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"The QEMSCAN system is the third generation of automated mineral analysis systems that began with the QEM*SEM at CSIRO 30 years ago (Butcher et al. 2000). It is now a successful commercial instrument with 39 instruments in operation around the world. Back Scattered Electrons (BSE) and Energy Dispersive (EDS) X-Ray spectra are used to create digital mineral images with mineral identification occurring online. Low-count EDS spectra are used preferentially to BSE brightness, allowing minerals to be accurately identified by chemical composition. Individual minerals or groups of similar compositions are identified by comparison to a comprehensive mineral database incorporated into the QEMSCAN software. Optical mineralogy and Scanning Electron Microscopy is a metallurgists’ tool for determining the ore process mineralogy and delivering a better flowsheet. These techniques have limitations, provide limited information and sometimes fail to provide representative information. In contrast, QEMSCAN provides information on the nature and occurrence of all mineral species present plus the liberation characteristics, looking at thousands of particles in the sample presented. Some of the data presented includes:• Particle and grain sizes• Dominant mineral species• Particle shape• Calculated metal content• Density• Deportment of elements of interest between the mineral phases• Quantitative mineralogy• Mineral associations, locking and liberation• Textural relationships (particle images)It can also be used on concentrates, polished sections or drill core. This is a significant improvement in ore characterisation providing lithology, mineralogy, liberation, ore grade and porosity from a sample. Theoretical grade-recovery curves can be created to be mineralogically limited from QEMSCAN analysis which, when compared with metallurgical results, are valuable in evaluating whether liberation or chemical selectivity is driving flotation performance. A number of case study examples are given where the QEMSCAN had a significant bearing on future project development at an early stage of exploration and mine development."

Jan 1, 2012

By Charles "Chick" Rodgers

"The Key Lake uranium mine is the largest single uranium producer in the world. It is owned 2/3 by Cameco Corporation and 1/3 by Uranerz Exploration and Mining. Cameco is the operator. Current production is fourteen million pounds per year of uranium oxide (U308).The mine's location is 570 kilometres north of Saskatoon on the southern edge of the Athabasca Basin approximately at latitude 57° 11 'north and longitude 105° 34' west. Access to the mine is by an all-weather road and a private airstrip.The mill was commissioned in 1983. A molybdenum plant was constructed in 1989 in response to increasing molybdenum content in the yellowcake or final product. Early test work had showed that the first ore body to be mined, the Gaertner deposit, would present few problems with regards to molybdenum in the product. However, the test work also showed that the higher molybdenum content of the Deilmann ore, the second Key Lake orebody to be mined, would result in increased molybdenum concentrations. Without the molybdenum plant, penalties would become excessive and some product might not accepted by the refineries.This paper will describe the current Key Lake mill process with emphasis on the molybdenum solvent extraction process. It will cover the chemistry of the process, process development in the mid 1980's, and current operating practices.The Key Lake milling process consists of five individual plants, crushing and grinding, leaching -counter current decantation (CCD), solvent extraction, yellowcake/crystallization and bulk neutralization (Figure 1. Simplified Mill Flowsheet). A detailed mill flowsheet can be found in the appendix."

Jan 1, 1996

By John Blackshaw

NEW sources of supply of tungsten concentrates became necessary when the flow from the Far East was blocked in 1942. In Canada, one source has been noted in the workings of the Hollinger mine at Timmins, Ontario. For many years, a small amount of scheelite had been removed with the gold ore, and an appreciable tonnage of scheelite still remained in the mine. At the request of the Dominion Government, a plant was built to recover this scheelite in the form of a concentrate that could be used by the alloy-steel industry without further preparation. The plant began operating early in March, 1942, and a small tonnage of ore, carrying scheelite and gold values, has been treated daily since then. The possibility of recovering the scheelite had been considered on several previous occasions. Each time the proposal had been given up because the total profits from the enterprise were estimated to be insufficient to repay the capital cost of building the recovery plant. At the time the plant was built, additional information had been gathered about the tonnage and grade of the scheelite ore in the mine, and several thousand tons of ore grading higher than 0. 25 per cent WO3 (tungstic trioxide) were known to be available.

