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By P. Abachi

Cemented carbides or hard metals that generally consist of hard tungsten carbide and a tough metal binder such as cobalt are important in many segments of the world economy, ranging from automobile related components to machining, cutting, and drilling tools. For metal cutting operations such as turning and milling, replaceable cemented carbide inserts are frequently used. The exposure of inserts to very severe conditions (e.g. temperatures as high as 1000°C) in combination with very high loads, limits their lifetime. When the tools and components are scrapped, they are collected with a view to recovering the tungsten carbide and cobalt due to both their environmental aspects and their strategic importance. In this work, a selective electrolysis process was used for recovery of WC powder particles from cemented carbide scraps. The WC-10Co and WC-10Co-VC up to 3 wt.% VC was produced using powder metallurgy route. The mean particle size of WC, Co and VC were selected as 2.5, l.5 and 2.2 µm respectively. Referring to electrochemical curves of WC-10Co cemented carbides in hydrochloric acid solutions with different concentrations, the recovery rate was enhanced in IN acid. Therefore, this solution was selected for recycling of all samples. The surfaces of as-produced and corroded specimens were investigated using a scanning electron microscopy (SEM). Detection of corrosion products was provided by energy dispersive spectrometry (EDS). According to results, the selective electrolysis process could be useful in the recycling of scrap carbide materials, although more studies should be undertaken on economical aspects of the process and the quality of samples produced using recovered powders.

Jan 1, 2005

By A. Piche, J. Nantel

"This paper describes the recent developments in Canada toward the establishment of a Canadian Centre for Mining Automation and Robotics, at McGill University and École Polytechnique in Montreal. The role of the Mining Association of Canada (MA C) and of the National Advisory Committee on Mining Automation will also be reviewed. IntroductionIn order to remain competitive, the mining industry must increase its productivity and reduce its costs. In the last two decades, this objective has been achieved through mechanization. From now on, any further improvement in productivity will be gained through increasingly more automated mining equipment.Recent international developments following the Versailles Economic Summit in June 1982, having given rise in Canada, to a renewed interest in applications of robotics and automation to mining.The mineral industry in Canada is at a crossroads. Competition in emerging from everywhere: lower grade ore bodies, increasing distances between viable mines and markets, third world massive production of certain commodities, substitution of "" space age"" materials (ceramics, plastics, composites, etc.) for metals.On the positive side, it is generally believed that present mineral commodities, i.e. base metal, gold, iron, industrial mineral s, etc ., will continue to be in high demand for centuries to come despite substitution. New applications for conventional metals will be found and the enhancement of certain properties of these conventional metals mean continued demand. For some mineral commodities, there will never exist an y substitute."

Jan 1, 1988

By Jean-Luc Collins

"This new tool can be used as a quick guide f or the assessment of the potential economic wealth of any risky capital project. It does provide an unambiguous recommendation of the type ""go or no go"" to the decision-maker simply by comparing two different ratios profit/investment. One ratio determines the minimum value required to at least break even while the other measures a probable value based on the asymptotic theory of statistical extremes.Its application is briefly illustrated by means of an underground gold mine extension project, an oil sands mine project and a polymetallic open pit project.Once a favourable recommendation has been obtained then a detailed ""cash flow after taxes"" analysis can be carried out for the project.IntroductionMany tools are used in financial decision-making such as the payback period, the discounted cash flow, the internal rate of return and the wealth growth rate (Berry , 1971).These tools are useful and meaningful in evaluating normal projects closely related to regular business where the number of assumptions made is usually very small and where the cost of capita! is usually selected as a discount rate or a hurdle value. In situations where a significant number of assumptions have to be made,two problems can emerge, namely:I. the risk involved is underestimated leading to a potential financial disaster; or2. a good opportunity is lost because the approach used in evaluating the project is too conservative.Each assumption has its own degree of uncertainty and it is well known that combining uncertainties together can lead to a total uncertainty of critical proportion. The easiest way to account for risk is to increase the discount rate or the hurdle value, but this approach alone is quite subjective and can easily lead to the problems described above."

