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By R. Singh

The present paper deals with the development of flotation based process for enrichment of a lead-zinc sulphide ore from Ganesh-Himal region of Nepal. Detailed characterisation and flotation studies were carried out under varying process conditions. The sample assayed 2.47% Pb with 13.6% Zn. The ore was predominantly made up of spahlerite and pyrite in association with subordinate amounts of galena, minor amounts of pyrrhotite and chalcopyrite. Dolomite was the main gangue. The modal analysis showed the probability of fair liberation of sulphides from gangues around 210 microns but the locking of galena with sphalerite and other sulphides continued to finer sizes. Under the optimum process conditions the rougher lead and zinc recoveries were 96.3% and 90% respectively. Multistage cleanings of rougher products proved helpful in improving the concentrate grade, meeting the required specification. Based on the studies undertake a process flow-sheet for the concentration of the ore to individual lead and zinc concentrates was developed.

Jan 1, 2014

By A. A. Sirkeci

In the scope of this investigation comparison between impact breakage and compression breakage were carried out for the separation efficiency of minerals using a chromite ore sample. The ore sample was broken below 1 mm employing a laboratory type roll crusher and an impact crusher. Concentration tests were conducted on -1+0.5 mm, -0.5+0.2 mm and -0.2 mm size fractions using a Wilfley type shaking table. Test results showed a remarkable difference between two types of breakage. Both concentrate grade and recovery was in the favour of impact crushing. Furthermore, the shape of the broken particles also showed differences such that in the case of impact breakage they were more spherical compared to compressive crushing. The results of the shaking table con-centration tests showed that a concentrate assaying 48.4% Cr2O3 were obtained with 78.5% recovery in the case of impact breakage. On the other hand the concentrate grade and recovery values were 48.8% Cr2O3and 52.4% respectively in the case of compression crushing. The losses in the tailings were also in favour of impact breakage proving that differential breakage occurred between chromite and gangue minerals.

Jan 1, 2014

By A. Ceylan

Pyrite is present as a gangue mineral in most of complex sulphide ores and most of time it is removed as a tailing. However, beneficiation of pyrite from tailings could be important because of its economical value and for the environmental concern. This paper presents a research for the enrichment of pyrite from copper plant tailings, Siirt-Madenköy/Turkey, by flotation. Siirt-Madenköy copper mine is operated by Park Electric Production Mining and Industry since 2005. In order to obtain the pyrite from Siirt-Madenköy copper plant tailings, laboratory test work has to be done to determine the type of reagents, the flowsheet, and the size of plant. The objective of the company is to develop a pyrite flotation circuit for concentration of pyrite from tailing dam to obtain 500.000 tons/year pyrite concentrate. There are about 3 million tons tailings that containing pyrite in the tailings dam. Experiments were carried out with three different types of tailings from the plant and the pyrite concentrate with 46% Fe and 90% recovery has been obtained. Therefore, this study shows that high grade pyrite with high recovery can be recovered from the tailings.

Sep 1, 2012

By J. Quinteros-Riquelme

Despite increasing demand, the supply of silver is limited by its inadequate recovery from ores. Due to its scarcity in nature, its high ore variability and complex mineralogy of current silver deposits, its recovery by mineral froth flotation presents a real challenge for process engineers. A silver ore often contains significant amounts of five to ten different silver minerals and knowledge of the mineralogy is a necessary precursor to flotation testing. In this work, a complex silver ore was treated by using batch laboratory flotation, in an effort to find the best experimental conditions to obtain the optimal silver recovery. Mineralogical characterization of feed samples was conducted using a combination of tools, namely the mineral liberation analyzer (MLA) and inductively-coupled plasma mass spectrometry (LA-ICP-MS), which indicated that most of the silver occurred as ?invisible? silver in pyrite. The pyrite assay of the ore was approximately 4%. The ore was processed in two flotation stages. The first stage, sulphide flotation, aimed to collect a sulphide mineral rich concentrate; then a non-sulphide flotation stage was performed by adding sodium sulphide and collectors to the remaining material in the cell, with the objective of obtaining a pyrite rich concentrate. To reach the target recovery of silver from this ore, various variables were altered. In the first stage: mixed collectors, activators, dispersants, and mainstream inert grinding were assessed. In the second stage, the conditions for sulphidization and subsequent flotation were both investigated. From the grade recovery curves for silver and sulphur it was possible to observe a similar metallurgical behavior for both elements, supporting the results given by the mineralogical characterization. Keywords: silver oxide, froth flotation, sulphidization, mig

