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By Szilvia Szabo, Jozsef Paulovics, Ljudmilla Bokanyi

"Waste recycling is one of the most important challenges of the XXI century. The recycling of wastes is closely related to and bases on the mineral processing. Many mineral processing techniques and equipment are applied in this field. The principles of the characterisation of wastes and design of technologies is rather similar to the classic mineral processing. Nevertheless, the diversity of the wastes and their complex composition and properties, as well as their environmental impact requires a special approach.Solar elements have sandwich structure of glass substrate and cover, as well as a very thin semiconductor layer. CdTe semi-conductor can be recycled by flotation. Within the RESOLVED (LIFE European Framework) R&D project on the recycling of solar elements the surface properties of pure CdTe semiconductor and pure glass were investigated by the measurements of zeta-potential using Zeta PALS Brookhaven instrument at University of Miskolc. Applied surfactants were: potassium ethyl xanthate; the anionic oxhydryl Aero Promoter 825 or Flotinor SM 35; the cationic Armoflote 43 or Armoflote 64, as well as Hostaflot LET (dithiophosphoric acid diethyl ester) and Hostaflot M91 (mercaptobenothiazole). The tested electrolyte was sodium-silicate. Zeta-measurements were carried out in full pH-range. Interfacial interactions were detected and interpreted. The basic results were verified by the flotation kinetic tests.Finally, the flotation technological experiments were carried out at a semi-technical scale using the real obsolete solar elements. The particle size at the liberation degree of 98% was as fine as below 5 µm. A special flotation cell providing the generation and distribution of very fine air bubbles was built. The pre-concentrate for the manufacturing of the test solar module was performed and transported to the BAM Institute (Berlin), the principal co-ordinator of the Project, and then further to the First Solar (USA) where a new panel was manufactured using recycled semi-conductor."

Jan 1, 2016

By Cesar A. Urbano Jr., Gretchen T. Lapidus

A series of experiments examined silver extraction from a high-grade sulfide concentrate employing thiourea solution. Thiourea was initially oxidized with hydrogen peroxide (H2O2) to form formamidine disulfide (FADS) and used to extract silver from the as-received concentrate and after various pretreatments. Very low recoveries (~30%) were obtained with the as-received concentrate due to competitive cementation reactions by metallic iron and easily oxidizable copper phases. Over 80% Ag recovery was obtained when the concentrate was pretreated to remove this iron and copper. The results suggest that an oxidative acid pretreatment of this concentrates significantly improves silver recovery upon leaching with thiourea.

Jan 1, 2014

By Kai Bartram

The successful application of color sorting machines has established sensor-based sorting in the mineral industry in recent years and is considered today as a significant innovation in processing technology. However, we are only at the beginning of (market) introduction. New sensor systems have been developed, which exploit material properties such as electrical conductivity, magnetization, molecular structure, thermal conductivity etc. This opens up new exciting preconcentration and upgrading possibilities for many applications such as nickel, gold, copper and other ores as well as for industrial minerals, diamonds and other gem stones.

May 1, 2009

By J. D. McFarlane, V. Robinson

"The paper begins with a brief account of the naturarly occurring resources of gypsum and anhydrite and a discussion of their relative value and utility as sources of sulphur. The fundamental chemistry of recovering sul-phur values from calcium sulphate is discussed. (a) Thermal decomposition -discussed as impracticable; (b) Reduction to calcium sulphide; (i) Total Reduction-The chemistry is outlined and the Dorr-Oliver and Bureau of Mines processes mentioned. The Elcor process is mentioned and certain deductions made from available information.(ii) Partial Reduction-This is stated as the basis of the only proven process, namely ""The Cement -Sulphuric Acid Process."" The possibility of recovering lime is mentioned as an aside, but dismissed for lack of commercial application. The history of the cement -sulphuric acid process is covered briefly and a list of plants in commercial operation included. A brief elementary account of the basic chemistry of cement production is followed by a discussion on raw materials and fuels. A short account of the flow scheme of a typical plant, with notes on the operating peculiarities, precedes an account of product quality. The latest developments which enable by-product gypsum to be used as a raw material are discussed, with an indication of how the flow scheme is modified. A statement of feasible plant capacities is followed by requirements of raw materials, services, labour, etc., and finally some indication is given of capital costs."