Jan 1, 1993

By W. S. Szolga, M. Moser, M. D. Soderstrom, L. Cohen

"CYANEX® 272 is a phosphinic acid-based solvent extraction reagent used commercially since the early 80’s to recover and purify cobalt from sulfate solutions. Historically, the design of CYANEX 272 circuits has involved the selection of an optimal pH profile during pilot-scale testing using mixbox pH control. The desired pH profile is required to be carefully controlled in the same manner during commercial operation. To assist operators in the design and optimization of their circuits, Solvay developed CYANEX 272-specific solvent extraction modeling software, which has enabled determination of the ideal pH profile and staging configuration. Solvay’s recent advances in modeling capabilities have allowed the simulation of circuits without direct mixbox pH control. Modeling has indicated that circuits operated without direct pH control can achieve the desired metal separation while simplifying the commercial operation significantly. This paper reviews a number of potential circuit configurations for the use of CYANEX 272 and demonstrates the separations achievable under the right design and operational conditions, some of which have historically been considered too difficult.INTRODUCTION CYANEX® 272 is a phosphinic-acid based reagent designed specifically for the separation of cobalt from nickel by solvent extraction from weakly acidic sulfate solutions (Rickelton, Robertson, & Burley, 1982; Rickelton, Flett, & West, 1984; Rickelton & Nucciarone, 1997). Following commercial introduction in the 1980’s, CYANEX 272 has been used in a number of hydrometallurgical flowsheets for cobalt purification and/or recovery. CYANEX 272 metal extraction occurs by means of a cation exchange mechanism. Extraction of a divalent metal ion M2+ is represented by the following equation where RH represents the CYANEX 272 ligand and MR2 represents the ligand-metal complex."

Jan 1, 2017

Introduction A Hypothetical Scenario: Suppose that your company's research department has developed a new device which represents a significant innovation. You would like to begin selling it as soon as possible. The new device has not been publicly disclosed. You're not sure about what type of intellectual property protection you should be seeking, or when you should be seeking it. As discussed below, assuming that the costs are worth it, a patent application probably should be filed before any public disclosure is made. In general, if you do not file a patent application prior to a public disclosure, you will lose rights. Major Types of Intellectual Property In this paper, intellectual property protection is broadly discussed. Practical steps which can be taken to minimize the possibility of losing intellectual property rights (and maximizing the possibility of benefiting from your company's intellectual property) are outlined at the end of this paper. The issues discussed in this paper are somewhat complex, because a number of outcomes are possible, depending on the facts. It is strongly recommended that you seek legal advice in your jurisdiction in connection with any particular circumstances relating to intellectual property rights. "Intellectual property" refers to a number of different types of rights. The major types of intellectual property are: (i) patents; (ii) trademarks; and (iii) copyright. Trade secrets are also usually considered to be a type of intellectual property, and they are also discussed in this paper because of their importance. In general, each of these types of intellectual property protects different subject matter, although there can be some overlap. Intellectual property rights are generally territorial in nature. The scope of protection of a type of intellectual property in a country (e.g., patent protection) depends on whether the specific national requirements for protection have been met.

Feb 1, 2008

By Robert B. Parsons

"The last edition of Tax Notes expressed concern about two proposed tax changes in Finance Minister Paul Martin's 1995 budget that could have detrimental effects on Canada's mining industry. This month, Tax Notes expands on these concerns. This article is based on a paper that the author presented at ClM '95 in HalifaxIntroductionOn a global basis, there are more investment opportunities in the mining industry today than at any other time in history. Countries in Central and South America, Eastern Europe, the CIS, Central Asia, and Asia are competing aggressively to attract investment to all sectors of their domestic mining industries. Today, the demand for investment dollars exceeds the amount of dollars that are available for investment in mining. It is not surprising, then, that the established mineral producing nations are witnessing a decline in spending on exploration and development on their home turf, and an increase in spending in developing countries. In the context of a developed country such as Canada, there are two manifestations of the problem of declining investment: (I) Foreign investors are allocating more of their capital budgets to new opportunities in developing countries; and (2) Canadian juniors and seniors are spending proportionately more abroad. This shift in global spending patterns is the source of some concern for the future of Canada's mining industry, particularly because it is widely believed that the current rate of discovery of ore reserves in this country is too low to replenish depleting reserves.""Government bashing"" has always been a popular pastime in Canada. Invariably, this pastime has focussed, at !east in part, on taxation. In view of the intense competition that Canada faces on the global mining scene, it is important that the role of taxation in the decision-making process be kept in perspective. This paper seeks to put the role of taxation into perspective."

