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By Shuan-cheng Gu

Roof bed separation often occurred due to the deformation incoordination of surrounding rock following the excavation of mine roadway. Bed separation has effect on the bolts, and the estimation of the influence will directly affect the safety of support systems. In this paper, the hyperbolic function model to analyze the load transfer mechanism on the bolts was simplified as the exponential function form for easy calculation. An elastic-plastic analysis model of the bolt loading occurred by the bed separation was established. And the development low that the bed separation affected to the bolt loading was discussed. According to the parameters analysis of different separation values and locations, the influence law of the bolt loading caused by roof bed separation was summarized. Finally, the effects of bed separation were considered for the bolting design, it was able to provide a reference to the anchorage design of stratified rock.

Aug 1, 2013

By Percy Coulter

"GeneralThe Malartic Gold Fields mill is presently treating ore from four different companies. The ore is delivered by truck, by the shipper, and dumped into the Malartic Gold Fields ore bin. This ore varies in size from 'Run of mine' to minus 8 11, All ore is crushed to pass a 3/ 8 11 x 4 11 cross slotted screen.Weighing and SamplingAfter crushing the ore passes over an adequate-weigher (250 T .P.H. capacity) on its way to the fine ore bins. This weigher has a remote counter at the sampling point.A 36” Vezin sampler cuts 15% from the ore stream as it enters the mill bins. This portion is elevated, by means of a short belt conveyor, to feed the No. 2 Vezin sampler. (This elevation is necessary to give headroom for the following machines). The ore on the conveyor is levelled to give a uniform stream to the second sample cutter. The second, third and fourth cutters are 2411 •The No. 2 Vezin sampler cuts 19% from its feed and this portion falls directly into a 1611 x 1011 Denver rolls crusher. This crusher reduces the ore to -1/ 8 11 , approximately. The discharge from the rolls crusher falls on a revolving circular plate with scraper, which gives a uniform stream to the No. 3 Vezin sampler.The No. 3 Vezin cuts 10% from its feed. This portion falls on another revolving plate to give a uniform stream to feed No. 4 Vezin."

Jan 1, 1966

By Michel Masse

1. A battery-powered wireless mesh network for dynamic diesel machinery tracking and operating status monitoring. 2. A real-time ventilation model and fan speed optimizer. 3. An OPC server for information interchange. 4. OPC linkage to existing control infrastructure. 5. A Human Machine Interface (HMI) providing data archiving, trending and reporting. 6. Live MS-Excel to interrogate the simulation, controls and optimizer. 7. The battery-powered network mesh also provides SCADA functionality to route optimized setpointsto the fans and automated regulators not linked to PLCs.

Feb 1, 2008

By R. W. Lawrence, O. Lopez

Many gold deposits in the world have not been developed clue to the presence of copper and other base metals which can cause metallurgical and environmental challenges clue to the formation of base metal cyanide complexes. SART technology (sulphidization-acidification-recycle-thickening) can resolve these issues by recovering copper as a high grade sulphide concentrate, recycling the associated cyanide back to the gold leach, and eliminating the downstream environmental liabilities. Project economics can be improved substantially, leading to a positive re-evaluation of new and existing gold-copper projects. Some aspects of the design and operation of two recently commissioned SART plants will be discussed.

Jan 1, 2011

By V. A. Leão, A. M. Silva, S. M. Bertolino, B. C. S. Ferreira, D. Guimarães

Although not considered a high risk pollutant as compared to toxic metals and acidity, environmental agencies worldwide are proposing regulations to control sulphate in effluents and drainages by setting a threshold value varying between 250 mg/L and 500 mg/L. The aim of this study was thus to compare four different techniques for removing sulphate ions from mining/metallurgy effluents. The first alternative studied was sulphate removal by precipitation as ettringite. Treating a synthetic solution containing 1650 mg/L sulphate at 22±1 ºC resulted in removals close to 85% during continuous precipitation. Sulphate sorption was also investigated using three different ion exchange resins as well as limestone. Fixed bed experiments produced sulphate loadings of up to 70 mg SO4 2-/L resin, at pH 2.0. In neutral wastewaters, limestone is also a potential adsorbent producing a maximum particle loading of 19 mg/g. Sulphate sorption on limestone seems to be an alternative to treating mine waters with sulphate concentrations below the 1200-2000 mg/L range, where lime precipitation is not effective. Subsequently, sulphate removal by sulphate reducing bacteria was also investigated and it was observed that reactor’s hydrodynamic conditions and the choice of substrate are important factors for the process. The different technical aspects of each technology are addressed.

