Search Documents

By M. J. Latva-Kokko, T. J. Riihimäki

"Oxidation autoclaves are normally operated at elevated temperature and pressure. The improvement in kinetics is due to combined effect of temperature and partial pressure of oxygen. In this paper exclusive effect of pressure has been studied with a low grade sulphide ore at below 100 °C temperature. These studies are related to development of a novel tower-like reactor that utilizes hydrostatic pressure. Technology is designed to generate high amount of effective fluid volume for high solid content slurries with lower energy consumption and improved kinetics compared to normal atmospheric operation.INTRODUCTIONEconomical utilization of low-grade ores requires handling of enormous amount of material. This sets new requirements for process equipment in terms of size and energy efficiency. For example on the field of mineral processing this has lead to a six fold increase in the operating volume of mechanical flotation cells over the past two decades. Ore beneficiation methods like flotation greatly reduce amount of material that needs to be further processed in smelters or hydrometallurgical refineries. However with some ore types, such as nickel laterites and refractory gold ores, traditional concentration technologies cannot be utilized. Thus direct leaching of ground ore could be an attractive option. In many cases normal atmospheric tank leaching has traditionally been a non-feasible option mainly due to high capital and operational expenses induced by large amount of stirred reactors required. Main restriction for increasing reactor size to beyond 500 m3 has been mechanical load and power requirements set by mixing in cases when high dispersion efficiency of gas is required. THEORETICAL BACKGROUNDIn hydrometallurgical industry autoclaves are typically operated at elevated temperature and pressure. In many cases increase in operating temperature is the desired phenomena and improvements in kinetics are strongly related to that. Thus increase in pressure might be induced solely by water vapor pressure. However when gaseous feed is present, pressure itself has a strong effect on leaching kinetics for various reasons and its role should not be neglected."

Jan 1, 2012

By Eric Poulin, Anthony Clapperton, Jocelyn Bouchard, Jaime Cristobal Rojas-Montes, Benjamin Legare

"Several grinding mill dynamic simulators have been developed in the last half-century. However, complete circuit simulations are mainly limited to academic investigations, and on-site applications for advanced control or real-time optimization are scarce. One particular issue that has certainly curbed a more widespread use is the time and efforts required for model calibration. This paper illustrates this challenge and presents a calibration method based on dynamic simulation using industrial data and laboratory testwork. The simulator models discussed originate from the work of Austin and Luckie (1972) for grinding mills, and Plitt (1976) for hydrocyclones. A two-stage approach based on a least squares minimization allows determining calibration parameters values. Firstly, laboratory testwork are required for characterizing breakage coefficients of the ore. Secondly, step change responses and their simulation— effect of ore and water feed rates on output flow rates and size distributions—allows identifying transport/mixing conditions. Simulation results are in agreement with actual process responses to variations of feed conditions obtained from a plant survey.INTRODUCTIONDynamic models for grinding circuits has been intensively studied since the 1970's notably by Austin and Luckie (1972b), Klimpel and Austin (1984), Rogovin and Hogg (1988), Napier-Munn et al. (1996), Liu and Spencer (2004), and King (2012) among others. The resulting models primarily serve in simulation applications for process equipment sizing, which incidentally also helps developing a better understanding of comminution operations. An obstacle curbing a more widespread and targeted use of grinding simulation for process control and optimization purposes is the time and efforts required for dynamic model calibration. It remains a cumbersome task that is typically not well detailed in technical papers. This could explain why dynamic process simulators are mainly confined to academic applications."