Sep 1, 2012

By Hui Zhang, Fei Yang, Tong Guan, Guangqin Fu, Lihong Deng, Yuanlin Chen, Xiaotong Zhou

"For a copper-sulfur polymetallic mine in south China, the main valuable minerals were chalcopyrite, pyrite and pyrrhotite. The flotability of pyrrhotite was similar with chalcopyrite and pyrite and it was easy to be oxidized. As a result, the indexes of copper concentrate and sulfur concentrate were unsatisfactory. Furthermore, the recycling of tailings water ulteriorly deteriorated the technical indexes of copper-sulfur ore beneficiation. After a large amount of experimental studies, under the condition that the tailings water recycling rate was 100%, the copper concentrate with a grade of 22.25%Cu and a recovery of 82.46% on average was obtained for the raw ore containing 0.517%Cu, 15.94%S, 25.46%Fe on average, through using new technology “magnetic separation-flotation” and effective adjustment of parameters in the industrial test which was continuously conducted for 14 shifts in 5 days with a scale of about 75t/d. Comparing with the production indexes (the copper concentrate with a grade of 17.49%Cu, the recovery was 62.27%) during the corresponding period, the grade of copper concentrate increased 4.76%Cu, and the recovery increased 20 percentage points. Besides, the indexes of sulfur concentrate gained a considerable improvement. Currently, the new technology was adopted in the design of the new-built plant with a scale of 7000t/d of this mine. The new technology provided powerful support for the tailings water recycling and indexes improvement of copper-sulfur ore beneficiation.INTRODUCTION Chalcopyrite was usually associated with pyrite and pyrrhotite in copper-sulfur ore. Due to the similar flotability, it was difficult to obtain copper concentrate and sulfur concentrate with high grade. Furthermore, sulfide ore was easy to be oxidized and a large amount of ions formed in the pulp by the dissolution of minerals, which made the pulp become acidic. As a result, pyrite and pyrrhotite were easy to be activated in acidic solution and their flotabilities became stronger. Meanwhile, hydrophilic film formed on the surface of chalcopyrite in raw ore. The flotability of chalcopyrite became weaker and it made the separation of chalcopyrite from pyrite and pyrrhotite more difficult. So it was more difficult for copper and sulfur recovering with the recycling of tailings water containing high content of heavy metal ions and reagents."

Jan 1, 2018

By Shuoshi Lu

The Cu-Co ore studied here belongs to the oxide type. The oxidation rates of copper and cobalt are69.30% and 78.78%, respectively. The content of Cu in ROM is 1.34% and that of Co is 0.096%. The ore contains 4.64% carbon.Based on the process mineralogy and previous metallurgy tests, the principalprocess flow-sheet of ?grinding fines 80% -0.074mm, sulphide flotation followed by oxide flotation, and flash flotation for oxides? has been determined.The handling of carbon is determined through tests. The depressant PNL-1 depressed carbon effectively, improved the recovery of sulphide minerals and reduced the reagents consumption.The operation of the flow-sheet was also changed to better at the same time. Keywords: Cu-Co oxide ore, process mineralogy, carbon depression, efficient depressant of carbon

Sep 1, 2012

By D. W. Lui

Tangdan copper oxide deposit, the largest independent copper oxide deposit in China so far, is located in the northeast of Yunnan province, southwest of China. The ore from this deposit is characterized by: low grade, high oxidation ratio, and fine-grained disseminated, resulting in poor flotation recovery. The analysis of plant flotation data reveals that the loss of copper minerals into tailings is mainly with coarse size fraction due to insufficient liberation and fine size fractions, especially minus 10 microns fraction, which proved to be very difficult-to-float with conventional flotation. In order to improve the performances of plant flotation of this ore, laboratory flotation tests were conducted with the pure malachite, which was the principle copper oxide mineral in Tangdan copper ore deposit. The results obtained suggested that a finer grinding (up to -325 mesh or even -400 mesh) be needed to decrease the loss with coarse size fraction, and vacuum flotation is a promising way for the recovery of the fine malachite effectively.

