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By R. B. Sudderth, A. Quiroz G., M. Torres M., C. Salgado Q., J. Fernández O., H. Bravo P., M. Torres B.

SNF FloMin, Inc. has introduced a complete line of extractants for recovery of various metals. Among them are the CuPRO MEX™ Brand of copper extractants that are based on the well- known 2- hydroxy 5-nonylsalicylaldoxime and 2-hydroxy acetophenoneoxime. This paper presents the laboratory and pilot plant trial results for SNF FloMin’s CuPRO MEX™ 3302 reagent, the equivalent to the wellknown ACORGA® M5640 extractant, and the composition of these reagents are described. Some examples of SNF FloMin’s CuPRO-Sim™ Advanced solvent extraction simulator are presented.

Jan 1, 2014

By Andrew Dobson, Cheryl Allen, Enrique Acuña

"Totten Mine return air raise was designed with two parallel fans equipped with silencers to reduce the noise emitted from the outlets into the environment. As development and production of the mine progressed through the past years, the silencer system needed to be upgraded, and additional maintenance strategies have been necessary to meet the regulatory noise limits enforced by the province of Ontario. The current mine plan will require the fans to reach the upper limit of their capacity by Q1 2019. To achieve this operational target, additional silencing capability has been required and Totten Mine has explored alternatives to further extend the noise silencing capacity available considering the current constraints at the mine site. The alternatives included a new silencer baffle design and a new layout that have allowed doubling the length of the silencer system. Using acoustic measurement data collected on several occasions, this paper presents and discusses the performance of the various silencing systems which have been installed on the return air fans at Totten Mine.INTRODUCTION Vale Canada Limited’s Totten Mine is a base metal, underground mine extracting nickel and copper, situated in the Sudbury Basin of Ontario. The mine initiated operations at the end of 2013, and is equipped with two main return air fans and two main fresh air fans located on surface. Both fresh air and return air fans are set in a parallel arrangement to operate as integrated units and are equipped with variable frequency drives (VFDs) to allow for the remote modification of their operating set point, usually between 600 to 880 rpm, depending on the mine’s requirements. The main return air raise (RAR) fans are also equipped with dissipative baffle silencers to attenuate the noise emitted to the environment. Approximately four years ago, acoustical measurements conducted to verify compliance with the applicable regulatory criteria, and respond to noise concerns from neighboring residents, concluded that the sound emissions of the main return air raise exceeded the noise design parameters. The acoustic tones of the fans were audible offsite, at a residential location, approximately 9 km northeast of the mine site. The elevated sound levels and offsite audibility was due to degradation of the original discharge silencers from moisture and particulate being drawn from underground workings and passing through the silencer baffles. The audibility was also due to an outlet directivity pattern which directed noise towards the residential location."

Jan 1, 2019

By Manqiu Xu, Pete Winn, Steve Wilson

"In the flotation of ultramafic ores at Thompson mill, Inco Limited, CMC is used as both a floatable rock depressant and electrostatic serpentine slime dispersant. CMC, being a high molecular weight polymer, creates a serious handling problem in its introduction into the flotation processes. Typically, it is added as a 1-3% solution. This requires an enormous handling facility and makes its metallurgical gains uneconomical.Laboratory studies have shown that dry CMC addition as opposed to wet addition is feasible, as long as sufficient conditioning time is provided. Dry CMC addition into the grinding mill is also possible but its effectiveness is slightly reduced as compared to dry addition after grinding mills. Dry CMC addition using a vibratory feeder into the mill discharge is successfully applied in the treatment of ultramafic ores at Thompson mill.INTRODUCTIONManitoba Division MineralogyAt Inco’s Manitoba Division, two distinctly different sulphide ores are processed at the Thompson mill - primarily by froth flotation. The Thompson and Birchtree mines are both located within the Thompson Nickel belt. Sulphide mineralogy is relatively simple and includes both hexagonal and monoclinic pyrrhotite, pentlandite and minor chalcopyrite hosted in metasedimentary and metavolcanic rocks. The significant difference between the two mines is the amount of ultramafic rock associations in the host material. Increasingly, more of the ultramafic associated ores from the Birchtree mine are being processed through the mill with a characteristic poor metallurgy."