Jan 1, 2016

By Xiao min Zhou, Yan Xu, Hongzhen Liang, Xiaonan He

"With the increase of shaft excavation depth, the thickness of the shaft lining increases sharply. It is difficult to reduce thickness of lining effectively by improving high-strength concrete performance. The concept of the New Austrian Tunneling Method (NATM) is that surrounding rock plays a certain role in tunnel support. The solution should be to find the correct relationship between shaft lining thickness and rock strength, which is related with the interaction between the surrounding rock and concrete lining. The plane strain mechanics model is introduced to calculate lining thickness. Shaft lining design of Cixi Colliery in China is completed with the mechanics-based method proposed in this study. The lining design is verified through numerical simulation and field monitoring. The simulation results show that the maximum mises stress is located at the inner edge of the shaft lining. The increase of lining thickness cannot effectively reduce concrete grade. The monitoring results indicate that a lining design thickness of 900mm with C60 concrete, is safe and reliable in the shaft over 1000metres.This analytical design method can well be referenced in similar deep shaft projects.INTRODUCTION The New Austrian Tunneling Method (NATM), thought to have helped revolutionize the modern tunneling method, is the most extensive design philosophy and construction principle in today's tunnel engineering. It began to attract attention in the 1960s based on the work of Ladislaus von Rabcewicz, Leopold Müller, and Franz Pacher in Austria[1]. NATM was originally developed for tunneling in depth and in high situ-stress conditions in the Alps. The history of sequential excavation was reviewed, which highlights the progress of tunnel design and construction in Europe after NATM[2]. Structural conditions were introduced into the equilibrium of tunnels in NATM, and the additional force was estimated to stabilize the excavation of the tunnel[3].From the perspective of applied mechanics, there was no accuracy theory to explain the interaction between the tunnel structure and the surrounding ground. Numerical calculation is an effective means to study the basic mechanism of tunnel excavation[4].Based on two-dimensional modeling approaches in the past, such as NATM and other derivatives, a three-dimensional model was studied to"

Jan 1, 2019

By J. E. Gill

Discovered in 1952, the deposits have been explored by diamond drilling on and near a group of islands in lake Nipissing and from under-ground workings. The ore mineral is a uranian pyrochlore. It occurs in breccia zones in association with calcite, apatite, a?cmite, feldsiiars, biotite, magnetite, sulphides, and fluorite in varying amounts. The pyrochlore concentrations occur in a steeply-dipping gneiss series with some crystalline limestone. Trends indicate a ring structure 114 miles in diameter. The main ore zone shows evidence of repeated brecciation and a succession of replacements .giving rise to a complex of rock types. Pegmatite and lamprophyre dykes cut the ore as do calcite-fluorite veins and later faults with small displacements. Columbium and uranium occur al-most exclusively in pyrochlore, but the proportions vary. There is no tantalum and only small amounts of titanium.

Jan 1, 1957

By M. Nusheh, C. Bumby, A-H. Puichaud

"Vanadium-bearing titanomagnetite ironsand deposits occur along a 480 km stretch of the west coast of New Zealand. In the present study, the leaching behaviour of NZ ironsand was investigated in hydrochloric acid (2–10 M) solution at 50–80°C for 2 h. The resulting leaching liquors exhibited Fe/V ratios in the range 150–180. The distribution of trace element contaminants between solution and solid residue was investigated, and processing conditions have been determined for rapid and efficient dissolution of Fe, Ti and V into the leaching solution. In addition, mineralogical analysis of raw ironsand and leached residues was performed in order to study the leaching mechanism. Samples were characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy (EDX), X-ray fluorescence spectroscopy, qualitative and quantitative X-ray diffraction and inductively coupled plasma mass spectrometry (ICP). Results indicate that the dominant dissolution process follows shrinking particle mechanism. However, ironsand particles containing ex-solution lamellae exhibited a different leaching behaviour compared to homogenous titanomagnetite particles.INTRODUCTION Titanomagnetite ironsand (blacksand) forms Quaternary onshore beach and dune deposits and offshore marine deposits (Figure 1) along 480 km of coastline from Kaipara Harbour south to Wanganui on the west coast of the North Island (Christie, 2016). It attracted the attention of scientists from the earliest times (Galbreath, 1998). The principal minerals in ironsand are titanomagnetite (TTM), ilmenite, quartz and ferromagnesian minerals such as augite, hornblende, diopside, and olivine with smaller amounts of rutile and apatite (Mauk, 2016).Several large ironsand deposits have been discovered and exploited since the late 1960’s. The Waikato North Head and Taharoa mines are currently operating and they have a 2015 measured resource of 400 million tonnes in total and provide over 2 million tonnes of concentrate per year by simple cost effective magnetic separation process (Christie, 2016; Christie & Brathwaite, 1997). The concentrate contains not only 7–8% TiO2 and 56–60% SFe, but also 0.3–0.6% V2O5, is both a valuable titanium mineral and a source of vanadium. All the production is used for steelmaking industries. The other potential for utilizing more of this resource without requirement of integration into an iron and steel producing plant is to develop a hydrometallurgical route with advantages of higher efficiency along with lower emissions. Currently, there is no existing commercial process capable of extracting all three of these elements as industrial-grade commodity products. Acid leaching of TTM concentrate with higher degrees of recovery and selectivity is a key step in any possible hydrometallurgical route."

