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By T. B. Williams

THE British Columbia Coal Control was established in 1946 as a branch of the Department of Lands. Its functions are the administration of the Goal Act, the making of field and laboratory investigations bearing on the delineation and utilization of British Columbia coal deposits, and the dissemination of information concerning them. The Department of Lands in the Province of British Columbia retains and administers many of the Province's resources until such time as they are actively developed under the departments of Agriculture, of Forests, of Mines, etcc. The work of the Control is one of stock taking and appraising. We are picking up where the geological surveys leave off. In an effort to assist in the orderly, scientific development -of our excellent and extensive' ?Coat resources, we are bridging the gap between exploration and geological examination on the -one hand and mining on the other. All coal analyses required in the course of the investigations, together with? those requested by prospectors and others, are carried out in the very modern and efficient laboratories of the Coal, Petroleum, and Natural Gas Control. At its inception, the Coal Control began an investigation of coal seams in the Peace River area, specifically those contiguous to the Pine River valley about one hundred miles west of Dawson Creek. The occurrence of coal in the Peace River canyon, east of Hudson's Hope, bad been known since 1792, but the first record of production is for 1923.

Jan 1, 1951

By Liguang Wang

The froth phase in flotation has received much less attention than the pulp phase despite the fact that froth stability plays an important role in determining flotation performance. Froth stability is largely determined by the stability of thin foam films, which in turn has a strong correlation with the critical rupture thickness (Hcr) of the films. In the present work, a new approach to predicting the Hcr values of thin foam films in flotation froth phase was proposed and examined. The Hcr values were calculated using an advanced capillary wave model with input parameters being surface tension, film radius, capillary suction pressure, and intersurface force. The intersurface force was estimated by using the Stefan-Reynolds lubrication approximation to fit the measured thinning rates of single foam films formed in a Scheludko ring cell, where the film radii were less than 50 microns and were kept constant during the film-thinning process. A comparison between the predicted and experimental Hcr values was made for the films with the use of sodium chloride as background electrolyte and in the presence of various frothing reagents such as methyl isobutyl carbinol (MIBC), polypropylene glycol with an average molecular weight of 400 (PPG400), and sodium dodecyl sulphate (SDS), at different concentrations and film radii. It was found that the model correctly predicted the trends of Hcr-versus-concentration and Hcr-versus-film radius curves. Moreover, the predicted Hcr values matched well with the experimental ones of the foam films containing either SDS or PPG400. For the foam films containing MIBC, however, the model overpredicted the Hcr values. The reason for this discrepancy was discussed.

Jan 1, 2016

By M. J. Nicol, C. van Wensveen

The kinetics of the oxidation of thiosulfate by copper(I I) in ammoniacal solutions have been studied in the presence and absence of dissolved oxygen. The formation of an intermediate mixed ammine/thiosulfate copper(II) complex ion has been confirmed and the rate of the reaction monitored by simultaneous on-line spectrophotometric, dissolved oxygen and potentiometric measurements. The rate of the anaerobic oxidation of thiosulfate by copper(II) was found to be orders of magnitude slower than that in the presence of dissolved oxygen and is inhibited in the presence of ammonia and anions such as sulfate and chloride as a result of competition with thiosulfate for the axial coordination sites on the copper(II) tetrammine complex. In the presence of dissolved oxygen, it was found that the copper(I) thiosulfate complexes are only very slowly oxidized while the copper(I) diammine complex is rapidly reoxidised to the copper(II) state. Thus, the initial rapid reaction with copper(II) leads to a pseudo steady-state condition in which the concentration of copper(I) is relatively constant and the rate of oxidation of thiosulfate can be predicted from the measured rate of oxidation of copper(I) by oxygen in ammoniacal solutions. The effects of the concentrations of ammonia and thiosulfate on the oxidation rate can be rationalized on the basis of the above coupled to the species distribution of copper(I) in the ammonia/thiosulfate system. It is shown that, with relatively simple measurements of dissolved oxygen and copper concentrations, the rate of oxidation of thiosulfate can be predicted under typical leaching conditions.

