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By C. Gosselin, G. M. Payenzo, C. Bazin, M. Desnoyers, G. Chevalier

"ArcelorMittal Mines Canada operates hydraulic classifiers to reduce the silica content of an iron oxide concentrate from 4.5% to less than 1.2% SiO2. Sampling campaigns were conducted to develop a preliminary model for the hydraulic classifier. Results show that iron oxide and quartz are respectively concentrated in the coarse and fine size fractions of the classifier feed. The mineral partition curves in the classifier and the size distribution of the minerals in the feed are used to simulate the classifier operation in order to identify the source of variability observed in the daily plant production data. Results indicate that most of the variation is probably caused by unsteady operating conditions of the classifiers.INTRODUCTION Hydraulic classifiers are a class of gravity separation devices (Wills, 1992) used to classify particles according to their size and specific gravity. Hydraulic classifiers also known as density separators (Hearn, 2002) combine hindered settling and upward flow of water to selectively entrain light particles to an overflow stream. Denser particles settle to an underflow stream. Hydraulic classifiers are used for various purposes ranging from cleaning of coal (Das, Sarkar, & Mehrotra, 2009), recovery of chromite from plant tailings (Kumar, Tripathy, & Rao, 2009) to upgrading iron oxide concentrate (Hearn, 2002). ArcelorMittal Mines Canada operates several hydraulic classifiers to upgrade an iron oxide concentrate by removing fine quartz and other light minerals from hematite that is the main iron oxide mineral. A project was initiated to analyze the operation of the classifier in an attempt to identify the source of the variability in the production results and to assess the potential of increasing iron recovery in the classifier. One possible disturbance for the classifier operation is the change in the classifier feed composition and size distribution, while the other considered disturbance is the operation of the classifier. The paper is divided into five sections. The first section summarizes the ore processing sequence for the production of iron oxide pellets to identify the position of the hydraulic classifier in the process. The second section describes the hydraulic classifier. The third section discusses the sampling campaigns conducted on the hydraulic classifier. The method used to process the data from sampling, the results of the data processing and simulation of the classifier are discussed in the remaining sections."

Jan 1, 2012

By George Chung

"The Iron Ore Company of Canada's Carol Lake Project is Located near the western boundary of Labrador, 960 air kilometers northeast of Montreal (Figure 1).The Concentrator operation was started in 1962 with a capacity to produce 7 million tonnes of concentrate per year. The bulk of the concentrate was pelletized at a 6 million tonnes per year pelletizing plant completed in 1963. The remaining concentrate was sold in the international market. The concentrator was first expanded in 1966 to 10 million tonnes per year capacity with the pellet plant also expanded in 1967 to match the increase in concentrate production. In 1973, the concentrator was further expanded to gear with the increase in concentrate sales. In 1977, more than 40 million tonnes of crude ore was processed to produce in excess of 17.4 million tonnes of concentrate and 10.4 million tonnes of pellets."

Jan 1, 1980

By P. Favreau

This paper describes the progress accomplished at the Noranda Technology Centre in the field of three-dimensional computer-aided underground blast design. Traditional methods of laying out underground blasts are reviewed, and the new computer-aided approach is described. Time savings achieved through the use of BLASTCAD can be advantageously used to better engineer blasts, using models and blast vibration analysis. Future work involving the attachment of blast models directly to the system is also addressed.

Feb 1, 1993

Les Mines Inmet ? La Division Troilus exploite une mine d?or à ciel ouvert depuis 1996 et produit un concentré de cuivre. La Division Troilus est localisée à 175 KM au nord de la ville de Chibougamau? au 51 parallèle.