Jan 1, 2017

By C. E. Baltzer

This is the fourth in a series of coal technology reviews being prepared. in accordance with a recommendation voted by the Coal Division C.I.M. in session at the Jubilee Meeting, Vancouver, 1948, that the Department of Mines and Resources be requested to arrange for publication by the proper Government authority of a Quarterly Review of Coal Technology for distribution among those concerned in the production and use of coal in Canada. Copies of the first review, which appeared in the November, 1948, BULLETIN, pp. 612-614, of the second review in the June, 1949, BULLETIN, pp. 272-275, and of the third review in April, 1950, BUL-LETIN, pp. 1,9?3-196 (also, respectively, in Transactions, Vol. LI, 1948, pp. 262-264 Vol. LU, 1949, pp. 117-120, and Vol: LIU, 1950, pp. 133-136), were distributed by the Dominion Coal Board and are still available on request. In this review, the first in the series in the field of combustion, development and trends during the period approximately from World War II to the present time are described and therefore the presentation is general. Later reviews will particularize developments in relation to the range of coals available in Canada.-ED. INTRODUCTION THE utilization of coal in heat and power producing equipment has become of paramount importance to the coal industry in maintaining stable and profitable markets. In the past, the chief concern was with mining, transportation, and overall supply problems, but modern conditions demand interest in and knowledge of all phases of the product, from coal in situ to its ultimate disappearance in the form of products of combustion. Even the last mentoined factor has caused complications, as is shown by current widespread activity in the field of smoke abatement

Jan 1, 1951

By Jim Truskoski, Alain Bouchard, Andy Kerr, Germain Labonté, Jim Barrett

"Improving mill grade recovery relationships is always good business. INCO’s Clarabelle Mill has just undergone a $16 million process upgrade that was designed to improve nickel recovery by 2%. The “Mill Redesign Project” was completed on time, under budget and delivered the promised improvement in recoveries.This paper describes the methodology of the Mill Redesign Team, details of the process improvements and the critical success factors that helped the team deliver on its promises.With a payback of under one year, the Mill Redesign Project will play a key role in ensuring a competitive edge as INCO embarks on its second century of operation.INTRODUCTIONIt is not uncommon in milling operations to encounter a crisis. That is the point when the process does not behave as expected and fails to respond to the increasingly desperate efforts of the metallurgists and operators. Flowsheet and process changes are attempted and abandoned. With luck, one or more of the changes achieves some mitigation of the original problem or more usually, the original cause of the problem disappears. Regardless, the metallurgist can sit back and bask in the apparent success of his or her endeavours.Less common is when a problem is carefully diagnosed, a team put together to explore all avenues and recommend a path of action that is implemented on time, on budget and immediately delivers on the promises which are sustained over time. This is one such story. It is the story of the Mill Redesign Project at INCO’s Clarabelle Mill in Copper Cliff, Ontario.BACKGROUNDThe Clarabelle Mill was built in 1971 on the southern rim of the Sudbury basin. At that time it was one of four mills operated by INCO in the Sudbury area. During the 1970’s, 80’s and 90’s, the need for increased process efficiency, higher levels of sulphur rejection to tails and the concurrent development of high capacity mills and flotation cells, resulted in the consolidation of INCO’s Sudbury area milling operations into a single, expanded facility at Clarabelle."

Jan 1, 2003

By John A. Legge Jr.

"ACCOMPANYING Alberta's great natural endowments of oil, wheat, scenery, fishing, and hunting is also a generous endowment of geophysical problems to plague the interpreting geophysicist. These problems — by no means unique to Alberta — are sufficiently numerous and outstanding to be of major concern in exploration. Some of them have been adequately solved, others are well on their way to being solved, and still others remain almost completely unsolved. Often a problem readily solvable in one area can be solved only with great difficulty in another. Many are closely allied with the geological conditions and require the best co¬ordinated efforts of the geologist and geophysicist for their solution.It is a fairly general practice to study rather carefully the geophysical characteristics of known producing reefs in order to obtain data on which to base an interpretation of unproven areas. This practice obviously has a very sound basis, for, as discoveries become more and more widespread in the Alberta basin, it is found that the variation' in geological conditions has a marked effect on the seismic results, as would be expected. By carrying this analysis over an area it is possible more and more to anticipate the geophysical picture which should be obtained in connection with reefing under the varying geological conditions. Another phase of this procedure, and one that has received less attention, though it is certainly of importance, is the analysis of the all too numerous failures. A study of these failures may be more fruitful than a study of the successes for it may indicate weaknesses of field procedure, computations, or in¬terpretation not particularly obvious in the discovery areas. These studies must not only include the geophysical characteristics of the observed `anomalies', but should also be coupled with a thorough geological study to ascertain whether some unanticipated geological condition is responsible for the erroneous geophysical interpretation."

