capacity of the fuel-briquet industry was 3,088,000 net tons, a decrease of 17 percent from 1956. The decline in capacity was caused in part by the permanent retirement of 4 plants and also by the reduction in capacities of 4 other plants. The rate of production of briquet plants also decreased as the industry operated at 35.8 percent of capacity compared with 40.9 percent in 1956. Every operating plant in 1957 had an annual capacity exceeding 25,000 tons.

Jan 1, 1958

By R. E. Lindstrom

Electrooxidation techniques were investigated on a bench scale by the Bureau of Mines to determine the applicability of the process for extracting molybdenum and rhenium from low-grade molybdenite concentrates. Parameters affecting the extraction, such as pulp density, power consumption, reagent requirements for pH control, and electrolytic cell configuration, were studied. Molybdenum and rhenium extractions of 98 to 99 percent were achieved from several concentrates containing 4.76 to 28.6 percent molybdenum and 180 ppm to 1,000 ppm rhenium. Optimum results were obtained by maintaining pH values between 5.5 and 7.0 during electrolysis and allowing the final pH to rise to about 8.2. Reagent consumption was 4 to 6 pounds of sodium carbonate per pound of molybdenum extracted. The power consumption declined from a range of 12 to 25 kilowatt hours per pound of molybdenum extracted with immersion electrodes to 9.7 kilowatt hours with a bipolar flow-through cell; however, molybdenum extraction was independent of cell configuration.

Jan 1, 1973

By McHenry Mosier

Although local conditions at each mining property affect the percentage of increase in drilling speed for a given reduction in gage of bit, the results of drilling tests conducted at the Mount Weather testing adit show such a large advantage in favor of the smaller gages that they should be indicative of the possibilities at most mines. GENERAL DISCUSSION Although it is common knowledge among miners that drilling speed ill- creases with reduction in gage of bit, the large amount o this increase is not so universally realized, A recent Bureau of Mines4/ survey of drilling practices in 28 metal mines showed that the maximum gage of starters is 3 inches and that at 50 percent of the mines starters are 2-1/4 inches or larger, Because this size appears too large for conditions at most' mines where abrasion is moderate and where powder distribution permits, the use of smaller bits presents a favorable opportunity for reducing drilling costs.

Jan 1, 1939

By V. Vallyathan, Xianglin Shi, N. S. Dalai

While Cr(VI) is a known carcinogen, the underlying biochemical mechanism is still not fully understood (1). In a pioneering study Jennette (2) utilized electron spin resonance (ESR) spectroscopy to demonstrate that a long-lived Cr(V) species is generated during the reduction of Cr(VI) by microsomes in the presence of NADPH. Later Wetterhahn and co-workers (3, 4) showed that incubation of chromate with isolated rat liver mitochondria causes the reduction of Cr(VI), as well as the formation of a Cr(V) species. Analogous Cr(V) species have also been detected in the reduction of Cr(VI) by other cellular systems such as Hanserulla polymorphared (5) and blood cells (6, 7). All these as well as other studies (8-12) have suggested that this Cr(V) species plays a significant role in the mechanism of Cr(VI) toxicity. Thus far, however, the chemical structure of this dominant Cr(V) species formed in cellular systems has not been identified, and this observation provided an impetus for the present investigation. Another reason for undertaking this study was that some recent reports (10-16) suggest that hydroxyl ('OH) radicals may also play an important role in the mechanism of Cr(VI) toxicity. In particular, it has been shown that OH radicals are formed in reactions between Cr(V) species and H2O2 (13-16), and that the radical yield depends on the chemical structure of the Cr(V) species (15). For example, while Cr(V)-diol complexes efficiently generate OH radicals, another Cr(V) species, the tetraperoxochromate (CrO3/8) ion, does not (15). Thus in the present study, we focused our attention on the following: (a) structural identification of the Cr(V) species generated in the reduction of Cr(VI) by subcellular as well as cellular systems, using microsomes, mitochondria, and Escherichia coli; (b) possible detection of OH radical in the same systems since there is no earlier report of chromium-mediated generation of 'OH radicals in a cellular system; (c) possible involvement of molecular oxygen in chromium-related OH radical generation since a recent report (17) indicated that Cr(VI) mutagenesis is strongly oxygen dependent; and (d) elucidation of the mechanism of OH radical formation in these systems.

