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By Yongsheng Song, Yong Chen, Wenjuan Li

"Detailed characterization and improved recovery of a micro-fine, low-grade refractory gold ore from a beneficiation plant in Yunnan Province, China, was investigated. Different analytical techniques, such as videlicet size analysis, scanning electron microscopy, and mineral analysis by a Mineral Liberation Analyser, were used for mineralogical characterization of the ore. This paper describes an experimental study on the effect of the grinding fineness and the use of various flotation reagent regimes involving collectors, depressors, and activators on the flotation behaviour of micro-fine auriferous pyrite. Two-stage flotation resulted in high gold grade (32.71 g/t) and gold recovery (80.02%) of the bulk gold concentrate. This process opens the possibilities of maximizing Au recoveries in a micro-fine low-grade refractory gold ore where low recoveries are common.INTRODUCTIONWith the rapid development of the gold industry, refractory gold ores are becoming increasingly important resources for gold production (O’Connor & Dunne, 1994; Agorhom, Skinner, & Zanin, 2012). Among these refractory gold ores, sulfur and micro-grained native gold ores represent a significant challenge, since they are not amenable to gold recovery by direct cyanidation. The gold contained in this type of ore is very finely disseminated and encapsulated in sulfides, which makes it inaccessible to the cyanide solution during direct cyanidation (Bulatovic, 1997; Allan & Woodcock, 2001). Autoclave pressure oxidation (AC POX) of the sulfide ore and subsequent cyanidation is a common technology used to recover the gold in such types of ore. Flotation is often used as a pre-treatment method to refractory gold ore (Monte Lins, & Oliveira, 1997).As the gold-carrier minerals are usually finely disseminated (sometimes under 10 µm) and intimately associated with gangue minerals, a fine grind is necessary to get a high degree of liberation. At the same time, the fine grind usually causes the production of significant quantities of slimes, which comprise easy-to-float gangue minerals such as mica, dolomite, and calcite. These mineral phases are naturally hydrophobic and float readily, competing with the value minerals in the froth phase and resulting in lower concentrate grades."

Jan 1, 2016

By M. Schmidt, P. Nord, M. Larinkari

Cathode stripping machine technology has been developed significantly both in electrorefining (ER) and electrowinning (EW) applications in the last ten years. The main driver has been robotic cathode handling, which has enabled increased flexibility to meet different layout and material handling requirements for both ER and EW processes. Additionally, cathode stripping stations have been continuously developed to optimize speed and to reduce mechanical stress of permanent cathodes. 'taco' type cathodes have been proven as beneficial approach for high capacity operations (particularly in Cu ER), where over 600 cathodes per hour continuous throughput has been achieved. However, the latest developments also apply to split type cathode stripping. Besides material handling, the modern cathode stripping machine has also an important role to provide information for production and quality monitoring. This paper describes the latest developments from the field of copper cathode stripping based on several different projects implemented in the recent years. INTRODUCTION After introduction of the permanent cathode technology in the late 1970s, it became the prevailing technology in copper refineries over the traditional starting sheet process by the end of 1980s. The main driver was less labour-intensive production due to fewer processing steps required along with more automated electrode handling equipment (cathode stripping machine, anode preparation machine, anode scrap washing machine and tankhouse cranes). Since then the design of the cathode stripping machine has followed the development of permanent cathode technology. The main development steps so far can be summarized as follows: Full Deposit Stripping Machine (FDSM) based on waxed permanent cathodes or cathodes with bottom edge strips resulting in split cathodes (copper sheets separated, see Figure 1) Wax less cathode stripping based on V-groove on bottom of the edge strip resulting in either ‘taco’ cathodes (enveloped copper sheets, see Figure 1) or split cathodes Full Deposit Robotic Stripping Machines (FDRSM) using 1–5 robots for permanent cathode handling and cathode stacking.

Jan 1, 2019

By R. Browner, J. Collard, D. Ibana

The extraction of cobalt from synthetic pressure acid leach solutions of nickel laterite ores by the direct solvent extraction route using ESPLIM is reported. It first explored the use of gaseous ammonia as pH modifier and then the variables that affect the dispersion of the aqueous phase in the organic phase such as ionic strength, viscosity of the phases, initial droplet size, etc. were explored so that phase hold-up and thus extraction can be effectively controlled. The results show that the technique allows better control of phase dispersion circumventing one of the main weaknesses of conventional solvent extraction.

