Search Documents

By D. C. Carter

"The Nova Scotia Department of Mines and Energy located a drillhole at Riverside Corner, Hants County, Nova Scotia, to examine the stratigraphy, structure and potash potential of the Kennetcook River gravity low. This evaporite-related gravity anomaly is one of the largest virtually unexplored gravity anomalies in Nova Scotia. The drillhole intersected a structurally complex sequence o flower Windsor Group ('B' Subzone) evaporites. Downhole geophysical wireline logs were used, in conjunction with detailed lithological descriptions, to interpret the structure and stratigraphy of the sequence. Similar application of total gamma ray, density, caliper and neutron-neutron log responses allows stratigraphic correlation of Windsor Group carbonate marker units separated by up to 35 km in Cape Breton. This work confirms the value of downhole geophysical logs as a tool in the exploration of evaporite deposits regardless of the presence or absence of high quality core. INTRODUCTIONThe exploration methodology for evaporite (specifically salt/potash) deposits in eastern Canada (and worldwide) is relatively simple: identify a negative gravity anomaly within a favourable geological setting, Windsor/Cordroy Group sediments in eastern Canada, and drill it (Anderle, 1980). Although this is an obvious oversimplification of the necessary expertise in the planning and complet ion of an exploration program, those familiar with potash exploration drilling can attest to the risks and expense, in terms of time and problems , associated with the location and drilling of diamond-drill wildcat holes. Potash exploration programs in eastern Canada, their results and inherent difficulties, have been documented by Anderle et al. (1979), Cooper (1981), Dekker (1982), Carter and Boehner (1986), Carter (1988) and Carter and Anderle (in prep .).Downhole geophysical wireline logs have become an important tool in the stratigraphic and structural interpretation of evaporite sequences in eastern Canada and, in many cases, represent the only information recovered or the only information available due to the drilling method (rotary) and/or the long term instability of evaporite cores. This paper documents examples of downhole geophysical log responses which, combined with detailed lithological examination of drill core, or in the absence of core, are used in the interpretation of the complex lithology and structure of a deformed evaporite deposit. Geological and geophysical data from the Nova Scotia Department of Mines and Energy (NSDME) Riverside Corner 85-1 drillhole are presented here as a partial case history and prime example of the use of this method to interpret the complex structure of an evaporite deposit. Drilling of NSDME Riverside Comer 85-1 was conducted in late 1985and early 1986by the Department (Carter and Boehner, 1986) under a program to assess the potash potential of selected areas of the province as part of the Canada-Nova Scotia Mineral Development Agreement 1985-89. A reinterpretation of a portion of the available data from two exploration drilling projects on Cape Breton Island in the Canso-Bras d'Or area is also presented (see inset, Fig. I). Several drillholes have intersected the Windsor Group evaporite sequence in these areas and the available geophysical logs are a valuable tool in the interpretation of the structure of the deposits. However, no attempt has been made to present or discuss the detailed geological investigation and comparison of these two deposits. They are presented here as an example of the reinterpretation of existing data and their application to stratigraphic correlation and structural interpretation of complex evaporite deposits. Further work is necessary to document the stratigraphic and structural correlation of these two areas."

Jan 1, 1989

By Jean-Paul Drolet

"The ultimate aim of the Law of the Sea Conference, held under the auspices of the United Nations, is to ensure that all aspects of the use of the sea are covered by international law. The question facing the nations of the world can be stated as: "" Who will control and benefit from the use and the wealth of the sea?""The United Nations Conference on Law of the Sea - known as UNCLOS - which reconvened in New York during the latter part of August 1978 was the third such Conference in the UN's history. The concepts of sovereignty over the territorial sea and freedom on the high seas have remained fundamental to the international law o f the sea until our time. The legal regime based on these two concepts developed initially from state practice meant that the unilateral actions taken by one or more countries were eventually accepted and followed by others.It was not until 1958, during the first Geneva Conference on the Law of the Sea (pursued in a second Conference in 1960) that the Law of the Sea was codified and modified to a certain extent by the then independent nations of the world in the four multilateral conventions on territorial sea and contiguous zone, continental shelf, high seas, and fishing and conservation of living resources.A third Conference got under way many years later when the members of the UN met in New York at the end of 1973 for preliminary discussions . This meeting stemmed largely from the need to fill gaps in existing international legislation which did not cover the new uses of the sea. The Conference was subsequently reconvened a number of times - in Caracas (1974), in Geneva (1975) and twice in New York (1976) for what was called "" substantive negotiating sessions."" A sixth session was held in New York in 1977; a seventh, held in Geneva at the beginning of 1978, recessed and reconvened in New York at the end of August 1978. This is what is referred to, in international jargon, as the seventh session of the Third United Nations Conference on the Law o f the Sea. The following dates are the principal markers of a saga which began some twenty years ago with the purpose of regulating the use of the oceans."

