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By M M. Hilden, M S. Powell, B Foggiatto

In an environment of decreasing ore grade, increasing costs and uncertainty with respect to commodity prices, the industry could benefit from evaluating alternative technologies and innovative circuit configurations. The flexible circuit approach suggests that the design of grinding circuits can be adapted to changes in feed properties and economic conditions. Advances in modelling and simulation are enabling metallurgists to predict the performance of more complex circuit configurations with increased confidence. Ore variability information and processing costs may be used as modelling inputs to determine the optimum processing conditions at a given time. A case study has been completed demonstrating the value of combining a flexible circuit with a model-based optimisation of the process. Ore properties and equipment performance data obtained in operating plants have been used to model and simulate flexible circuit configurations.This paper explores strategies to introduce flexibility to existing circuit configurations when processing ores with high variability. Multicomponent models incorporated in the model developers’ kit (MDK) allow the simulation of more complex and flexible circuits. This capability enables demonstration of the potential to enhance metal production through adapting processing routes according to the ore type being processed. The simulation of different flow sheet configurations allowed the definition of the best option for maintaining the metal production when treating lower grade ores, highlighting the advantages of flexible circuit configurations compared with a one-process-fits-all approach.CITATION:Foggiatto, B, Hilden, M M and Powell, M S, 2014. Advances in the simulation of flexible circuits, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 391–398 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By Segnit ER, Jensen G

The decoppering of soft and hard leads was investigated by stirring in an open pot, using sulfur or sulfur plus pyrites, or sulfur plus pyrrhotite, as reagents. Lead samples taken during the process were analysed for copper. Dross samples were examined by optical micro- scope, SEM and XRD. Soft lead containing silver can be decoppered satisfactorily by stirring with 0.1% S at low temperatures - close to 330¦C. Soft lead, whether containing silver or not, can be decoppered satisfactorily at higher temperatures by stirring with 0.1% S plus 0.4% pyrites. Then CuFeS2, Cu5FeS4 and PbS are formed, instead of Cu2S, CuS and PbS when using S alone. Hard lead containing tin can be decoppered satisfactorily by stirring with 0.1% S at temperatures from 320-400¦C. When stirring with 0.1% S plus 0.4% pyrites, reversion of copper from dross to lead on prolonged stirring does not occur. Hard lead without tin can be decoppered with S plus pyrites better than with S alone, but the presence of antimony hinders the decoppering, which is less effective on lead with 5.5% Sb than with 2.3% Sb.

Jan 1, 1980

The organisers of this function have suggested that this presentation should accomplish the following broad goals:set the technical tone for the conference to follow, implying some discussion of the æstate-of-the-artÆ of reserve estimation; and raise some current and common problems or deficiencies in our art in order to be thought provoking. As an engineer it is always easier to raise problems than to solve them with state-of-the-art. Consequently, I have had to limit the extensive list of problems that could have been discussed within this presentation. In regard to the state-of-the-art, this presentation will not be an esoteric discussion of the latest statistical estimation processes, although I intend to challenge those with skills in that area to address some of the thought provoking issues later on. The subtitle of the paper was established after reading an excerpt from æLife on the MississippiÆ by the American humorist Mark Twain in which Twain observed that the Mississippi River had become shorter during his working period on the River due to natural cut-offs and man made channels. Projecting into the future, he calculated that by now, Cairo, Missouri and New Orleans, Louisiana would become a single city with one mayor (the two cities are still separated by some 500 air miles). As a moral to this story Mark Twain observed that one can obtain: æwholesale returns of conjecture out of such a trifling investment of factÆ.

Jan 1, 2000

By Munive L

As a result of commissioning No.5 B F, 2670m3 inner volume, in March 1972, the largest B F in Australia; new expertise in maintenance, furnace operating practices and design have been obtained. This experience has also been extended to the other furnaces. A series of operating problems were con- fronted; all parts of the furnace, including the hearth side walls and bottom,were adversely affected. In December 1977, serious hearth wall wear was detected at No.5 B F, and a potential hearth breakout was averted. Hearth wear in No.4 B F was discovered in March 1979, and emer- gency underhearth cooling was installed to reverse an extremely advanced hearth bottom erosion. Hearth behaviour of No.5 B F oampaign 1972-1978 and`No.4 B F campaign commencing 1972, has been studied and discussions on the causes, effects and measures undertaken to protect the hearths are presented in this paper.