Jan 1, 2005

By A. Zorkovská, S. Castro, P. Baláž, Z. Bujnáková

Enargite (Cu3AsS4) belongs among refractory copper minerals with very low hydrometallurgical extractability of copper. An application of enargite leaching in acid solutions leads to simultaneous dissolution of copper and arsenic and the final leach solutions have to be treated for the separation of both elements. However, the alkaline leaching of enargite is selective. Arsenic passes into leach while produced copper sulphide represents the raw material suitable for pyrometallurgy. The hydrometallurgical processing of mineral can be influenced positively by mechanochemical route. We have shown that more than 80 % of arsenic can be extracted from enargite concentrate by atmospheric alkaline leaching at 95 °C when mechanical activation in an attritor is applied. The produced Cu2S can be further treated with elemental iron where mechanochemical intervention is applied in the second stage of enargite processing. The final product forms Cu/FeS nanocomposite from which copper nanoparticles can be easily separated. The illustrated concept of copper obtaining from copper sulphide is an example of so-called “dry” processing, as reactions in gas and liquid phases are excluded. This concept of environmentally friendly metallurgical processing can be classified as an impetus for novel technology to produce copper from enargite concentrates.

Jan 1, 2012

By M. Bozorgtabar

Metal Matrix Composites (MMC) have a ductile matrix containing ceramic particles, Due to their improved wear properties, Al?SiC composites have economical applications in many industrial uses where wear is a problem, One of the most serious difficulties in manufacturing Al-SiC composites is obtaining adequate 'wetting' of the particles by the melt. In this research work, a stir casting system was designed for the improved manufacturing Al-SiC composites, The effect of some production variables such as the addition of SiC particles to the aluminum melt on wettability, was also studied. The results showed that the manual addition of particles would not be successful in manufacturing and that a system of adding silicon carbide particles through controlled temperature, atmosphere and improved mixing was needed.

Jan 1, 2005

By Z. Huda

The effect of various percentages of cold-working and recrystallization on the microstructure and hardness of commercially-pure aluminum plate, has been studied. The 'A critical deformation for the aluminum, has been determined. Experimentation involved cold rolling and recrystallization processes followed by quantitative metallographic practice and the hardness measurements. The raw material chosen was a plate of commercial aluminum which was cold rolled to different percentage of cold-work and then recrystallized by heat treatment at 150°C. The critical deformation percentage of aluminum was computed to be around 30% of cold-worked.

Jan 1, 2007

By R. O. Grieve

"IntroductionCALEY (1945) and Evans (1950) pointed out that certain instances of convergence between Devonian and Silurian horizons, frequently evident in wells drilled for oil and gas in Ontario, appear to be related to local thinning of salt beds in the Salina formation and they suggested that leaching of the salt beds may have occurred. Exploratory drilling by Imperial Oil Limited since 1945 has brought to light several examples of structures similar to those discussed by Caley and Evans. The writer has had the opportunity to examine cuttings and data from wells which penetrated these structures and the attempt to interpret them in the light of the theory of leaching and subsidence proposed by Landes ( 1945a) to explain the marked brecciation and deformation of Upper Silurian and Middle Devonian sediments which crop out in the Mackinac Straits region of northern Michigan has led to the observations presented in this paper."

Jan 1, 1955

By I. M. Masters

Iron removal and control in processes employing pressure leaching technologies developed at Dynatec Corporation are reviewed. Discussions are focused on recent developments in the processing of nickel-copper matte and copper concentrates, and on the Ambatovy laterite project in Madagascar. Iron control and its implications on flowsheet design in the pressure acid leaching (PAL) treatment of laterite ores and in the oxidative pressure leaching of mixed nickel-cobalt sulphide intermediates are also discussed.