Jan 1, 2014

By F. Boylu

In this study, Ca-bentonite was subjected to a series of systematic hydrocyclone tests with the aim of developing separation procedures and in turn achieving optimum recoveries. In hydrocyclone tests, vortex and apex diameters and also feed pressures were investigated. In each hydrocyclone set, vortex diameter was kept constant while the other two parameters varied to produce bentonites con-centrates of various smectite contents. The separation efficiencies were evaluated based on the cation exchange capacity (CEC), particle size and swelling index. The detailed hydrocyclone tests showed that, upgrading of Ca-bentonites require procedures different from the bentonites reported in the literature. Sodium and mixed bentonites are easy- to-disperse and easy-to-separate whereas calcium types need to be scrubbed rigorously for disintegration. Scrubbing properties of ca-bentonite were investigated as a function of scrubbing time and percent solids by weight (PS). The scrubbing conditions at 700 rpm for 1.5 hours and percent solids of 30 % were found more effective for achieving a better quality bentonite. In addition to the parameters mentioned above, the effect of percent solids on hydrocyclone separation was also studied. Although Ca-bentonites permit studying at higher percent solids, increasing solids content of the pulp deteriorated the quality of the clean products. Application of an appropriate separation scheme enabled the development of a unique separation procedure involving stage wise scrubbing followed by hydrocycloning which yielded calcium bentonite concentrates with CEC of 90 meq/100 g and high swelling indexes of 12 mL from the original bentonite of 65 meq/100 g and 7.0 mL, respectively. These results indicate that upgraded bentonite products can be conveniently used in various diverse industrial applications including bleaching earth, desiccant, cat litter, paper etc.

Jan 1, 2014

By C. L. Tang

Parts of the wastewater are reused directly and the rest moderately purified and reused, so the utilization rate of wastewater of the whole processing plant reaches 100 percent. At the same time, beneficiation indicators have been improved stably, and great economic and social benefits have been achieved.

Jan 1, 2014

By Zhong Hong

A novel ilmenite collector, tert-butyl benzoic hydroxamic acid (TBHA), was investigated in this paper. The flotation performance and adsorption mechanism of TBHA to ilmenite were evaluated through pure mineral flotation tests, ?-potential measurement and IR spectrum analysis. The experiment results indicated that TBHA exhibited strong collecting capability to ilmenite under pH 6.0-8.5. At pH 7.0-10.0, TBHA existed in the form of anionic species in aqueous solution, and the ?-potential measurement results showed the surface of ilmenite maintained negative and more negative after the adsorption TBHA on it, which inferred that TBHA might adsorb on the surface of ilmenite through chemical interaction. The IR spectrum analysis further confirmed the chemical interaction between TBHA and ilmenite surface. Keywords: Tert-butyl benzoic hydroxamic acid, Ilmenite, Flotation, Chemical adsorption mechanism