Jan 1, 2014

By R. Heikkilä

The utilization of Building Information Modeling (BIM) and model based 3-D control of work machines have increased a lot in new road construction in Finland as well as in other Nordic Countries. Up today, much less attention has been paid into the development of maintenance and rehabilitation processes. As a part of a large research and development program RYM PRE Infra FIN BIM in Finland, a focused research project of the BIM with experiments in total five (5) pilot projects has been performed. A main idea of the new BIM based process has been to utilize mobile laser scanning method for initial data acquirement, the use of novel 3-D analyze and modelling methods for point cloud processing, the use of new type optimization method for the planning of geometric and structural improvements needed for the existing uneven road surfaces, and further, through the creation of 3-D machine control models apply the newest 3- D machine control systems for continuous 3-D control of practical construction work using milling machine and asphalt paver. Finally, an evaluation is made between the new process model and the traditional way of working.

Aug 1, 2013

By Harry J. Cain

Introduction The property of Pioneer Gold Mines of B. C., Limited, is located in the Lillooet mining district of British Columbia, on Cadwallader creek, 54 miles distant by motor road from Shalalth, a station on the Pacific Great Eastern railway. Milling by the present Company was commenced in 1924, a small amalgamation plant, consisting of a crusher, Bryan mill, and plates being operated until 1928. Tailing from this plant was impounded and later treated in the 100-ton continuous counter-current decantation cyanide plant which was erected during 1927-28 and placed in operation during May of 1928. A second cyanide plant, employing continuous counter-current decantation, having a nominal capacity of 200 tons, has been erected during the past few months and was put into operation during September of the present year. The ultimate capacity of the combined units of the present mill has not been determined, but it is expected to be much in excess of the rated capacity. The Ore The ore, as received at the mill, consists chiefly of quartz carrying free gold, with small amounts of pyrite, arsenopyrite, and pyrrhotite in evidence, though probably amounting to less than one per cent of the total. Some gold is very closely associated with the sulphides. The country rock is a basic igneous rock, probably an augite diorite. Near the vein it is highly altered to sericite, which slimes readily on grinding, and does not settle very well. The quartz is of two types, clear and ribbon. In the latter, the ribbons, which are not much thicker than paper, consist of shattered sulphides. In crushing this ribbon quartz, breakage is often along the streaks, exposing these shattered faces to advantage in subsequent treatment. While gold is the metal for which the ore is mined, some silver is also present and is paid for by the mint. It is, however, unimportant from a commercial viewpoint. From the standpoint of crushing and grinding, the ore might be termed 'medium 'hard'.

Jan 1, 1932

By J. Ouellet

The authors participated in a study for a new mine shaft in Saskatchewan?s Athabasca Basin where ground freezing is desired to reduce water inflows. Constraints were imposed on the design in terms of permissible water leakage (less than 10 m3 / hour) inside the shaft. Since the shaft goes through highly permeable formations, water control measures had to be incorporated into the design. Ground freezing was selected as the most reliable and proven method for the sinking and a hydrostatic liner design was implemented. While exploring various technological options available for providing a fully hydrostatic liner, the authors came up with a new design concept that offers a more cost effective solution while meeting all the design constraints. The new liner concept is a composite design using concrete and a sprayed-on membrane system. A proof of concept program comprising laboratory testing and field testing was successfully implemented. This paper presents the innovative liner design, as well as the adapted sinking methodology, developed for this type of project. The new concept offers a new cost effective high performance hydrostatic mine shaft liner comparing favorably with traditional methods. RESUME: Les auteurs ont réalisé une étude pour un nouveau puits de mine dans le Bassin de l?Athabasca en Saskatchewan. Des limites sévères sont imposées sur le design en terme de volume d?infiltration d?eau acceptable (moins de 10 m3 / heure). Comme ce puits de mine traverse des formations très perméables la congélation des terrains a été sélectionnée, une méthode éprouvée et fiable. Un design hydrostatique a été choisi pour le revêtement du puits. Dans le processus de design, les différentes technologies disponibles ont été étudiées. Les auteurs ont développé un nouveau concept de revêtement composite offrant un rapport performance/prix plus avantageux que les technologies conventionnelles. Le nouveau design proposé est composé de béton et d?une membrane projetée. Un programme expérimental a été réalisé pour démontrer la faisabilité du concept. Cet article présente le nouveau concept ainsi que la méthodologie de fonçage de puits adaptée. Ce concept innovateur offre un revêtement hydrostatique performant à un cout avantageux par rapport aux techniques de construction utilisées jusqu'à maintenant.