Jan 1, 1943

By Ilpo O. Auranen

Background: Mines of today are moving ever increasing tonnages of rock. The new ore bodies tend be of lower grade and located deeper in the earth?s crust. The industry?s focus to overcome this ?deeper but poorer? ore problem has traditionally been to lower the costs by increasing the scale of mining. This has resulted in an ever increasing size of mining equipment like drills, loading shovels, dump trucks. The main focus has been in reducing the cost per ton of mining. This cost focus has often resulted in increased waste rock dilution and more ore losses. From costs to value: Waste rock dilution means waste rock in the concentrator feed. It?s value in open pit mining is equal to the value of ore it replaces. In underground mining, waste rock dilution?s value is equal to the value of ore it replaces added to the costs of mining it. It is commonly accepted that waste rock dilution in open pit mining ranges between 5 and 20% and in underground mining between 5 and 40 % . In a typical large open pit mine ore value is from 20 to 60 USD per ton and mining costs are 1 to 3 USD per ton. One percentage point reduction in waste rock dilution represents savings corresponding to about 20% of total mining operation costs. The difficulty of reducing waste rock dilution comes from the complicated nature of the ores. Accurate ore waste-border detection has not been possible due to excessive costs. Core drilling combined with geochemical lab analysis is the most accurate method for locating ore waste borders. However, it is also expensive and time consuming, which is why it is often combined with somewhat lower cost methods like sampling drill cuttings from blasting drill holes or from reverse circulation drills and analyzing them in a laboratory. The main drawback with these methods, in addition high costs, lies in the sampling accuracy and in the quality control of the whole process when a large number of samples have to be handled manually. In every mine it is possible to halve waste rock dilution by using new on-line analysis technology .

Oct 1, 2009

"Syncrude Canada Ltd. operates one of the largest surface mines in the world. The mining operation has two distinct phases: (1) the removal of the overburden, utilizing trucks and shovels; and (2) the mining of oilsand with drag lines and bucketwheels. Both phases combined move approximately 330 000 BCM per day.In support of current production demands and to provide a contingent oi/sand source, Syncrude has developed an Auxiliary Production System (APS) supported by the truck and shovel operation. This system utilizes oilsand sources within the existing mine area on an as-needed basis.The recent increased capabilities of the processing plant to handle a larger volume of oilsand has increased the reliance of the APS system. To facilitate the increased capacity, an auxiliary mine was developed external to the Base Mine operation with a production capacity of4.7 MBCM of oilsand per year.Development of the Northwest Auxiliary Pit began in January 1990, with the first cubic metre of oilsand taken to the plant in June, 1990. The Auxiliary Pit, as designed, has a total ore reserve of 68 MBCM of oi/sand."

Jan 1, 1993

By M. K. Mishra, U. M. R. Karanam

Relative to slender pillars, larger size pillars exhibit improved strata control. Fly ash, though traditionally treated as a waste product, is emerging as an alternate engineering material. This paper deals with the development of a strong fly ash composite material with additives. The geotechnical properties of this fly ash composite were determined and used to trap model core pillars, which resemble squat pillars. The trapped samples were tested under uni-axial loading in the laboratory and the results showed higher load-bearing capacity of the model core pillars. The reinforced fly ash composites provide lateral confinement and exhibit improved post- failure behaviour of the model cores.

Jan 1, 2008

By P. P. Andrieux

The recovery of the Zone G crown pillar, located between the bottom of the open pit and the top of the underground workings at the Raglan Katinniq Mine in Nunavik, started in the summer of 2008 and should be completed by the end of 2009. This article describes the rock mechanics-based approach implemented to design the recovery of this valuable block of ore. The stereophotography-based ShapeMetriX3D technique was first used to provide a comprehensive assessment of the various joint sets that comprised the pillar. Then, the statistical distributions obtained for the dip, dip direction, spacing and persistence of these sets were used in conjunction with the geometry of the large-scale faults present in the area to build and run a series of explicit rigid numerical models. Each of these models had a slightly different jointing geometry, randomly constructed from these statistical distributions. Incorporating in a properly formulated numerical model the variability of some of the input parameters has allowed the engineering team to assess in a rational and reliable manner the likelihood of success of the proposed mining method and sequence.