Sep 1, 2012

By Shi Shuaixing Zhang Yuejun, Fan Xuesai Zhangming

"For the traditional principle of flotation cell design, or in the perspective of some researchers, the mixing effect of impeller for flotation cell is not only to suspend the particles off the bottom, but also to mix slurry well to achieve a uniform system. But for some special processing conditions, the depth profile of slurry concentration and particle size demonstrates an obvious difference. In the part around of the impeller in the cell, the slurry concentration is much higher than the part below the lip.For the vanadium titano-magnetite flotation process, distinguished with high concentration and large coarse particle size fraction, even though the concentration is very high, it can reach good gas dispersion, which is a fundamental principle for flotation cell design and application. The gas dispersion is not a challenge in the high slurry concentration environment, not only in the vertical direction, but in the cross section. Different levels (the distance from the lip is 400mm, 700mm, 1200mm, 1700mm, 2200mm, 2700mm) slurry in the flotation cell is sampled and analyzed. The slurry concentration of the 3 levels(1700mm, 2200mm, 2700mm) is about 55%, but the slurry concentration decreases from 55% to 25% sharply towards the lip.Therefore, a new understanding and viewpoint is presented, that the uniform system of slurry is not always reasonable for all of the flotation process. For some special process, if the coarse particles are needed to agitated well and transported to the upper cell, the quiescent zone in the upper cell will be destroyed and enhance the detachment probability for the coarse particles. The difference of slurry concentration and particle size fraction benefits the air dispersion and coarse mineral particles recovery.1.INTRODUCTIONNowadays, flotation is the most widely used separation process in the mineral processing industry. The importance of flotation technology in the global economy is significant. A rough estimate of the quantity of crushed ore treated by flotation is about nine billion tons per year, and the portion of base metals processed using this method is approximately 95% (Brewis, 1996)."

Jan 1, 2018

Rotor speed is one of the key hydrodynamic parameters in froth-flotation and it plays an important role in bubble-particle attachment. Laboratory scale studies for optimizing the rotor speed to achieve maximum flotation rate constant (K) of quartz, ground by ball mill, are. Purity of quartz was 99.4 percent and d80 of ball mill product was 230 µm. Each size fraction was separately subjected to flotation at three different rotor speeds, namely, 1200, 1000 and 800 rpm, and the flotation rate constant was calculated. The results showed that the flotation rate constant was high at the rotor speed of 1200 rpm. The flotation rate constants achieved at 1200 rpm were 8.676, 8.232, 7.818, 7.248, 7.068 and 6.984 min-1forthesize fractions of +300, -300+250, -250+212, -180+150, -150+125 and -125+106 µm, respectively. Keywords: froth flotation, rotor speed, flotation rate constant, ball mill, quartz

Sep 1, 2012

By M. N. Chandraprabha

Arsenopyrite is often associated with sulphides like pyrite, chalcopyrite and galena in refrac-tory gold ores. Selective flotation of arsenopyrite from associated sulphides is desirable for effective gold extraction when the gold is preferentially associated with the arsenopyrite matrix. By contrast, presence of arsenopyrite in flotation tailings poses a serious environmental threat due to arsenic dissolution. To prevent arsenic contamination from the mine wastes, it would be more economical and environmentally beneficial to remove this mineral during the froth flotation step. Use of Acidithiobacillus thiooxidans in the detoxification of arsenic containing sulphides is outlined in this pa-per. Biomodulation using Acidithiobacillus thiooxidans resulted in the preferential depression of pyrite from arsenopyrite. By suitable conditioning with cells and collector effective separation of arsenopyrite from pyrite was achieved. Biomodulation with wild cells did not yield separation of arsenopyrite from chalcopyrite. However, bacterial affinity could be induced to a desired sulfide mineral through environmentally controlled adaptation techniques. Through the use of arsenic-adapted bacterial cells, selective removal of arsenopyrite from chalcopyrite was readily achieved.

Jan 1, 2014

By Susanna G. de Jager, Francis W. Petersen

"The aim of the project was to develop a methodology applicable to different South African coal types to be able to predict with a high degree of certainty what kind of reagent will be suitable for flotation of a certain coal type.The study included 5 coal samples from different collieries and included Highveld seam 3 and 4 coal (as one sample), Waterberg coal (zone 10 -11), Highveld seam 5 upper coal and Witbank seam 2 and seam 4 coal. Seam 3 and 4 (mixture) coal, Waterberg and the seam 5 upper coal were all found to be vitrinite rich coals. The coal characterisation study included petrographic analysis, proximate analysis, float-sink analysis, oxygen-containing functional groups, surface extraction, flotation release analysis and contact angle measurements.The flotation tests showed that the best reagents to float all of the coal samples studied are iso-decanol and dodecene. These reagents produced flotation products that are near to the release curve. Statistical relationship for predicting ash content and yield that can be expected for a certain coal type and selected collector was obtained. From the relationship, the accuracy of the yield is above 95% (p-value below 0.05) with a linear regression of 0.9289. The accuracy of the ash is slightly lower with a linear regression of 0.7841 but also above 95%."

