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By Alfred W. G. Wilson

THE state of development of its iron and steel industries serves as a 1eading index to the general condition of a nation's business affairs. In this paper, the authors present an economic study of the progress of this group of industries in Canada for the decade 1927-1936. The statistical data and most of the tables which accompany this article have been com-piled by John Casey, Statistician, Bureau of Mines; the text and some of the computations have been prepared by the seni0r author. The principal source of statistical information has been the publications of the Dominion Bureau of Statistics; where other sources have been consulted, they are noted in the text. All weights are given in short tons. Records for the years 1913 and 1918 are also presented in the group of tables dealing with iron ore and pig iron; they will serve as a basis for comparison with nearly normal years in the two decades prior to 1927-36, which included the abnorma1 years of the Great War. GENERAL REVIEW At the beginning of the decade under review, this group of industries had returned to almost normal production, as determined by pre-war conditions. Iron ore consumption showed a steady increase between 1927 and 1930; a marked decline began in 1930 and reached its culmination in 1932, when the recorded consumption of ore was 293,353 to11s, about 16 per cent of the average consumption during the first four years of the decade; the last four years of the decade show a gradual increase in consumption; the amount of ore used in 1936 was still slightly below the amount used ten years before, in 1927 (see Table 1, top).

Jan 1, 1938

By Barbara H. Scott Smith

"During the last two decades lamproites have joined kimberlites as the only two known primary sources of economic quantities of diamonds. This paper contrasts the petrography, primary and xenocrystic mineralogy and pipe geology of these petrogenetically separate rock types. The petrographic discrimination of kimberlites and lamproites from each other, as well as other rock types found during diamond prospecting, is discussed. Kimberlites and lamproites can be classified texturally and mineralogically. Such classifications highlight the differences between, and among, lamproites and kimberlites. The implications of these differences for diamond exploration programs are discussed, with particular emphasis on the application of petrography. IntroductionKimberlite was the term coined in the late 19th century to describe the host rock of diamond at the type locality, Kimberley, South Africa (Lewis, 1887, 1888). Innumerable kimberlites are now known worldwide; some of them contain economic quantities of diamond (e.g. South Africa, Botswana and Russia) while many are barren. Jennings (1989) suggests that less than 3% of the known kimberlites can be considered to be commercial. Kimberlite was thought to be the only important primary source of diamond for approximately a century. Until the late 1970s, lamproites were thought to be only academic curiosities. Some workers (e.g. Wade and Prider, 1940), however, did comment on certain similarities between lamproites and kimberlites and, hence, inferred a potential for lamproites to carry diamonds.The term lamproite was introduced by Niggli (1923) for leucite-bearing rocks from southeast Spain and Wyoming which had some unusual geochemical characteristics. Wade and Prider (1940) used the term lamproite (as defined by Troger, 1935) to embrace rock types found in the West Kimberley area of Western Australia. All the lamproites described by Wade and Prider (1940) form distinct topographic features. Subsequently in the late 1970s, additional pipes, which have little or no relief, were discovered in the same area, but only as the result of a major diamond exploration program (Atkinson et al., 1984; Jaques et al., 1984, 1986). Some of these bodies are diamondiferous. In 1979, the Argyle pipe was discovered in the East Kimberley area which, in terms of grade, is the richest known primary diamond deposit in the world with some parts of the body having grades greater than 500 carats/100 tonnes (Madigan, 1983; Boxer et al., 1989). All the initial new discoveries in Western Australia resulted from classic stream sampling for ""kimberlite indicator minerals"" (Atkinson, 1989)."

Jan 1, 1992

By R. D. Lindsay

Pamour Porcupine Mines, Limited has been actively engaged in the ''Custom Tolling'' of Gold-Bearing materials throughout the past decade. Experience acquired in this area was utilized to design and commission a custom gold milling facility at its operations in Timmins, capable of:(a) Accepting a bulk ore test sample at the rate of 150 t/d for crushing, sampling, and metals analysis;(b) Processing gold-bearing ores at a rated capacity of 150 t/d, to produce a goldbearing sulphide concentrate;(c) Processing free milling gold ores at a rated capacity of 80 t/d for total cyanidation;(d) Cyaniding custom gold flotation concentrates at a rated capacity of 80 t/d; and(e) Processing of complex gold/copper or carbonaceous ores, requiring an impurity flotation concentrate separation stage prior to cyanidation, at a rated capacity of 100 t/d.Items considered in the process design and development included:- various gold ore types available for processing;- flowsheet flexibility required;- sampling strategy as related to head grade determination and metals accounting; and- contract considerations.This paper highlights how these various considerations were used to design Pamour's ''Custom Gold Milling Facility''.