Jan 1, 2006

By Yoginder P. Chugh

This paper discusses an ongoing field study in southern Illinois (USA) that focuses on: 1) Identifying mechanisms of instability in the set-up rooms (SR) and their T-junctions with headgate and tailgate entries, 2) Developing alternate 3-entry and 4-entry set-up rooms geometry using 3-D numerical analyses, 3) Implementing developed geometries in cooperation with mining professionals and regulatory agencies, and 4) Demonstrating performance of implemented geometries through field monitoring. Illinois longwall mining operations typically experience ground control problems (roof falls, rib sloughing, floor heave, etc.) within SR layouts and around the T-junctions of SR. These occur around the areas where the SR for adjacent longwall face (to be mined) connect with the SR of the previously mined face, and around the tail-gate entries of the mined-out longwall face and around the T-junctions of SR. The problems manifest as highly fractured immediate roof strata, major shear zones in the roof, horizontal displacements within the excavations that result in shearing off the heads of the bolts, floor heave and severe rib sloughing. Similar observations have also been made in longwall mining in Utah.

Aug 1, 2013

By C. J. K. Purdy, H. E. Jamieson

"The comprehensive assessment of the environmental impacts of mining rare earth element (REE) deposits depends on a sound knowledge of the mobility of REEs in low-temperature aqueous environments. Temperature, pH and water chemistry are important factors controlling the aqueous mobility of REEs, while REEs are known to readily form complexes with both inorganic and organic ligands, and it has been shown that sorption and colloid formation may play an important part in dictating REE transport in the low temperature weathering environment. Ore and host rock mineralogy is also a key factor controlling the extent to which REEs are leached from mine waste. INTRODUCTIONThe aqueous mobility of rare earth elements (REEs) has commonly been explored in the past due to their potential application as tracers of geochemical processes in aqueous systems. REE mobility in low-temperature solutions has been shown to be dependent on the pH, temperature, ionic strength, and solution chemistry. For example, the aqueous transport of REEs can be modified by complexation with organic and inorganic ligands (Johannesson & Zhou, 1999; Klungness & Byrne, 2000; Luo & Byrne, 2004; Schijf & Byrne, 2004; Tang & Johannesson, 2010; Wood, 1990, 1993), or through sorption to suspended particles and colloids (Bau, 1999; Quinn, Byrne, & Schijf, 2004, 2006a, 2006b, 2007; Sholkovitz, 1995). Here we review the coordination chemistry, sorption behaviour and potential colloid association of REEs with respect to low temperature aquatic settings.RARE EARTH ELEMENT CHEMISTRYREEs include lanthanum to lutetium of Group IIIA in the periodic table. All share very similar chemical and physical properties. Often included in REE studies is another Group IIIA element, yttrium owing to its similar properties, and occasionally scandium, although its considerably smaller ionic radius makes for different properties and will not be discussed further here. The REEs are often subdivided into the light REEs (LREE), La to Sm, and the heavy REEs (HREE), Eu to Lu, which also usually include Y (hence are often referred to as YREE). The REE may be subdivided further into the LREEs, middle REEs (MREEs), and HREEs, in which case each classification includes La-Nd, Pm to Ho, and Er to Lu as well as Y, respectively, although definitions vary throughout the literature."

Jan 1, 2012

By Ho-Sung Yoon, Jyothi Rajesh Kumar, Jin-Young Lee

"Global population is a key factor in future energy requirements, especially considering the important elements of global energy resources, electricity production, the accessibility/non-accessibility of electricity, greenhouse gas emissions and the states of nuclear reactors. Everyday human requirements depend on industrial products, and industries need a considerable amount of electricity to run. Nuclear fuel is inexpensive and bolsters industrial growth. As uranium reserves are being consumed rapidly, an alternative source of energy in the nuclear industry is thorium. Here, primary energy supplies by various sources from 1993 to 2011 as well as estimates of future needs to 2020 are discussed. This study finds that primary energy sources are mainly fossil fuels, renewables sources, and nuclear and hydro energy. In addition, growth depends on increases mainly in renewable sources.Recovery of thorium from its ores by using hydrometallurgical routes were described and discussed. The final part of this paper was presented a case study of the thorium extraction from Korean monazite ore leach liquors by using Prieme JM-T diluted in A150 diluent as an extractant system. And possible separation of the thorium from rare earths (REs) and base metals were calculated by measuring of separation factors and finally, the recovery of thorium from loaded organic of Prieme JM-T was established.THORIUM IS FUTURE NUCLEAR FUEL?Global energy consumption is increasing everyday with the high population growth, high industrialization of numerous countries and the higher level of good and services consumption that follows it. If we look at specific sectors of the economy, oil consumption grew by 0.8 million barrels per day, globally, whereas the increase was 0.4 % for natural gas and coal 1.8 % for nuclear power and just under 2.0 % for hydroelectric power (Asheley 2009). Use of renewable sources of energy for power generation and transportation increased by 3% in 2014 (BP 2015)). Thus alternative source of energy must be identified and developed to meet this increasing demand. Thorium is a potential one for the nuclear industry."

