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By T. C. Crosby

"Grinding has a marked effect on concentrator recovery and operating cost, and improved operation through automatic control can enhance plant performance. The correct application of automatic control can only be accomplished after the basic process variables and their effect on mill operation have been defined. This paper develops a control system for a closed circuit grinding system. Typical control systems, such as those for feed, water flow, level and circulating load, are discussed. A method of determining controllability, using the calculated reaction curve technique, is outlined. Various successful automatic grinding control applications are discussed and future possibilities are outlined. Although this paper primarily deals with closed wet grinding• circuits, the principles involved can be readily applied to other processes."

Jan 1, 1967

By Louis Frost

The coal-mining industry of Nova Scotia, particularly of the island of Cape Breton, today faced as no other industry with economic problems calling for progressive engineering with production on an economic basis, must soon enter upon a phase of reorganization wherein all factors conducive to the cost of producing coal relative to the prolongation of the life of the collieries with the ultimate winning of the maximum submarine area must be closely reviewed. Bearing this in mind and applying the process of elimination to coal-mining costs generally, we are left with only three channels through which we may approach the problem of cost reduction in producing coal: (a) intensive mechanization (b) reduction in the cost of labour (c) reduction in the cost of materials. Assuming that mechanization has reached an economic stage and that labour costs have reached an economic limit, we must turn our attention to the general material costs, which may be classified as 'live' and 'dead' costs. The former take in all things which can be accredited with a fractional depreciation and written off the balance sheet over a period of years. On the other hand, the ?dead'costs-of which the cost of supporting the underground workings form part must be completely written off: for these, no return may be expected, other than the economic return in the reduction of the cost per ton of coal produced.

Jan 1, 1928

By D. B. Dreisinger, M. R. Tavakoli

Vanadium has been produced from both primary and secondary sources having various compositions. Vanadium pentoxide and vanadium trioxide are the most available and known sources of vanadium oxides. In this paper, an overview of leaching both oxides has been reported. The problem of vanadium pentoxide leaching under acid conditions is the low solubility of the dissolved vanadium. This was investigated and then supplemented with further studies of leaching at mildly basic pH’s as well as under acid reductive leaching conditions (to form vanadium (IV)). Atmospheric oxidative leaching of vanadium trioxide was investigated using oxygen and ferric ion as the oxidant. It was shown that the leaching of vanadium trioxide using oxygen is very slow; however, ferric ion can dramatically increase the kinetics and leach efficiency.

Jan 1, 2014

By J. Petit, P. Girard, A-M. Gilbert, D. Faucher

L&apos;annee 2000 a été une année stratégique et significative pour l&apos; Aluminerie de Bécancour dans la réduction des gaz a effets de serre. L&apos; équipe s&apos; etait donne comme defi un jour d&apos;arriver a l&apos;objectif de zero effet d&apos;anode dans les sa11es de cuve (720 cuves au total). Le cha11enge s&apos;averait tres ambitieux car la fa<;on d&apos;alimenter une cuve d&apos;electrolyse pour obtenir son maximum de rendement faraday est de travailler le plus pres possible de l&apos;effet d&apos;anode pour eviter l&apos;embourbement de ce11es-ci. Ceci signifie que techniquement nous a11ons en moyenne, quotidiennement, 12500 fois pres de l&apos;effet d&apos;anode sur !&apos;ensemble de nos 720 cuves qui produisent aujourd&apos;hui environ 405 000 tonnes d&apos;aluminium liquide annuellement. Des 695 kg equivalent en C02 par tonne d&apos;aluminium produite en moyenne annue11ement, de 1990 a 2000, nous en sommes rendus ace jour a environ 35 kg equivalent en C02 par tonne produite. Nous sommes pres d&apos; atteindre notre objectif mais les demiers gains sont plus difficiles a atteindre. Les strategies d&apos;automatisme et d&apos;informatique, incluant l&apos;aspect de !&apos;implication humaine sur les bonnes pratiques de travail sur les cuves d&apos;electrolyse, sont les cles de ces resultats.