Jan 1, 1987

By C. Jay Hodgson

Hydrothermal systems form on land where and when an impermeable cap-rock unit ( either natural or self-sealed) , a permeable aquifer. and permeable discharge and recharge channels (cross-stratal permeability) develop in an anomalously hot part of the crust. A consideration of the relationship between magmatic and tectonic events in volcanically active areas indicates these conditions arise during: (1) the resurgent doming stage of the resurgent caldera cycle; (2) following movement on the bounding faults of tilted fault blocks ; and (3) as a result of hydrothermal boring associated with the intrusion of major sills. On the assumption that the submarine hydrothermal systems which deposit volcanogenic massive sulphide ores are comparable to subaerial hydrothermal systems, it is suggested that: (1) the horizon of mineralization corresponds to the time period when conditions favour the development of hydrothermal systems, as outlined above; (2) exploration for Cu-rich Cu-Zn-Pb or Cu-Zn ores should be directed to paletopographically high areas near discharge conduits , whereas exploration for Cu-poor ZnPb ores should concentrate on paleotopographically low areas down slope from conduits; (3) deposits with stringer zones lying above normally permeable units may be underlain by regionally extensive weakly mineralized and altered zones (self-seal caps) ; (4.) in the absence of a self -sealed cap, the ore horizon may be underlain by a naturally impermeable unit (e .g. a fine clastic sediment) ; (5) the condition of cross-stratal permeability may be evidenced by features such as dykes. alignment of vari ous magmatic and hydrothermal phenomena, abrupt thickness changes in stratiform units indicative of ponding against syn-volcanic faults, and fault-scarp slump deposits; (6) the condition of high heat flow may be evidenced by near-surface magmatism and steep thermal gradients preserved in metamorphic mineral assemblages.

Jan 1, 1977

By Philippe Angers

This article analyzes the social acceptability process of a mining project located in an existing city. It will explore how the principles of sustainable development have been integrated in the project of the Canadian Malartic open pit mine held by the Osisko Mining Corporation, and the corporate social responsibility (CSR) initiatives proposed to strengthen the social acceptability of the project. This mine is located on the ancient south quarter of Malartic and has required the displacement of hundred of houses and five institutions. The location and the inherent social impacts generated by the relocation of the citizens of the south quarter makes this case particularly interesting to understand social dynamics in an era of environmental consciousness. These major constraints of the mine generate high expectations within the urban population with regard to the social and economic benefits it will receive from the project. In a context where society demands higher CSR from the corporation, Osisko is closely followed regarding their actions toward the sustainable development principles to see if they respect the environment and the desires of the community. From the beginning, the company had to be a model of sustainable development in various aspects reflected by the manifold interest of the population. To understand the endeavor made by the company to fulfill the demand of CSR, we will analyze how the company understood sustainable development principles and what CSR initiatives Osisko company put forward. We will explore the involvement of the company in various social aspects like employment, employee satisfaction, and the level of commitment to non-discrimination policy in employment, notably with the native populations. We will also take a closer look at the relationship built by the company with the community and the level of commitment with the various stakeholders of the community. In this way, we will be able to seize the level of involvement of the company in the fulfillment of the principles of sustainable development toward a higher CSR, and to specify the trajectory adopted to build social acceptance.

Aug 1, 2013

By S. Vézina

"Environmental issues have evolved considerably over the last two decades. The main contributing factors, to name a few, have been the changing values of modern societies, the globalization of trade and its linkage to environment, evolution and accessibility of information/ communication technologies, better educated populations, climate change, longrange transport of toxics, and the increasing influence of non-governmental organizations (NGOs) and multistakeholders.As well, environmental management of mining operations had to be realigned in order to meet these new realities and to respond to more elaborated regulations oriented towards sustainability. Environmental management systems (EMS) have been introduced not only to meet the assurance of conformance to regulations but also to prevent pollution and to apply the continuous improvement of mining processes. EMS models have been developed and certification to international standards (e.g. ISO 14 001) is a common practice.Globalization has imposed challenges and additional requirements to environmental management. Developing a mine in emerging countries implies dealing with international agencies, local communities, and a variety of government infrastructures to obtain a “license to operate.” This paper presents the structure of Cambior’s EMS and how it was adapted and implemented in the company’s operations in South America."