Jan 1, 1995

By M. S. King

"A simple method is proposed for determining the long-term deformation behaviour of evaporites. The theory developed can be tested by measuring the change in diameter as a function of time of a vertical mine shaft opposite evaporite strata. Ultimate shaft closures predicted by the theory agree well with those calculated with the very much more complex theory of Serata (1968), provided that sufficiently high octahedral shear strengths are used in the former.An analysis of measurements made in an isolated opening in a Saskatchewan potash mine shows that the octahedral shear strength of the surrounding potash and halite was approximately 500 psi several years after the opening was mined. This value is less than that deter-mined experimentally for halite by Serata. The same data indicate, furthermore, that the in-situ octahedral shear strength is decreasing slowly with time.The current controversy regarding the actual deformation of evaporites will only be resolved by the cooperation of potash producing companies in releasing data on the long-term deformation of their mine shafts."

Jan 1, 1971

By G. S. Barry

INVESTIGATIONS to date have shown that, should there be the need or the appropriate economic stimulus, Canada's mineral resources are sufficiently extensive to allow considerable expansion of its non-fuel mineral industry, during the remaining part of this century and possibly beyond (1, 2). The availability of sufficient capital will be one of the critical factors which will determine whether this potential will be fulfilled. The following analysis centers on the capital requirements of the Canadian non-fuel mineral industry under one set of basic assumptions of capacity growth, cost of new and replacement capacity, rates of depletion and depreciation of mines and plant, and the cost of exploration and infrastructure. Mindful of the fact that exploration and development will not thrive in Canada unless a very positive approach is taken, the writers make no apologies for being "optimistic" about long-term production prospects. Furthermore, in the event that world demand does escalate as anticipated and the forecast realistically attainable levels of Canadian production are not reached, then Canada will not have reaped the full range of economic benefits available, and opportunities will have been lost. Projections for Canadian production between 1976 and 2000 are essentially based on the forecast published in the 1974 paper, "Towards a Mineral Policy for Canada - Opportunities for Choice (3), with some updating on the basis of recent developments.

Jan 1, 1977

By Haibin Ma, Jie Song, Qingyou Han, Xiaoming Wang, Wei Vian

In the grain refinement of aluminum, Al3Ti and TiB2 particles are introduced to reduce the casting grain size down to 200 micrometer level, which makes cold working possible. The particles are brought in by the addition of Al-Ti-B type master alloys. It is generally believed that TiB2 particles are stable and nucleate a-Al grains in solidification in the presence of extra titanium than the stoichiometry of TiB2 from the dissolution of Al3Ti particle in the master alloys. Titanium in solution either form Al3Ti layers on the surface of TiB2 particles or as solute to promote the nucleation and to restrict the growth of a-Al grains. However, a consensus on a grain refinement mechanism is still to be reached due to the lack of direct observation. This paper presents finding on the TiB2/Al3Ti interfaces in an aluminum matrix. It demonstrates a strong epitaxial growth of Al3Ti on the surface of TiB2 particles, a sign of the formation of an Al3Ti layer on the surface of TiB2 particles in grain refinement practice. The Al3Ti layer has a crystal coherency with a-Al and hence offers a substrate for heterogeneous nucleation of a-Al grains.

Jan 1, 2015

By J. E. Dutrizac

Mercury balances have been obtained for the flotation circuits at Pamour Porcupine Mines, Timmins, Ontario, and at Brunswick Mining and Smelting Corporation, Bathurst, New Brunswick. The mineral form of mercury in both deposits has been ascertained. At Pamour Porcupine, the mercury is approximately evenly divided among sphalerite, native silverelectrum and tetrahedrite-tennantite; at Brunswick Mining, this element is contained mostly in the sphalerite, although tetrahedrite (and possibly pyrite) also contains minor quantities.