Feb 1, 2008

By R. J. McLeod

"CONTROL STRATEGYThe Lake Dufault Division of Falconbridge Copper Limited has been concentrating a complex copper zinc ore since late 1964. An ARL X-ray on stream analyzer was installed in 1966 for process control. A Digital Equip-ment Corporation PDP8 was added in 1968 for more complete control. To improve the system the computer was exchanged for a Moded PDP-81 in 1971.The new computer is time sharing with 8K core memory and 32K disc storage. A new interface was installed to accommodate 14 X-ray streams and additional analog signals for process control. The system gave us additional capacity and flexibility to make changes in operating programs and control strategy while on line. As the computer is used for process control a modified focal language was chosen as the operating language for ease of operation. This language is more suitable for process control than for statistical work.The main components of the control system are(a) Computer(b) Interface(c) Production Control X-ray Quantometer(d) Teletype terminals(e)Reagent feeders(f) Sample SystemThe operation of the system consists in the computer selecting the various streams to be analyzed by a PCXQ Quantometer. When the flowing sample is presented to the X-ray the intensities of the various elements are read by the computer from analog to digital converter, the assays are then computed. From the tonnage and assays the computer is programmed to determine the amount of reagent added to various parts of the circuit. The computer drives the feeders via the interface for the required amount of reagent. After following a certain sequence the computer prints out the performance and control data on an ASR35 Teletype. The data is printed out approximately every seven minutes. Any des¬ired changes in the program or strategy can be made during operation via an ASR33 Teletype connected to the computer."

Jan 1, 1973

By Mario E. Rossi

The full economic evaluation of a mining project requires a block model that provides an estimate of the tons and grades of available resources. The model must be representative of the mineralization to be found at the time of mining for specified extraction periods and within acceptable error margins. In an operating mine, there may be a reasonable understanding and estimates of actual dilution and ore loss. This paper discusses the issue from the perspective of a project at a feasibility or preproduction level of development. Three types of dilution are discussed. Internal dilution (or change of support) is function of the spatial distribution of the mineralization and its relation to the operation?s selectivity. Geologic contact dilution is the unavoidable mixture at contacts or boundaries of material with different geologic characteristics, grades, or metallurgical performance. Operational planned and unplanned dilution should also be considered, sometimes incorporated by factoring the resource model, but more accurately by mimicking the grade control process. The resource estimation process always carries uncertainty, which is sometimes significant, and usually caused by several factors. These include quantity and quality of drill hole information; quantity and quality of geologic data; grade estimation methodology; dilution and mining recovery factors applied; etc. A key decision is to whether estimate as accurately as possible the in-situ geologic resource or to estimate the tons and grade of the material to be fed to the processing plant. The geologic modeling and grade estimation methods used are conditioned by this decision.

May 1, 2009

By P. Favreau

"This paper describes the progress accomplished at the Noranda Technology Centre in the field of three-dimensional computer-aided underground blast design. Traditional methods of laying out underground blasts are reviewed, and the new computer-aided approach is described. Time savings achieved through the use of BLASTCAD can be advantageously used to better engineer blasts, using models and blast vibration analysis. Future work involving the attachment of blast models directly to the system is also addressed.IntroductionThe Noranda Technology Centre's (NTC) Environment and Mining Laboratory, in cooperation with the mining operations of the Noranda Group, is committed to the development and implementation of new technologies in the field of mineral extraction . Within the frame of its research program, the Blasting Technology Program is developing computer "" tools"" designed to assist the blasting engineer or technician. These computer "" tools"" are regrouped under a global software system called BLASTCAD.The BLASTCAD project started in 1990 at NTC. At that time computer programs designed to calculate and model various blasting parameters had been accumulated. These programs cam e from different sources and were mutually incompatible. Furthermore, they were developed as research programs with tittle effort spent on user interface. These programs are very useful, but are highly specialized, need large input files and can be quite tedious to use as ""standalone"" packages .Therefore, the situation being faced was one where all these programs were available at the Noranda Technology Centre, but not a t the operations. The two following options were then considered: 1. continue to run all the models and programs at the Noranda Technology Centre, and present results through reports to the mines, or2. regroup all the different programs under a single one that would make them share the same data base and be transported to the user. This second option is the one that was adopted; the result is BLASTCAD."