Jan 1, 1969

By Ken G. Stowe, Stephen L. Chryssoulis, Christian Bendel, Joe Y. Kim, Ewald Niehuis

"TOF-SIMS (Time-of-flight secondary ion mass spectrometry) was used to detect collectors sorbed onto the surface of mineral particles in concentrate and tailings samples from the Brunswick, Matagami and Kidd Creek concentrators. This technique uses ion beams from either Cs or Ga sources to sputter the particle surface, a method which reduces fractionation of the collector molecule during sampling.In the Brunswick Zn circuit, sphalerite particles lost to the scavenger tails had less amyl xanthate and isobutyl xanthate compared to sphalerite recovered to the Zn final concentrate. Xanthates were detected on the surface of sphalerite particles floating to the CuPb final concentrate.At Matagami, significantly more isopropyl xanthate and isobutyl dithiophosphate were detected on sphalerite recovered to the Zn final concentrate, compared to sphalerite lost in the Zn rougher tails.In the Zn circuit of Kidd Creek, sphalerite lost to the tails had on average ten times less xanthate compared to sphalerite recovered into the Zn final concentrate. Xanthate was also detected on the floated pyrite particles. In addition to isobutyl xanthate, amyl xanthate was also detected on the floated sphalerite and pyrite particles.This preliminary investigation has (a) demonstrated the ability of TOF-SIMS to detect individual collectors on particle surfaces from plant samples and (b) shown that TOF- SIMS is an excellent tool, complimentary to TOF-LIMS, in establishing the surface chemistry of minerals as related to mineral processing."

Jan 1, 1995

By Zygmunt Kowalczyk

"A theory permitting the determination of expected surface deformations for planned underground exploitation is proposed and discussed in this paper. The relations between surface subsidence and various methods of mining are analyzed, and allowable horizontal .deformations for protected objects, according to the degree of their significance, are reviewed."

Jan 1, 1966

By T. Kalliomäki, A. T. Aji, M. Lundström, J. Aromaa

The settling properties of anode slime in copper electrorefining have crucial effect on copper cathode quality. Anode slime settling is affected by electrolyte composition and temperature, electrolyte circulation, and the sizes and density of the slime particles and agglomerates. Typically, the industrial copper electrolytes contain 40–60 g/dm3 Cu2+, 130–220 g/dm3 H2SO4, 0.04–25 g/dm3 Ni2+, 0.005–30 g/dm3 As, and have operating temperature of 55–70°C. In optimal electrorefining process, the settling rate of anode slime is sufficiently high to avoid the risk of getting the slime entrapped in copper cathodes. In this research the settling properties of copper electrorefining bottom slimes, mainly consisting of Cu, Ni, Ag, Se, Pb, As, Bi, Sb and Ba compounds, were studied by settling rate tests. The tests were conducted in water and synthetic electrolytes with known viscosities and densities. In addition, the effect of agglomeration was taken into account – it was observed that breaking the agglomerates which existed in the as-received slimes decreased the particle sizes on average 56–73%, which decreased the settling rate. The results of this study provide detailed information of anode slime settling and thus clarify the conditions causing cathode contamination risks in copper electrorefining. INTRODUCTION Settling rates of Cu-ER anode slimes affect the purity of cathode copper and faster settling rate decreases the contamination risk (Davenport et al., 2002; Shi & Ye, 2013). The settling rates are affected by the properties of anode slime particles (Wills & Napier-Munn, 2011; Aaltonen, 2014; Kiviluoma, Aaltonen, Aromaa, Lundström & Forsén, 2016) as well as viscosity and density of the electrolyte (Davenport, King, Schlesinger, Biswas, & Robinson, 2002; Shi & Ye, 2013). Thus, it is crucial to find out how the viscosity and density affect the settling rates. Small spherical particles with diameter below approximately 50 µm obey Stokes’ law (Equation 1) (Wills & Napier-Munn, 2011). v = gd 2 (ρS – ρF) (18η) -1 (1) where v is terminal velocity (m/s), g acceleration due to gravity (m/s2), d diameter of particle (m), ρS density of particle (kg/m3), ρF density of fluid (kg/m3), and η dynamic viscosity (Pa∙s). The approximate effects of kinematic viscosity (ν = η / ρS), density (ρS) and particle sizes on settling rates defined for small anode slime particles based on Stokes’ law are presented in Figure 1. However, Stokes’ law does not take into account other than spherical shapes, and it is only applicable for small particles. Consequently, the real settling rates of the particles are lower than these (Wills & Napier-Munn, 2011). Moreover, some of the anode slime particles are larger than 50 µm (Aaltonen, 2014).