Jan 1, 2003

By X. Cui

Hydrocyclone is widely used in closed-circuit grinding process. However, in the first classification operation of coarse particles with high pulp density, the shortcomings of traditional cyclone are that the grinding cycle load is much high, the apex of cyclone is easily to be blocked and classification efficiency is less. Specifically, the problems of traditional cyclone used in grinding process are as follows: (1) Mill utilization factor is low and its handling capacity is small. (2) Coarse particles mixing in cyclone overflow affects the following separation process and fine particles mixing in underflow causes over-grinding, which affects the total recovery rate of valuable minerals. (3) High grinding cycle load leads to large amount of high-density slurry pumping, which causes high energy consumption and severe wear of cyclones, pipelines and pumps. The applications of new type pre-classification hydrocyclone with centrifugal volute in the first classification process of Iron Mine Mill are introduced in the paper. Pulp particles fed in the centrifugal volute were arranged in advance, so that coarse particles can be far away from the overflow pipe, which can reduce the short circuit current to avoid coarse particles entering overflow and improve classification efficiency and accuracy of cyclone. The strong points of the new cyclone in the coarse classification operation are as follows: (1) finer overflow and less fine particles mixing in underflow improves classification efficiency more than 10%; (2) lower ball mill load cycle improves ball capacity more than 10%;(3) grinding energy consumption reduces by more than 20% and cyclone feed pump reduces energy consumption by more than 12%. In short, new type pre-classification cyclone with centrifugal volute solves the problems of fine particles mixing in underflow, high grinding cycle load and less classification efficiency in the coarse classification operation. Therefore, it has broad application prospects in ferrous metal and non-ferrous metal ore dressing plant.

Sep 1, 2012

By Ela Mielczarski, Jerzy A. Mielczarski

"The adsorption of xanthate takes place at a different potential on each major sulfide mineral, hence, as it was demonstrated in the past, each mineral component can be selectively separated from ore under well controlled potential conditions. In real flotation this concept never works out for two reasons: the potential of single mineral particle results from complex surface reactions controlled by solution chemistry, and there is a galvanic interaction between different mineral particles present in the flotation pulp.In this study the formation of amyl xanthate hydrophobic products on pyrite, galena and chalcopyrite has been spectroscopically investigated in the presence of combinations of these minerals. The type of the adsorbed species and their amount were determined directly on mineral surfaces by infrared external reflection technique. Galvanic contact between grains of two different minerals has tremendous consequence on the adsorption of collector on both minerals. The detected changes are dramatic, from no adsorption to a coverage formation of a few monolayers. The results obtained indicate clearly that the observations and conclusions about the collector adsorption, hence also the surface hydrophobization, made for a single mineral system does not describe the real situation in a multi-component mineral system such as flotation pulp."

Jan 1, 2003

By W. Q. Zhao

In order to raise the utilization rate of phosphate resource of Al-Jalamid Mine in Saudi Arabia, a flotation experiment for its phosphate rock was carried out by using WF-01collector that have been produced by Wengfu Phosphate Mine. The results showed that WF-01 collector had extensive adaptability for Al-Jalamid phosphate rock, and the grade of phosphate concentrate could be up to 33% P2O5 mixing the upper, middle and lower beds rock as well as its 80% more recovery.