Jan 1, 1981

By R. G. Bradbury

The paper uses two hypothetical, but typical, situations to show that hydraulic rock drilling equipment has very significant economic advantages over pneumatic equipment both in drifting applications (even in the situation where advantage is not taken of the high productive capacity of the hydraulic drill) and production drilling applications. Other factors, including the non-economic advantages and the disadvantages of hydraulic drilling, are discussed. The paper concludes with a brief analysis of why the Canadian mining industry has been slow to take advantage of this apparent broadly advantageous advance in rock drilling technology.

Jan 1, 1979

By L. Kong, V. G. Papangelakis, L. Li

"The Eh-pH diagram of lithium-titanium-water system at 25°C, 100 °C and 200 °C was constructed. It shows that there exist thermodynamic stability areas of Li2TiO3. This indicates a thermodynamic possibility for the formation of Li2TiO3 in aqueous solution. A hydrothermal process has been applied for the preparation of Li2TiO3 using TiCl4 and LiOH•H2O as raw materials. The prepared samples were examined with X-ray diffraction, scanning electron microscopy and thermo-gravimetric analysis and differential scanning calorimetry. The results show that temperature and washing condition have significant effects on the phase composition of the product. Phase-pure Li2TiO3 powders were obtained at 200°C with Li:Ti molar ratio of 2.0.INTRODUCTIONLithium-containing ceramics enriched in 6Li, such as Li2O, LiAlO2, Li4SiO4, Li2ZrO3 and Li2TiO3, are considered as tritium breeding materials (Saito et al., 1998; Roux et al., 1998; Johnson et al., 1998; Hoshino et al., 2002). In view of its admirable properties: low-activation, good thermal stability and thermal conductivity, excellent tritium release performance and reasonable lithium atom density (Kopasz et al., 1994; Roux et al., 1996; Saito et al., 1998; Wu et al., 2008), Li2TiO3 is recognized as one of the most promising candidates of tritium breeding materials. Meanwhile, Li2TiO3, as the precursor of H2TiO3-type lithium absorbent, receives more attention as the development of extracting lithium from salt lakes (Zhong, 2004; Zhang, 2010).Several synthetic techniques have been applied to prepare Li2TiO3 powders, such as solid-state methods (Lulewicz and Roux, 2002; Ramaraghavulu et al., 2011; Mandal et al., 2012), sol-gel processes (Deptula et al., 2002; Lee, 2008) and solution combustion routes (Cruz et al., 2006; Jung et al., 2006; Sinha et al., 2010). A solid-state method may produce a series of problems, including impurity contamination and difficulty in morphology control of the obtained powders, although the process involved is simple. The solgel process is prolonged and usually demands for multi-step reactions, while solution combustion route requires plenty of energy and easily causes product contamination by the fuel used. Owing to its environmentally benign and highly suitable characteristics in fabricating materials, hydrothermal technology has been widely used and became a powerful tool in the field of material synthesis (Yoshimura and Byrappa, 2008). For example, ZnO in the form of bulk single crystals, fine particles and thin films, which is an attractive photoelectric material, was successfully synthesized by hydrothermal process (Sekiguchi et al., 2000; Ohshima et al., 2004). A hydrothermal technique was also used to the preparation of carbon nanotube, which possesses outstanding mechanical, structural and electric properties (Bernholc et al., 1997), and is superior to the commonly used method (Gogotsi and Libera, 2000). There, it provides an option for preparing Li2TiO3. Laumann et al. (Laumann et al., 2010) synthesized cubic a-Li2TiO3 by hydrothermal reaction at 180 °C for 18 h, using TiO2 powder, comprising of anatase and rutile, and lithium hydroxide in de-ionized water. However, the prepared a-Li2TiO3 is extremely unstable with a maximum lithium loss of 75% when treated in bathing experiment."