Jan 1, 2019

By H. Tokuichi, H. Ohta, K. Sato

A physical separation technique of tantalum capacitors from waste print circuit boards is in a development phase in Japan. A tantalum capacitor consists of an exterior coating of resin (epoxy resin) mixed with silica fillers and a sintered tantalum compact, the latter of which is impregnated with manganese dioxide (MnO2). In this study, we developed a process to recover tantalum oxide from tantalum capacitors by roasting, fluidized-bed separation, and hydrometallurgical treatments. Our aim was to recover tantalum oxide with high purity from waste tantalum capacitors. In this process, the exterior resin was selectively decomposed by roasting without oxidation and pulverization of the sintered tantalum compact at a proper temperature. Furthermore, the decomposed resin with silica filler on the surface of the sintered tantalum compact was mostly removed by fluidized-bed separation. The surface of the sintered tantalum compact was cleaned by ultrasonic irradiation in an acid solution to remove the MnO2 paste as well as residual Ag paste and silica filler. The impregnated MnO2 in the sintered tantalum compact was leached as Mn(II) ions using acid solutions via the reducing effect of tantalum metal to recover purified tantalum oxide.

Jan 1, 2014

By Rodrigo Madariaga, Tracy T. Morris

The practice of stripping copper starter sheets from titanium blanks to be used in a conventional electrolytic tankhouse has been around since the advent of Electrometallurgy. Historically it has been done manually, utilizing many people to produce in some cases thousands of starter sheets per day. Some other conventional tankhouses have successfully converted to using mechanical means to strip starter sheets or have made the switch to permanent cathodes and although robotics have been around for quite some time they have not been used to strip starter sheets until recently. The Amarillo Copper Refinery began using robotics to strip several years ago and the details to how this came about and how the robots work will be described. INTRODUCTION ASARCO LLC (Asarco) was organized in 1899 as the American Smelting and Refining Company. Originally a consolidation of several lead-silver smelting companies, it evolved over the years into an integrated producer of primary non-ferrous metals, including copper, lead and zinc and associated co- products (Marcosson, 1949). Grupo México, S.A.B. de C.V acquired Asarco in 1999. Today, Asarco is a vertically integrated producer of primary refined copper and associated co-products such as gold, silver, molybdenum, selenium and tellurium. Asarco operates three open-pit mines and mills and two solvent extraction-electrowinning (SX-EW) plants all in Arizona plus a copper smelter in Arizona and a copper refinery in Texas. Figure 1 illustrates how the copper metal comes out of the ground at the mine and ends up as a refined product at the refinery The copper refinery in Texas is known as the Amarillo Copper Refinery (ACR) and is located in Amarillo, Texas. It was built in 1975 to replace 3 other aging refineries and was designed to produce 550,000 tons (500,000 MT) of refined copper per year using conventional starter sheet technology. At the time it was commissioned it was the largest tankhouse in the world at just under 1/2 miles long under one roof.

Jan 1, 2019

By T. R. Madhavan

The development of contact angles on highly polished ?uraninite surfaces, using sodium oleate and dodecyl ammonium acetate as collectors, has been studied at different collector and hydrogen ion concentrations. It was found that sodium oleate in acidic media (up to a neutral: PH) and dodecyl ammonium acetate in neutral and alkaline media give good contact angles. It appears that the combined forms of these collectors, viz., oleic acid and free amine, are more important in effecting contact. W ITH the emergence of uranium as a strategic metal in the last fifteen years, considerable effort has been directed toward the commercial recovery of uranium from its ores. This has resulted in the development of a uranium technology. It is only in recent years, However, that fundamental data regarding the floatability and surface properties of uraninite and ?pitchblende have been elucidated by different methods. Contact-angle measurement is one of the important tools for tl1e evaluation of the conditions of floatability