Jan 1, 2014

By Liu Chun-Bao Sun, Hong-Jun, Wei Zhang, Tao Xu

SABC circuits have gained widespread attention within China, and are being gradually applied to many mines. However, the domestic knowledge of comminution process is still relatively basic, and the design and production management of the application of SABC technology lack guidance of scientific theories. This research project focuses on the Phase I SABC milling circuits of Wu Shan Porphyry copper mine. Targeting the design and operation problems of existing process and circuit, and without increased investment and alterations in equipment, the new technologies will combine ordinary crushing and grinding theories as theoretical guidance, and borrow JK Simulation Software (JKSimMet) for analysis in order to optimize the comminution process, efficiently allocate production output and energy consumption, eventually resulting in increased production and energy efficiency. Using JKSimMet Simulation Software, and combining theoretical optimizing and practical production techniques, as well as the on-site situation, the eventual SABC comminution process and circuit optimization plan is: increasing the grinding Ball charge from 8% to 10% v/v in the SAG mill; Setting the Ball charge in the Ball mill to 27% v/v and the maximum operating power draw to 5 800kW; replacing the HP Series crusher with a TRIO TC84 crusher, which is without a power controller, and adding a pebble bin. The final optimization result is: Maximum system processing capacity increased between 20%-26.7%, specific energy consumption reduced by more 2.0 kWh/t, creating an economic benefit of over 300 million RMB, thus achieving the goal of increased production, reduced energy consumption, and improved profitability.

Jan 1, 2014

By G. Deschênes

In the last 4 years, the high price of silver attracted more interest for improving its extraction. Metallic silver and silver minerals require a high concentration of cyanide and show slow leaching rates and poor extraction. This investigation determined the effects of dissolved oxygen, lead nitrate and a pretreatment on silver leaching from slurry containing quartz mixed with metallic silver and high purity acanthite. Stephanite, pyrargyrite and polybasite were also used in the study. The silver minerals were characterized by chemical assay, X-ray diffraction analysis (XRD), image analysis (MP-SEM-IPS) and electron microprobe analysis (EMPA). Increased dissolved oxygen of the slurry produced the fastest silver leaching kinetics. The leaching of silver from high purity acanthite was determined under various conditions and compared to a new process called ?CANMET Enhanced Leaching Process (CELP). For a slurry containing acanthite, a 23% improvement (from 76% to 99%) in silver extraction was obtained with the CELP. In presence of pyrargyrite and polybasite, silver extraction increased from 75% to 90% and 86% to 99% respectively using the CELP. No improvement was obtained for the slurry with stephanite (99% extraction in 72 hours). However, the sliver leaching rate was much faster with the CELP. XPS analysis of individual silver mineral particles showed that CELP leached surfaces were considerably more oxidized relative to the conventional cyanidation leached surfaces. Leaching of two gold/silver ores indicated that the efficiency of the CELP increased with the refractoriness of the sample. Gold extractions were comparable for the two technologies while silver extraction improved up to 5% (70g/t) for the CELP. The final leach solutions contained lower concentrations of copper, which consequently reduces the effluent treatment costs.

Jan 1, 2014

By Peter Ay, Bodo Müller, Jens Markowski, Manfred Kanthak, Florian Logsch

"Presently the global commodity situation for non ferrous-, precious- and rare metals is characterized by a strong increase in consumption and a simultaneous shortage of materials derived from primary sources. So the use of secondary raw materials gains is important due to economic and ecological reasons. Non Ferrous-, precious- and rare earth metals were detected in household waste (Municipal solid waste, MSW) for years. In MSW-treatments plants NF-metals are actually mostly separated from dried fractions. The separation of these metals is carried out with the aim of removing particles which disrupt further processing. A selective enrichment of individual non-ferrous metals has not been carried out previously. The separated fractions contain mixtures of Al, Cu, Zn, Pb, Sn, alloys, precious metals (e. g. Au, Ag, Pt) and rare metals (Ga, In, Nd etc.) along with considerable amounts of contaminations. The R&D project "NE-Rec" selectively processes the coarsely separated non-ferrous-metal-conglomerates increasing the concentration of targeted metals. Metals and metal mixtures are concentrated by sorting steps and the impurities are discharged from the process. Still contaminated precious metals are then subjected to a wet-chemical treatment. So metals can be specifically brought into solution or can be precipitated to separate unwanted components (inerts, polymers, foreign metals). Further the relevant metals will be concentrated by thermal-metallurgical processes. The technology, developed in the R&D project, enables identification, separation and processing of non-ferrous metals, precious metals and REM in household waste and transfers them into further processable individual fractions."

Jan 1, 2014