Jan 1, 2012

By A. A. Levinson, M. B. Kirkley, J. J. Gurney

"Scientific advances in the past decade have greatly clarified our understanding of certain concepts relating to the age and origin of diamonds. These advances are largely the result of geochemical studies of mineral inclusions in diamonds, made possible by modem analytical techniques which enable the accurate chemical analysis of micro-sized particles of the order of 200 microns in maximum dimension. As a generalization, the inclusions indicate that most diamonds formed from either of two rock types, peridotite and eclogite. Peridotitic diamonds have yielded ages of 3300 million years, whereas eclogitic diamonds areyounger and rangein agefrom approximately 1000to 1600million years. Kimberlite and lamproite, the two rock types usually associated with diamonds, typically are much younger than the diamonds they contain. Thus, it is now dear that kimberlites and lamproites are only the transporting mechanisms which brought diamonds to the surface and are in no way related to the formation of most diamonds. The latest concepts which developed during the past decade regarding the sources of carbon for the crystallization of diamonds from peridotite and eclogite, and the mechanisms of kimberlite and lamproite emplacement, IntroductionThe decade of the 1980s has seen major advances in our understanding of the age, origin and emplacement of diamonds. The information presented herein is applicable to virtually all natural diamonds, excluding diamonds related to meteorite impacts. There is still some question, however, as to the applicability of the new information to industrial grade ""fibrous"" or ""coated"" diamonds, and to microdiamonds (< 1 mm). In addition to drawing upon our own experiences, this review is summarized from a voluminous literature and for those interested in the original sources we recommend the books by Mitchell and Bergman (1991), Ross (1989), Nixon (1987), Mitchell (1986), Glover and Harris (1984) and Dawson (1980), and the review articles by Mitchell (1991), Gurney (1989) and Meyer (1985).are also discussed."

Jan 1, 1992

By D. G. Osborne

"The paper describes current &apos;tools&apos; available to the coal preparation engineer for carrying out the evaluation of data, process design, selection of equipment and layout and design of coal preparation plants.Laboratory and pilot-scale equipment is widely available and test data can be used to provide valuable design information regarding capacities and sizing for specific applications. Pilot plants, unless they fit closely to the basic design envisaged for the eventual commercial plant, C(In often provide only limited useful information.Computing aids such as equipment simulation, plant modelling, etc. are becoming widely applied for establishing design criteria and investigating flowsheet options . Other computer tools such as computer-aided design systems are taking over some of the time-consuming tasks of detailed layout and design and estimation of quantities, etc. and providing the means for detailed examination of more than a single option.Besides computer modelling there is also physical modelling of plant buildings, plant sites and entire proposed mining areas; the former can be especially useful in finalizing design and threading&apos; pipework and electrical reticulation systems through the plant without the resultant risk of impairment of flow, obstruction or wastefulness. Not the least of the benefits of plant models is the assistance provided for training new operating and maintenance staff."

Jan 1, 1985

By V. S. Sastri, G. R. Doey, R. W. Revie

"Different forms of corrosion, the various corrosive environments encountered, the mining equipment subject to corrosion and the methods to control corrosion in the mining industry are briefly reviewed along with the savings that could be achieved by corrosion control. IntroductionCorrosive conditions in mines and metallurgical plants, lead to deterioration and wastage of equipment and of materials. The cost of corrosion in the mining industry can be significant, and measures to minimize corrosion must be taken to reduce this cost(l-3). Although the data in Table I are twenty years old they indicate the significance of corrosion costs in four industrialized countries. The costs of corrosion in the U.S. metallic ores sector and in the Canadian mining industry are presented in Tables 2 and 3, respectively. Significant savings in the mining industry can be achieved by using corrosion control methods. For example, corrosion in the Canadian mining industry in 1991 cost $1460 million of which $97 million was avoidable. Indirect costs of corrosion associated with plant shutdown, lowered efficiency of equipment and overdesign are additional to the direct costs cited here."