Jan 1, 2005

By Q. B. Li, B. Gonçalves da Silva, J. T. Germaine, H. H. Einstein, Z. Moradian

"Shale gas and oil production has grown rapidly in recent years, and consequently there are increasing demands to understand the mechanical and microseismic properties of shale. Acoustic emission (AE) monitoring provides useful information on the fracture mechanisms of shale rocks, and provides a basis for interpreting field seismic observations. While there have been attempts for microseismic monitoring of conventional hydrocarbon reservoirs, shale presents a large number of issues that require further investigation. For this purpose, experiments were conducted to understand the characteristics of the AE waveforms propagated through Opalinus shale rock in the time and frequency domains. Frequency range, arrival time, first arrival amplitude and other parameters such as counts, duration and energy of the waves generated from artificial and natural sources in the shale specimens were detected and compared with AE characteristics of granite, a brittle rock that has been extensively investigated. The experimental tests showed that there are some important factors that influence the analyses and interpretations of seismic surveys and microseismic monitoring of shale compared to granite. One of these factors is the anisotropic behavior of shale that causes the wave to propagate with different velocities in different directions. Also bedding planes and micro-discontinuities in the shale cause attenuation of the waves. Thus the AE waveforms that arrive at the sensor are a distorted and attenuated versions of the source waveform.INTRODUCTIONMonitoring microseismic activity from hydraulic fracturing of shale provides vital information for mapping injection paths and fluid migration in order to check the effectiveness of the hydraulic fracture stimulation. Analysis of microseismic source locations can be used to identify fracture networks induced or mobilized during the hydraulic fracturing operation (Rotherd and Shapiro, 2003). On the other hand, by monitoring and assessing detected signals from hydraulic fracturing one can evaluate the induced seismic impact of the stimulation operation.While there have been attempts to monitor microseismic events in conventional hydrocarbon reservoirs, shale presents a large number of issues that require further investigation. For this purpose, experiments were conducted on Opalinus shale to understand its acoustic emission (AE) characteristics in the time and frequency domains."

Jan 1, 2015

By Hyumng Sup Choi

The role of the interfacial electrical 'Condition on the adsorption of col-lectors on mineral surfaces has been studied by electrophoretic mobility and adsorption measurements made on zircon. From the investigation of the electrokinetic properties of zircon, H+ and OH-are seen to act as potential determining ions, thus controlling the electrical nature of this mineral. The isoelectric point of zircon occurs at a pH of approximately 5.0, and it is evident, therefore, that the zircon surface would be positively charged below a pH of 5.0 and negatively charged above this pH. The adsorption of collectors therefore de-pends strongly on the pH of the solution; anionic collectors are adsorbed on positively charged surfaces and cationic collectors on negatively charged surfaces. This, in turn, de-fines the effective flotation condition, with respective collectors, for this mineral. The above results have been correlated with the flotation behaviour obtained by the simplified flotation test using a modified Hallimond tube.

Jan 1, 1963

By Andrew Bamber

Outline ?Background to Mine-Mill Research at UBC ?Mine Mill Integration ?In situ mining methods ?Underground Pre-concentration ?System Design and Supporting Technologies ?Case Studies: ?INCO -McCreedyEast Mine ?Placer Dome ?Porcupine JV ISL Study ?Musselwhite, South Deep ?Falconbridge ?Fraser Copper ?Thayer Lindsley ?Wayside Gold, other scoping studies? ?System Designs ?Summary ?Future work ?Conclusion