Jan 1, 1953

By D. Nower

"The supply of copper is expected to be at a large deficit in 2012. To recover from these deficits mining companies are required to maximize production and there is no better way to accomplish this than to optimize the use of their mobile mining equipment fleets. To optimize these fleets, each equipment type has to be monitored in its own unique way. Automation would not only improve production, but also minimize the safety risks and eliminate planning errors. The automated vibration monitoring of multiple systems on the shovel can determine the machine’s condition at all times. This reduces unplanned downtime and keeps critical shovels in production. This paper will discuss the details of how shovels can be successfully monitored, continuously. INTRODUCTIONP&H Mining, part of Joy Global, is the world’s largest manufacturer of above-ground mining equipment. Its electric rope shovels, such as Figure 1, with capacities up to 115 tons (104.3 metric tons), are used for high production loading in surface mines; its draglines, such as Figure 2, have bucket capacities to 160 cubic yards (122 cubic meters). P&H also produces blasthole drills, mobile mining crushers and other essential mining equipment. Headquartered in Milwaukee, WI, the company does business on every continent, except Antarctica. ECONOMIC FACTORSDue to the global demands for metals and power, mines are required to operate at full capacity. Mine operations cannot afford any critical assets to shutdown unexpectedly; depending on the ore type and quality, downtime for a single shovel can be as much as $300,000 per hour.Electric rope shovels are one of the most critical assets in open pit mining. They are very large, complex machines with DC or AC motors, multiple reduction gearboxes (some of them complex planetary) and multiple large rolling element bearings. This complexity, combined with the tough 24/7 service, results in too much unplanned shovel downtime, which can affect the entire downstream process."

Jan 1, 2012

By A. Ignatieff

Introduction Some interest is being shown in Canada in underground gasification of coal and, as developments have now taken place in several countries of the world, it is thought that a review of progress, particularly from the viewpoint of a mining engineer, may be of interest. The literature on the subject, and notably that of Russian origin, is already very voluminous. The various methods of underground gasification of coal have evolved from initial attempts to employ underground workings as gasifiers of previously fragmented coal or to use some method that involves little or no preparatory work underground. The 'stream' method, shown schematically in Figure 1, has been the only one used in tests to date in countries outside the U.S.S.R. Other methods, involving preparatory work underground prior to gasification, are the early 'chamber' method, where fragmented coal was gasified in rooms between inlet and outlet entries, and the underground borehole' method, illustrated in Figure 2, where gasification is developed in a succession of boreholes which are temporarily sealed and then abandoned in turn after gasification. The stream method appears. to be particularly suitable for pitching seems as it is claimed that the pitch prevents ash accumulation or serious blockage from roof falls, and it also aids the circulation of the stream. As a considerable proportion of Canadian medium and high-rank coal seams are inclined, it would seem that, at least at the outset, the stream method or a modification thereof would be the one most applicable to all but the Saskatchewan lignite fields and the flat domestic-coal fields of Alberta.

Jan 1, 1949

By Magdy Ibrahim

This paper presents experimental design and development of a low-cost remote sensing hardware designed to support automated site data acquisition for near real-time progress reporting of construction operations. The developed hardware utilizes open source microcontroller equipped with multiple sensors that include 3D accelerometer, GPS, Data logger and Bluetooth. The use of open source microcontroller makes the developed design cost effective; freeing it from the need for costly license fees. Its platform configuration is flexible; enabling the addition of temperature, weight and other sensors, Wi-Fi and Xbee capabilities to suit individual field applications. Pilot tests have been carried out in laboratory and outdoor environments. The results prove effectiveness and robustness of the developed configuration. The paper provides description of the individual components used in the development of this prototype hardware. It also describes the technical characteristics, capabilities and limitations of the developed hardware. The findings of comparison with alternative technologies used for outdoor tracking of construction operations are presented. The comparison is carried out with respect to range, cost and suitability for outdoor environment. The developed hardware is expected to support a wide range of applications including tracking of earthmoving operations, highway construction and onsite resources. As well, it is expected to enhance safety on construction jobsites.