Jan 1, 2006

Block caving is an underground mining method for the profitable extraction of massive, low-grade orebodies. Lately, it has become the mining method of choice, for many mining companies, because of depleted high-grade orebodies, and declining metal market prices. Block cave mining, however, still faces several challenges. Lack of access to the cave remains a major issue in understanding the rockmass response to mining for method optimisation. Improving our understanding of the rockmass response to caving will lead to safer and more productive operations. Combining large datasets from multiple sources with virtual reality scientific visualisation (VRSV) is a viable alternative to understanding complex cave behaviour without access to the cave. This is achieved using immersive environments with the ability to view complex multi-dimensional data (beyond 3D) graphically. VRSV offers a unique platform where it becomes possible to immerse the multi-disciplinary experts, and/or management team, in a virtual mine environment for quick decision making and fast resolution to conflicting conclusions. The underground mining system is complex due to multiple interrelating factors such as geology, excavation geometries, stress and time. Block caving is even more complex than most underground mining methods due to the network of tunnels required, and the use of induced stress, among others. As a consequence of the complexity in the block caving environment, it is vital that the mining system is analysed holistically, as a system, rather than optimizing individual factors one at a time. This paper presents a customised software module developed for use in the Advanced Visualisation Interactive Environment (AVIE) at The University of New South Wales (UNSW), Australia, to enable VRSV investigation into block cave mining systems (BCMS). This approach has the potential to provide a better understanding of the effect of time in in rock engineering, which has proven to be an important factor in hard rock mines (Ma & Daemen, 2006; Malan et al., 1997; Suorineni, 2010) but never validated. This work back analyses the early undercutting phase of a case study block caving operation with the view to understanding time/sequence effects. There is evidence that heterogeneous rockmass time-dependent behaviour governs the seismic response of the rockmass following undercut developments.

Jan 1, 2015

By Soumitry J. Ray

Poor visibility of powered industrial vehicles, such as forklifts, used in industry is often the cause of accidents that include pedestrians. Current standards allow up to 20 % non-visible regions for forklifts where measurement of these regions is performed by using lamps. A collaboration of research organizations, including National Institute of Standards and Technology, Georgia Institute of Technology (NIST), and Direct Dimensions, has been evaluating advanced methods for measuring a forklift operator?s visibility. These methods can potentially improve visibility standards. They can also help forklift and sensor manufacturers to determine (1) how visibility-assist sensors and algorithms can be designed and (2) where sensors can be mounted on forklifts. This paper includes explanation of visibility measurement experiments performed and results, associated language suggested to standards organizations, and a prototype design for measuring the visibility of forklifts automatically.

Aug 1, 2013

Scope / Agenda ? What is Situation Awareness (SA)? ? Background on SA theory ? SA is critical in a wide variety of domains ? SA and human performance ? Consequences of poor SA ? Significant challenges for SA in mining operations ? Technology centric design ? SA-oriented design methodology ? Goal-Directed Task Analysis ? Design ? SA Measurement and Evaluation ? Applications of SA-oriented design