Jun 1, 2012

By George B. Saunders

It is the purpose of this paper to point out conditions as they exist in the merchandizing of coal, to compare these conditions with methods in use by competitive producers of coal substitutes, and to present briefly some suggestions which may help the individual operator to market more coal in the immediate future, while we are waiting for the scientist and research worker, who are now busy on coal betterment , to produce in a practical way the results which they now write about in such glowing terms. While it may be unnecessary to call the attention of coal operators to the present deplorable condition of the industry, it might be well to impress upon our members in other branches of mining, as well as upon the public at large, the seriousness of the situation. Emerging from the war and the period of reconstruction that followed, the coal industry found itself with too many mines and too many men for normal conditions. To make matters worse, the interruptions in deliveries caused by strikes, the unfavourable publicity caused by socialistic propaganda, and the repeated governmental investigations, made the market a fertile field for coal substitutes which were not so handicapped. These substitutes were well advertised, and were marketed in an up-to-date manner, furnishing an example from which the coal operator could well profit. Now, whether or not there is agreement as to the cause or causes of this condition, there can be no doubt that we are today face to face with the fact that the sale of coal has not kept pace with the sale and use of other commodities. Had it done so, we would ere this have been able to take care of the surplus labour and work our mines at least approximately full time.

Jan 1, 1929

By E. C. Goodhue, R. D. Coleman, I. E. Puddington, A. F. Sirianni

Iron ore samples containing apatite are fractionated to acceptable products by spherical agglomeration methods. The phosphorus is upgraded by a factor of 10 at an elevated pH. High-grade iron products are obtained in good yields from the tailings in a second step of the operation. The grade of the phosphorus separated appears to reach a maximum at about pH = 10; recovery of iron decreases below about pH = 4. Both the recovery and grade of iron are found to be reduced sharply above about pH = 8.

Jan 1, 1968

By Evelynn Stirling

"The paper/presentation will review the evolution of diesel technology from older diesel engines (1990 vintage) through to the latest technology as a result of the ever changing emissions regulations. It will encompass the EPA Tier levels as well as the latest Euro Stage V emissions. The next step with technology will be to address the CO2 emissions, which translates to improving fuel efficiencies of the product as well as other technologies like battery electric, hybrid and fuel cells. As technology progresses it also becomes important to improve connective diagnostic systems to support maintenance practices and improve efficiencies. What will also be presented will be the key emissions changes to the different gaseous and particle mass elements as the products have transitioned from the EPA Tier 3 through to Tier 4 Final regulations. Offering a range of different technologies to the underground mining market matters as not all pieces of equipment will perform optimally due to its duty cycle and application. INTRODUCTION Rudolf Diesel built his first well-known prototype of the high-compression engine in 1897. Since that time, the diesel engine has evolved into one of the world’s most capable and reliable forms of power generation. Diesel engines can be found in a wide variety of vehicles and equipment, powering everything from agriculture and construction equipment to power generators and marine vessels. In the early days the emissions from diesels was very poor and extensive work has been accomplished over the decades to make the product more environmentally friendly. This is more important in underground mining where the space is limited and ventilation is expensive and challenging. DISCUSSION The key driver of the development of diesel technology is the legislation globally around engine emissions. The emission level requirements over the years has forced diesel engine manufacturers to build a deep technical understanding of the system and how to innovate and optimize key elements of the engine. Cummins expertise has been built over the years as the diesel engine has evolved from a relatively simple mechanical engine to an electronic system with advanced air handling, fuel system, after treatment, and controls. Cummins has also continued to expand into systems beyond diesel, including natural gas. Many new components have been added to diesel engines to reduce emissions while improving fuel efficiency and reliability and, at the same time, reduce the total cost of ownership to the customer."