Jan 1, 1994

By Guoxiang Chi

Hydrocarbon fluid inclusions entrapped in diagenetic minerals may be used to constrain hydrocarbon exploration models in two aspects. First, the distribution of different types of hydrocarbon inclusions in different tectonostratigraphic domains, and their relationships with organic matter maturation levels may reflect a regionalscale variation in the thermal regimes of the hydrocarbon systems. Second, the relative timing of hydrocarbon inclusions in the diagenetic history may provide constraints on the evaluation of reservoir potential. This paper summarizes the distribution of hydrocarbon inclusions in four different Paleozoic tectonostratigraphic domains in eastern Canada, discusses its implications on hydrocarbon systems in the different domains, and finally provides two examples to show how the relative timing of hydrocarbon inclusions may be used in the evaluation of reservoir potential. Oil inclusions mainly occur in host rocks that are within the oil zone, although some are found in units in the condensate zone. Light hydrocarbon inclusions occur in the dry gas zone, and methane inclusions were found from dry gas zone to anchimetamorphism zone. This correlation between hydrocarbon inclusions and host rock maturation implies that the hydrocarbons were derived from source rocks having a maturation level broadly similar to the host rocks. Although the Paleozoic rocks are generally relatively poor in reservoir quality, the two examples provided in this paper show that in some stratigraphic units, significant secondary porosities could have existed prior to some hydrocarbon migration events, thus favoring the accumulation of hydrocarbons.

May 1, 2001

By Steve Piercey

Introduction ? VMS Deposits: The Target ? Key points for every belt: heat flow and extension. ? Good felsic rocks ? Good mafic rocks. ? Petrochemical assemblages. ? Summary Key Points Throughout ? Common themes: ? Heat ? driver of the hydrothermal system ? Extensional geodynamic setting ? conduits to focus fluid flux ? (e.g., Lesher et al., 1986; Swinden et al., 1991; Barrie et al., 1993; Lentz, 1998; Syme et al., 1999; Piercey et al., 2001, etc.) ? We must identify rocks, belts and tectonic environments that encompass these two criteria (among others but?) ? e.g., forearc rifts, intracontinental rifts, arc rifts, and back-arc basins.

Apr 1, 2005

By P. R. A. Andrews, R. K. Collings

"There are more than thirty-five deposits or occurrences of celestite in Canada, chiefly in Newfoundland, Nova Scotia, New Brunswick, Ontario and British Columbia. Deposits of economic interest are the Lake Enon and MacRae deposits in the Loch Lomond district of Cape Breton Island, Nova Scotia. Two Cape Breton deposits were operated from 1969 to 1976 by Kaiser Celestite Mining Limited, which supplied an upgraded celestite concentrate to an associated strontium carbonate plant at Point Edward, near Sydney.The MacRae deposit is of current interest because of its possible development for strontium carbonate production using the ""black ash"" process. This process involves chemical leaching, rotary kiln calcining with petroleum coke, washing and treatment with carbon dioxide.Celestite is the basic material used in the manufacture of strontium chemicals, principally strontium oxide, carbonate, nitrate, chromate, chlorate, chloride, sulphide and phosphate. Strontium chemicals, in turn, are used in the manufacture of glass and ceramics, in pyrotechnic devices, in the production of strontium metal and in other metallurgical applications. Recently, strontium ferrites have been introduced into permanent ceramic magnets."

Jan 1, 1991

By H. R. Butler

"The Ontario Division of Inca Metals Company, a Unit of Inca Limited, operates eleven mines, four mills, three refineries, one smelter and one iron ore recovery plant. All but one mine, mill and refinery are located within a fifty kilometer radius of Sudbury, Ontario. A mine-mill complex is located some 100 kilometers west of Thunder Bay on the shore of Lake Shebandowan and a nickel refinery at Port Colborne.During the past 10 years the use of recycled water in our milling operations has increased to more than 95% at each mill. This high degree of water reuse has reduced the (a) need for fresh water and (b) the contaminant level of the downstream aquatic environment. The aggregating of effluents in a common receptor provides a process water having a consistent quality thereby minimizing upsets in mill metallurgy while concurrently improving the operating economies and the downstream aquatic environment."