Jan 1, 2016

By J .. Carignan, Y. Dembele, J .. Guha, A. Fowler, A. Gobeil

The Barlow Lake stratigraphic section comprises the top of the Gilman Formation, the Blondeau Formation and the three sills of the Cummings Complex. Representative samples were analysed to allow characterization of the chemo-stratigraphic profile and geochemical affinity of the six rock facies found in the section. All the mineralized horizons are associated with sedimentary units. Geochemical signatures associated with the mineralizations are either very weak or very localized and shown by increases in K20 around the mineralizations and Fe203 near them. The mineralizations are stratiform, synvolcanic but resedimented and remobilized by regional metamorphism and possibly by hydrothermal activity initiated by the intrusion of the Cummings Complex. The evolution of the sedimentary basin with the decrease of its depth is confirmed by the chemo-stratigraphic profiles. Stratigraphic position in the section is important in order that the chemo-stratigraphy may serve as a guide for mining exploration in the distal facies of the Blondeau Formation.

Jan 1, 1984

The uphole bench extraction strategy at EKJV Management Pty Ltd?s Raleigh Mine, requires simultaneous horizontal and vertical exposure of paste filled stopes. In order to prevent excessive ore dilution, the paste fill must be of sufficient strength to prevent failure during exposure. A numerical modelling methodology has been developed to accurately simulate the initial stress distribution within paste filled stopes, together with the strain-softening loading response of paste fill material. Due to the narrow orebody width and high deformation behaviour of the host rock mass, high closure strains are likely to cause a stiff, brittle fill material to undergo crushing failure upon exposure. The stability of paste fill exposures at the Raleigh Mine was determined by conducting a series of three-dimensional numerical models that incorporate the extraction, filling and exposure sequence of paste filled stopes. Stability charts for 2.5 m and 3.5 m wide simultaneous horizontal and vertical exposures have been derived based upon the numerical modelling results. Implementation of the stability charts has proved successful in limiting the amount of ore dilution from paste fill and provides a basis to optimize paste fill cementation and stability throughout the life of the mine.

May 1, 2007

By CIMVAL

This Code for the Valuation of Mineral Properties (the “CIMVAL Code”) is the result of a review more than a decade after the release in 2003 of the “Standards and Guidelines for Valuation of Mineral Properties” (the "2003 Standards"). The purpose of the review is to update the 2003 Standards to reflect domestic valuation, international valuation, and regulatory developments. The CIMVAL Code was adopted by the Canadian Institute of Mining, Metallurgy & Petroleum (the "CIM") Council on November 29, 2019. The CIMVAL Code supersedes the 2003 Standards. The 2003 Standards were dated February 2003 and were adopted by the CIM Council on March 9, 2003 as the first comprehensive set of standards for Valuation of Mineral Properties in the Canadian mining industry. The 2003 Standards followed recommendations of the Mining Standards Task Force of the Toronto Stock Exchange and the Ontario Securities Commission, where in its Final Report (January 1999), the CIM was specifically asked to form a committee of valuation practitioners to review and advise on standards for the Valuation of Mineral Properties. The Special Committee on Valuation of Mineral Properties ("CIMVAL") was created on May 5, 1999 with the mandate to recommend standards and guidelines for Valuation of Mineral Properties to be used by the mining industry in general. The CIMVAL Code is limited to the Valuation of Mineral Properties (including any interests therein) and does not cover valuation of corporations or other entities that hold Mineral Properties as assets. The CIMVAL Code does not cover petroleum and related assets. CIMVAL recommends that the CIMVAL Code be followed for all Valuations of Mineral Properties, including those required by securities administrators and stock exchanges. However, when a Valuation is required under the applicable rules of securities administrators or stock exchanges, such rules prevail to the extent of any inconsistency.