Aug 1, 2013

By Robert A. MacGregor

"Following several months of test work, water leaching in mined-out areas at Stanrock commenced on a production basis in February, 1963. A combination of fast high-pres-sure washing and rewashing of stopes on a predetermined cycle, and the intermittent sprinkling of low-grade heaps, using both fresh water and recirculated acid water, has proved most successful. There was also a correlation of daily sampling data points to a relationship between the leach water grade and the grade of the material being washed, the leaching time and the location along the dip. An increasing tolerance for uranium by the acid-producing bacteria is also indicated. A steady production rate of 10,000 to 12,000 lbs. of u.08 per month is being maintained, with an over-all mine water grade of 0.25 lb. per ton and a pH of 2.3."

Jan 1, 1966

By Don Thompson

Canada’s oil sands are a controversial topic and virtually every newsmaker and layperson seems to have an opinion about this 179 billion barrel resource. The oil sands represent 97 per cent of Canada’s remaining oil reserves, but misinterpretation and misrepresentation of the facts are threatening development of a resource that generates significant employment and tax revenue for Canadians. Join Don Thompson, president of the Oil Sands Developers Group, as he dispels the top ten myths about Canada’s oil sands and presents an alternative perspective on an industry that can play a critical role in North America’s economic recovery.

Jan 1, 2010

By J. Ran

"Hangingwall sloughing is the major cause of unplanned stope dilution in open stope mining. Understanding the hangingwall sloughing mechanism can guide the stope design in minimizing the unplanned dilution and improving muck size and therefore mining efficiency. Though the modified stability graph method may be adopted to assess the hangingwall stability, for mines where the hangingwall is inaccessible, the required parameters are difficult to define and some of the simple influential factors cannot be easily identified in this method to provide guidelines for stope design.This paper identifies the main modes of hangingwall sloughing in open stope mining based on detailed data collected from mined-out stopes and site observations, applies the voussoir beam notation to analysis of the hangingwall sloughing mechanism, compares the model analysis results with the collected stope data, and provides guidelines for stope design and model application. Finally, examples are given to demonstrate the time and support effects on hangingwall sloughing and stope dilution."

Jan 1, 2002

By R. W. Boyle, W. Dyck

"Scientists throughout the world have observed radioactive disequilibrium in the uranium decay series. Radiometric and fluorometric determinations of U in plants from the Goldfields district and in sediments and rocks from the Beaverlodge district exhibit marked radioactive disequilibrium. The eU/U ratio in plants rooted in mineralized ground shifts from greater than unity to less than unity for those rooted in background soils. A similar shift is observed in the transition from rocks to stream sediments and to lake sediments in the Beaverlodge district.Results of a Rn-Ra-U survey of lake bottoms in the Key Lake district show that anomalous hydromorphic U from U mineralization is parallelled by anomalous Rn, even though there is much less Ra in the lake-bottom sediments than one would expect from the amount of U present. IntroductionDisequilibrium in the U decay series has been studied for many years and is observed in almost all surficial environments. Rosholt (1959) measured U, 234Pa, 23O'fh, 226Ra, 222Rn, and 210Pb in a large number of U ores and outlined six types of situations to explain disequilibrium. Davy (1974) outlines the geological significance of radioactive disequilibrium situations with respect to exploration. Levinson and Coetzee (1978) discuss possible mechanisms by which separations of parent and daughter elements are affected and suggest analytical pitfalls that may be encountered in the use of radiometric techniques when disequilibrium has occurred. Generally, it is the oxyphile and easily complexed parent 238U (with its associated isotopes 235 U and 234U) that is leached from rocks and soils at a faster rate than are the daughters, 230Th, 226Ra, 2loPb, and 206Pb. This mobilized U is adsorbed on sediments in streams and lakes, or enters groundwaters, where it is eventually precipitated under reducing conditions, occasionally in oregrade concentrations. This surface leaching and"

Jan 1, 1980

By K. Awuah-Offei

Long-term production scheduling optimization has been a challenging issue for the mining industry because of the size and complexity of the problem. The current planning algorithms have limitations in terms of addressing the stochastic variables underlying the mine planning problem. In this paper, an intelligent agent-based mine planning framework based on reinforcement learning is introduced. The long-term mine planning is modelled as a dynamic decision network. The intelligent agent interacts with the block model by means of a stochastic simulation and employs a Q-learning algorithm to learn the sequence of pushbacks that maximizes the net present value of the mining operation. The intelligent open pit simulator (IOPS) was implemented with an object-oriented design in Java®. A comparative application case study was carried out to verify and validate the models. The proposed method was used in planning an iron ore deposit and the results were compared to the Milawa scheduler used in Whittle® software. The outcome of the study demonstrates that the intelligent agent framework provides a powerful basis for addressing real-size open pit mine planning problems.