May 1, 2006

By Isabel F. Barton, J. Brent Hiskey

Chalcopyrite (CuFeS2) is the earth’s most abundant copper ore mineral, but is refractory to leaching with sulfates, chlorides, and other common lixiviants and oxidants. This has led to increasing research into alternative lixiviants for recovering Cu from chalcopyrite. Here, we review the leach kinetics of chalcopyrite in glycine, ionic liquids, and methanesulfonic acid, compared to baseline ferric sulfate and ferric chloride. Glycine (CH2NH2COOH) has long been used in applications such as biocatalysis and electroplating, and has recently been examined as a lixiviant for whole ores and concentrates of both copper and gold. It is nontoxic, biodegradable, and capable of strongly complexing Cu2+. Compatible oxidants are peroxide, dissolved oxygen, and ferric sulfate. Chalcopyrite leaching rate in glycine is chemical reaction-controlled, but the effects of grain size and the reaction orders with respect to lixiviant and oxidant concentrations and mass transfer vary. The use of ionic liquids as a leaching agent for chalcopyrite has been extensively investigated in recent years. This system is based primarily on the use of the imidazolium molecule (C3H5N2), which is a planar 5-member ring structure. This lixiviant has been applied to the leaching of chalcopyrite in the form of pure mineral, concentrates, and ores. Kinetics of ionic liquid leaching of chalcopyrite vary substantially depending on the type and concentration of ionic liquid. Methanesulfonic acid (HCH3SO3) is one of the newest lixiviants available in leaching, having only been examined in the last decade. It has been examined as a substitute for sulfuric acid, since it is less corrosive, is biodegradable, and breaks down to carbon dioxide and sulfate over time. The rate of copper leaching from chalcopyrite by methanesulfonic acid is controlled by diffusion and exhibits a strong dependence on oxidant type and concentration. Despite promising reaction rates and total extraction by some of these novel lixiviants, comparison with baseline ferric sulfate and ferric chloride systems makes it doubtful that any will be commercially viable in the near term. Only at very high reagent concentrations and temperatures, and/or very fine grain size, did any of the systems perform comparably to the much cheaper ferric chloride at extracting Cu from chalcopyrite. Most had similar overall reaction rates and total extraction to ferric sulfate, which is relatively common and cheap. However, the leaching kinetics of these novel lixiviants offer valuable insight into the dissolution behavior of chalcopyrite in various systems.

Jan 1, 2019

By Rod Abbott

High Definition Scanning (laser scanning) is a proven technology that is accurate to within 6mm in 50m (¼? in 150?). It can capture in excess of one million 3D point measurements in an average 2 hour scan. It has numerous applications including brown-field retrofits, bridge measurement and analysis, verifying as-built conditions, and crime scene investigation. We most commonly use it for plant design to capture current site conditions, so as to prevent interferences and problems before construction begins. All vital information is captured in the first site visit, which limits the need for extra field trips.

Oct 1, 2010

By W. Beres, R. E. Miller, B. Shiari, L. R. Zhao

A dynamic multiscale (MD/FE) method has been used to study dislocation generation and plastic deformation during a nanoindentation process which is physically associated with the generation of heat within the specimen and as a consequence with a temperature rise. Two different techniques are applied to study the temperature effect on the nanoindention process. In the first technique, a global Nose-Hoover thermostat is applied to the entire atomistic region to keep temperature constant during simulation (finite temperature approach). In the second method, the thermostat is applied only on a damping region along the MD/FE interface. Both techniques are able to effectively and efficiently absorb high frequency reflected waves from atomistic/continuum interface. The temperature profile of the atomistic region beneath the indenter is reported and discussed at four different initial substrate temperatures for both techniques. The loaddisplacement (load/unload) curves for different temperature-controlling techniques are compared and discussed. The nucleation and propagation of dislocations in the atomistic region are investigated for both techniques. Correlations between the observed features in the load-displacement curves with the motion and pile-up of dislocations are reported as a function of temperature.