Jan 1, 2000

By T. Orser

In 2010 Newmont made the decision to purchase a 42 foot (ft) Semi-Autogenous Grinding (SAG) mill from Metso and a 28 Mega-Watt (MW) Gearless Mill Drive (GMD) from ABB for the Conga Project in Peru. The test and study work showed that a single line 42 ft SAG mill circuit gave the most favorable project economics in comparison to an equivalently powered single line 40 ft SAG mill circuit. This paper does not address the process design or the project economics, but instead focuses on the key aspects of the SAG mill design, GMD design and the associated component manufacturing. This paper also addresses, where applicable, the potential reliability differences between the initially proposed 40 ft SAG mill and the finally accepted 42 ft SAG mill.

Jan 1, 2012

By E. L. C. Martins, M. J. Nicol, D. Majuste, A. D. Souza

The effects of organic compounds on the current efficiency (CE), morphology, crystal structure and mechanical properties of the metal deposited during the electrowinning of zinc are described. A flotation collector and lubricating oil were selected based on observations made during the industrial production of zinc from silicate ores, in Brazil. The analysis by Fourier transform infrared spectroscopy of these compounds, which may be present in minor amounts in the electrolyte solution, indicated the presence of a polar amine group in the collector, while the lubricating oil is a non-polar compound. The average CE value obtained from organic-free industrial solution was 91.15 ± 0.26 %. The CE dropped to 54.35 ± 0.73 % in the presence of 100 mg·L-1 of collector in the solution, and a negative effect was also observed in the presence of similar amounts of oil (88.84 ± 0.61 %). The characterization of the deposits by scanning electron microscopy and X-ray diffraction revealed the formation of pores in deposits obtained from solutions containing the oil, while a different growth pattern (perpendicular zinc platelets) was identified when the flotation collector was added to the industrial solution. In the presence of these contaminants in the solution, guided-bend tests revealed that the deposits have a higher resistance to deformation, but lower ductility, properties that may affect the performance of the stripping stage. As a result of this work, simple control and optimization actions were applied in the industrial plant, which resulted in important improvements in the electrowinning process.

Jan 1, 2014

By M. Labrie, H. L. Gibson, G. Doiron, J. J. Watkins, D. H. Watkinson

The Corbet deposit is one of 17 proximal Cu-Zn massive sulfide deposits located. within the Noranda Cauldron which occurs within the core of the Noranda Volcanic Complex. The deposit is located at the top of the Havrian Formation, the lowermost formation of the 3000 m thick Mine Sequence; the deposit has Yielded 2.75 M tonnes of ore grading 3% Cu, 0.96% Zn, 2.06 g/t Ag and 1.0 g/t Au. The multi-lens Corbet deposit formed within a 250 m wide crater that occurs within a localized breccia pile. The Corbet breccia pile was constructed by explosive magmatic and hydrovolcanic eruptions localized along the south flank of a larger andesitic shield volcano that formed during the waning stages of Havrian volcanism. The breccia footwall of the deposit allowed unfocused and widespread hydrothermal discharge that resulted in the development of a large area of chlorite and fringing sericite alteration that exceeds, by six times, the size of the sulfide lenses and represents a significant exploration target.

Jan 1, 1993

By F. Hassani, R. Mikaeil, B. Ferdowsi

Two analytical solutions for estimating the ovaling deformation and forces in circular tunnels are widely used in engineering practice, due to soil-structure interaction under seismic loading. This paper discusses the discrepancy between the two analytical and finite difference methods. A comparison of the two analytical methods shows that the calculated forces and displacements are identical for the condition of full-slip between the tunnel lining and ground. However, the calculated lining thrusts differ by an order of magnitude when considering no-slip between the tunnel lining and the ground. The analytical solutions are compared to numerical analyses of the no-slip condition using the finite difference method to validate which of the two methods provide the correct method. To achieve the goal, numerical modelling, field data of the Kuhin railway tunnel and Manjil earthquake characteristics are used. Numerical analysis results agree with one of the analytical solutions that provides a higher estimate of the thrust on the tunnel lining, thus highlighting the limitation of the other analytical solution.