Jan 1, 1964

By Yan Qun, Chen Xiao-ming, Ma Pei-long, Luo Xian-ping, Luo Cai-gui, Feng Bo

The effect of leach promoting reagent LPF on the leaching process of a weathered crust elution-deposited rare earth ore has been investigated and the mechanism is discussed. The result shows that the leach promoting reagent LPF can enhance the leaching extraction of rare earth ore effectively. With the addition of LPF to the lixiviant at a concentration of 0.1%, the leaching extraction increased by more than 8%, the ammonium sulfate concentration could be decreased by 25%, and the leaching liquid/solid ratio reduced by 34%. The mechanism analysis shows that LPF can react with rare earth ions and form soluble coordination compounds, thus reducing the activity of the leached rare earth ions, increasing the concentration difference for ion diffusion, and promoting the rare earth leaching process. These results will hopefully help point to a new approach to making the leaching process of low-grade weathered crust elution-deposited rare earth ore more efficient and with lower lixiviant consumption.

Jan 1, 2014

By S. Dessureault, M. Yildirim

More mining companies are now investing in IT, including updating one of the traditional IT process control tools used in the mining industry: real time in-pit truck allocation control and monitoring systems, or fleet management systems (FMS). These systems have been used to maximize the overall mine production by improving equipment utilization and reducing production costs. Most modern operations monitor the in-pit operations using GPS and wireless communications to produce data. Improvements in bandwidth, sensors, and computing power are causing modern systems to become more complex and generate more data. However, human analysis by simple regression or table generation in spreadsheets of the data is becoming impossible. Data mining solves this data management problem. Data mining finds patterns and relationships in very large data sets. This paper describes the application of modern data mining techniques on truck dispatching systems in a real open pit hard-rock copper mine. The analyses conducted included determining how the trucks performed under particular conditions and allocation systems. The long-term benefits of this work are to identify strengths and improvement opportunities in truck assignment systems and establish the skill sets and IT infrastructure needed in undertaking more complex datadriven technology such as a truck dispatcher trainer.

Jan 1, 2007

By A. Valdivieso

Reducing accident rates keeps getting more and more complex as the usual tools enter a curve of diminishing results. Fortunately, nothing modifies behaviour in a stronger and wider way than having a robust safety culture. On the other hand, managing cultural change is difficult and the risk of back-fire is very high, especially if the workforce does not trust our intentions. A personalized approach of well chosen and targeted actions tends to be the only yet difficult option. We have found, via experience in the metallurgy and chemistry industries, a way of preparing the company and the workforce to accept these sorts of culture changing measures faster and easier. Using company-wide changes based on workplace perception, yields the most optimal acceptance. It is based in the principle that we all use clues in our environment as guides to choose our behaviour. So, controlling the perception that our workplace generates can affect behaviour and simplify our task before it even starts. It is a matter of using the tools that other disciplines such as marketing, social engineering and architecture bring to us and adapting them to a very defined objective: Having our installations “sell” safety so that our people unconsciously believe that they must adapt to safety values in order to “do well” in said environment. INTRODUCTION After decades of improvements in accident rates, we are understandably hitting a diminishing results curve: most actions that spectacularly reduced accidents in the past (e.g., Innovation in Personal Protection equipment, adapting international standards and legislation, and innovative safety programs; Figure 1) now hardly get us the exponential gains we saw years back, regardless of the investment we put on them. Furthermore, the improvements in safety of the last 3 decades have been creating new sets of issues that start to show their face such as: By reducing accidents we can create feelings of invulnerability as we lose view of the consequences. With innovative protection equipment we increase Risk Homeostasis, meaning that people behave in a more dangerous way in order to maintain a constant level of risk in their lives (Getting closer to fire after getting better fire-proof garments for example). Too much Legislation can create a feeling of disengagement from personal responsibility. And despite improvements, we haven’t really solved the production vs safety confrontation, it is now stigmatized and less visible, yet it tends to reappear in moments of weakness.