Jan 1, 1979

By Laxman M. Amaratunga

Laboratocy flarmnability tests were perfonned on dust samples from Fraser Mine in a 1.2 L Lindenburg horizontal tube furnace to detennine the percentage of sulphur oxidized during ignition. The explosion pot ential of sulphide dusts depends on their degree of spontaneous oxidat ion, which was measured by the quantitative analysis of so2 gas released during ignition. Test results indicated that dusts with low sulphur content could exhibit a higher degree of oxidation than a sample with high sulphur content. txlst characterisation using image analysis techniques suggests that the structure and the texture of dust are important factors influencing the explosibility of sulphide dust at ignition temperatures. Therefore for safe mine operations% sulphur content cannot be considered as a reliable single index that could be used to predict the potential of a sulphide dust explosion. Physical, chemical and mineralogical characterisation of dust plays an important role in the detennination of suitable indices for the prediction and prevention of sulphide ore dust explosions.

May 11, 1988

By P. L. Schwartz

The present method of shipping potash to the myriad of consumers is inefficient, not only because of the extreme and unpredictable nature of seasonal demand, but also because railway car turnaround times are very lengthy. The Floating Train system employs unit trains of potash operating from Saskatchewan mines to distribution warehouses located throughout the six corn-belt states of Minnesota, Iowa, Wisconsin , Illinois, Indiana and Ohio, transshipment points at Thunder Bay and the U.S. waterway network, and, where applicable , large consumers. These unit trains would "float", meaning that they would not originate at the same mine nor terminate at the same warehouse on each trip . They would " float " freely among the origins, destinations and participating railways. The potash would be shipped uniformly throughout the year and usually stored in warehouses located within the six states. It would be subsequently delivered to consumers within a 75-mile radius. Distribution warehouses and rolling stock would be provided by a new company, Potash Distribution Limited, consisting of major potash producers and the Canadian railways. Potash Distribution Limited would be responsible for the distribution of potash from the origin through the warehouses to the final consumer. The additional costs of providing warehouse space and outbound delivery will be offset by the reduction in both rail rates and "peaking" expenses.

Jan 1, 1978

By Noel Brien, O&apos

General: National Asbestos Mines Limited has operated an asbestos mine and mill near Thetford Mines, Quebec, since 1958. As a result of additional exploration of the orebody in 1962-63, it became apparent that long-range mining plans would have to be revised to allow for a large increase in both ore and waste tonnages. It was decided that the task of checking out possible mine designs could best be analyzed by a computer to obtain data from which an optimum open-pit configuration could be plotted. Object: It was desired to arrive at an optimum open-pit configuration with an over-all pit slope of 45 degrees and a minimum operational width of 200 ft. at the bottom. Calculations were based on assay values from diamond drill holes in cross sections of the mine. The computer's assignment was to select and describe, by coordinates, the optimum cross section for the mine. Mine engineers then assembled the various optimum sections to produce the pit outline. As this would not necessarily result in a practical mining arrangement, the computer also provided alternate solutions,

Jan 1, 1965

By M. Staite

This paper analyzed the feasibility of converting a 5kW natural gas SOFC power generator system designed to operate on natural gas to be fuelled by methanol. The analysis included laboratory methanol fuel processing experimentation, methanol reformate SOFC cell testing, and SOFC system mass and energy balance modelling. Methanol fuel processing experimentation indicated that theoretical reformate compositions can be achieved for high temperature (600-900°C) methanol steam reforming. A 6% open circuit voltage decrease and a 10% peak power current density decrease between cell operation on humidified hydrogen and methanol reformate was observed. SOFC system mass and energy balance modelling indicated that a natural gas SOFC system can be converted to operate on methanol fuel with minimal (1%) efficiency impacts, however the systems' thermal integration can be impacted.