Jan 1, 2019

By D. Michaud, C. Bazin, S. Lévesque, L. Pérez-Barnuevo, H. Longuepée

In recent years, with the emergence of Geometallurgy, a great effort has been made to characterize ore resources as early and accurately as possible, to allow better design and a more efficient operation of mineral processing circuits. In this context, core logging plays an important role, since drill cores provide the first insight into the ore characteristics. However, to satisfy geometallurgical requirements, traditional core logging does not suffice. New tools and methodologies need to be developed for the automation of core logging and the acquisition of mineralogical data better related to mineral processing performances. In this paper, a methodology for the geometallurgical characterization of drill cores is proposed, based on the drill core textural patterns. Textural pattern is defined here as the macroscopic spatial arrangement of minerals. The Mont-Wright iron ore deposit (Quebec, Canada) is used as a case study. The first part of this work aimed at analyzing the potential link between the iron ores textural patterns observed in drill cores and their response to ore processing, namely comminution and concentration. Preliminary results show similar performances in terms of energy consumption and heavy liquid separation for samples showing the same textural pattern. In the second part, this work seeks to develop a methodology for the automated identification of drill core textural patterns by the application of digital image analysis and discriminant function analysis. The results obtained show that this methodology is able to discriminate between the textural patterns identified at Mont-Wright with a good rate of success. Therefore, this work lays the foundation for the development of a new drill core characterization tool, which would allow for the early prediction of the iron ore behaviour during mineral processing through the identification of drill core textural patterns.

Jan 1, 2016

By Karl J. C. Harries

"14.1. INTRODUCTION1The boilerplate of an agreement is not a single provision, but a series of provisions that are expected in “every agreement”. They are sometimes also referred to as the “lawyer’s provisions”. Many businessmen consider the boilerplate to be superfluous and, to some extent, window-dressing by the lawyers – even legalese. They will often offer advice to the effect that it can “pretty well be ignored”. Such advice could not be more wrong.Most boilerplate provisions are essential parts of every agreement. Some may be part of a “standard package” and may have little relevance to the agreement at hand, but these are the exception rather than the rule. The exceptions should not be treated as justification for giving all these provisions short shrift. The boilerplate should receive the same review, consideration, and negotiation as the provisions that set forth the business deal. It is often these provisions that make the deal work or that are turned to at the time of disputes. If they are inadequate, as they sometimes are (unfortunately, some draftsmen are also loath to review or update their standard boilerplate provisions or to tailor them to the deal at hand), they can create problems, rather than offer solutions. Such problems can be costly and time-consuming for the parties to address. Inadequate or incomplete provisions may ultimately be one of the reasons for the parties to turn to the courts to settle their differences. On the other hand, good boilerplate provisions can help keep them out of the courts.One of the principal objectives of an agreement should be to provide procedures, or mechanics, for implementing agreed principles and for the parties to follow to settle their differences, real or perceived, without going to the expense and disruption of a lawsuit. An agreement should aim to keep the parties away from the courts, not serve as a springboard to the courts. It must nevertheless be acknowledged that, if there is a major falling-out among the parties to an agreement, the chances are that, however carefully the provisions of that agreement have been negotiated and drafted, the parties will end up before the courts or some other adjudicating body."

Jan 1, 2003

By Maureen McGuiness

"The pastefill circuit at the Bell Allard Mine in Matagami, Quebec started up in August 1999. The surface pastefill plant produces a cemented paste which is sent underground by gravity through a vertical pipeline in the mine ventilation shaft. Difficulties with paste flow during the start-up highlighted the importance of understanding paste rheology and the effect of operating procedures on line wear. By June 2000, the original circuit had been modified to include a paste pump to transport the paste to the shaft.The steps taken during the paste plant commissioning are discussed. The final flow sheet is presented, focussing on the use of instrumentation to ensure full column flow and proper distribution underground. Resistance modelling and accelerated curing of samples are examined as possible ways of predicting paste resistance to ensure compliance with the mine’s paste specifications.INTRODUCTIONCommissioning a new plant can be difficult and time consuming. The start-up of Noranda’s Bell Allard paste backfill plant was no exception. Since the first day it went into operation, the paste circuit could not meet the tonnage and paste quality requirements of the mine because the paste would not flow by gravity into the vertical pipeline in the mine’s ventilation shaft.Diagnosis of the pastefill problems proved difficult. It was only when the rheology of the Bell Allard paste was understood that the flow problems were solved. To ensure that the paste placed in the stopes meets mine requirements, two methods of paste resistance prediction are being developed."