Aug 1, 2013

By R. W. Hodder

"Archean lode gold deposits of both vein and chemical sedimentary types typically have major enrichments of certain rare elements, including Au, Ag, As, Sb, B, W, Se, Te and Bi, coupled with low or negative enrichments of the more abundant and mobile base metals, Cu, Pb and Zn. On the other hand, in massive base metal sulphide deposits Au, Ag, Cu, Zn and in some instances Pb are all enriched by a factor of 200 to 2000 t:'Jf'1pared to background and there is no large separation of gold relative to the base metals.The fluids from which gold was precipitated in veins were at temperatures of 320 to 480°C, at lithostatic pressure, had significant C02, and Na """" K; whereas the fluids which generated base metal deposits were at 250-300°C, at hydrostatic pressure, had C02 < < H20 and Na > > K.Many lode gold deposits are characterized by K, C02 and Si additions to their enveloping rocks, whereas base metal deposits typically have a fixation of Fe, Mg, Si and S in footwall rocks. Lode gold deposits may also have a relatively large halo of low-temperature oxidative, sadie spilitization in enclosing volcanic rocks, where seawater has later streamed into cooling stocks or flows that have initially acted to focus gold mineralizing fluids along thermal contraction fractures. The submarine environment is one hydrologically appropriate for the mixing of two initially independent hydrothermal systems, and the blending of their separate characteristics. Hence, lode gold and base metal massive sulphide deposits appear to be products of two distinctly different crustal and hydrological regimes. The former involves a high-temperature, high-pressure discharge of fluids which probably were generated during dehydration accompanying burial and progressive accumulation of volcanic-sedimentary sequences, with an additional influence of marine water in the near-sea-floor environment. The latter represents thermally driven convection of ocean water at lower temperatures and under hydrostatic conditions.Auriferous fluid systems with only minor base metal content could plausibly be generated during dehydration accompanying burial and metamorphism, when the water-to-rock ratio is low and halogen availability is limited by crustal abundance (- 60 ppm Cl). These two factors may constrain the uptake of the abundant base metals into fluids, but the solubility of rare elements is not constrained by limited fluid; and preferential uptake of Au along with other rare elements may be promoted if such elements compete more successfully for the limited halogens than the base metals, and/or have an alternative complexing agent such as CO or C()j-."

Jan 1, 1982

By K. Bartholomew

The Functional Performance Equation for ball milling circuits provides plant staff with a new means to improve circuit performance. However, successful execution of a plant processing performance improvement project, with verifiable improvements, requires a significant number of accompanying steps beyond using this equation. In order to identify and articulate all these steps, a study was undertaken with the metallurgical staff from two milling operations and process application specialists from a grinding media manufacturing company. “Task analysis” of improving plant grinding performance was carried out. This analysis identified the required steps, and ultimately yielded a “Plant Grinding Circuit Processing Performance Management/ Improvement System.

Jan 1, 2015

By Lachezar Tsotsorkov

Corporate social responsibility Is a principal trend of the corporate strategy for sustainable development of Assarel-Medet JSC ? the largest Bulgarian company for open pit mining and ore processing the production activities of which date back to 1964. Sustainable development Social responsibility is considered as one of the three pillars for sustainable development, together with the economic and environmental responsibility.

Aug 1, 2013

By R. W. Brigstocke

History The birth of the mining industry of Canada took place about 1670. According to Salone (Salone E., La Colonisation de la Nouvelle France, page 205) the first discovery of ore in the country was made by an iron-master, Monsieur de la Potardiere, near Trois Rivieres, Quebec. Under French rule some prospecting was done; but at this time no one seemed to consider the working of mines practicable. It was not until the time that Begon became Intendant, when the Marquis of Vaudreuil was Governor, that mining was attempted. Begon was a patron of industrial arts and did his best to promote home manufactures. The mining industry was developed under his regime and discoveries of copper and lead ores were made in 1730. About this time the St. Maurice Forges were erected to treat bog-iron ore, and they were in operation for many years. Prior to 1747, iron pans to the value of £21,000 were manufactured, together with bar-iron and plough-shares. About 1769, that is, ten years after the conquest by Wolfe, stoves and other articles, and, later, potash kettles, appeared. What is still more interesting to us-or was, at least, to General Wolfe-is that cannon balls made at the St. Maurice Forges delayed his operations. A map dated 1744, a copy of which appears in the report of the Ontario Bureau of Mines for 1913 (Vol. XIX), indicates the extensiveness of the wanderings of the French and also shows the location of the lead mine on the east shore of Lake Timiskaming. Bog-iron ore was turned into metal, with charcoal for fuel, at Norman-dale, Norfolk county, Ontario, in 1813, and at Clementsport, Nova Scotia, in 1825. In a volume published in 1672, reference is made to the occurrence of coal on the Atlantic seaboard, and in 1677 Monsieur Duchesneau, the Intendant, levied a royalty of twenty sous per ton on all coal taken from Cape Breton.