Jan 1, 2006

By S. C. Bouffard

Barrick's Zaldivar operation in Chile produces copper by heap leaching, solvent extraction, and electrowinning. The heap consists of a dynamic pad, and its stacking and operating conditions have changed over its 11 years of operation. These changes have included pad re-mining midway through the cycle, tightening of the irrigation drip lines, an increase of the coarseness of the particles, and an increase of the heap height. This paper reviews the heap operating data to understand the effects of these changes on the kinetics and recovery of copper minerals. Field tests demonstrated that neither re-mining nor tightening the irrigation grid added value for both low and high grade oxide and sulfide ores. The P80 of the feed ore was increased by 0.8 mm, which did not reduce the copper recovery of oxide and sulfide ores. The increase of the heap height above 8 m lowered moderately the copper recovery from sulfide minerals, and very slightly the recovery from oxide minerals. Despite the lower recovery, the higher tonnage stacked in the taller heap increased the copper output. Optimizing the chemistry of the agglomeration and feed solution holds more promise for increasing the copper recovery than the above physical changes.

Jan 1, 2007

By Paul Graham

Presentation Focus ? What is LTUG / What do we do? ? History of LTUG ? Examples of Benefits from LTUG Participation ? Encourage Participation What is LTUG? ? An informal gathering of surface mining companies to discuss and work issues of common interest and to share information and best practices around large tires.

May 1, 2008

By P. Van Marcke, X. Sillen, G. J. Chen, I. Troullinos, A. Dizier, J. Leysens, X. L. Li, J. Verstricht

"In Belgium, Boom Clay is considered as one of the potential host formations for the disposal of the High Level radioactive Waste (HLW). The URL HADES at 223 m depth at Mol site was constructed in order to study the feasibility of HLW disposal in Boom Clay. Since 1995, the URL R&D programme has focused on large scale demonstration tests like the PRACLAY experiment.The PRACLAY in-situ experiments include a set of three tests: The gallery and crossing test, PRACLAY Heater test and PRACLAY seal test. The main aim of the Heater test is to study at a large scale the thermal impact of a HLW repository on the host rock. The test is housed in the PRACLAY gallery. A hydraulic seal, made of compacted swelling and low permeable bentonite annular ring was installed at the intersection between the heated and the non-heated part of the gallery. The primary objective of the seal is to provide undrained hydraulic boundary conditions for the Heater Test.The PRACLAY gallery was constructed in 2007 and the hydraulic seal was installed in 2010. The bentonite is hydrated by natural and artificial process. The swelling, total pressure and pore pressure of the bentonite are continuously measured and analysed by numerical simulations to get a better understanding of this hydration processes. The performance of the seal is tested systematically by means of gas injection breakthrough tests and permeability tests at interface bentonite / Boom Clay and in the Boom Clay around the seal.The PRACLAY Heater will be turned on at the end of Oct. 2014, since a sufficient seal swelling has been attained to fulfill its role for the PRACLAY Heater test. This paper will focus on the PRACLAY Seal test: How we understand the process behind the hydration of the bentonite and how we test the performance of the bentonite seal."

Jan 1, 2015

By Patricia Dillon

EHS Management Standards Communication and Reporting (8) ! Establish processes for internal and external communications ! Designate responsibilities for communication with COI ! Report as defined by senior management ! Report annually to employees, shareholders, COI on EHS and social performance Community Rights and Public Consultation (9) !Identify COI?s and establish process to hear concerns !Acknowledge and respond to complaints !Support local communities !Plan for closure and conduct public consultation !New projects include identification of COI?s, concerns to be considered in design