Jan 1, 2019

By H. A. Kishawy, S. Kannan, M. Balazinski

Metal Matrix Composites (MMCs) are new generation engineering materials that possess superior physical and mechanical properties compared to nonreinforced alloys. However, the presence of abrasive ceramic reinforcements in the ductile matrix causes severe tool wear and premature tool failure. Flank wear was found to be the dominant wear mode while the main wear mechanism was abrasion. Analysis of the cutting tools using scanning electron microscopy has shown that both two body and three body abrasion are operational during machining MMCs. A methodology for predicting the tool flank wear progression during bar turning ofMMCs was presented in an earlier paper [1]. In the proposed model, the wear volume due to two body and three body abrasion mechanisms was formulated. Then, the flank wear rate was quantified by considering the tool geometry in 3D turning. The main objective of this paper is to investigate the contribution of two body and three body abrasion towards the tool wear volume during cutting MMCs.

Jan 1, 2006

The hydrometallurgical treatment of copper ores and concentrates continues to be an active field of innovation. The direct extraction of copper from ores containing chalcopyrite is an important development to provide an alternative to flotation-smelting and refining. Jetti Resources (with the University of British Columbia) and the JX Nippon Group have developed process options for chalcopyrite heap leaching. Biological heap leaching developments for chalcopyrite are also continuing in parallel. These direct leaching technologies are also very attractive for arsenical ores. The atmospheric leaching of copper concentrates is an attractive option along with autoclave processing. The Galvanox™ Process is the focus of commercialization by InCoR Galvanox Holdings under exclusive license by the University of British Columbia. The Galvanox™ Process can be used to treat chalcopyrite or enargite containing concentrates to high copper extraction with simultaneous precipitation of arsenic as atmospheric scorodite. FLSmidth has continued development of the Rapid Oxidative Leach (ROL) and associated technologies for chalcopyrite leaching. The Glencore Albion Copper Process using ultra fine grinding of copper concentrates and atmospheric leaching has found application in central Africa. The pressure leaching of copper concentrates continues to be attractive for rapid, complete oxidation of sulfide minerals with high copper extraction and arsenic stabilization of iron-arsenate minerals and precipitates. The Ecometales PLCC project is designed to use high temperature total pressure oxidation for treatment of an arsenical copper concentrate with use of existing copper SX-EW facilities for copper cathode production. The excess acid from the autoclave process will be used to make up the acid demand for associated copper ore heap and dump leaching operations. INTRODUCTION The recovery of copper from ores is dominated by the flotation of copper concentrates followed by smelting—converting and electrorefining. This process has been enabled by the development of froth flotation and progressively made more efficient by advances in smelting and converting technologies.

Jan 1, 2019

By Jie Zhu

Coal bumps are a special form of release of geologic strain energy that has already been one of the most dangerous hazards to underground mining safety in China. A number of coal-bump models have been developed to quantify coal failure under assumption that a bump is a kind of non-gas induced outburst. However, some technical experts in charge of micro-seismic and gas monitoring have found unusual gas emissions before and after bump, which suggests that it is possible for gas to trigger coal bumps. Considering the coal reservoir as geological body composed of the coal matrix and gas, a new model based on Lippmann?s bump model is proposed to understand the initiation of coal bumps. The redistribution zone from excavation of a roadway has been calculated and analyzed regarding its relation with mining depth. It is shown that high gas pressure may push the coal seam to overstep the critical state due to extension of the plastic disturbed zone, and this is harmful to the stability of coal seam. This model successfully explains the bump phenomena of the Xinzhouyao mine at shallow depth.

Aug 1, 2013

By H. E. Lake

VERY EARLY in the initial stages of underground development work at Eldorado's Beaverlodge operation, the decision was made to use mill tailings as a backfill product. Mining and milling commenced in June, 1953, using locally available sand as backfill, while test work and installation of a plant was carried out to prepare ?and deliver the tailings to the mining areas. The first use of tailings was made in February, 1954, a sandslime separation being carried out with hydraulic cyclones. To date (January. 1956), approximately l 40,000 tons of fill have been used in the stoping areas, providing very effective support in a 50 deg. Vein system of cut-and-fill mining. The recoverable portion of the mill tailings amounts to 40 to 45 per cent, which has resulted in a product giving a percolation rate of 6 to 10 inches per hour. Owing to the fact that Eldorado has milled from 15 to 2 5 per cent more ore than it has mined, through the purchase of custom ore, the degree of control on the sand-slime separation has not been as critical as it might normally be when the filling operation must depend only on the tailings from ore mined. A description of the conditions involved and of the plant as finally installed is given below. It might be mentioned here that, with the impending increase in milling capacity from 700 tons to 2,000 tons p.er day, the present plant will be considerably altered within the ensuing year to handle the increased tonnage and distribution.