Jan 1, 2008

By Carlos Alberto Spier

The Águas Claras and Pico mines are two world-class, iron-ore mines hosted within Lower- Proterozoic banded iron-formations (locally known as itabirites) of the Minas Supergroup located in the Quadrilátero Ferrífero District, Minas Gerais, Brazil. The Águas Claras orebody consists of a 2,500 m long roughly tabular-shaped lens hosted within the dolomitic itabirite of the Cauê Formation. Dolomitic itabirite is the protore of the soft high-grade iron ore, which is the main ore type of the Águas Claras orebody, and represents more than 85% of the 284 Mt mined since 1973. Hematite is the main constituent of the iron ores. It occurs as martite, granular hematite and, locally, as specularite. Magnetite appears subordinately as relicts within martite and hematite crystals. Gangue minerals are very rare. These consist of dolomite, chlorite, talc and apatite and are especially common close to the contact with the protore. This virtual absence of gangue minerals is reflected in the chemistry of ores which are characterized by very high Fe contents (an average of 68.2% Fe). The Pico orebody is a continuous ~3,000 m long body of lenticular shape hosted within quartz itabirite, which is the protore of the soft high- and low-grade ores at the Pico mine. The soft high-grade ores, together with the low-grade ores, called iron-rich itabirite, are the main types of ores at the Pico mine, respectively representing approximately 51 % and 29 % of the reserves within the pit. The iron oxide mineralogy is the same as that of the Águas Claras mine, but in different proportions. Gangue minerals are very rare in the high-grade ores, but are slightly more common in the iron-rich itabirite. Quartz is the dominant gangue mineral, and is found with minor quantities of chlorite. The chemistry of the high-grade ores is characterized by high Fe contents (an average of 67.0 %) and low P, Al2O3, and SiO2 which are concentrated in the fines. Iron rich itabirites average 58.6% Fe and 13.5% SiO2.

May 1, 2003

This paper describes the results of a laboratory study on the upgrading of Algoma siderite by the amine flotation of silica and silicate gangue. The experiments indicate that a virtually complete removal of silica is possible in a rougher flotation con-ducted in tap water at natural pH, without prior desliming of the ore. Grinding considerably finer than the apparent liberation size is essential for maximum silica rejection. A cationic collector, Aeromine 3037, gave best results when used in combination with a modifier. Of the several modifiers tested, a Dutch potato dextrin, Dextrin 4356, was found to be the most effective. Both iron recovery and the grade of the final iron product are enhanced by floating the pyrite contained in the ore prior to the amine flotation of the silica, and by scalping the magnetics from the silica concentrate. F OR over twenty years, the Algoma Ore Properties Division of The Algoma Steel

Jan 1, 1963

By C. Ayora

The Iberian Pyrite Belt (SW Spain and Portugal) contains one of the largest reserves of pyrite in the world with mining activities dating back to prehistoric times. About one hundred abandoned mine wastes and galleries release a huge acidity and metal load to the Tinto and Odiel rivers. Once the mining activity is over, polluting discharges can persists for decades or even centuries with no specific responsible entity. In-situ passive remediation technologies are especially suitable for these orphan sites. The concept is to insert a reactive porous material in the natural flow path of contaminated surface and ground waters, and it is implemented through infiltration ponds and reactive barriers, respectively. Calcium carbonate pea-size gravel is the common alkalinity supplier to neutralize acidity and precipitate metals. These remediation systems have been traditionally implemented in coal mines. However, the acid drainages from the Iberian Pyrite Belt contain metal concentrations one to two orders of magnitude higher than those from coal mines and require special designs to avoid quick clogging or passivation (coating) of the grains of reactive material. To overcome these problems, a Dispersed Alkaline Substrate (DAS) mixed from fine-grained limestone sand and a coarse inert matrix (e.g. wood chips) was developed. The small grains provide a large reactive surface and dissolve almost completely before the growing layer of precipitates passivates the substrate. The high porosity and the dispersion of nuclei for precipitation on the inert surfaces retard clogging. However, limestone dissolution only raises pH to values around 6.5, which is sufficient to precipitate the hydroxides of trivalent metals (Al, Fe), but it is not alkaline enough to remove divalent metals. Magnesium oxide, which hydrates to Mg hydroxide upon contact with water, buffers the solution pH between 8.5 and 10. A DAS system replacing limestone with caustic magnesium oxide has been tested to be very efficient to remove divalent metals (Zn, Cd, Mn, Cu, Co, Ni, Pb) from drainage previously treated with limestone.

Aug 1, 2013

By L. Bichler

Utilizing thermal analysis techniques, pioneering research into the solidification mechanism of a popular magnesium alloy AZ91E cast by the Lost Foam Casting (LFC) process was carried out, Foam characteristics, section thickness and application of vacuum were seen to have profound effect on the cooling rate, thermal gradients and casting temperature profiles.