Jan 1, 2006

By T. Bednarski, T. McCallum, L. Moya, L. Nsenga, B. Mbao

The accumulation of solids in solvent extraction (SX) circuits can cause problems with the physical and economic performance of the operation. These solids are responsible for the formation of crud, a solid stabilized emulsion containing organic, aqueous, air, and fine solid particles. The build-up of crud in SX settlers can limit SX operation throughput, require plant downtime, lead to higher organic losses, or result in higher aqueous in organic entrainment (all of which can have a significant, negative economic impact). Current practices for crud management are typically reactive. Crud is physically removed after it has been allowed to build to excessive levels in the circuit and processed mechanically using centrifuges or filtration. A new proactive solution has been developed to prevent crud formation and build-up. Low ppm dosage of an additive, ACORGA® CR60, into the pregnant leach solution (PLS) has resulted in reduced crud formation in pilot and commercial scale for a variety of PLS streams. This paper will review results from operations in North America and Africa, covering heap leach, concentrate leach, and agitated leach feeds. INTRODUCTION Crud formation and build-up in solvent extraction (SX) circuits has been a long time topic discussed and claimed to be crucial to the whole hydrometallurgical process (Liu, et al, 2006). Crud formation is present in all SX systems be it copper, uranium, zinc, etc., and Ritcey (1980) defined crud as a stabilized emulsion containing organic, aqueous, and fine solid particles. The ore type and feed composition is a major determining factor of crud formation and typically contains Si, Al, Fe, P, and sulfates (Ritcey, 1980). It typically builds at the interface between the organic and aqueous, but can also be observed as floating crud on the surface of the settler, or bottom crud, which is common to find in circuits treating agitated leach feeds such as in Africa. As crud formation has been unavoidable, many of the current crud management techniques are reactive, allowing crud to form and build in SX circuits. Once it does, it is removed and treated via different mechanical techniques, typically through some type of filtration or three-phase centrifuge, to remove the solids and recover the organic phase trapped within the emulsion (Ritcey, 1980). Automated pumping systems have also been designed and are frequently used in North American operations. The time and capital required to react to crud formation can be an overwhelming aspect to SX operation.

Jan 1, 2019

By Ming’an Wei, Qifu Duan, Jianmin Wu, Lusheng Zhou, HMR Group Limited / HMR Technology Canada Ltd., Wenjian Wu

"The development and industrial applications of magnetic liners have been around for decades. A Swedish company Skega first introduced rubber magnetic liners, and then followed by the Chinese invention of metal magnetic liners. Traditionally, both liners were used in secondary ball mills and regrind ball mills for industrial applications, especially for ores containing magnetic materials. Mostly steel balls or equivalent forged steel balls, usually below 60 mm in diameter, were used as grinding media. With the development of mineral resources over the years, SAG mills and larger ball mills have become the dominating components for comminution circuit design. Due to the development of larger diameter ball mills and thus larger ball charge diameter (up to 80mm) especially in non-ferrous metal mining operations, the application of magnetic liners have been very limited. Based on “Magnetism theory” and the development of new materials, the HMR Group Limited has been conducting researches on examining the structures of magnetic liners, associated materials and magnetic circuits which led to the invention of the Nano Alloy Steel Magnetic Liner (NSML). Recently, NSML had a successful application in a 5.5 m diameter × 6.5 m ball mill at the Erdenet Copper Mine in Mongolia. The NSML successfully handled a ball size up of to 80 mm, while achieving a service life of nearly 24 months, which is almost 3 times wear life of the original manganese steel liners.INTRODUCTIONDuring the development and utilization of mineral resources, mineral processing is an indispensably operation. The effective separation of various useful minerals depends on sufficient monomer dissociation of minerals in the ores. The crushing and grinding operation is prior operation of mineral processing. Ball mills are used in different concentrators. As the main consumption parts of mill, liners have been studied constantly. As a new kind of liners, magnetic liners besides can meet the requirement of production, and also have characteristics with maintenance-free, saving energy and increasing efficiency. So the magnetic liners are worth to be spread and applied world widely."