May 1, 2009

By A. Boehm

"For recycling LD slag into the steel making process, the phosphorous containing calcium silcate phases have to be removed from iron oxide phases. One possible technical solution could be magnetic separation in a wide range of susceptibilities from ferromagnetic to paramagnetic. To check the feasibility of magnetic separation the distribution of the magnetic susceptibility in size classes as well as the liberation of the phosphorous containing phase were evaluated by a new method combining two dimensional physical property analysis with QEMSCAN analysis. The particle size classes of energy controlled comminution products were subdivided into fractions of defined magnetic susceptibility using a hand magnet of well known field properties (pick up method). On the one hand the susceptibility classes were wet assayed on the other hand analyzed by QEMSCAN followed by data evaluation using iDiscover 5.3.1(FEI), which was adapted to the data structure of two physical properties (size and magnetic mass susceptibility). The results allow the comparison of mass based (3D) cumulative distribution of grades from the wet assays with the area based (2D) distribution from QEMSCAN analysis, in order to control a systematic (size dependent) stereological error for this special type of material. As the physical separation property forms a crucial parameter the results from the liberation analysis by QEMSCAN can be interpreted more profound with respect to an expectable separation result. Once the various mineral compositions of the particles are assigned to the physical properties the Henry Reinhardt chart serves to predict the best possible separation result and thus the feasibility of a separation technique.INTRODUCTIONThe two Austrian steel plants operated by voestalpine AG produce about 650,000 t (voestalpine 2014) of LD slag in the course of steel production from pig iron according to the basic oxygen process blowing oxygen in the converter by an oxygen lance. The process is also known as the Linz Donawitz (LD) steelmaking process. By the addition of lime (CaO), carbon, phosphorus, silica, manganese and sulfur, which are present in the molten pig iron, shall be oxidized and bound in the slag either as oxide or silicate phases, or leave the slag in the gaseous phase (CO). The average chemical composition of the investigated LD slag is given in table 1."

Jan 1, 2016

By G. Belzil, F. Robichaud, M. Fullam

"The Goldex mining and milling complex is operated by Agnico-Eagle Mines Ltd. and is located in the Abitibi greenstone belt of Northwest Quebec, Canada. The mill operates presently at a throughput of 8,250 tpd with gold grade varying between 1.8 and 2.2 g/t. The ore is very high in gravity recoverable gold (GRG) at about 92% and as such a significant emphasis was placed on the gravity circuit. Commercial production started in 2008. Average gold recovery is 93.5% with about 68% of gold recovery coming from the gravity circuit. Over the course of the first several years of production, several gravity audits were carried out. In 2009, a complete gravity audit was completed, including ore, classification, Knelson Concentrators, and the gold room. In 2011, an audit was undertaken of the flotation circuit to determine the efficiency by which GRG is floated. Large samples of flotation feed and tails were collected and process for GRG content. This allowed a link between gravity and overall recovery to be made. This paper presents results of the audits and the development of a model linking gravity and overall gold"

Jan 1, 2012

By John Canterford

Quay Magnesium Limited (QMG) listed on the Australian Stock Exchange in late September 2004 having raised approximately A$30 million with the object of designing, constructing, commissioning and operating a 15,000 t/a magnesium alloy production facility in Nanjing, China, Site construction commenced in February 2005 with installation of all major components completed by the end of October 2005, Hot commissioning was simultaneously commenced with the final stages of installation, leading to the first stage of continuous ingot casting by mid November 2005, Since that time ramp-up to the name plate capacity has been undertaken, This presentation highlights some of the more significant technical and logistical hurdles that have had to be overcome in order to meet the high quality product specifications required by a range of QMG customers.

Jan 1, 2006

By Pierre Roy, Claude Gosselin, Maryam Sadeghi, Michel Bourassa, Christian Rochefort, Claude Bazin, Gautier Mahieu, François Lavoie, Marilène Renaud, David Cataford