Jan 1, 1932

By R. Charlier, G. Radioti, J. -P. Radu, S. Delvoie, F. Nguyen

"In order to investigate the fracturing of the bedrock and its possible heterogeneous distribution in situ, four boreholes equipped with double-U geothermal pipes of 100 m long were installed on the campus of the University of Liege (Liege, Belgium) over a surface area of 32 m². The bedrock, which starts at a depth approximately of 8 m, is quite fractured and consists mainly of siltstone and shale interbedded with sandstone.Different geophysical methods are applied at two different phases, after drilling the boreholes and after injecting the grouting material. The first approach consists in lowering an ultrasonic borehole imager (borehole televiewer; Zemanek, Glenn, Norton, & Caldwell, 1970), an instrument that acts as an ultrasonic transducer and receiver, into the boreholes to obtain high-resolution, continuous images with 360° coverage of the local geology and fracturing. Moreover gamma-ray logs of the four boreholes are obtained and inclinometry is conducted.After drilling the boreholes fiber optic cables are attached along the pipe loops and the double-U pipes are installed inside the boreholes. Then the grouting material is injected. The second approach consists in measuring the temperature along the fibers by applying the Distributed Temperature Sensing technique (Soto, Sahu, Faralli, Bolognini, Di Pasquale, Nebendahl, & Rueck, 2007). A laser pulse is injected into the optical fiber and the temperature along the fiber is determined by the intensity of Raman stokes and anti-stokes reemitted signals. Temperature evolution is measured during hardening of the grouting material. Local maxima of the temperature curve are probably due to a local lower thermal conductivity and/or a local larger quantity of grouting material due to gathering of fractures.A detailed fracture characterisation (position, opening, orientation, dip angle) is obtained based on the acoustic signal travel time and amplitude. The fractures are characterised by the same dipping and orientation but significantly vary in number and location in the four boreholes, despite the close distance between them. Gamma-ray data and observation of the cuttings during drilling result in rock identification through depth as well as in determination of the layer dipping. The inclination of the four boreholes tends to be perpendicular to the dipping. The combination of the two geophysical methods as presented provides information useful for the hydro-thermo-mechanical behaviour of the bedrock. The contribution of the thermal behaviour of borehole heat exchangers to bedrock investigation will be further studied by conducting Distributed Thermal Response tests (Fujii, Okubo, & Itoi, 2006). During the tests we will measure the temperature variation thanks to the installed fiber optics. These data will allow us to correlate any anisotropic thermal behaviour to the geological characteristics. The available information could be used for a detailed numerical model."

Jan 1, 2015

By Erwin L. Zodrow

"IntroductionThrough an extensive coal sampling project in the Sydney coalfield of Nova Scotia during 1981 - 1984 involving a majority of the mineable coals (Zodrow, 1985, Fig. 1), a sizeable inventory on trace, minor and major metals was established. In this paper, results of studying the inventory are summarized, concentrating mainly on the relationship that exists between metal variations and thickness of coal channel samples (i.e. trends) and on explaining the trends in geochemical and sedimentological terms. As an over-all conclusion the Everglades peat of Florida is proposed as a modern-day analogue to Upper Carboniferous peat swamp development that took place in the Sydney Basin.Data InventoryFor this study 17 channel samples were cut , 8 cm to 14 cm channel width and 8 cm to 10 cm depth, from 10 successive coals which in stratigraphically descending order are as follows: Point Aconi (3), overrider Lloyd Cove (2), Lloyd Cove (2), Stubbart (2), Harbour (4), Backpit (I), Phalen (,I), Shoemaker (1) and McAulay (I), where bracketed values signify the number of channel samples cut from a seam (Zodrow, 1985, Fig. I). Each channel sample was subdivided by 15 em incremental length yielding a total sample size of 137 for analysis. By appropriate modern techniques these samples were analyzed to determine concentration levels for 32 chemical elements and ash content, the average results of which are presented in Table 1.Tests were also made for Pd, Pt, Ga, Nb, Cd, Cs, Sm and W but their concentration levels in many instances hovered on the lower detection limits that were used and on this accounts are excluded from discussion. Ashing, when necessary for the determination of concentration levels, was done for 12 hours at a temperature not exceeding 450°C. Concentration levels for the elements are reported in reference to whole-coal or whole-coal equivalents and discussed on this basis. In the course of the analyses, lower detection limits received careful attention."