Jan 1, 2016

By A. Warczok

Metal losses in discard slag are the main factor determining overall recovery. The metals are present both in dissolved form and as matte or metallic inclusions, varying in size from 2 to 1000 µm. Pyrometallurgical slag cleaning usually consists of heating the slag, reduction of oxides and settling of matte/metal droplets. Heating the slag decreases viscosity and accelerates reactions. Reduction of magnetite liberates inclusions and facilitates co-reduction of dissolved metal oxides. A significant amount of the matte and metal is present as very fine metallic inclusions, too small for settling. The coalescence of these matte or metal inclusions is required to remove them from the slag. The developed new concept of slag cleaning combines DC furnace technology with an extra magnetic field for vigorous slag stirring, enhancing mass transfer to the reductant surface, accelerating the rate of reduction, and destabilizing the emulsion of matte or metal inclusions. Intensive slag stirring increases the probability of collision of inclusions, will accelerate their growth and will therefore improve settling. The process is carried out in a patented DC channel furnace, where the liquid metal or matte layer acts as a cathode and the floating coke bed on the slag surface is the anode. In the first part of the furnace, a superimposed magnetic field induces a Lorentz&apos;s force causing the slag to start an intensive circular motion. The next furnace zone does not experience any stirring and is dedicated for quiet sedimentation of the inclusions. A mathematical model of gravitational coalescence combined with forced slag motion showed the possibilities of effective removal of copper matte inclusions. The results of laboratory pilot scale tests of continuous slag cleaning showed fast slag reduction and confirmed the improved matte removal from the slag. Conceptual analysis shows the potential use of the technology in various other non-ferrous industries, like for example nickel plants. It is also possible to use this technique batch wise.

Jan 1, 2007

By Zoltan Hajnal

Magnetic studies have been carried out on 88 surface and 157 underground samples from the Coronation Mine area of northern Saskatchewan. The intensity of the surface samples was compared to trace element determinations from the same locality. A good correlation was found between the titaniferous constituent of the rocks and the intensity of magnetization. From the direction of the remanent magnetism, two virtual geomagnetic poles were determined -latitude 12° 54&apos; North, longitude 158" 17&apos; West; and latitude 23" 42&apos; North, longitude 163° 45&apos; West. The sulphide ore specimens showed anisotropic susceptibility characteristics. A relationship was found between the measured maximum susceptibility values of the ore specimens and the direction of the tectonic forces which are considered to have formed the structure at the Coronation mine. Introduction T HIS paper summarizes the results of a study of the magnetic properties of samples from well-known Precambrian formations. The observed data give information for an interpretation of the magnetic field conditions in Precambrian times. The high magnetic intensity values indicate the importance of the study

Jan 1, 1965

By JOHN DUNFIELD

Good quality sphagnum peat bogs occur across Canada in areas of ample rainfall and cool, temperate climates. Early peat production techniques were restricted primarily to hand digging blocks of peat and piling them up to be dried by sun and wind. Suburban de velopment in the 1950s and the concomitant spread of home gardening triggered a dramatic growth in peat demand; labour costs rose in the same period. Peat production techniques had to alter accordingly. The three mechanical inno vations attempted were hydraulic mining, mechanical block digging and vacuum harvesting. Of these, the last method pro ved the most successful in Canada and is used to harvest 80% of Canadian peat production. Escalating transportation costs are the most important feature affecting future development of the Canadian peat industry.

Jan 1, 1984

By Redhead Robert J.

"In 1991, the Canadian Council of Ministers for the Environment (CCME) charged its Waste Management Task Group with developing a nationally coordinated strategy to measure, monitor, and achieve the objective of decreasing the generation of waste (solid and hazardous) by50% from 1988 levels by the year 2000.With the encouragement of the CCME, which viewed hazardous waste as largely an industry problem, a committee, the “Industry Action Group”, representing eleven industry trade associations with a strong interest and involvement in hazardous waste was recruited.The Municipality of Markham, Ontario was also recruited (Appendix 1)."

Jan 1, 1996

By W. B. Gallup

"The Athabasca Bituminous Sands have been subject to sporadic investigations since the beginning of the century. It is probable, however, that much of what has been learned and achieved concerning the deposit has been accomplished in the last few years.Current exploratory techniques, generally speaking, involve a moderate amount of coring. Electrologs and often radioactive logs are run on most holes and certain types of these archieved excellent qualitative analysis when backed up by some core analysis for calibration. Exploration - is moving back from the river and consequently a permanent network of access roads has been developed within the last few years. Most of the operations take place in the winter time. There are about 90 permit holders at the present time.Some exploratory techniques are set up to go into recovery experiments where rich tar beds are found. It is probable that in the final analysis there will be several successful methods of extraction and that both mining and various in situ techniques will be applicable depending upon the problem locally."