"Spirals are gravity concentrators used for the concentration of iron oxide minerals from ores. This paper presents the mineral size recovery curves observed for spirals operating in two Canadian iron ore processing plants. The size recovery curves are presented for rougher, cleaner and re-cleaner spirals. The partition curves observed for the spirals are significantly different than those observed for typical gravity concentration devices such as hydrocyclones or hydraulic classifiers. The size recovery curves show the complex behaviour of the minerals as they flow down a spiral and are analysed with a view toward process modelling and simulation. Initial simulation results show that gains in the iron recovery can be achieved by increasing the recovery of coarse iron oxide particles in the rougher spirals.INTRODUCTION Spiral concentrators are gravity based separation devices used for the preparation of coal, iron and different heavy minerals ores (Wills, 1992). The classification of the particles in spirals is based on the combination of gravity, centrifuge, drag, lift and Bagnold forces (Atasoy and Spottiswood, 1995; Burt, 1984; Bouchard, 2001). Several papers are dedicated to the analysis of the forces acting on the particles flowing down a spiral (Das and al., 2007; Sivamohan and Forssberg, 1985; Holland-Batt and Holtham, 1991; Holtham , 1992). Most of these papers aim at the development of a general model for the simulation of the classification of the particles for coal ore processing. Few papers deal with the operation of spirals for processing iron ores (Hyma and Meech, 1989; Srivastava, 2001; Dallaire et al., 1978) and fewer papers present results for spirals used as cleaners following a rougher stage. Since the classification in spiral classifiers is dependent on the particle size and specific gravity a partition or performance curve commonly applied to classifiers (Mai Manga et al., 2012) is used here to analyse spiral operation. Few papers were found to describe the operation of spirals in terms of partition curves (Atasoy and Spottiswood, 1995; Holland-Batt and Holtham, 1991; Richards et al., 2000). Most of the investigations presented the application of a model to simulate the position of coal particles of various sizes and specific gravities along the trough of a spiral (Kapur et al., 1996; Holland-Batt and Holtham, 1991). In addition most of the available literature on spirals deals with one stage of concentration by spirals (Dallaire et al., 1978; Das and al., 2007; Sivamohan and Forssberg, 1985) while industrial circuits usually consist of rougher and cleaner spirals."

Jan 1, 2014

By H. T. Kennedy, D. L. Flock

"The project described in this pa-per was undertaken to provide a more thorough understanding of the effect of contamination by drilling fluids on the electrical properties of porous systems. The basic work per-formed was filtration tests on both consolidated and unconsolidated sands and the determination of their resistivity profiles with the aid of screen-type electrodes spaced at convenient intervals along the core.Four drilling fluids were selected, ranging in resistivity from 447.0 ohm-cm. to •5.76 ohm-cm. The permeability of three unconsolidated and four consolidated cores, on which resistivity measurements were made, varied from 1,257 md. to 4,560 md. Five additional cores with permeabilities as low as 49 md. were tested to investigate the effect of permeability on the depth of invasion of drilling fluids.The effect of drilling fluid invasion on resistivity profiles was determined on cores containing brine only, and on those containing 80 to 90 per cent oil and 20 to 10 per cent brine. The study included measurements of (a) clay content of different sections of the core, (b) saturation of the invaded fluids and oil in different parts of the core, and ( c) changes in resistivity as a result of gravitational re-distribution of fluids and diffusion of electrolytes.The data showed that the resistivity of an invaded core is, as was expected, controlled by the resistivity of the filtrate, the resistivity of residual core water, the resistivity of the clay particles, and the amount and distribution of the filtrate, clays, residual oil, and brine. In most cases there was a significant increase in resistivity owing to the presence of clay solids which had invaded the core. The change in resistivity, as a result of the diffusion of salts, was substantial after a period of five hours. There is evidence in some cases that the residual oil and core water saturations of the unconsolidated cores, after substantial invasion, are very low, indicating almost complete displacement by invading fluid."

Jan 1, 1959

By L. T. Pasiechnyk

After a brief review of the various hydrocarbon storage methods currently being utilized and statistics on underground hydrocarbon storage, this paper will briefly describe the technology involved in solution mining salt to create caverns of engineered shape and size and briefly discuss the economical and environmental advantages of hydrocarbon storage in solution-mined salt caverns. Other possible uses of salt caverns will be mentioned.