Mar 1, 1992

By Edwin M. Thomasson

Helium shipments for 1965 exceeded the volume shipped during the previous year for the 16th successive time. Shipments from Bureau of Mines helium plants were 698.6 million cubic feet, 2 about 4.7 percent more than in 1964. Production at Bureau of Mines plants totaled 757.4 million cubic feet, and an additional 3,549.6 million cubic feet was produced by private companies participating in the helium conservation program and purchased by the Bureau of Mines and stored underground for future use. The Bureau of Mines continued to sell helium at $35 per thousand cubic feet, the price established in 1961. Production and sales of helium increased from the one private plant operating entirely outside the Government's helium program. A second private plant was virtually complete at yearend, although actual production had not commenced.

Jan 1, 1967

By Michael G. Zabetakis, Aldo L. Furno, George H. Martindill

Hydrazine vapor is flammable in the absence of air at elevated temperatures and atmospheric pressure . The minimum concentrations of benzene , toluene , m- xylene , cumene , and n- heptane needed to inhibit flame propagation through vapor mixtures of hydrazine and hydrocarbon were determined at 125 ° C and atmospheric pressure . These concentrations can be correlated with either the heat of formation or the heat capacity of the hydrocarbon .

Jan 1, 1964

By Richard J. Mainiero

The Bureau of Mines investigated coal-mine-type short-delay electric detonators marketed by three domestic manufacturers to determine the accuracy of delays and the probability of overlap between adjacent de- lay periods. The Winzer index was computed and compared with the probability of overlap. A close agreement between the Winzer criterion and overlap probability was demonstrated. A permissible blasting unit capable of delivering a maximum firing energy of 4.0 J and a digital oscilloscope were used to measure the delay time with an accuracy of 20.25 ms. Another oscilloscope and a pulse transformer were used to record firing current. Experimental data indicated negligible overlap probability in detonators of shorter delay periods: periods 1 to 4, which correspond to 25 to 250 ms. However, a significant probability of overlap was detected in some detonators of longer delay periods: periods 5 to 9, which cor- respond to 300 to 500 ms.

Jan 1, 1985

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

APPENDIX E EQUIPMENT USED FOR FIELD TESTING OF MINE SEALING SYSTEM I. Drilling Operation - Equipment supplied by local drilling contractor 1. Mobile drill rig. 2. Flat bed truck, containing 20 lengths of drill pipe. 3. Auxiliary compressor. 4. Pickup truck for small parts and supply of diesel fuel. 5. Bulldozer. 6. Water supply, in this case the nearby stream. 7. Supply of casing, positioned next to the drill rig. 8. Ready mixed cement grout. 9. Drill bits, stabilizer units, cutting and welding equipment, other miscellaneous tools and supplies. II. Sonar Probing Operation 1. 25 foot tower with pulley mounted atop. - FMA 2. Electric winch with 100 feet of 1/4-inch cable, Model No. 100A, City Engineering Co. , Indianapolis, Indiana. 3. 400 feet of 1-1/2-inch-diameter aluminum pipe with alignment holes and coupling grooves. - FMA*

Jan 1, 1973

By D. M. Soboroff

Etchants containing hexavalent chromium and sulfuric acid are used in a variety of surface-finishing operations. When the resultant spent solutions are discarded, substantial quantities of chromium are lost and pollution prob¬lems are created. To minimize the undesirable environmental effects while improving metal and minerals recycling technology, the Bureau of Mines is conducting research on a method for the economic inplant recycling of these waste etchants. Trivalent chromium, produced when the etchant reacts with a sub¬strate, is oxidized in the anode chamber of a diaphragm cell; other metals, dissolved during the etching operation, are transferred to the catholyte. When waste brass etchants are treated in this manner, all of the trivalent chromium is oxidized and more than 40 percent of the copper and zinc is removed. Similar copper removal and chromium oxidation are achieved with waste printed circuit board etchants and rinse waters from plastic etching operations. The electrical energy needed to regenerate 1 kg sodium dichromate is less than 9 kwhr. Regenerated brass etchants evaluated by two companies equaled or exceeded the performance of fresh etchants.