Jan 1, 1960

By Jr. Fackler

The ionization potentials of gaseous Group 11elements are similar, with Au(0) being 1.5 eV greater than the next highest member of the group, Cu(0). The ionization potentials are all very much greater than the alkali metals, making these ?coinage? elements rather unreactive to chemical oxidation. Ionization from the first oxidation state shows a different pattern, with Ag(I) being the most difficult of the Group 11 ions to lose an electron. Gold(I) is noble and only normally oxidized in the presence of strongly coordinating ligands such as thiols or cyanide. Gold(I) compounds are 2-, 3- and 4- coordinate, with 3-coordinate species generally showing visible photoluminescence under UV excitation. Dinuclear Au(I) compounds with strongly coordinating S or C ligands can be oxidized to form isolable metal-metal bonded Au(II) compounds which are often readily isolable. Many have been structurally characterized. T he ease with which electrons are lost from closed shell dinuclear sp ecies (with anti-bonding M-M interactions) increases when metalmetal bonded compounds are formed. T his observation was made by our group with oxidative-addition studies of dinuclear gold(I) ylide complexes. It was superbly demonstrated recently by Cotton?s group who reported the isolation and characterization of a dinuclear closed shell transition metal species which is more readily oxidized than cesium. Trinuclear Au(I) pyrazolates, TR(pz), carb eniates, TR(carb), and benzylimidazolates, TR(bz), are well known and undergo electron loss through oxidative addition forming Au(I,III) mixed valence species and ultimately trinuclear Au(III) species. Au(II) species are absent from isolation in these oxidations. These carbeniates and benzylimidazolates also are excellent bases for metals ions such as Tl(I) and Ag(I). The acidic, neutral trinuclear compound [Hg(C6F4)3]3 also interacts with these bases. We have also shown that the neutral organic pi acids C6F6 and TCNQ form stacked pi-acid pi-base products with the trinuclear Au(I) compounds. In this paper, the structure of the octafluoronaphthalene acid-base product will be described. It displays a feature not observed previously in that the product is photoluminescent with a bright yellow emission. The 3.5 ms lifetime is very long and reminiscent of the long lifetimes observed by Balch for the stacked methyl,methoxy Au(carb). The electrochemical oxidation of tetragold(I) clusters, [Au4(form)4] have been studied in 0.1 M Bu4NPF6/CH2Cl2 at Pt working electrode at different scan rates. Three waves are obtained at 0.75, 0.95, and 1.09 V vs Ag/AgCl at scan rate 500 mV/s. The potential of the three reversible waves is independent of the scan rate in the range 50 mV/s to 3 V/s. The current at the third wave is larger than those at the first two waves. These tetranuclear species app ear to be effec tive catalyst precursors for the oxidation in air of CO. Introduction. The electronic structural relationships of the coinage elements and the alkali metals are similar in the sense that each have a [closed shell]ns1 configuration, yet their ionization energies (Table) and chemistries are clearly vastly different. The Group 11coinage elements have an underlying nd10 level immediately below the ns1 level. Unlike the alkali elements, ionization leaves the filled d electron shell the next accessible for further ionization. The coinage elements are all relatively ?noble?, much less reactive to environm ental conditions than the alkali metals. With the coinage elements, oxidation becomes very much dependent upon the types of ligand s availab le to bo nd to the ionized state.

Oct 1, 2003

By N. Tassé

Les substrats organiques sont à la base des biofiltres utilisant la réduction des sulfates pour générer de l&apos;alcalinité et diminuer la concentration des métaux dans des effluents contaminés. Afin de tester l&apos;efficacité de résidus forestiers utilisés dans de tels contextes, cinq types d&apos;écorce de nature et d&apos;âge variables ont été placés dans des contenants hermétiques et mis en présence d&apos;une solution synthétique de drainage minier acide. Le pH, l&apos;alcalinité et les concentrations de Fe2+ et SO4 2- ont été mesurés à intervalles réguliers pendant 70 jours. L&apos;importance d&apos;un éventuel neutralisant minéral et du type de souches de bactéries sulfato-réductrices pour l&apos;initiation et l&apos;évolution des réactions d&apos;oxydo-réduction ont été évalués en utilisant de la dolomite ainsi que des inocula de sédiments portuaires réducteurs et de boues d&apos;usine d&apos;épuration. Une augmentation de pH et des diminutions de Fe2+ et SO4 2- ont été notées dans tous les réacteurs. En l&apos;absence de dolomite, le pH augmentait de 1.6 à 5-6, Fe2+ diminuait de 400 à moins de 5-100 mg/L, et SO4 2- diminuait de 2500 à 750-1250 mg/L. Les échantillons inoculés avec des sédiments s&apos;avéraient légèrement plus performants que ceux avec boues. En présence de dolomite, le pH atteignait 6.5-7.0, et Fe2+ et SO4 2- tombaient à <5 et 20-40 mg/L, respectivement. Le degré de réactivité des résidus forestiers n&apos;était pas une simple fonction inverse de leur âge. Les échantillons ayant le mieux réagi, bien que parmi les plus vieux testés (années 1980), étaient ceux contenant une proportion significative d&apos;écorces de feuillus et peu de bran de scie. Les échantillons avec des proportions élevées d&apos;écorce de conifères ou de bran de scie étaient associés à des taux de réduction moindre. Nonobstant l&apos;amélioration rapide des conditions obtenue avec la dolomite, grâce à une neutralisation initiale plus prompte, il s&apos;avère que le type de résidus forestiers éventuellement utilisé dans une barrière réactive est de première importance pour l&apos;efficacité des mécanismes de réduction. Un système basé sur l&apos;utilisation de résidus forestiers devrait utiliser des écorces (plutôt que du bois) provenant de feuillus (plutôt que de conifères).