May 1, 2004

By Paul E. Mather, Matthew J. M. Krane

Anode or fire refining is the final pyrometallurgical step in the production of copper anode. Part of this process purifies liquid copper by reducing its dissolved oxygen with a natural gas-steam mixture. Until now there have been no transient models of this process coupling the injected gas jet mass transport with its chemical reactions. A transient, 1D flow, chemical reaction model was made to estimate the time-dependent behavior of anode copper composition, soot formation, and the transient gas jet composition along its height. Model estimates were made for reduction rate, soot emission rate, and exergy loss and destruction distributions for two melt temperatures and a range of steam addition rates. It was found that increases to melt temperature and steam addition rate increased reduction rate and decreased soot emission, while having little effect on exergetic performance. Estimates for reduction histories were compared to industrial data. INTRODUCTION Anode/fire refining is the final pyrometallurgical step in the production of copper anodes; it is essential for removing dissolved gases which cause porosity in cast anodes. Despite its significance, the open literature appears devoid of any transient models of the entire process; furthermore, there are very little published process data with which to validate any models made. This dual dearth of modelling work and process data inhibits studies of the tradeoffs between process and performance changes, desirable for decreasing reduction time and soot formation as well as quantifying changes in the exergy losses and destructions of the process. This work introduces a reduced-order, transient model of reduction during fire refining, examines performance trends with operating conditions, and compares model estimates with industrial data. Overview of anode refining The purpose of anode refining is to produce liquid copper which can be cast with minimal gas porosity, which disrupts the downstream electrorefining process. Dissolved sulfur is removed first, then oxygen, by reactions with different injected gases. The removal of oxygen (the reduction step) is the subject of this proceeding and is effected by the bubbling of natural gas, typically mixed with steam, through the melt from tuyeres. A typical refining run reduces dissolved oxygen from 3000 ppm to 300 ppm in 2–3 hours (Schlesinger, King, Sole, & Davenport, 2011). The refined copper is then cast as anodes. Figure 1 shows a schematic of the furnace vessel.

Jan 1, 2019

By M. Imamura

Sumitomo Metal Mining Co., Ltd. has developed a novel hydrometallurgical process for producing not only copper metal but also iron metal from copper concentrates. Because copper concentrates generally contains the same amount of iron as copper, cost-effective rejection of the iron is a key issue for the development of the process. Conventional hydrometallurgical processes produce a large volume of goethite or hematite for disposal and the residues are not environmentally friendly. In the novel Sumitomo hydrometallurgical process, copper is leached effectively from chalcopyrite concentrates using chlorine gas, followed by purification through solvent extraction and electrowinning for copper and iron recovery. This process has many advantages such as the minimization of the volume of solid waste by the recovery of metallic iron and the production of high purity copper. Iron metal with a purity of more than 98% can be recovered from the purified raffinate. This paper presents the results of the batch and continuous tests of the process flowsheet.

Jan 1, 2006

By Ken Major, Anita Marks, Craig Sams

In 2007 Copper Mountain Mining determined that there were sufficient resources to consider reopening the Similco Mine near Princeton, BC. The mill facility that had been built by Newmont Mining in 1972 was closed in 1996 and all of the process equipment removed. The mill had been built on the west side of the Similkameen River to facilitate mining of the Ingerbelle Deposit. In 1980 construction was completed on a primary crusher and cable belt to deliver ore across the Similkameen River from the Copper Mountain deposit to the Ingerbelle mill. With the decision to restart mining of the Copper Mountain deposit, the decision was made to design and build a 35,000 tpd grinding and flotation mill near the mining operations. This paper discusses the application of historical operating data for the selection of the mills for the new grinding circuit and provides an overview of the grinding circuit design.