Jan 1, 2008

By Jodi Roberts, Curtis Deredin, Jean-Guy Paulin

"Since the establishment of the Six Sigma quality improvement program in 2001, several projects have been successfully carried out in the copper-lead, zinc, copper separation, lead upgrading and bulk flotation circuits in the Brunswick Concentrator.This paper provides an update on the process improvement initiatives that have taken place since 2004 using the Six Sigma methodology:•,The recirculation of warm water to the flotation circuit (to save on energy costs)•,Installation of a heat recovery tower to recuperate the heat lost from the zinc dryers•,Installation of an extra row of cleaner-scavenger cells for the copper-lead circuit for extra capacity, and a new reagent scheme for the copper separation circuit that have increased copper and lead recoveries.INTRODUCTIONThe Brunswick Mine Concentrator (Xstrata Zinc Canada) is located near Bathurst, New Brunswick and is one of the world’s largest lead/zinc mines. Milling of ore commenced in 1964 from the No. 12 orebody, with an expansion in 1966 to accommodate ore from the No. 6 open pit mine. The concentrator utilizes selective flotation to produce zinc, lead, copper, and bulk lead/zinc concentrates. The ore is a complex massive sulphide, consisting of approximately 20% valuable minerals, 60% pyrite and 20% silicates.Figures 1, 2, and 3 illustrate the historical annual average metallurgical performance and process improvements achieved at Brunswick Mine for the zinc, lead and copper concentrate products. The objective is to continuously direct metallurgical performance towards increasing grades and recoveries while minimizing operating costs."

Jan 1, 2008

By C. A. Y. Shephard, H. L. Brusset

Pressure maintenance by water flooding in the Pembina Field made consideration of wet crude dehydration and disposal of the produced water mandatory. Crude dehydration, the treatment and disposal of produced water, as well as the sale of gas and crude oil were expected to be handled more efficiently at one central point than at several conventional batteries. This plan was effected by routing the produced fluids to the central station by way of several well testing batteries referred to as satellites. To realize the full efficiency inherent in such consolidation the entire system was made self-regulating. Programming ensures the testing and proper routing of all products to their destination. Forty producing wells have been self-operated during the winter 1959 -1960 with gratifying results.

Jan 1, 1960

By G. A. Vissac

In this paper we intend to deal particularly with the economic side of coal washing as it applies to our mines. We will then discuss why the dry-cleaning process has been selected, and give a brief description of our plant, dwelling only on its specific features and referring the reader to the numerous papers published on the subject for any details on the principles and machinery used in dry cleaning. ECONOMIC DISCUSSION The washery introduces an extra cost for depreciation, operation, and loss in treatment. A certain proportion of the coal, now being sold, and which the miners have been paid for. will have to be wasted. As a whole, the total increase in cost would be approximately 60 cents per ton. On the possibility of recovering this amount depends the success of the washery. There are two advantages to be expected from the washery, the first, which occurs at the mine and which will be certain; the second, more difficult to estimate, because it depends upon convincing our customers that they should pay more for a better product.

Jan 1, 1924

By M. Reda

Inorganic oxidizing agents of the type MeOx-z such as Chromate, Vanadate, Tungstate, and Molybdate... etc. are widely used as corrosion inhibitor. In non acidic solution these oxidizing agent are reduced on the surface of the meta, according to OX + m e + p H20 Red + n OH" In which y = (n-m)/m. The purpose of this publication is to show that for many metals the value of y for any oxidizing agent determines the possibility of that oxidizing agent being an inhibitor or activator for the corrosion process. The inhibition efficiency for other ions such as Pertecnetate and Tellurate which have not been extensively studied can be predicted. A mathematical, equation was derived to express the relationship among the concentration of oxidizing agent, degree of retardation of the corrosion process I cord cor ° (ratio of corrosion current in the solution containing inhibitor to the base solution) , ionic strength of the solution and the coefficient y. The validity of y and the mathematical, equation were verified by many experimental, works on various metals such as zinc, aluminum and steel. Al, the above research works are based on the published research works of Prof. Mikhailoviskii (from 1979 til, 1998) from the Russian Academy of Science.

Jan 1, 2010