Nov 1, 2002

By E. Landry, W. Naudts

"The amenability theory was developed by Alex Naudts and considers grouting operations as continuous permeability tests where Newtonian test fluid water, is replaced by a cementitious or solution grout. It utilizes hydraulic conductivity and grouting data to establish the amenability coefficient of a particular grout zone. The amenability coefficient reflects the quantity of apertures or voids accessible to the selected grout, divided by the number of apertures accessible to water, in the zone intersected by the grout hole. By calculating, in real time, the effectiveness of a particular grout at the start of a grouting operation, the most appropriate grout to match design criteria can be targeted. By incorporating the amenability theory in every grouting operation, schedule savings and an increase in productivity are typically achieved. Three short case studies illustrate different enhancements in productivity: At an underground mine during the construction of declines, a cement based suspension grouting program was highly ineffective and did not appear to affect the inflow into the mine workings. The amenability theory was utilized to evaluate the grouting program and based on this evaluation, changes to the grouting program were made which allowed the grouting to meet the project’s objectives. On another project, a pre-excavation grouting program implemented during shaft sinking operations utilized the amenability theory to select the most suitable grout for the program. Schedule constraints also influenced the selection of the grout. In the third case history presented, the amenability theory was used to select the grouting sequence of every individual grout hole for a grouting project in a highly heterogeneous soil formation. INTRODUCTION The amenability of a given soil, civil structure or rock formation for a particular grout formulation is a measure of the ability of that grout to permeate the pores, fissures and apertures water will flow through. The amenability coefficient of a particular grout for a specific zone equals the percentage of apertures, pores and fissures accessible by water that are also accessible by grout. Grouting should be viewed as a continuous permeability test, where the apparent in-situ hydraulic conductivity value for a particular grout zone is continuously evaluated, using grout instead of water as test fluid."

Jan 1, 2019

By Unknown

Diesel locomotives for underground haulage have been used in coal mines in Continental Europe for twenty-five years or more. In Great Britain, it was not until 1935 that permission was granted to use them in gassy coal mines, but since that time they have been employed in increasing numbers both in gassy and non-gassy coal mines and in metal mines. Their use underground in coal mines in the United States is still prohibited and the same was the case in Canada until 1946, when permission was granted to operate a Diesel underground in the Adanac mine of West Canadian Collieries, Limited, at Bellevue, Alberta. The locomotive used here is a 50 h.p. Hunslet Mark II. More recently, a 100 h.p. Diesel was placed in operation for underground haulage at No. 18 Colliery of the Dominion Steel and Coal Corporation, in the Sydney coalfield, N. S. Thus, on this continent, Canada has been a pioneer in the use of these locomotives underground in coal mines and there is no doubt that more and more of them will be employed as time goes on. We feel, therefore, that the following notes concerning their design and performance, which we have received from the High Commissioner for the United Kingdom, will be of interest to our members.

Jan 1, 1949

By C. H. Bucknam

Net carbonate value (NCV) characterization methods for acid generation potential measurement originated from studies on the Carlin Trend during the 1990&apos;s and have been subsequently standardized through cooperation of the Acid Drainage Technology Initiative Metal Mining Sector and the American Society of Testing and Materials International. The paper describes the evolution and standardization of the NCV methods, the importance of mineralogy in interpreting the results and application of the methods to implementation of the Global Acid Rock Drainage (GARD) Guide.