Jan 1, 1993

Although Canadian bentonite is competitive in quality for most uses, it has not been accepted for the pelletizing of iron ore concentrates. In 1962, Canada consumed about 10,000 tons of imported bentonite for this use. By the end of 1965, the planned domestic consumption for this purpose alone will probably be more than 100,000 tons a year, valued at about $3 million. Consequently, a challenge exists for the establishment of a Canadian source of high-quality bentonite for pelletizing. Such a bentonite would also be suitable for the two other major applications -well drilling and foundry use. Brief mention is made of such topics as the identification, 1noperties, occurrences, exploration, applications, technology and laboratory testing of this clay. In particular, the type of bentonite in demand, the geological horizons warranting exploration, and simple preliminary test methods are discussed.

Jan 1, 1964

By K. Trapani

"The study undertaken aims to investigate an ice stope heating and cooling system for its potential to be implemented in sub-arctic mines, as a low carbon alternative to conventional natural gas and refrigeration chiller systems. Its performance was simulated for a years’ worth of data, taking into consideration hourly temperature data. Results showed that to supply the required heating and cooling loads, the ice stope system had to supplement its heating with natural heating. The techno-economic performance of this system was compared to that of a conventional heating and cooling system in a mine, with the ice stope thermal storage system hawing the lowest annuitized cost and significantly lower carbon emissions.INTRODUCTIONConventional heating and cooling, in a mine is implemented using natural gas heaters and chiller refrigeration systems respectively. This results in a significant portion of energy consumption in underground mines attributable to ventilation (De Souza, 2015), including the conditioning of the air to ensure that temperatures do not exceed work comfort standards (ACGIH, 2011). Especially at depth where heat could become a significant issue. An ice stope thermal storage, using ice as the storage medium is being proposed as an alternative to provide the heating and cooling—with the ice creation resulting in heating and the ice melting providing the cooling required. A techno-economic investigation of the two systems is undertaken to identify the capital and operating costs for the two systems, and to assess the ice stope’s potential to be considered a low cost and carbon solution for heating and cooling of mines in sub-arctic climates.NATURAL STORAGE SYSTEM – CONCEPT DEVELOPMENTThe concept for the natural storage system is developed from the ice stope at Frood-Stobie Mine, ON, Canada (Stachulak, 1991). The ice stope was developed for mine air heating, with the heating occurring by spraying warm return service water onto the cold intake air—resulting in the air temperature increasing and ice being created in the stope. In summer this ice was melted by passing warm air on top of it, resulting in slight cooling of the air but no significant temperature difference which could allow effective cooling. A schematic of the Frood-Stobie Mine ice stope is provided in Figure 1."

Jan 1, 2019

By C. Joulian, A. G. Guézennec, A. Chmielarz, Y. Ménard, M. Hanke, P. d’Hugues

"The copper concentrate used in this study is produced by flotation of a black shale organic rich ore. This resource is a carbonate-rich, polymineral concentrate. In the last 5-6 years, ore characteristics changed and the concentrate grades degraded. This study evaluated bioleaching of the concentrate in stirred tank reactors as an alternative to the pyrometallurgical technology that is currently applied, and which may no longer be feasible in future given the concentrate chemistry.The first part of the study focused on testing non-traditional operating conditions during continuous bioleaching experiments: high solids concentration (> 20% solids), reduced agitation and aeration rates. For the same residence time, bioleaching performance at high solids loading (25%) was the same as that reached during previous bioleaching experiments at 15% solids. No mixing or microbial issues were encountered. The bacterial consortium used in the experiments demonstrated a high copper tolerance.The second part of the study was devoted to technology development for metal recovery from copper bearing solutions obtained during bioleaching experiments. Due to the high copper concentration of the leachate, solvent extraction prior to electrowinning was not necessary. After iron removal, high quality copper cathodes (morphology and composition) were obtained from the PLS by electrowinning."