Jan 1, 2005

By D. H. Stonehouse

Of the f ive Canadian cement producing regions- Atlantic, Quebec, Ontario, Prairie and Pacific-Ontario has the greatest capacity and normally produces the most cement. However, during the last 5 years the greatest activity within the industry in Canada has been in the Prairie and Pacific regions where major capacity increases have taken place. Most Canadian cement companies produce normal Portland, high-earlystrength Portland and sulphate resisting Portland cements. Some companies also manufacture moderate Portland cement, and low-heat-of-hydration Portland cement. Escalating energy costs highlight the need for technology research into more energy-efficient equipment for the energy-intensive cement industry. The industry is well integrated and plants are well situated to support construction in Canada. Expansion into the United States has become common during the past decade.

Jan 1, 1984

By F. S. Thurner

This paper, a description of the new ore-unloading and stockpiling facilities at the Sydney Works of DOSCO Steel Limited, deals with a new approach to arrive at the most economical solution to combine ore unloading facilities for common bulk carriers and for different types of self-unloading vessels. Also discussed is the design and installation of a 1-mile-long steel-cord belt conveyor sys-tem with a most modern type of mobile belt conveyor stacker, along with automatic and semi-automatic controls for the entire ship-unloading and stockpiling operations.

Jan 1, 1968

By W. G. Stevenson

With the author's background of extensive experience, this paper delineates the role of the prospector in modern-day exploration programs. The stages in the development of a prospect to a producing mineral district are outlined, and examples are given from the Ross River area of the Yukon Territory and the Peachland and Highland Valley areas of British Columbia.

Jan 1, 1970

By M. R. KEYS

"The property is about 120 miles north of Red Lake in the Favourable Lake area, district of Kenora ( Patricia part) , Ontario. The original discovery was staked by K. Murray in December, 1927. The first development work was done by the Favourable Lake Mining and Exploration Company. In 1936 Newmont Mining Corporation acquired control of the property and developed it to production by September, 1939. Production to the end of 1945 had a value of $7,534,656 from 441,457 tons of ore, an average value of $17.04 a ton . This production was mainly from gold and silver, with lead and zinc of subordinate importance.The rocks in the vicinity of the mine trend in a north-south direction. From east to west the sequence is: (1) A dark-coloured, massive rock, presumably a flow, composed mainly of quartz and biotite. ( 2) A buff- coloured, scricitized rock locally containing quartz phenocrysts and black hornblende. This is an alteration product of the dark variety and is later than the folding. It occurs mainly within the dark rock. (3) A series of sediments comprising thin beds of greywacke, grit, quartzite, conglomerate, and iron formation. ( 4) A gabbro sill, now largely altered to amphibolite.With the exception of the buff type, these rocks dip 80°E. The buff rock has a very irregular outline in comparison with the other rocks and appears to dip somewhat more flatly east. Felsite and diorite dykes are also present. These have a general strike of S.60°E. and dip 65°S .W. A post-ore diorite dyke trending N.15°E. occurs about 2,000 feet east of the mine area."

Jan 1, 1954

By K. J. Heale, G. G. Richards, D. J. Rioux, R. L. Stephens

Slag fuming has remained a key process for the recovery of Zn, Pb, and minor elements in the integrated flow sheet at Teck Cominco's Trail Operations for more than 75 years. Since the start-up of the KIVCETTM process and the #3 slag fuming furnace in 1997, a range of process intensification projects have been completed to improve metals recoveries and throughput based on improved process control, mechanical modifications, and, most recently, the implementation of oxygen enrichment of the blast air. This latter project, initially named 'nitrogen depletion' and now 'nitrogen oxygen performance enhancement' (NOPE), is the primary focus of this paper. NOPE reduces the amount of heat required to heat the inert nitrogen gas, and therefore more of the energy input can be used for reduction. It also frees up boiler capacity because the inert nitrogen gas does not then have to be cooled down. A dynamic METSIMTM model was developed to determine the opportunities to improve the process capacity and heat balance to both assist with justifying the project and to verify the observed furnace behaviour. Several process safety management issues were also addressed and a few key minor mechanical modifications were made to allow the project to proceed to commercial implementation at 25% blast air oxygen enrichment. Short term plant trials have confirmed the model predictions. The first three months of a long term, continuous trial showed a 6% increase in zinc fuming rate from average furnace performance despite the implementation of a KIVCETTM fluxing change to assist with minor element recovery that was expected to negatively impact the zinc fuming rate by 3 to 5%. This encouraging result is also in line with the model predictions.