Jan 1, 2011

By Yi Yang, Mark Zoback

"We report laboratory studies of the time-dependent deformation of core samples from four different formations in the Williston Basin - the Lodgepole formation, the Middle and Lower Bakken formations and Three Forks formation. The laboratory tests reveal varying amounts of viscoplastic deformation in response to applied differential stress. The time-dependent deformation is generally greater in rocks with higher clay and organic content, and can be described by a power-law function. Because the magnitude of the creep strain is linearly proportional to the applied differential stress, we can utilize viscoelastic theory and geophysical logs to estimate the degree to which tectonic stress is affected by viscoplastic stress relaxation. We suggest that viscoplastic stress relaxation results in the Upper and Lower Bakken Formations act as frac barriers during hydraulic fracture stimulation in the Middle Bakken, but the Lodgepole and the Three Forks Formations are not frac barriers.INTRODUCTIONHorizontal drilling and multi-stage hydraulic fracturing in shale reservoirs are critical for successful exploitation of ultra-low permeability shale gas, tight gas and shale oil reservoirs. Characterization of the mechanical properties of the reservoir rocks is essential to understanding the behavior of rocks during drilling and completion. Previous laboratory studies have shown that the timedependent deformation in clay-rich shales can be characterized as linear/viscoelastic deformation (Chang et al., 1997; Hagin and Zoback, 2004a, b; Sone and Zoback, 2013b, 2013c). Sone and Zoback (2013c) showed that laboratory measurements of time-dependent deformation in various gas shale reservoir rocks, and demonstrated that the viscoplastic deformation of these rocks can be characterized by a power-law function. They interpreted the results in the framework of linear viscoelastic theory to quantitatively assess the geomechanical effect of viscous time-dependent deformation over engineering and geological time scales. (Sone and Zoback, 2014) further extended the theory and proposed a viscous relaxation model that can be applied to predict the continuous differential stress magnitude using the geophysical logs. They tested the validity of their model by comparing the stress prediction with the occurrence of drilling induced tensile fractures (DITFs) and the vertical hydraulic fracture penetration observed from microseismicity."

Jan 1, 2015

When selecting a method for monitoring crack growth in pipeline steel, the sensitivity or crack-size resolution plays a dominant role. Even though there are several visual and non-visual methods, the direct current potential drop (DCPD) method is very effective for monitoring crack growth because of its resolution. This method has been used for the past few decades and has gained increasingly wide acceptance in fracture research as one of the most accurate and efficient methods for monitoring the propagation of cracks. Furthermore, most R&D experience has proven that the electrical potential method can be used in most "aggressive" environments. For these reasons, the DCPD method was selected to design a testing machine to monitor corrosion fatigue crack growth. The use of finite-element modelling is shown to facilitate the application of the DCPD method for monitoring crack growth in steels. The 2D model calibration provided a good description of the test data and proved more accurate than the analytic Johnson&apos;s formula.

Jan 1, 2005

By Maxime Tacher

BRP (Bombardier Recreational Products) designs and commercializes recreational vehicles such as watercrafts, sport boats, snowmobiles, ATVs... The Spyder roadster is the last product in the Can-Am product family lineup. To remain at the forefront of innovation, a hybrid motorization version of the Spyder is being developed in order to reduce fuel consumption and emission of greenhouse gases. But, the addition of electric components (e-motor, lithium-ion battery... ) raises the issue of added weight and volume. This article deals with the mass reduction of this Spyder by optimizing its frame.

Jan 1, 2011

By T. T. Chen

The iron- and elemental sulphur-rich residues generated during batch and continuous pressure oxidative leaching of Inco Limited&apos;s Voisey&apos;s Bay nickel sulphide concentrate at 150°C in sulphate-chloride media have been characterized by X-ray diffraction analysis and scanning electron microscopy. The residues produced during the continuous leaching of the pentlandite- and pyrrhotite-rich concentrate consisted predominantly of hematite and elemental sulphur, with minor amounts of goethite. Although the iron species generated in the batch leaching tests were similar to those formed during continuous leaching, the morphologies of the hematite and goethite particles were significantly different. In addition to the tiny spheroids and bubble-like particles, the hematite and goethite generated during batch leaching occurred as larger "hollow" shell-like particles that contained residual pentlandite or sulphur cores. Although the leach solution from which the iron oxides had precipitated contained 5-15 g/L sodium, sodium jarosite was detected only in trace amounts in a few of the leach residues.

Jan 1, 2006