Jan 1, 1978

By J. R. Goode

"The Las Cristinas deposit in Venezuela contains reserves of 12.8 million ounces of gold at a grade of 1.20 g/t (Crystallex, 2004). The deposit comprises fully oxidized saprolite (SAPO) overlying a layer of sulphide-enriched saprolite (SAPS) which lies above carbonateleached bedrock (CLB) and carbonate stable or un-leached bedrock (CSB). Gold occurs at about the same concentration in all lithological groups. The bedrock units contain minor amounts of copper (about 0.1%) as chalcopyrite, while SAPO contains virtually no copper which has been leached and deposited in the SAPS zone.A previous owner began investigation of the Las Cristinas deposit in 1991. Over the next seven years, the company drilled 1,174 holes with a total length of 159 km, conducted extensive metallurgical testwork, including pilot plant operations, and completed feasibility studies. Construction was started in 1997 and again in 1999, however, on each occasion was suspended.Crystallex has been producing gold inVenezuela since the early 1990s. In 1997, Crystallex acquired Inversora Mael which had held two of the claims to the Las Cristinas concessions since 1986. In September 2002, Crystallex entered into a definitive agreement with the Corporación Venezolana de Guayana (CVG) to develop the Las Cristinas deposit.An extensive program of studies and testwork was started in late 2002 to determine an optimum development plan for Las Cristinas. Mine Development Associates, SNC–Lavalin Engineers and Constructors, SGS Lakefield Research Limited, J.R. Goode and Associates, and A. Laplante at McGill University acted as the main contractors.Because of the potential value of by-product copper, earlier flowsheets used carbon-inleach for SAPO, but processed all other ore types by flotation to produce a gold-copper concentrate with cyanide leaching of cleaner tailings to maximize gold recovery. Cyanide recovery was necessitated by the high copper content of the leach feed. Initial studies of available data by Crystallex revealed that direct leaching of all ore types would provide about 11% more gold recovery than the previously selected flotation route with reduced capital and operating costs.Bench and pilot-scale studies have confirmed that a SAG-ball mill-gravity-CIL route is very effective for all ore types and will give about 89% gold recovery. This paper describes the testwork conducted in 2003, discusses a 20,000 t/d plant design, and presents economic data."

Jan 1, 2005

By J. E. Nesset, W. Zhang, J. A. Finch

Frother influences water recovery through control of bubble size and a chemical effect. De-coupling the two is necessary to establish the extent of the chemistry effect. A setup is described to give steady state water overflow rate (Jwo) along with measurements of bubble size into and on top of the froth. Arguing neither bubble size correlates directly with water overflow, a frother mass balance is solved to estimate the bubble surface area flux in the overflow (Sb0 ). The solution required measurement of frother concentration using TOC analysis and frother adsorption density using surface tension data. The relationship between Jwo and Sbo reveals the frother chemistry effect, quantified for discussion purposes by an equivalent water layer thickness.

Jan 1, 2009

By Murray Wood, Michael Schaffer, Makat Katom

"An expert system applied to the control of mineral process unit operations is, by its nature, the site best operating practice, having been designed by the local experts in conjunction with consulting metallurgists. The “common sense” layer in a MET (MinnovEX Expert Technology) solution determines an appropriate action for the current operating conditions through a developed heuristic model of the process (expert system). The magnitude of the setpoint change that is made is proportional to the confidence that the system has in its interpretation of the current conditions (fuzzy logic). The solution is always striving to take the process to a constraint and thereby optimise the operation. An accepted limitation of the solution is that the only way the system can determine if a constraint has been reached is to exceed it and then withdraw – essentially “experimenting” with the process. By leveraging a model, which can accurately ""simulate"" the process, this restriction can be circumvented by pre-testing the set point change through a ""what if"" analysis and then modifying the solution as appropriate.At Ok Tedi, the introduction in 1999 of a MET expert system for SAG milling resulted in significant improvement in circuit throughput. Yet, with the additional inclusion of an accurate model of the process there was still more that could be achieved. Hence, in 2002 a MET Neural Network model was developed and deployed to enhance the existing expert system solution. The principal objective of this model was predicting the effect that changes in SAG tonnage and density would have on the power draw of the mill - essentially a power predictor. The results have seen a decrease in process variance with an associated increase in average circuit performance.This paper describes the methodology by which the Neural Network model was implemented, the considerations and limitations when applying this technology and ultimately the results that were achieved."

Jan 1, 2003

By John Tribe

"This paper gives the organizational history of Luscar Ltd. and its various coal producing operations. Each 0/ the operations is then described individually. They include the Bienfait Mine, the Boundary Dam Mine, the Diplomat Mine, the Luscar Mine and the Coal Valley Mine. The company's plans/or expansion are also discussed. IntroductionLuscar Ltd. is an Edmonton-based energy company formed in 1967 through an amalgamation of two pioneer coal companies-Mountain Park Collieries and Luscar Coals Ltd. In 1912, Mountain Park Collieries initiated the development of an underground mine in the Coal Branch area of Alberta. This mine necessitated the establishment of a townsite and the provision of rail access. The second operation, Luscar Coals Ltd., was established in 1921 at Luscar, Alberta. This was also an underground operation and required the development of a rail spur and townsite. The product from both mines was used to fuel railway steam locomotives until the 1950's. The market demand for coal decreased as the use of the diesel locomotive increased, so that these operations were finally closed in 1954. Through the amalgamation of the two companies in 1967, however, Luscar Ltd. was formed to become an active participant in the revival of coal operations. Western Canadian Luscar Ltd. is involved in the exploration, development, production and marketing of coal, coal products, oil and gas. Luscar Ltd. is currently participating in five producing mines (Fig. I). The Diplomat Mine, approximately 125 miles southeast of Edmonton, was in production when it was acquired in 1949 by Luscar Coals Ltd. In 1966, the Bienfait Mine and char plant were added. The Luscar Mine, which is a 50/50 joint venture of Luscar Ltd. and the Consolidation Coal Company of Canada, and is operated by Cardinal River Coals Limited, started production in 1969 on the original Luscar Coals Ltd. mine site. The Boundary Dam Mine was opened in 1974. Both the Bienfait and Boundary Dam operations are located in the lignite coal fields of southeastern Saskatchewan. The most recent addition to the group is the Coal Valley Mine, 40 miles southwest of Edson, Alberta. It commenced commercial production in July, 1978 under the operation of Luscar Stereo (1977) Limited."