Nov 29, 2019

By G. R. Guillet

THE LATE Dr. D. F. Hewitt, Ontario's foremost authority on industrial minerals, was the first to point out the importance of urban minerals when he produced figures (Hewitt 1968) to prove that the Toronto-Hamilton area was Ontario's second largest mining camp in 1966 (Fig . 1). In that year, the value of mineral production within a 60-mile radius of downtown Toronto exceeded individually that of Steep Rock, Kirkland Lake, Timmins, Manitouwadge and Elliott Lake. Only the nickel and precious-metal production of Sudbury .surpassed in value that of Toronto's pits and quarries. Although that position was unchanged for some years during the early sixties, it was admittedly an unusual situation: gold was still pegged at an artificially low value; uranium was stagnant; and Texasgulf had not entered the scene. However, the point had dramatically been made. The combined value of production from hundreds of sand and gravel pits and dozens of limestone and shale quarries was of formidable proportions. The mining industry of the urban fringe could not be denied. Construction aggregates, cement, building stone and bricks were fueling an apparently insatiable appetite for urban expansion and redevelopment.

Jan 1, 1978

By Peter N. Calder

The orientation of planes of inherent weakness (joints) with reference to an excavation in rock is the critical factor determining stability. The purely frictional 'residual' strength remaining following the breakdown of initial cohesion is the only strength which can be counted on to resist sliding for the long term. A simple method of resolving driving and resisting forces in three dimensions along joint intersections 'undercut' by the excavation is presented. Contrary to the case of slope failure in soils, it is shown how significant changes in the slope angle sometimes have no effect on the degree of stability pre-sent in rock slopes. Wall control by reorientation of the slope, the use of cable bolts and water diversion are briefly discussed.

Jan 1, 1970

By V. Schwinn, P. Fluess, N. Cauderlier, J. Bauer

From a strategic and economic point of view, the development of fine grain high strength steels for long distance pipelines is intensified world wide to satisfy the demand for natural gas in the future.The project related property profiles based on strength, toughness, crack arrest and sometimes resistance against HIC at defined design temperatures require an effective structural refinement using advanced steelmaking and processing in the rolling mill. The microstructure of modern line pipe steels ranges from ferritic pearlitic to ferritic-bainitic and structures where bainite is the dominant component, possibly upgraded by secondary phases. This paper illustrates microstructures and properties of recent orders on line pipe steels both for onshore and offshore application using different processing routes in the plate mill. Examples will be given for SAWL 485 offshore grades, X65 HIC and X70 HIC onshore grades, respectively. Finally, production results of a recent X80 order will be presented.

Jan 1, 2005

By V. G. Papangelakis, A. Dani

"Alkaline pressure oxidation, particularly in the presence of trona as additive, can be used to oxidize high carbonate refractory gold ores as it prevents the formation of CO2 in the autoclave. However, the presence of silica in the ore can lead to the encapsulation of pyrite due to the solubility of silica in alkaline solutions and its subsequent reprecipitation on the reacting pyrite surface, leading to the formation of a passive layer. This fundamental study investigates the chemical composition and thickness of the passive layer on a rotating pyrite disk using XPS and SEM, as a function of process conditions at 230°C, in an aqueous slurry containing silica sand, sodium carbonate and calcium carbonate under 100 psi of oxygen overpressure.INTRODUCTIONAlkaline pressure oxidation (POX) has been used successfully to treat high carbonate refractory gold ores, which contain carbonates in addition to sulphides, most notably at Mercur and Goldstrike mines operated by Barrick Gold. There are several advantages to using alkaline POX over its acid counterpart, especially due to high carbonate content. First, it eliminates the production of CO2 in the autoclave without resorting to pre-acidification, which allows for high oxygen utilization. Second, alkaline POX suppresses the formation of elemental sulphur and intermediate sulphur oxyanions (such as thiosulphates and dithionates), which reduce gold recovery. Third, the use of sodium hydroxide or salts prevents the formation of anhydrite scale by forming soluble sodium sulphate. Other advantages are the use of cheaper materials of construction and the formation of non-acidic residue that do not require further treatment prior to cyanidation (Thomas, 2005).Sodium carbonate in particular is a promising reagent for alkaline POX because it was shown to significantly accelerate the kinetics of pyrite oxidation by molecular oxygen, when compared to other reagents such as sodium hydroxide, sodium borate and calcium hydroxide. This has been attributed to the following factors: a) the faster oxidation kinetics of Fe2+-CO3 complexes compared to Fe2+ oxidation, b) the buffering effect of carbonate ions on the acidic pyrite surface, and c) the increased solubility of oxidizing Fe(III) species due to carbonate complexation (Caldeira, 2010)."