Jan 1, 1979

By Thomas M. Kohler, Gerald L. Finfinger, Gregory M. Molinda

The Bureau of Mines has completed an investigation of the effectiveness of methane drainage in the Lower Sunnyside Coalbed at Kaiser Steel Corp.'s Sunnyside No. 1 Mine in Utah. Most of the previous at- tempts to drain methane gas using long horizontal holes were conducted in the Eastern Coal Province. From the high degree of success realized in these efforts and the large body of knowledge gained from associated research, it seemed natural to extend the technology to western coalfields. Previous work had indicated that properties affecting gas drainage were variable in the Sunnyside Coalbed. In an attempt to characterize these properties, four degasification holes were drilled from the out- side entries of an advancing section. The holes were drilled to lengths of 780, 1,680, 1,315, and 1,047 ft and produced initial flow rates of 50,000, 180,000, 340,000, and 240,000 f t3/d, respectively. A total of over 300 million f t3 of commercial-quality gas has been removed from the Sunnyside Coalbed. The four holes have reduced face emissions by 78 pct.

Jan 1, 1986

By James R. FitzSimmons

This report describes an instrument developed by the Bureau of Mines as an improved device for examining roof rock in bolt holes. The unit consists of a commercially available fiberoptic unit adapted for use as a flexible stratascope. Field testing in both metal and coal mines has shown the instrument can be easily transported and used by a single operator. The size and flexibility of the instrument eliminate the need for specially drilled holes.

Jan 1, 1979

By H. H. Schrenk

The safe use of a refrigerant or any substance depends on knowledge of its pertinent properties and conditions of use; therefore some of the properties of refrigerants that are related to life, fire, and explosion hazards are discussed herein. These data serve as a basis for suggested control measures in the use· of refrigerants. The properties of refrigerants may be broadly classified into three main groups: (1) Those important for refrigeration, (2) those significant from the standpoint of confining the refrigerant, and (3) those that become important if the refrigerant escapes from the :machine or container. The first group of properties, such as latent heat of vaporization, specific heat of vapor, specific heat of liquid, etc., is not considered to be directly related to safety and is not discussed here. The second group, those properties important in confining the refrigerants, has particular significance because· it relates to "built-in" safety. This group is emphasized because it is believed the soundest procedure in designing equipment is to give due consideration .to both the health and safety hazards likely to be associated with the equipment. Furthermore, the toxicity, fire, and explosion hazards are controlled as long as the refrigerant is confined. Some properties of this group are (1) stability, (2) corrosiveness, (3) boiling point, (4) pressure developed in the system, (5) warning odor or irritation, and (6) ease of detection. The third group includes such properties as toxicity (of compound and decomposition products), irritating action, and explosibility.

Feb 1, 1942

By G. S. Scott

It is sometimes desirable to know what changes in sizing characteristics would appear in screened coals if screens of different - size openings than those employed had been used . This report is concerned entirely with the application of the Rosin- Rammler law to a solution of this problem .

Dec 1, 1943

By David E. Emerson

An improved method and apparatus for determining the impurities in helium by preconcentration and subsequent analysis by mass spectrometry are described. Preconcentration of the impurities is accomplished by passing a known volume of helium, at slightly above atmospheric pressure, through a metal coil and trap assembly immersed in liquid helium. The concentrated impurities are then analyzed by mass spectrometry. This method can detect impurities in the range of 0.01 to 600 ppm with an accuracy of better than ±0.05 ppm at the 1-ppm level. One operator can analyze 15 samples in an 8-hour day.