Jan 1, 1980

By Z. Xiao, A. R. Laplante

"The recovery of gold by gravity from grinding circuits differs from virtually all other gravity recovery approaches in that stage (or unit) recoveries are low, typically 1 to 5%, but overall recoveries are generally in the 25 to 60% range, because individual gold particles are presented many times to the primary recovery unit. Full-scale recovery is difficult to predict from benchscale tests. Further, maximizing metallurgical recovery is generally not the primary objective, because of the more efficient downstream recovery circuit (flotation or cyanidation). In this paper, a new concept, the gravity recovery effort, is presented to assist in the design and optimization of gold gravity circuits. It is defined as the product of the circulating load treated by the primary gravity unit, the recovery of this unit, and the gold room recovery. Predicted gold recovery is linked to the recovery effort, the size distribution of gravity recoverable gold (GRG), the dimensionless retention time in the mill and the partition curve of GRG. A case study of economic optimization of the gravity recovery effort is presented. INTRODUCTIONPredicting gold gravity recovery from grinding circuits has always been a hit-and-miss exercise. The problem can be traced to the highly variable gravity recoverable gold (GRG) content of ores, high GRG circulating load, fraction of the circulating load treated, and performance of primary gravity recovery and gold room. Typical values, highs and lows are shown in Table 1."

Jan 1, 2001

By O. Matwijenko

"The Kidd Creek concentrator is located twenty-six kilometres east of Timmins, Ontario, within a metallurgical complex including a 109,000 MTPY zinc plant and a new 59,000 MTPY copper smelter and refinery. A complement of 159 persons is employed in the operation of the concentrator.Ore from the Kidd Creek Mine is crushed underground to minus 15. 0 cm, then transported twenty-seven kilometres by rail 1:0 the concentrator. After being crushed to minus 1. 6 cm, the ore is further processed by grinding and flotation.The concentrator commenced operations in November of 1966 at a designed capacity of 8,200 MTPD. Two parallel flotation and grinding circuits treated copper-zinc ore (2.28% Cu, 5.63% Zn) and a third treated silver-copper-lead-zinc ore (230 g/MT Ag; 0.57% Cu, 0.88% Pb, 7.89% Zn).By 1975, the concentrator was treating 9,100 MTPD of ore. Seven concentrates were being produced, namely, high silve1: copper, low silver copper, lead, low silver zinc, high silver zinc, pyrite and tin.Planned minesite expansion to a second underground mine required increased concentrator throughput. Expansion of the concentrator enabling a thirty-three percent increase in copper-zinc ore throughput occurred during the period 1975 through 1978. This expansion included increased load-in capacity, major redesign in the crusher house, the addition of a fourth grinding and flotation circuit, the building of a fourth dryer, and numerous expansions of services."

Jan 1, 1980

Surfaces forces have been measured between gold sphere and gold-coated glass plate in xanthate solutions using an atomic force microscope (AFM). The measurements conducted in potassium amyl xanthate (PAX) and potassium ethyl xanthate (KEX) solutions showed long-range hydrophobic forces, with the force curves showing no evidence for nanonubbles on the surface. The strongest hydrophobic force was measured at contact angle of 94° with a decay length of 23 nm. The hydrophobic force became weaker at higher concentrations and after a long immersion time, which may be attributed to the xanthate species adsorbed on top of the first mono layer. The hydrophobic force became stronger when the residual xanthate solution is displaced by pure water, indicating that hydrophobic force becomes the strongest in pure water.

Jan 1, 2009