Jan 1, 2012

By A. Demers, M. Chapman, N. Reynier, R. Lastra, M. Courchesne, C. Laviolette

Historic medical isotope production at Canadian Nuclear Laboratories (CNL) in Chalk River involved the dissolution of irradiated isotope targets prior to extraction of Mo-99. This process generated liquid waste that was cemented in 5-gallon containers and transferred to an outdoor waste-management facility for intermediate storage. Research was undertaken to develop an innovative method for uranium, mercury and cesium recovery from the radioactive cemented waste (RCW). Regulations prohibit the removal of active radioactive waste from the Chalk River facility. Thus, CanmetMINING produced surrogate material following the same procedures and conditions to those used at CNL. The selective recovery of the uranium from the surrogate radioactive cemented waste (SRCW) could offer CNL more disposition options for the resulting wastes. Leaching tests were performed using four different SRCW at 1 kg scale. Different conditions, operating parameters, and the presence of plastic and corrosion products were evaluated on solubilization. The research investigated the use of potassium iodide with the sulphuric acid leach to increase metals recovery. Iodine improves the solubilisation of metals and the U dissolution reached 99%. The increase of leaching time reduces the U solubilization due to silica gel formation. Therefore, it will be important to control leaching time to avoid the loss of U during the pilot scale experiments. For Hg, the solubilization ranged from 60 to 80% due to the presence of metallic mercury and mercury sulphide found in SRCW cured at 60°C and/or aged for 30 months. Ion exchange (IX) was found the best method to separate the uranium from the impurities and produce a purified and concentrated uranium solution suitable for yielding a uranium product (yellow cake).

Jan 1, 2020

By J. Álvarez, J. Mesías, C. O. Gómez

"Operations routinely run flotation tests in laboratory mechanical cells to determine adjustments to plant operation based on feed flotation response or the effect of new reagents and dosages. The metallurgical results of these tests are certainly affected by changes in bubble size, which simultaneously impact the recoveries of the collection and froth zones. It is known that bubble size depends on the characteristics and operation of the machine in use, particularly on the gas flow rate delivered to the unit and the selected frother type and dosage. Although flotation rate constants have been related to bubble size, bubble surface area flux seems to be a more fitting variable to correlate flotation kinetics and cell performance, as it integrates bubble size and superficial gas velocity effects. However, although some evidence has been provided, a categorical relationship between cell recovery and bubble surface area flux has not been established. Our interest is to demonstrate this relationship to use it as a basis for developing soft sensors to track on-line collection zone recovery in cells. Flotation tests were designed to produce Cu concentrates for a range of bubble surface area flux values, obtained through changes in frother concentration at a constant gas flow rate, and by increasing gas flow rate at the same frother concentration. The tests were run on samples prepared from an ore batch supplied by a local operation, following strict grinding and flotation procedures, with a shallow froth to approximate cell recovery to that in the collection zone. Bubble sizes were determined using the sampling-for-imaging technique developed at McGill. The results unequivocally showed a consistent positive correlation between cell recovery and bubble surface area flux, and significant variations in performance when frother addition and gas flow rate were changed.INTRODUCTIONMineral flotation is a separation process to produce concentrates of valuable minerals by selective attachment of particles to the surface of bubbles. The process is carried out in machines where air is injected through a mineral pulp to form bubbles, and operated to create two zones: a bottom one (collection zone) where bubbles are continuously generated under conditions adequate to form bubble-particle aggregates by collision of the rising bubbles with suspended particles; and a top one (froth zone) where bubbles and bubble-particle aggregates continue to rise while concentrating and forming a froth layer for water and entrained particles to drain back to the collection zone, before overflowing as a concentrate stream. The phenomena occurring in these zones are complex and, in many cases, interactive, as they simultaneously affect stages of the particle separation sequence occurring in both zones. Although there have been significant advances in instrumentation to characterize particle and bubble populations, these have not resulted in knowledge to explain or models to describe phenomena from fundamental principles. Measurements continue to be limited to the development of empirical models for predicting the effect of operating variables on performance."

Jan 1, 2016