Jan 1, 2012

By Alan B. Morrow, William A. Poe

"Minerals processing operations are constantly challenged with improving production rates, yields, energy efficiency and process stability. Advanced Process Control has proven to be an effective tool for improving operations by capturing the full process capabilities consistently. However, the velocity of applying the technology as well as the sustainment of these significant benefits has been hampered by the usability of the software and adaptability of the applications.Some of the new technology developments that improve the usability and adaptability of advanced process control include:• modern and intuitive user interfaces,• customizable models to support unique process behavior,• fast and flexible OPC connection tools,• automated model building,• integration with first principles dynamic models and• improved performance monitoring.This paper will briefly discuss the new technology developments that have improved the usability and adaptability of advanced process control and how this can affect minerals processing operations.In today’s environment, Minerals Processing plant managers continuously face new challenges and requirements including:• higher energy efficiency,• increased run lengths,• reduced product quality variability,• reduced emissions,• higher availability, and• lower operating costsOperating a unit to meet these challenges in real time is not easy for operators and conventional process control systems. However, innovatively using existing technologies in Minerals Processing plants can improve operations on a minute by minute basis and reap significant benefits.Advanced Process Control (APC) can extract the maximum performance benefits from existing equipment while respecting plant operating constraints. Expensive capital projects to upgrade equipment are not always necessary. Advanced Process Control can deliver significant economic benefits by maintaining the plant at its most profitable point as conditions change."

Jan 1, 2016

By H. Utsunomiya

Most magnesium alloy sheets show low deformability in rolling. Edge cracks and transverse fractures are common difficulties. In addition, rolled sheets show well-developed basal texture <0001>//ND. The texture causes high anisotropy in mechanical properties and low formability in subsequent metal forming. Differential-speed rolling, where the upper and the lower rolls rotate at different speeds, introduces shear deformation through the thickness. Not rolling texture but shear texture evolves in the sheet so that the asymmetric rolling can be a method of texture control. However the primary slip system of the hcp alloy, is basal, the shear texture should be also basal. Differences between the two basal textures, i.e., the rolling texture and the shear texture, have not been understood completely. In this study, conventional (same-speed) rolling and differential-speed rolling have been applied to commercial AZ31B sheets at 623K. Microstructures, textures and mechanical properties of the rolled sheets before/after annealing are compared. It is found that the basal texture is more pronounced by the asymmetric rolling. On the other hand, the asymmetric rolling is effective to decrease the grain size and the planar anisotropy.

Jan 1, 2006

By A. Eslami, H. Tabatabaei, M. Kolandoozan, Z. Manafi, A. R. Shahverdi, M. Noaparast, M. Oliazadeh

Application of Acidithiobacillus ferrooxidans bacteria to flotation of Sarcheshmeh low-grade copper sulphide ore was studied. Sarcheshmeh low-grade ore contains pyrite, which causes some problems in the flotation of copper minerals. In this study, A. ferrooxidans was used to change the surface chemistry of pyrite and copper sulphide ores and consequently, their flotation behaviour. In the presence of A. ferrooxidans and xanthate as a collector, pyrite was depressed whereas chalcopyrite and other sulphide minerals were unaffected. In addition, the pulp pH remained unchanged. It was shown that the surface chemical properties of the bacteria can be manipulated successfully to achieve the desired effects in a flotation process. The results showed that the recovery of pyrite in the presence of the bio-depressant is 50% lower than when no bacteria were present. At the same time the recovery of chalcopyrite remained unchanged.

Jan 1, 2004

By D Martín, G. Díaz, F. Cubeddu, A. B. Mejias

The Modified ZINCEXTM Process (MZP), developed by Técnicas Reunidas, is an industrially proven flexible process. It can handle a wide range of primary and secondary raw materials, producing SHG zinc. The core of the Modified ZINCEXTM Process is the zinc solvent extraction unit. This unit is an effective barrier for any leachable impurities present in the raw material. As a result of this an ultra-pure zinc solution is always obtained. The high versatility of the process makes the application of the technology in different scenarios possible. MZP can be effectively applied when developing a whole new plant (Skorpion) or adapting its scheme to an existing refinery (Akita), in both cases giving the same results. Flexibility in terms of capacity of the plant is a great advantage of the MZP, there is the possibility to adapt the global process to a wide range of production capacities. Zinc production capacities of over 150 000 t/a may be achieved with a single solvent extraction plant train. The robustness of the Modified ZINCEXTM Process has been recently proven on two new plants currently in operation: Portovesme (Italy) and Horsehead (USA) after start up during 2013. The status of both plants is described in this paper.

Jan 1, 2014