Jan 1, 2002

By P. MacPhail, G. S. Dobby, I. M. Flint

"The objective of the laboratory work described in this paper has been to develop a method f or producing small gas bubbles at moderate to high gas rates in a flotation column. Small bubbles are particularly important for attaining reasonable flotation rates of fine particles. An ultrasonic aerosol generator has been employed to add frother solution directly to the gas stream. Using porous glass and filter cloth spargers, aerosol frother addition has produced bubbles at 1/2 to 2/3 the diameter of those produced by conventional frother addition to the liquid, at a lower frother consumption.IntroductionGas bubbles are generated in a flotation column most commonly by forcing gas through a porous medium called a sparger. Typical sparger material includes rubber (pierced with small holes) , fabric (such as filter cloth), fritted glass, or porous metal (steel or bronze) . Solid sparger material is suitable for laboratory use; however, for industrial applications a flexible sparger such as rubber or fabric is necessary to prevent the eventual plugging of orfices with solid particles and/ or precipitates. An exception to this is the use of a gas liquid contactor external to the column in combination with pressure release of gas in water, a method that has been demonstrated to produce very small gas bubbles. The typical objective of bubble generation for flotation column purposes is to produce bubbles with diameter of about 0.1 cm (and less) at a gas superficial velocity of 1 cm/s to 3 cm/s. In general, the smaller the bubble, the better. In man y cases, though, there is little , or nothing, gained by generating bubbles less than about 0.05 ern in diameter.Several factors affect bubble size when generated by a sparger: gas rate, orifice diameter, sparger surface area, surfactant type, surfactant dosage, and static head. At very low gas rates bubble diameter is independent of flow rate and is proportional to orifice diameter. At the moderate gas rates encountered in flotation columns bubble diameter, db' is related to gas flow by: db oc vg n, where vg is superficial gas velocity (rate of gas flow per unit column area). For porous steel and filter cloth, n has a value of about 0.25 for vg between 0.2 cm/s and 2 cm/s(2). The magnitude of the effect of orifice diameter at these gas rates is unclear. The effects of frother type and concentration on bubble size issuing from a single orifice have been measur ed by Miagkovaru , shown here in Figure I(IS). The reduction in bubble diameter upon surfactant addition is due to the lowering of interfacial tension created by adsorption of surfactant at the gas liquid interface."

Jan 1, 1988

By Jamel Sgaoula

During 1998 COGEMA Resources Inc. announced that operations at the Cluff Lake mine will be suspended indefinitely by the end of year 2000 as a result of deteriorating uranium market conditions. To remain profitable, Cluff Lake mine started an aggressive cost reduction program. A cost reduction team was formed to look for ways to lower production costs. The focus of this team was to screen all areas and to come up with ideas to improve the economy of the mine and ensure the viability of the operations over the remaining three years of operations. Among the areas where significant savings were achieved are: (1) replacement of portion of cement with fly ash in backfill; (2) backfill optimization; and (3) new shotcrete plant installation on site for bulk in-house shotcrete production. This paper details the research work carried out by Cluff Lake mine on these projects and results of its application.

May 1, 2001

By Eugene Sun, Qiang Xu

This presentation will review current applications of composite materials in aircraft design and discuss the challenges involved in maximizing the potential of the composites in aircraft applications.