Jan 1, 2005

By Lloyd F. Dunham

"Crucial to the implementation of new computer-based information systems at Sudbury Operations of Falconbridge Limited was a data communications network that would take computing power to the various mine and plant sites. Falconbridge required a capability to provide on-line data entry, inquiry, and reporting capabilities in three geographical areas, six mines, two mills, a smelter, approximately fifty shops, seven warehouses and numerous administrative offices throughout the Sudbury basin.Conventional cabling methods were rejected based on the projected cost of installation of necessary cables; lack of flexibility to meet the changing requirements of the mine environment; and the risk of losing service to an entire area depending on solitary communication lines.Instead, Falconbridge selected and installed a Data Carrier System (DCS) and Packet Switching Communication System from Teltone Limited, Markham, Ontario. This combined system ""piggy-backs"" computer data over voice-grade twisted pair wire, bringing data to the associated PBX equipment. From there data packets are assembled and routed to the central computer site where they are disassembled for entry into the host machine.Falconbridge has been successful in using existing technology to solve communications problems in a difficult environment. Plans for the future of this network will increase its utilization for technical and real time data communications in addition to the business systems workload it now handles. The Computer Services group in Sudbury is confident that the data highway will handle communications traffic well into the future.IntroductionIn late 1984, the Sudbury Operations of Falconbridge Limited undertook a review of their existing business computer systems. The results of this review indicated that there was an opportunity to improve the timeliness and quality of information coming from the existing computer-based systems while achieving an investment payback by undertaking the project. The greatest benefits from this project would be achieved if the computing tools could be delivered to the employees that were the day-to-day users of the data. Falconbridge's existing business systems were oriented to the batch mode of processing. An alternative solution to using the existing programs had to be found."

Jan 1, 1988

By A. Ansari

Standard depressants used in the selective separation of copper and molybdenum sulfides by flotation pose environmental and health hazards. In this investigation, the floatability of chalcopyrite and molybdenite in the presence of six well-characterized lignosulfonates was studied through Hallimond tube flotation and adsorption tests. The results define the physicochemical conditions (lignosulfonate type and dosage, pH, presence of ions) for possible selective separation of molybdenite from chalcopyrite. Dissolved polyvalent cations, especially calcium, appear to serve as "activators" for lignosulfonate adsorption on both minerals. From this point of view, the use of lime as a pH modifier is not always appropriate for optimum selectivity since high dosages of lime to produce high pH tend to indiscriminately depress both sulfides.

Jan 1, 2006

By P. A. Riveros

This paper describes the leaching of the common copper minerals tennantite (Cu12As4S13), tetrahedrite (Cu12Sb4S13) and enargite (Cu3AsS4) in acidic media using Fe(SO4)1.5, FeC13 or 02 as oxidizing agents. At temperatures <100°C, tennantite dissolves slowly in Fe(SO4)1.5-H2SO4 media, and the rate is directly proportional to the area of the sized tennantite. The rate increases sharply with increasing temperature and the apparent activation energy is 69 kJ/mol. Increasing Fe(SO4)1.5 concentrations slightly increase the tennantite leaching rate. The kinetics of dissolution of disks of synthetic iron-bearing tetrahedrite in Fe(SO4)1.5-H2SO4 media are linear; the leaching rates are slow but increase significantly with increasing temperature, with an apparent activation energy of 120 kJ/mol. The dissolution of sized particles of natural Ag-bearing tetrahedrite in FeC13- HC1 solutions proceeds according to the shrinking core model, and both Cu and Ag dissolve at about the same rate, provided that the total chloride concentration of the solution is sufficiently high to solubilize the AgC1 reaction product. The leaching rates are slow, and the apparent activation energy is 116 kJ/mol. The addition of sulphate ions to the FeC13-HC1 system reduces the tetrahedrite leaching rate to values similar to those realized in the Fe(SO4)1.5-H2SO4 system. At <100°C, enargite dissolves slowly in either Fe(SO4)1.5 or FeC13 media, and the dissolution rate obeys the shrinking core model. The rate increases with increasing temperature and the apparent activation energies are 50-64 kJ/mol. The rate increases slightly with increasing FeC13 concentrations in 0.3 M HC1 media. The leaching of enargite at elevated temperatures and pressures was also investigated. Potentially useful leaching rates are achieved above 170°C, at which temperature sulphate, rather than sulphur, is produced. Lower temperatures (130-160°C) lead to fast initial leaching rates, but the dissolution of the enargite is incomplete because of the coating of the enargite particles by elemental sulphur.