Jan 1, 2014

By E. C. Payne

"IntroductionTHE SMALLER industrial and commercial steam generating plants in the United States are suffering from an ‘engineering deficiency' which, if allowed to continue, will probably result in the extinction of the species• that now burn •approximately 75 million tons of coal. We will classify as 'small' those plants which should require not more than one operating man per shift, including those in which as little .as thirty minutes per day should be adequate for .all service attention. These are the small steam plants that need the most, and get the least, expert attention for fuel :planning, equipment selection, design layout, .and proper operating technique. Dissatisfaction with bituminous coal is usually caused by one or more preventable weaknesses such as excessive or burdensome labour •for firing, .coal or ash handling and manual operation, smoke and fly ash emission above nuisance levels:, high maintenance and premium coal application for acceptable operation, and .finally, overall steam costs which are not .competitive. These 'deficiencies', so .common in the small coal-fired steam plants, can be readily eliminated by competent engineering and modern equipment with automatic controls."

Jan 1, 1953

By D. DeGagne, E. De Souza, J. F. Archibald

This paper describes the potential use of anew agent material for backfill consolidation, ground waste glass, to be used as partial replacement of Portland cement fractions within backfill. Significant fractions of commercial and residential silica glass production is currently utilized as waste landfill and must be disposed of at high cost and with no foreseeable environ-mental benefit. This paper also demonstrates that waste glass materials could be effectively recycled as backfill additives, and that a significant, large and stable source of additive supply, currently land filled, can be developed. This new application will generate added value for such materials, serve to promote positive environ-mental stewardship and satisfy engineering sup-port requirements in mines.

Jan 1, 1997

By F. A. Auld

"During the period 1958-1980 seven deep shafts were sunk from the surface in the UK. From 1977 until 1989 sixteen deep shafts were sunk in the UK, all concrete lined. Subsequently from 1989 up to the present day no deep shafts have been sunk in the UK, a period of 30 years. Developments in the design and construction of deep shaft linings in the UK therefore were predominantly carried out throughout the period 1977–1989. This knowledge is recorded in several published papers by the author over that period which will be referred to in the paper. INTRODUCTION The paper includes a review of past precedent for the design of deep shaft concrete linings in the UK and sets out the principles for future designs, including the design load to be adopted and Factors of Safety (SFs) to be used in the design. Hydrostatic pressure increases with depth from the surface and therefore the concrete lining must increase in thickness and strength throughout its depth to resist the pressure. High strength concrete mixes were developed to enable economic linings to reach greater depths and these will be detailed. The ground conditions to sink through in the UK consist of predominantly competent (self-standing when excavated) rock, which can be water bearing, and hence a hydrostatic pressure resisting lining is required. The paper describes the construction measures needed to produce a dry shaft by way of pour length, joint detail, backwall grouting and joint sealing details. PAST PRECEDENT FOR UK DEEP SHAFT SINKING AND LINING Seven deep shafts were sunk from the surface in the UK from 1957–1977 over a 20-year period (Auld, 1987). These are listed in Table 1. Three shafts were for British Coal, two were for Cleveland Potash Ltd and two were for the Central Electricity Generating Board. The British Coal shafts were 5.486 m and 7.315 m internal diameter to depths of 550 m and 780 m, respectively. At 5.5 m internal diameter and a depth of 1150 m, the two Boulby Mine shafts for Cleveland Potash Ltd are currently the deepest shafts in the UK. The two Central Electricity Generating Board shafts of 5 m and 10 m internal diameter, to depths of 255 m and 440 m, respectively, were ventilation shafts for a pumped storage scheme. Six of the shafts were sunk by Thyssen (GB) Ltd and one by Cementation Mining Ltd."