Jan 1, 1970

By N. S. Dalal, X. N. Hu, X. Shi, V. Vallyathan

"Although silicosis has been studied extensively, the mechanism is still not fully understood. Experiments do provide evidence that the actions of unique properties of silica surface on the cell membrane are the starting point of silicotic processes. This paper summarizes literature on chemical properties of silica surface, and the effect of particle size on silica toxicity. This paper also discusses the ways in which silica dusts are thought to interact with the cell membrane, with emphasis on freshness, hydrogen bonding, and free-radical interactions.INTRODUCTIONSilicosis is a debilitating pulmonary disease that afflicts persons (miners, foundry workers, ceramic workers, heavy construction workers, etc.) who chronically inhale silica-containing dusts (Schepers, 1960; Silicosis and Silicate Disease Committee, 1988). Since silica is second only to oxygen in weight percentage of the earth's crust (about 28%) and is found in an enormous diversity of minerals, it is natural that silicosis is one of the major industrial health hazards all over the world. Although silicosis has. been studied extensively, the mechanism by which the dusts exert their toxic actions on cells and the processes by which these actions progress to fibrogenesis are still poorly understood. The biological characteristics of the dusts are largely unknown, although it is suggested that the dust size, shape, surface charge, roughness, surface chemical composition, trace metal content, and crystallinity; dose of silica in the ambient air of the workplace; duration of exposure; genetic variation in exposed subjects; personal respiratory patterns; and presence of any coexisting disease (such as tuberculosis or rheumatoid arthritis) all influence the expression of silicosis (Koskinen et al., 1983; Noweir et al., 1980; Raask and Schilling, 1980; Reiser and Last, 1979; Thorne et al., 1985; Wolff et al., 1981). The actual biochemical mechanisms through which these factors operate are still unclear. However, the experiments do provide evidence that the actions of certain unique properties of silica surface on the cell membrane are the starting point of the silicotic process (Allison et al., 1966; Allison and Harrow, 1971; Bateman et al., 1982; Marks, 1957; Parazzi et al., 1968; Reiser and Last, 1979; Summerton et al., 1977). This article summarizes literature on chemical properties of silica dusts and how silica dusts are thought to interact with the cell membrane, with emphasis on hydrogen bonding and free-radical interactions."

Jan 1, 1989

By W. A. Jacob, E. W. Dean

The Pittsburgh petroleum laboratory of the Bureau of lines has recently developed an improved method for the determination of water in pctroleum emulsions. It has been described in detail in an article entitled "A convenient method for the determination of water in petroloum and other organic emulsions" by E. W. Dean and D. D. Stark (Jour. Ind., and Enc. Chem. Vol. 12, ſay, 1920, page 436). It is essentially a modification of the familiar procedure of "distillation with an iniscible solvent", the improvement consisting in the use of apparatus that is rºck more convenient than any previously employed. The method has been used with marked success in the Bureau's laboratories for a period of about a year and has also been tried with equal satisfaction by a number of other laboratories. It has been most extensively employed for determining the water content of heavy fuel oils but has been applied also to several other types of emulsions, including shale oils, tars derived from coal, greases, and mixtures of powdered coal, oil and water. The Bureau has received a number of requests for information regarding commercial sources for the apparatus used, and having been assured of the value of the method, has taken steps to render it available for general use. - The equipment is, with the exception of two items, made of parts that are obtainable from the ordinary stock of chemical supply houses. The two exceptions are (1) the so-called "distilling tube receiver" and (2) the electric heater. The former is an essential part of the equipment; the latter is a convenient ac cessory but it can if necessary be roplaced by a gas burner. Efforts on the part of the Bureau staff to ronder these two items of apparatus available for purchase from supply houses, or for production by the user are hero described.

Sep 1, 1920