Jan 1, 1956

By S. M. Bulatovic, D. M. Wyslouzil, K. R. Rawlings

"The suitability of a new organic reagent DS20 as a depressant for oxidized and carbonaceous pyritic lead-zinc ore from Nanisivik Mines Ltd. has been evaluated in the laboratory and in the plant.The depressant DS20 is a mixture of Lignosulphonate-Dextrin-Quebracho and was developed specifically for depression of highly oxidized and carbonaceous pyrite.The laboratory test work indicated that the poor metallurgy resulting from the oxidized ore could be improved to normal plant performance by the addition of the DS20 depressant with the existing plant reagents. The laboratory data suggested that lime consumption could be reduced when using DS20.In this paper, the development work and the plant trials with DS20 are described.INTRODUCTIONNanisivik Mines Ltd. treats approximately 2000 tonnes per day of lead-zinc massive sulphide ore, containing currently 1% Pb and 9% Zn. The concentrator operations have been described previously (1,2) and typical metallurgical performance is detailed in Table I.The concentrator flowsheet (Figure No. 1) and the standard reagent scheme (Table No. 2) demonstrate the relative simplicity of treatment of this coarse grained ore.A recently discovered satellite orebody - Area 14 - containing 2% Pb and 12% Zn was brought into production in October 1983. This ore had been oxidized to varying degrees by ground water; the pyrite mineralization was found to be very fast floating and a carbonaceous constituent present in higher than normal proportion also affected flotation. The simple high lime addition could not control the pyrite, and very low grade lead concentrates resulted; zinc metallurgy was also affected by this oxidized condition (Table 3)."

Jan 1, 1986

By D. A. MacFadyen, J. J. Brummer, C. C. Pegg

"The first record of a kimberlite found in Canada (1946) was the identification of thin dykes intersected while drilling for gold in Michaud Township, Ontario.Sampling of the Munro Esker (1964) in the Kirkland Lake area, Ontario, by the Geological Survey of Canada identified the occurrence of detrital grains of pyrope garnets along a length of 35 km of the 113 km tested. A search for the source of the garnets resulted in the identification (1968) of a narrow subsurface kimberlite dyke in the Upper Canada Mine. This discovery resulted in a staking rush. Unfortunately, subsequent work did not identify the source of the kimberlite indicator minerals.During 1978 the Ontario Geological Survey started a multi-discipline study of 29 townships (2560 krn2) in the Kirkland Lake area, to encourage exploration for gold, base metals, and kimberlites. Back-hoe sampling (1979 to 1982), where the overburden was thin, and reverse circulation drilling, in areas of thicker drift, yielded samples of the till. These were analyzed for several elements and a mineralogical identification of the heavy minerals was completed. Pyrope and chrome diopside grains were identified.Studies of the Pleistocene geology indicated only the most recent direction (167 degrees) of ice advance (Matheson) and the associated deposits, out of a possible three advances known to occur in the general region straddling the Ontario-Quebec boundary, is present in the immediate area of Kirkland Lake. Contouring the distribution of pyrope grains (1990) showed a concentration centered over an area of 616 km2 extending down-ice from Gauthier Township. This included a smaller area containing chrome diopside grains. Kimberlite boulders were identified (1981) in gravel pits on the Munro and Misema River Eskers located within this anomalous area. The next step would be to use the airborne geophysical data to locate the kimberlite pipes which yielded the indicator minerals and boulders. The source area is likely to be in the northern half of the Ontario Geological Survey study area."

Jan 1, 1992

By B. B. Adhikari, S. Alam, Ohto Kawakita, Abe Pangeni

Effective recovery of gold was investigated by using adsorption gels prepared from pure cellulose, cotton and paper by treating with concentrated sulfuric acid. Only gold was adsorbed with extraordinary high loading capacity from varying concentrations of hydrochloric acid separated from other precious metals and base metals. The formation of fine powders of metallic gold was visually observed, which is attributable to the selective reduction of gold (III) ion to metallic gold clue to its high oxidation-reduction potential. Recovery of gold from the leach liquor of hydrochloric acid of circuit boards from spent mobile phones was attempted using pure cellulose gel.

Jan 1, 2011