Jan 1, 2019

By Chris Dougherty

"This presentation will provide a demonstration of the methodology used in designing a modern shaft and hoisting plant utilizing a review of the challenges faced and solutions delivered for the Elk Creek Superalloy Materials Project (Niobium/Scandium). The development of the design required the review of complex hydrogeological conditions, mine production requirements, demanding capital expenditure (CAPEX) limitations and tight schedules. Through an extensive review of various alternatives to satisfy these constraints, the Nordmin Group (including Nordmin Engineering Ltd.) (Nordmin) was able to define a concept and design that addressed risks to the project, met production requirements, cost and schedule constraints and improved constructability. INTRODUCTION The Elk Creek Project, owned by NioCorp Developments Ltd. (NioCorp) presently, will become Nebraska’s first underground metals mine, built to access the Elk Creek Niobium/Scandium deposit. The development of the design for this facility required the review of challenging hydrogeological conditions, mine production requirements, demanding CAPEX limitations and tight schedules. Through an extensive review of various alternatives to satisfy these constraints, the Nordmin Group was able to define a concept and design that addressed risks to the project, met production requirements, cost and schedule constraints and improved constructability. This paper will review the challenges faced, and solutions arrived at in a demonstration of a methodology used in designing a modern shaft and hoisting plant. THE CHALLENGES Nordmin became involved in the project in 2015, invited by the Feasibility Study Consultant to provide input on estimating and layouts for the new operation. Many of the fundamental decisions regarding mining methodology, water handling and production strategy had been made, and the scope of Nordmin’s involvement was very limited in this first engagement. Following submission of that study in late 2017/early 2018, Nordmin had opportunity to discuss the overall effort, and its many assumptions and challenges, with NioCorp’s project team. The dialogue quickly identified several significant opportunities to improve the project construction schedule and costs along with the mine production profile and operational approach while reducing project risk."

Jan 1, 2019

By Holt. Grover J.

"IntroductionThe history of iron ore production in the United States has followed a pattern not far different from that set in the production of non-ferrous ores; the first interest of the prospector and miner being the discovery and development of high-grade ores. In the early stages of development of most mining districts, high-cost low-grade ores are usually of slight interest due to the additional capital investment required in concentrating plants, as well as the increased requirements of •power and other facilities. As the reserves of higher grade ores are depleted and the technical knowledge of ore beneficiation is broadened, production of concentrates from the lower grade ores is stimulated.The real stimulus necessary to arouse serious consideration of beneficiated iron ore in the Lake Superior district has been provided by the serious inroads made in the high-grade ore reserves by two World Wars.The first shipment of high-grade iron ore from the Mesabi range in Minnesota was recorded in 1892, and the first token shipment of concentrates was made 15 years later, in 1907. Not until 1910 did the production of concentrates assume any great importance. A steady increase in concentrate production over the years is shown by the fact that, in 1910, concentrates accounted for 8 per cent of the total shipments from the State, whereas by the time of World War II this percentage had increased to 22 per cent and by 1948 had risen to 26 per cent. It seems a safe assumption that the shipment of concentrated iron ore, from the Mesabi range in particular, will continue to increase even more rapidly from now on, with other iron ranges of the Lake Superior district following this lead."

Jan 1, 1950

By J. A. Irvine

In 1972, a cooperative program to map and estimate the quantity of Tertiary coal resources in southern Saskatchewan was initiated by the federal and Saskatchewan governments. More than 700 exploratory boreholes were drilled over a two-year period, and data were obtained from other organization s on an additional 1500 boreholes in the area. Stratigraphic data and data on each coal seam penetrated in the boreholes, along with technical and location data for each borehole, were stored in a computer data base for convenience of retrieval, modification and manipulation. Programs and program packages were developed or adapted to: (1) select borehole information defined by variable retrieval parameters from the data base; (2) calculate derived information , such as overburden ratios. cumulative net coal thicknesses , mean weighted center of gravity of coal seams in each borehole, etc., from the selected data ; (3) produce posting maps of either selected data or calculated information in various combinations at variable scales on a plotter or CRT display; (4) produce contoured structure, isopach or ratio maps , and perspective diagrams as appropriate , utilizing plotter or CRT display; (5) calculate and categorize quantities of coal in place within user- defined "mineability-economic-reliability" limits. The emphasis in computer utilization was placed on geological credibility of the results and ease of operation by relatively untrained geological personnel, resulting in extensive use of interactive methods. The single most important benefit derived from using computer-assisted procedures is the ability to produce new maps and quantity estimates rapidly and inexpensively as a result of availability of new data or/and changes in external criteria which impose economic or mineability constraints.