Jan 1, 1980

By F. J. Hrach, S. A. Gasiorowski, J. D. Bittner

"Separation Technologies, LLC (ST) has developed a processing system based on triboelectric charging and electrostatic separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. In contrast to the other available electrostatic separation processes that are typically limited to particles greater than 75 µm in size, the ST belt separator is ideally suited for separation of very fine (<1 µm) to moderately coarse (500 µm) materials with very high throughputs.. The technology has been also successfully applied to the beneficiation of a variety of minerals including calcium carbonates, talc, and potash. TECHNOLOGY OVERVIEWThe ST separator utilizes electrical charge differences between materials produced by surface contact or triboelectric charging. When two materials are in contact, material with a higher affinity for electrons gains electrons and thus charges negative, while material with lower electron affinity charges positive. This contact exchange of charge is universally observed for all materials, at times causing electrostatic nuisances that are a problem in some industries. Electron affinity is dependent on the chemical composition of the particle surface and will result in substantial differential charging of materials in a mixture of discrete particles of different composition.In the ST separator (Figures 1 and 2), material is fed into the thin gap 0.9 – 1.5 cm (0.35 -0.6 in.) between two parallel planar electrodes. The particles are triboelectrically charged by interparticle contact. For example, in the case of coal combustion fly ash, a mixture of carbon particles and mineral particles, the positively charged carbon and the negatively charged mineral are attracted to opposite electrodes. The particles are then swept up by a continuous moving open-mesh belt and conveyed in opposite directions. The belt moves the particles adjacent to each electrode toward opposite ends of the separator. The electric field need only move the particles a tiny fraction of a centimeter to move a particle from a left-moving to a right-moving stream. The counter current flow of the separating particles and continual triboelectric charging by carbon-mineral collisions provides for a multistage separation and results in excellent purity and recovery in a single-pass unit. The high belt speed also enables very high throughputs, up to 40 tonnes per hour on a single separator. By controlling various process parameters, such as belt speed, feed point, electrode gap and feed rate, the ST process produces low carbon fly ash at carbon contents of 2 % ± 0.5% from feed fly ashes ranging in carbon from 4% to over 30%."

Jan 1, 2012

By N. Shi, T. G. Joseph

ABSTRACT A revised equilibrium approach to evaluate dipper-ground interactions during the dig cycle of ultra-class mining shovels operating in soft unblasted uniform ground conditions is presented. A review of previous approaches, leading to an outline of the modifications and ground condition considerations, is made in support of the reasoning and basis for the derivation presented. An analytical solution is provided to the scenario of a cable shovel dipper digging in soft ground material such as oil sands.

Jan 1, 2012

By Sukumar Bandopadhyay, Arunapuram Sundararajan

"For the last three decades, the application of network planning has provided a basis for a formal and general approach to the discipline of project management. For fixed activity duration, a very simple algorithm commonly known as critical path method (CPM), gives the length of time required for the total project as well as indicates the activities which are vital to the completion of a project. Project Evaluation Review Techniques (PER T) on the other hand, generalize the above approach to recognize uncertainty in the activity durations by allowing them to be random variables. One of the misleading aspects of current "" PER T"" solution method is, however, the implication that there is a unique critical path. In general, any number of paths could be critical, depending on the particular realization of the random activity durations that actually occur. In this case, simulation can be utilized to estimate completion time of a project.In this paper, the concept of criticality indexing is discussed, and a simulation model application which defines the critical path based on the criticality indexing concept, to a longwall development - extraction network, is presented. The model also provides suitable scheduling of resources based on the resource constraints and smooth s out period-t o-period assignments. IntroductionThe successful management of large-scale projects require careful planning, scheduling , and coordinating numerous interrelated activities. To aid in these task s, formal procedures based on the networks and network techniques (variously called PERT or CPM) were developed. In its original form the completion time for individual activities of a project was assumed fixed and known in advance: this in turn led to the familiar algorithms for computing the critical path, earliest start time, slack, and so forth. The unreality of such an assumption is, of course , apparent in many contexts. Consequently, attempts were made to introduce probalistic activity completion times, allowing representation of the stochastic nature of most projects."

Jan 1, 1987

By Robert B. Parsons

"This article addresses the relationship between mine evaluation, the tax system, and economic risk. It is based on a paper presented by the author at recent seminars in Moscow and Tashkent on the subject of mine evaluation.IntroductionTaxation can have a strong influence on the feasibility of a mining project. For the most part, because metal prices are determined on a global basis, the mining concern is not able to pass on to its customers any portion of taxes which the concern has to pay. Taxes are a direct charge against the project. The purpose of the article is to highlight the various ways whereby different taxes can affect the financial viability of a mining operation.The first part of the paper identifies different forms of taxation, and the second part of the paper addresses the different forms of taxation in terms of risk analysis and impacts on the mining project. Finally, the third part of the paper makes brief mention of using the taxation system to provide incentives with respect to investment in mining activities."