Jan 1, 1986

By M. J. Collins

"Autoclaves were first used in the metallurgical industry in 1893 to recover alumina from bauxite. In the 1940s and 1950s, several high temperature and pressure processes were invented in the laboratory of Professor Frank Forward at The University of British Columbia, in parallel with advances in equipment and processes by the Chemical Construction Corporation. Sherritt Gordon Mines Limited enlisted these groups to help develop the nickel sulfide ammonia leach process that was commercialized in 1954. Autoclave processes that have since been commercialized include high-pressure acid leaching of laterites, zinc pressure leaching, and pressure oxidation of refractory gold feedstocks. RÉSUMÉ En 1893, l’industrie métallurgique est la première à utiliser les autoclaves pour l’extraction de l’alumine dans la bauxite. Dans les années 1940 et 1950, plusieurs procédés à haute température et à haute pression sont inventés dans le laboratoire du Pr Frank Forward de l’université de la Colombie-Britannique (UBC) ; parallèlement, la Chemical Construction Corporation fait de grands progrès en matière d’équipement et de procédés. Sherritt Gordon Mines Limited fait appel à ces groupes pour qu’ils aident la société à développer le procédé de lixiviation du sulfure de nickel dans de l’ammoniaque, commercialisé en 1954. Les procédés de lixiviation en autoclave commercialisés depuis incluent notamment la lixiviation acide à haute pression de latérites, la lixiviation sous pression du zinc et l’oxydation sous pression des matières premières de l’or réfractaire.INTRODUCTION Autoclaves are chemical reactors that are built to contain processes taking place at elevated pressure. They are used in metallurgical refineries throughout the world to take advantage of the increased reaction kinetics and different reaction products that can be obtained in aqueous systems above the boiling temperature at atmospheric pressure. The word autoclave comes from the French “auto” and the Latin “clavis” and literally means self-locking—that is, the core distinguishing feature of an autoclave is that it includes a means for pressure regulation (e.g., a pressure relief valve). Denis Papin (Figure 1a), one of the inventors of the steam engine, was the first to make use of a safety valve to control steam pressure. He is credited with inventing the autoclave in 1679. Papin’s “digester” (Figure 1b) was a type of pressure cooker that was originally used to liquefy bones. Most commercial autoclaves are horizontal, multicompartment vessels with mechanical agitation, as shown in Figure 2a; however, the steam-agitated Pachuca vessels used to leach laterite ore in Moa, Cuba (Figure 2b), are also classified as autoclaves according to the self-locking definition provided above."

Jan 1, 2018

By John D. Carr

Introduction The Flin Flon zinc plant operates on what is known as the low density or standard sulphate process, that is, the zinc is carried through the plant solution circuit attached to the SO4 or sulphate radical at a concentration not exceeding 175 grams per litre zinc. The process may be described briefly as follows: The zinc is received in the zinc concentrate chemically combined with sulphur and mixed with many other impurities. The concentrate is roasted and most of the sulphur is burned to a gas, which is discharged from the plant. The roasted concentrate, or calcine as it is called, is leached with a weak sulphuric acid solution so that the resulting leach solution contains a high zinc content but a very small proportion of the impurities. The solution is separated from the solids and is purified further by agitation with zinc dust to remove copper, cadmium, and cobalt. This purified zinc sulphate solution is then pumped to the electrolytic department. The solids from the first leach are again leached, but this time with a stronger acid solution to dissolve all of the remaining zinc which is soluble in the strength of acid available. The solids and solution from the leach are then separated. The solids are stock-piled for further treatment at some future date and the solution, carrying a relatively high amount of impurities, is sent to the first leach, where the chemical action is such that the contained impurities are precipitated as solids. The electrolytic department is nothing more than a large number of electroplating cells in which the zinc is plated on aluminium sheets. Since zinc does not plate tightly to aluminium, the zinc plating or sheet is easily stripped from the aluminium and the sheets are collected to be melted and cast into the standard market bars or slabs. In the electro-deposition cells, the zinc sulphate (ZnS04) is split to metallic zinc (Zn) which plates out, and sulphate (S04) which combines with the hydrogen of the water of the solution to form sulphuric acid (H2S04). When one pound of zinc is deposited, about one and one-half pounds of sulphuric acid are formed. This acid is sent to the leaching section, where it dissolves one pound of zinc from the calcine. The solution is purified and is again pumped to the plating cells. The solution travel forms a complete circuit.