Jan 1, 2010

By Nicholas Bonderoff, Amily Xu

The evaluation of battery electric vehicles (BEVs) in underground mines involves comprehensive business case analysis beyond just the capital and operating costs of the equipment itself. BEVs demonstrate benefits from an EHS perspective, reduced mine ventilation costs, lower energy operating costs, reduced overall GHG emissions (dependent on the source of electricity), elimination of DPM, lower equipment maintenance costs, and reduced cooling requirements in deep mines. When including batteries and supporting infrastructure, BEV capital costs are approx. 80% greater than that of diesel equipment. The project economics are highly dependent on the cost of electricity and diesel fuel, and these can vary widely depending on the location of the mining operation. Battery charging and swapping methodologies must be evaluated as there are a variety of approaches that can be employed which vary by manufacturer and type of equipment. Careful consideration of the cycle times, charging methodologies, and location of the battery charging infrastructure is necessary. Specific operating conditions must also be taken into consideration. For example, the time for blast gases to clear will be increased by reducing ventilation flow, and the potential impact on production needs to be evaluated. Similarly, the electrical distribution system needs to be evaluated for peak loading conditions when BEVs are charging. Criteria including maintainability, reliability, commercial availability, and performance need to be evaluated. BEVs have fewer components than diesel equipment and this correlates to lower overall maintenance costs, however, BEVs require maintenance personnel with specific skill sets in order to maintain the equipment. Battery lifecycle costs need to be considered as battery replacement incurs significant capital expense. Some manufacturers offer services to offset these capital costs through usage agreements. Recycling and disposal of batteries at the end of their lifecycles also need to be considered. With the increased selection of BEV equipment that will be available in the next 2-4 years, 100% BEV adoption is also possible. We recommend a holistic approach when evaluating BEVs for underground mines. This will ensure that everything is considered in order to evaluate the full impact of BEV implementation.

Jan 1, 2023

By Karl J. C. Harries

"7.1. INTRODUCTIONThis chapter addresses the joint venture and examines a number of general concepts of the joint venture relationship. Chapter 8 looks at some specific concepts related to the provisions of a joint venture agreement, which are equally applicable to a shareholders’ agreement or other contractual relationship. The term “joint venture” is used because the author is a common law solicitor (a matter of convenience for which apologies are offered to civil law readers), but it should be noted that, in many aspects, the legal structure of an entity is irrelevant. It is the relationship of the parties, be they venturers or shareholders, that is important, and the areas of concern are surprisingly similar (except for terminology).The details of the joint venture relationship and agreement could fill several books. Accordingly, this chapter and the next focus on selected topics that appear to have caused problems or confusion or to be the basis for disputes. And remember that, although the following discussion is in the context of a joint venture, many of the comments apply, either directly or indirectly, to virtually any common undertaking and the agreement defining it.For interest’s sake, this chapter starts with a summary of some of the earlier types of agreements and arrangements that have evolved into the joint venture agreement of today in Canada, the philosophy of their format, and the reasons for their demise.7.2. EVOLUTION OF THE CANADIAN JOINT VENTUREThe Early DaysMuch of the opening up of Canada’s north is due to exploration for and development of mines. The early discoverers were relatively free to roam and explore at will and, if they were fortunate enough to find something, they dealt with the appropriate government to acquire exploitation rights. The early interests lay in gold or silver. Workings were small, usually worked by the owner alone or with only a couple of helpers to extract the native gold or silver. If the owner wanted to move on, he could sell his property outright and use his stake to look elsewhere.As logging and mining camps were opened, the development of better roads and railways made access easier. Entrepreneurs saw the opportunity to make money by assembling large parcels of land and working them as a single operation. In order to do this, some owners who were not ready to sell out had to be convinced to do so through more attractive offers"

Jan 1, 2003

By T. H. Etsell, P. C. Holloway

Vanadium is concentrated in the fly ash which is produced as a solid waste from oil sands operations in northern Alberta. Although a process flowsheet using sodium chloride as a roasting reagent has been developed at the University of Alberta, recent studies examine the p otential o f p otassium o r c alcium s alts a s alternative reagents for roasting Suncor fly ash to recover vanadium. Suncor fly ash was roasted with CaO, Ca(OH)2, CaCO3, CaSO4.2H2O and KC1 at 750, 850 and 950°C. Water leach extractions for the calcium compounds were low (<45%); leaching with 100 g/L Na2CO3 gave maximum extractions of 56 to 69% at 950°C. Ash roasted with KCI behaved similarly to ash roasted with NaCl. These tests indicate that similar roasting conditions (25 to 30% KCI, 850°C, and 2 to 4h) could be used to achieve similar water leach extractions (75 to 85%). However, the lower solubility of KVO3 in solution, compared to NaVO3, would make the use of KCI instead of NaCl less attractive from a process and economic standpoint. Mineralogically, leucite (KAlSi3O8) was the predominant phase in ash roasted with KCl while, in crystalline samples of ash roasted with calcium compounds, anorthite (CaAl2Si2O8) and pseudobrookite (Fe2TiO5) were identified. Ash roasted below 950°C with the calcium compounds remained poorly crystalline.

Jan 1, 2004