Jan 1, 1978

By Leroy C. Stewart

Owing mainly to the use of ethylene dibromide in the production of tetraethyl lead for gasoline treatment, there has been a tremendous increase during the past decade in the demand for bromine. In the United States, production, derived mainly as a by-product from the treatment of brines from salt wells, rose steadily from about two million pounds in 1924 to nine million pounds in 1931. In 1936, production amounted to between 20 and 21 million pounds. Much of the increase during the past four or five years has been due to the operation of the Ethyl-Dow Chemical Company's plant, which extracts bromine directly from sea water. The process employed by the Ethyl-Dow Company is somewhat similar to that in use on salt-well brines at their plant at Midland, Michigan, but whereas these brines contain around 1,300 parts per million bromine, sea water contains only 65 to 70 p.p.m.-about as much as the waste effluent in the brine process. By intensive research, however, a process was developed whereby a very considerable percentage of the bromine content of sea water could be recovered, and at a satisfactory operating cost. In its essentials, the process consists in liberating the bromine from the sea water by treat-ment with chlorine, blowing the bromine out of the water by a current of air, and finally absorbing it in a solution of soda-ash.

Jan 1, 1938

By Tim Hughes, A. H. (Sandy) Gray, Jennifer Abols

"The selective recovery of gold and silver from solutions containing other metals such as copper is possible using AuRIX®100 resin in conjunction with the Gekko Resin Column. Selectivity is driven by controlling the solution pH, which enables activities such as loading copper, gold and silver and then selectively stripping copper before gold and silver. Alternatively gold and silver can be loaded and the copper left in solution. The selective loading of gold while reducing the silver loading has also been demonstrated opening the possibility of producing high grade gold doré from high grade silver pregnant leach solutions. This paper reviews the AuRIX®100 resin and Gekko Resin Column Technologies, discusses the uses of AuRIX®100 in the recovery of gold and silver and the chemistry relating to several projects for which AuRIX®100 is being tested.INTRODUCTIONGekko SystemsGekko Systems specializes in the design, development and distribution of innovative mineral processing equipment and systems with a particular focus on gravity separation for the gold and diamond industries. The company, which has been around since 1996, has five main products: the InLine Pressure Jig, the InLine Spinner, the InLine Leach Reactor (ILR), Gekko Resin Column and Modular Systems.The InLine Leach Reactor is an intensive cyanidation reactor that uses high cyanide (0.5 – 2 % NaCN) and high oxidant (20 ppm dissolved oxygen as O2 or hydrogen peroxide) to dissolve gold from medium and high-grade gravity or flotation concentrates. The ILR, which typically replaces a shaking table in the gold room, is available in both batch and continuous models. There are 42 installations worldwide. Further details on this technology can be found in papers written by Gray et al (2003) and Longley, McCallum and Katsikaros (2003). By replacing a shaking table with an ILR, the overall gravity and plant recoveries can be increased significantly. Other advantages include reduced security risks, lower operating costs, reduced operator involvement due to the automatic process and increased safety for gold room operators."