Jan 1, 1935

By K. S. Raja, F. Battick, B. Pesic

"CeO2 doped with lower valence cations, such as Y3+, Sm3+, Gd3+ etc. is considered as electrolyte material for low temperature SOFC. Doping introduces additional oxygen vacancies and improves ionic conductivity. This work describes the preparation of yttria-calcia doped-ceria precursor material, its sintering in DC and AC field methods, and characterization of sintered electrolytes with respect to the ionic conductivity. Doped precursor materials were prepared by a controlled co-precipitation process. Sintering of prepared, pelletized particulates was carried out using three different methods such as: 1) conventional; 2) spark plasma sintering; and 3) an alternating current field at 1125°C (AC assisted sintering). The mechanism involved in the conductivity improvement as a function of defect density, grain boundary area and phase stability will be discussed. INTRODUCTIONThe performance of SOFCs depends highly on the properties of materials. Subtle variations in the composition, microstructure, or density of SOFC components can considerably alter the power output capabilities of fuel cells. Early SOFCs utilized zirconia based electrolytes but efforts in lowering the operating temperatures of SOFCs have prompted investigations into several other oxygen ion conductors – often modified with dopants to either promote the formation of oxygen vacancies or to stabilize a vacancy rich high temperature phase – such as bismuth oxide, lanthanum gallate, and ceria.The transport of oxygen ions through the electrolyte first begins with diffusion into the material. While this is generally a surface kinetics phenomenon, it is safe to say that it is highly dependent on oxygen pressure and vacancy gradients. The role of the cathode in SOFCs is to reduce oxygen at the electrolyte surface creating an O2– ion gradient which induces permeation into the material. Once inside and under the influence of a potential field, O2– ions migrate by a vacancy hopping mechanism, Catlow, C.R.A. (1990), effectively exchanging positions throughout the matrix until they reach the anode and react, thus leaving the matrix."

Jan 1, 2012

By É. Roberge, S. Makni, G. Gagnon, F. Lavoie, A. Faucher

"Feed particle size is an important variable for the primary grinding mill operation. Several commercial vision systems have proven to successfully measure online many types of ores and are used for automatic control. However, due to limitations associated with segmentation algorithms, these systems fail to provide good measurements when the feed is composed of a specific bimodal particle size distribution: very big rocks and a large amount of fine particles. This is typically the case for crushed iron ore. This paper presents a technique to overcome the limitations of existing vision systems by using 3D cameras and appropriate processing methods. It provides online particle size distribution indicators and bulk volume flow rate measurement. It is designed to be very cost-effective, robust, precise, easy to install and to maintain. The 3D system was validated in two iron ore processing plants and the results clearly show that it can be used to optimize primary grinding mill operation where 2D segmentation vision systems fail.INTRODUCTIONFragmentation measurement using digital image processing has successfully been applied in mining and mineral processing operations. Several maintenance and operating applications are already deployed in the industry: Measurement of rock fragmentation after blasting (Maerz, 1999; Palangio, 1999) (Pragyan, 2012) Truck inventory (Palangio, 2005) Monitoring of crusher mantle wear Automatic control of crushers and SAG mills (Bouajila, 2000) (Bartolacci, 2001)Commercial technologies like WipFrag (Maerz, 1999), VisioRock and others proved to be very efficient to precisely measure the particle size distribution of many types of materials. These products are mainly composed of a camera, a lighting system and an image processing system based on a segmentation algorithm. By controlling adequately the lighting conditions and with periodic maintenance on the segmentation algorithm calibration parameters, it is almost always possible to achieve reliable measurements.However, the segmentation algorithm is not adequate when the particle size distribution contains big rocks and a large amount of fine particles. In this case, the area containing the fine particles is accounted as a big rock while big rocks get segmented as multiple smaller sized particles, leading globally to a wrong measurement. This situation prevails for crushed iron ore and coke, among other materials. Figure 1 shows a picture of a material which is typically very difficult to process through segmentation techniques."

Jan 1, 2015

By G. W. Poling

This paper evaluates current environmental protection legislation, guidelines and criteria, focusing mainly on the land and water disposal of mill tailings. Effluent criteria and regulatory mechanisms are proposed, and submarine tailing disposal is discussed at length. The importance of basing regulations on the best available rationale is stressed.

Jan 1, 1979