Jan 1, 1993

By S. Flewelling, M. Scobie, G. R. Baiden

"SynopsisA feasibility study to develop a research program, the Mine Automation Plan (MAP), was recently completed. This was undertaken by a team comprised of Inco Ltd., Falconbridge Limited, the Canadian Centre for Automation and Robotics in Mining (CCARM) and the Centre for Resource Studies (CRS). The study was sponsored by PRECARN Associates, which is a consortium of thirty-six Canadian companies focussed on research and development in artificial intelligence and robotics. PRECARN Associates was formed in 1987 when a number of research proposals were funded in the fields of process control systems, robotics systems and intelligent engineering systems. In July 1991, PRECARN accepted the next round of proposals for research. The MAP project was one of the successful proposals, being awarded $100,000 for the development of a feasibility study defining a long-term R&D plan for underground hardrock mining automation.The development of the feasibility study started by addressing the fundamental structure of the mining process, and its relationship to the metallurgical process, over-all infrastructure support and management systems (Fig. I).Mining may be considered as comprising five subprocesses: (I) delineation; (2) development; (3) production; (4) backfilling; and (5) infrastructure support services. Within these subprocesses many applications for artificial intelligence and robotics exist. The mining process is dependent upon the interaction between the physical mining process and information. For example, the delineation process is dependent on geomechanical, geochemical and geophysical techniques to develop a model of the orebody based upon access to such data. This same relationship between the physical and information models holds true through the development, production, backfill and infrastructure support systems.The foundation for the MAP study has been the recent development by Inco Ltd. of an underground communications system (Fig. 2). The system has the ability to supply high bandwidth communications, over voice, data and video to mobile and stationary locations within the mining operation. It is seen to be the future backbone of a comprehensive, automated information system which should permit the application of the concept of Computer Integrated Manufacturing (CIM) to underground mining. CIM, through the automated flow of information, has been successful in integrating the engineering, production and various support groups in manufacturing."

Jan 1, 1994

By Leroy G. Hagenbuch

"IntroductionAn integrated Truck Management Information System (Truck MIS) evolves as seemingly separate functions combined to yield a single homogeneous result / product. The concept of a computer integrated Truck MIS includes truck dispatch, truck maintenance management and truck weighing.A truck management system is only as good as the information / data bases input to it. The concept of an integrated system works best with automated data gathering. Automated data gathering provides timely and normally, the most accurate historical information/data bases. Data bases are, however, historical, which is a problem to be overcome in a computerized truck management information system, especially in regards to a truck dispatch system as loading sites / loading conditions and some dump site conditions continually change. As these changes occur, data base s must change as well, and thus the need for the continual update of data bases that the computer uses for a Truck MIS.For a truck dispatch system to achieve reliability / viability, dispatch decisions need to revolve around real time data gathered in an automated way. Integration of all truck management function s through automated data gathering lead s to the best over-all system.An integrated system is a combination of many different factors and is only as good as each factor / building block put in the system. With the proper building blocks, an integrated Truck MIS is very feasible - an MIS System that includes weighing, time and motion study, truck maintenance and maintenance management, as well as truck dispatch.Truck MISAn integrated Truck MIS provides for truck dispatch as the ultimate end result, a truly automated /integrated truck dispatch system (to function non-operator-dependent). The following comprises its central building blocks:-Time.- Haul Cycle Segments.Truck Status, i.e. Load on truck,- being loaded,- loaded,- unloaded,- in service,- out of service.- Vehicle Location.Loading Equipment Status.- in service,- out of service.Optional- distance travelled in each haul segment.With this data provided on a non-operator dependent basis, it is possible to build good data bases so a computer can make truck dispatch decisions. Knowing what information is needed as the central core to a good Truck MIS, how can this information be automatically gathered and fed into a central control computer?"

Jan 1, 1986

By Alan G. Galley

"Advances in our knowledge of the petrochemical attributes of deposit environments and of the character and extent of hydrothermal systems associated with certain deposit types has resulted in increased application of lithogeochemistry to exploration programs. Lithogeochemistry can be used to vector an exploration program toward an area of high potential through the use of a series of collapsing scales of analysis from a tectonic subprovince down to a particular stratigraphic segment. In the case of volcanogenic massive sulphide (VMS) deposits this involves the recognition ofsuitable volcanic domains, and the identification of subvolcanic intrusions and cogenetic felsic extrusive complexes. The recognition of chemical vectors within regional-scale alteration zones and associated chemical sedimentary rocks allows the geologist to identify the stratigraphic units with the most potential for hosting a base metal deposit.An integrated lithogeochemical program requires the judicious use of major, trace and rare-earth element and isotopic analysis. Standard discriminant plots may be employed to identify suitable tectonic and lithologic environments. Analysis of the chemical and mineralogical variations in broad-scale, semi-comfortable alteration zones provides a useful set of vectors to VMS mineralization. These may include contouring raw data, element ratios on XY plots, normalizing data against known rock values, or calculating mass changes in alteration zones."