Jan 1, 2006

By Huilan Yang, Feng He

This paper intends to introduce the development of copper smelting and converting technologies in China in recent years, with a particular emphasis on the introduction of various continuous converting technologies, and moreover, it analyzes the advantages and disadvantages of those technologies, including their impact on the downstream anode refining from different points of view. INTRODUCTION At present, many converting technologies are used in copper pyro-metallurgical plants in China, including Peirce-Smith (PS) converter, flash converting furnace, multi-lance based top blowing, bottom blowing and so on. These technologies have spanned a wide range of time. PS converter technology has been applied in copper smelters for many years and most of the blister copper have been produced by this technology; flash converting technology has been developed since 1990s and been maturely applied in several plants up until now; top blowing and bottom blowing technologies have been revived in China in the past decade and boast good environmental protection performance, energy efficiency, throughput capacity and short process flow. All of the said technologies have reference operations in treating high-grade matte. As more and more attention is paid to environmental protection globally and copper smelters continuously seek for cost reduction, it is necessary to share those converting technologies, especially those new converting technologies derived in China, with copper smelting practitioners in the world. This paper aims to analyze the advantages and disadvantages of various technologies from a macroscopic view and discuss their actual application effects, current developments and future improvements. BRIEF INTRODUCTION OF VARIOUS CONVERTING TECHNOLOGIES IN CHINA China has seen a rapid development in copper smelting industry in the past 30 years and has become the largest gathering place of copper smelters in the world, most of which are operating with PS converting furnace technology, however, with the increasingly strict environmental requirements of the Chinese government in recent years, the low-level pollution issue and the disadvantage of large gas exhaust amount per unit of copper of converting furnaces are particularly prominent.

Jan 1, 2019

By Kyle Selga, Christopher J. Greet

"The Pulp Chemistry Monitor (PCM) has been installed and operated in a number of concentrators in Australasia, and has produced some very interesting results. PCM measures the pH, Eh, dissolved oxygen, temperature and oxygen demand of process streams within a concentrator continuously and in real time.In the example presented in the paper the cleaner feed pulp chemistry is measured, and related back to changes in the mineralogy as well as variations in metallurgical response. For example, a decrease in Eh and dissolved oxygen as well as an increase in the oxygen demand. These changes in the pulp chemistry appear to coincide with increases in the feed grades, probably higher pyrite grades. Further, these variations in pulp chemistry and feed mineralogy have a negative impact on the concentrate grade and recovery.The implication is that if the pulp chemistry is monitored it is possible to predict changes in the mineralogy of the system, and from this the metallurgical response. Further, the changes in pulp chemistry can be used in a control system to counter the changes in mineralogy and maintain the metallurgy.IntroductionIt has long been recognized at a fundamental level that the flotation behaviour of sulphide minerals is dependent on the pH and Eh of the system (for example: Tolun and Kitchener, 1964; Woods, 1976). However, measuring pulp chemical parameters within an operating concentrator has had limited attention. Woodcock and Jones (1970a and b) were among the first to actually collect data from operating plants. Jones and Woodcock (1984) identified some of the chemical complexities of flotation pulps, and noted that most concentrators already operate at high levels of metallurgical performance but there was still considerable scope for improvement. These gains would, in part come from more effective chemical control. In the same volume, Healy (1984) discussed metal ion hydrolysis and precipitation, redox chemistry and how the surface chemistry of sulphide minerals can be influence flotation behaviour. The impact of grinding environment on the pulp chemistry and flotation response of a complex polymetallic sulphide ore is discussed by Forssberg and Subrahmanyam (1993). Their work essentially contrasts the pulp chemical and flotation performance of pulps ground with conventional ferrous grinding media to a fully autogenous system. The data suggested that the reduction or removal of iron hydrolysis contamination from the system could have a positive influence on flotation behaviour, and perhaps the first stage of “controlling” the chemistry of the system should be in the grinding circuit. Grano et al (1995) demonstrated that the collection of pulp, solution and surface chemical data could identify weaknesses within a concentrator, and from these data develop, test and implement solutions that improved the process. Greet et al (2006) showed that the pulp chemical trends observed through primary grinding and rougher flotation circuits of most sulphide flotation concentrators are approximately the same. There are differences in the magnitude of various pulp chemical parameters (pH, Eh, dissolved oxygen, temperature and oxygen demand) as a result of variations in the feed mineralogy and processes employed. Further, it was noted the Eh shifted to more reducing values of the ten days measurements were collected, and this change could be traced to an increase in the iron sulphide content of the feed. Metallurgically, this resulted in an increase in nickel recovery through the recovery of nickeliferous iron sulphides, and a decrease in nickel concentrate grade."

Jan 1, 2016