Jan 1, 2008

By Nick Hazen

Many successful actions are required to bring a profitable extractive metallurgical operation into production. Competent process development performed within the project development schedule increases the chances of obtaining project financing and decreases the risk of engineering design errors being built into the commercial plant. The general sequence of steps in process development is well known: technology review, desktop studies, scoping studies, prefeasibility, and so on, with an increasing requirement for experimental evidence as the studies advance. This paper suggests principles for guiding process development work so that the efforts stay on track toward a smooth startup and a profitable commercial operation. It emphasizes closely aligning the research with the corporate goals of the mining company management, understanding the mineralogy and variability in the deposit, and guiding by flowsheet and material balance. Examples of hydrometallurgical process development leading to the early use of solvent extraction in the mining industry are given.

Jan 1, 2014

By E. Herrera Alarcón, L. Mariscal Samaniego

The Teniente Converter (wet charge type) was commissioned in august 1995 and was designed to smelt 744 tpd (metric tons per day) of dry copper concentrates. Its products are white metal (73% Cu) that is sent to the Peirce Smith converters, slag that is cleaned in Reverberatory Furnaces and the process gases that are sent to the Sulfuric Acid Plant. Since its start up, the Teniente Converter smelting capacity was increased 1.6 times, from 800 tpd to 1,280 tpd using 33% oxygen-enriched air, and reaching an operative availability of 97%. By the other hand its campaigns have reached a record duration of 530 days without hot patching tuyeres and a partial refractory lining repair in the last four campaigns. This paper describes the most relevant improvements, as well as the strategies that had been used to reach these achievements.

Jan 1, 2007

By E. E. N. Smith

"Uranium exploration by Eldorado prospectors north of Lake Athabasca began in late 1944 and resulted in initial discoveries in 1946 in the Beaverlodge region with mill production starting in early 1953. The operation was closed in mid-1982 having produced 21,457,947 kilograms U30 8 from the Eldorado FayVerna mine, Eldorado satellite operations and from other district producers on a custom basis.The Fay- Verna mine consists of pitchblende-brannerite orebodies spatially associated with both sides of a regional eastwest structure, the St. Louis Fault. The orebodies in the footwall (Fay) are elongate deposits of two types raking steeply to the southwest along the 50 degree south dip of the fault.One type consists of networks of fractures and veins filled with pitchblende, calcite and quartz in chlorite, epidote-altered mylonitized mica schists and amphibolites of the Middle Aphebian Tazin Group. The other type is comprised of fragments of mylonitized metasomatic quartz-feldspar granite of Late Middle Aphebian age cemented with a matrix of pitchblende, brannerite, calcite and some quartz. The vein networks lie en echelon in the footwall of the breccia ore bodies which, in part, are capped by the mud gouge of the St. Louis Fault; in other places, the breccia orebodies are overlain by basal conglomerates, grits and arkoses of the late Aphebian Martin Formation which itself immediately underlies the plane of the fault.Orebodies in the hanging wall (Verna) are a series of irregular, tabular deposits lying within a tightly overturned syncline of Tazin mica schists, amphibolites and siliceous mylonites. They consist of pitchblende, calcite-filled fractures grouped into zones and deposits displaying stratabound habits within individual rock types.Also described are several Eldorado satellite properties which were significant producers of uranium and which display complementary geology to that in the Fay- Verna mine.In general, uranium deposits in the Eldorado Beaverlodge region are closely related to minor structures associated with major faults. Uranium appears to be best concentrated where the rocks are well mylonitized and brecciated. Pitchblende fills networks of veins and fractures in metasediments and metavolcanics as well as matrix material cementing brecciated, mylonitized granite. All deposits in the Beaverlodge region lie in close proximity to the unconformity between the Martin Formation and the underlying Tazin Group."

Jan 1, 1986

By Michael S. Moats, Alex Luyima, Tomas Oliveira

Some commercial copper electrowinning facilities use Cyquest N-900 (a polyacrylamide) or HydroStar (a modified polysaccharide) to improve the density and smoothness of copper electrodeposits. However, the effects of these additives have not been studied extensively in the open literature. Thus, the electrodeposition of copper at 40 oC from a non-stirred synthetic electrowinning electrolyte (40 g/L Cu2+, 160 g/L H2SO4, and 20 mg/L Cl-) in the presence of various concentrations of either additive was evaluated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). CV results show that neither additive has much effect on the nucleation overpotential of copper electrodeposition on stainless steel. However, Cyquest N-900 polarized the copper deposition reaction upon the return sweep. The EIS data indicates that Cyquest N-900 increases the reaction’s charge transfer resistance and creates a second low frequency loop. HydroStar had minimal effect on the electrochemical data generated by CV or EIS. Thus, the mechanism by which HydroStar affects the copper deposition reaction still needs to be determined.

Jan 1, 2014