Jan 1, 1995

By C. T. Dzgoev, S. S. Gudkov, IRGIREDMET JSC, S. G. Schtoick, A. V. Yepiforov, S. V. Balikov, I. I. Yevtuschevich

The pressure oxidation (POX) and pyrometallurgical process comprises POX of gold containing sulfide and polymetallic lead-zinc concentrates prior to reduction smelting of POX products to generate a lead-silver-gold alloy. Refined lead and gold-silver alloys are then obtained using conventional processes. Zinc and other base metals are recovered from the POX solution. In the course of POX, zinc dissolves in the solution and lead concentrates in a solid residue in the form of sulfate compounds. Sulfur forms the major iron sulfates and jarosites. In order to dissolve sulfur and arsenic from solid residues to the solution, the slurry hot curing was carried out at the temperature of 95°C within 2 hours. After filtration of the slurry, zinc was recovered from the solution. The resulting cake was washed with water and subjected to hot alkaline treatment. After alkaline treatment, the cakes were blended with fluxes and subjected to reduction smelting to generate lead concentrate containing precious metals. This concentrate was refined to obtain refined lead and gold-silver alloy. After iron and arsenic were removed from POX solutions using sodium carbonate, zinc was precipitated as carbonate. After thickening and filtration, zinc precipitate was roasted to generate saleable zinc oxide. Using this process, the recoveries of values to saleable products were 97% Au and 95% Ag to the alloy, respectively, 91% Pb to refined lead and 5% Pb to lead and antimony alloy and 94% Zn to zinc concentrate. The features of the technology is that it has high recovery indices of precious and base metals to saleable products and can be used to process various polymetallic ore and technogenic raw materials.

Jan 1, 2016

By A. C. Headon, K. W. Lam, D. P. Dautovich

"Microbiological activities affecting the performance of materials have been encountered in diverse situations within Ontario Hydro. Case histories of bacterial problems which are presented include ground rod corrosion at transformer stations, corrosion of a bare steel cooling water intake structure in Lake Huron and corrosion of steel components in a nuclear generation station vacuum building. Possible microbiological activities which may affect the corrosion behaviour of containers for the disposal of nuclear fuel waste in the future are discussed, as are bacterial actions suspected of causing an odour problem in residential water heaters.IntroductionBacteria are ubiquitous. Except by use of sterilization methods, bacteria -free environments are no t possible to find. Bacteria lie dormant in hostile environments, spread easily through air and water currents and reproduce rapidly under favourable conditions. Although different types of bacteria have different preferable conditions for growth, they are highly adaptive and in general, whenever there is a source of water and carbon (carbon dioxide or organic matter), there will be bacterial activities . These activities often induce or enhance costly metallic corrosion in industries and water odour problems in rural water supplies . Underground structures and systems in contact with natural water or water containing organic matter are most susceptible to bacterial attack.The types of metal-degrading bacteria , their characteristics and the conditions for growth have been reviewed extensively in the literature(1,2,3). There are several often encountered groups of bacteria which, through their metabolic processes, may lead to the degradation of metals. A large variety of bacteria produce corrosive in organic or organic acids as waste, such as the well known formation of sulphuric ac id by aerobic sulphur oxidizers . Anaerobic sulphate reducers produce hydrogen sulphide which is corrosive and has an obnoxious smell, slime-forming bacteria from slime which shelters sulphate reducers and iron bacteria oxidize ferrous to ferric ion which precipitates as hydrated oxides creating oxygen concentration cells . The following are bacterial problems encountered in Ontario Hydro. Although the number of recognized cases has been few, they show the diversity of location and environment where bacterial problems could arise. These include ground rod corrosion at transformer stations, corrosion of bare steel in a water intake structure, corrosion of steel in a nuclear generation station vacuum building and an odour problem in residential hot water tanks. In addition, possible bacterial- enhanced corrosion in containers for future disposal of nuclear fuel wastes are also discussed."

Jan 1, 1984