Jan 1, 2007

By T. G. Sitharam, Resmi Sebastian

"Wave propagation studies across jointed rocks have significance in the fields of rock mechanics and geophysics. The passage of a seismic wave induces strains in rocks and often, these strains are of low magnitudes except at the vicinity of source. These low magnitude strains are generally in the elastic range and hence elastic constants necessary for the design and analysis of strength of rock mass, can be derived from wave velocities. Measurement of travel time velocities and measurement of resonance frequencies are the two methods usually adopted for obtaining wave propagation velocities.Resonant column apparatus measures wave velocities from the resonant frequencies obtained during testing. Depending on the type vibration applied, torsional or flexural, shear and compression wave velocities are secured. By varying the amplitude of vibrations applied, various strain levels can be introduced and corresponding resonant frequencies and wave velocities can be calculated. The resonant column experiments were performed on a model material, hardened Plaster of Paris (POP) samples, in laboratory. The paper explains the preparation of samples and the working mechanism of resonant column apparatus along with the estimation of wave velocity from resonant frequency. The numerical simulation of resonant column apparatus using distinct element method and its validation with the experimental results are presented in the paper.A distinct element code is usually used to simulate the movement of materials with intersecting discontinuities. Finite rotations and displacements of individual blocks representing the material are permitted and new contacts between the blocks are identified as the calculation progresses. Three dimensional Distinct Element Code (3DEC), the software intended for the numerical simulation of rock engineering projects, can well simulate the behavior of jointed rocks under static and dynamic loading conditions. The numerical simulation of resonant column apparatus has been performed with 3DEC considering its efficiency in modeling jointed rocks.The numerical modeling of the resonant column apparatus with application of torsional and flexural vibrations to the sample is elaborated in the paper. The response of samples to a range of frequencies is obtained and the frequency that induces maximum displacement in the sample is measured as the resonant frequency, for any particular strain level. The displacements measured at various points of the sample during application of vibrations are compared and presented. The numerical modeling of resonant column apparatus with an intact sample (without joint) and a sample with a joint incorporated are explained at a particular strain level. The resonant frequencies obtained from laboratory experiments and numerical simulations are compared and illustrated. It has been found that resonant frequencies obtained using numerical and laboratory experiments are in good comparison and can be extended for various strain levels and sample conditions."

Jan 1, 2015

By Seong-Ho Ha, Shae K. Kim, Young-Ok Yoon

In the this study, surface segregation of Mg and Ca with Mg addition range from 5 to 10wt% in Al-Mg alloys with Mg+Al2Ca master alloy and its effect on the oxidation resistance were investigated. The addition of Mg+Al2Ca master alloy as the Mg alloying element led to the surface enrichment of Mg and Ca during high temperature oxidation. As a result of the oxidation test by TGA, the oxidation resistance of all the examined alloys was significantly improved with increasing Al2Ca content. The weight change of Al2Ca added Al-5Mg and Al-7.5Mg alloys indicated the complete oxidation resistance during the whole oxidation test time, while a slight weight increase was shown in the case of Al-Mg alloys even with Al2Ca addition. The improvement of the oxidation resistance in Al2Ca added alloys may be attributed to the formation of the protective oxide layer mixed with CaO and MgO on the surface.

Jan 1, 2015

By Keith Jones, Largo Albert

"Decelerometer testing of a rigid guide system in a mine shaft pro vides usefuI information to operating and maintenance people. High acceleration/deceleration rates can lead to high maintenance costs to bath conveyances and shaft and can also present an operating risk . Possible disastrous results in the shaft have been avoided by restricting the maximum conveyance speed until the shaft and/ or conveyance problems have been solved.The test instrument is a valuable aid especially during commissioning or updating of a hoisting installation. High acceleration/deceleration rates also lead to reduced hoist rope life. During the past fourteen years, a total of 15,000,000 feet of testing was performed in 74 assorted shaft compartments.Based on this experience, it is possible to establish acceptable conveyance maximum speeds provided that all other conditions in the shaft compartment are normal. The body of the paper will present examples of several tests made under actual operating conditions.IntroductionMore and more mine operators are recognizing the real value in the use of the decelerometer for determining the state of shaft guide alignment in their shaft compartments , not only during the initial mine start-up periods, but also on a regular basis while the mine is in production.Decelerometer testing, is a technique in which an accelerometer , commonly known as a decelerometer, is used for measuring conveyance acceleration/deceleration in a lateral plane. lts purpose is to determine the severity of shock loads produced by misaligned shaft guides. Testing is performed by mounting the instrument on the conveyance and operating the conveyance (empty and loaded) at various speeds up to and including full speed . However, full speed may not be attained due to conditions indicated by the tests. These conditions may present an operating risk to the plant."

Jan 1, 1984