Jan 1, 1981

The selection and implementation of the right technology for a project is critical to the future development of the resource industry. It is essential for companies to ensure ongoing competitive viability that where practical new or alternative technology be adopted. Analysis of historical data relating to development of resource-based process plants provides an enlightening insight into the key factors which influence their success or failure. The adoption of new technology does not guarantee the success of a project. The outcomes of this analysis have been used to develop some general guidelines and principles the author believes are useful in the selection and implementation of new or alternative technology in resource projects. This paper is available as a PowerPoint presentation only.

Jan 1, 2006

By S K. Ray

Open fire in a mine gallery causes large-scale damage to property and sometimes precious lives. Such fires produce two distinct effects, the throttle effect and the buoyancy effect. These effects disturb the ventilation system of the mine. To understand the complex dynamic phenomenon of open fire and its effect on ventilation systems, a mine fire model gallery has been designed and constructed at Central Mining Research Institute, Dhanbad. Two sets of experiments at air velocities of 1 and 1.5 m/s were conducted in the gallery using coal samples from the Dobrana seam of the Raniganj coalfields. After about an hour of development of fully-fledged fire, heavy backlash, with smoke and fumes, was observed. At the time of backlash occurring the gallery was divided into two zones. In the region of the gallery from the base up to 1.4 m the airflow was normal, in the remaining upper portion the airflow was the reverse. Air quantity reduced substantially, while pressure dropped across the fire zone, the products of combustion (POC) and temperature increased during the period of the throttle effect. It has been revealed from these studies that with an increase in airflow, pressure drops across the fire zone, POC, temperature and reduction in airflow increases. This paper addresses the important design features of the gallery, the instrumentation system, the experimental procedure and assesses the effect of open fires on mine ventilation systems.

Jan 1, 2005

By Lawson F

Chrome chemicals are commercially produced by the alkali roasting of chromite ores with sodium carbonate. Results of tests conducted in a laboratory furnace indicated that the sodium carbonate reacted rapidly with part of the gangue material to form a metastable intermediate that later reacted further with the chromite. For the conditions used, the recovery of water-soluble sodium chromate was able to be described empirically as yield % = a tn with a = 0.24 T - 241.3; n = 3.90 - 3.12 × 10-3 T and t is the reaction time in hours.The major rate limiting step in the overall reaction sequence appears to be the rate at which oxygen can get to the reaction sites across the liquid film coating the solid reactants.Sodium sulfate alone was found to be an unsatisfactory source of alkali for reaction with chromite. However when limestone also was added in quantities sufficient to allow the reaction CaCO3 + Na2SO4 + H20 ? Ca SO4 + 2NaOH + CO2 to take place, the results obtained were comparable to those found when sodium car-bonate was used.For chromite particles in the size range -124 + 105 µm, the use of stoichiometric excess of sodium carbonate did not appear to increase the yield or the reaction rate significantly. However, with smaller sized particles, - 53 µm, increased yields of water-soluble chromate were obtained when roasted with more than the theoretical quantity of sodium carbonate.

Jan 1, 1984

By O N. Antzutkin, W Forsling, K J. Pike an

The adsorption mechanism of three different O,OÆ-di-alkyl-dithiophosphate (dtp) collectors, K[S2P(OR)2] with R = Et, i-Bu and i-Amyl, on the surface of synthetic chalcocite (Cu2S) was studied by means of solid-state 31P CP/MAS NMR spectroscopy. The morphology changes on the conditioned Cu2S surfaces, in the collector concentration range 0.1 - 10 mM, were also monitored with scanning electron microscope (SEM). In order to assign Cu(I)-dtp species on the surface of Cu2S, the corresponding bulk Cu(I)-dtp compounds, which are clusters of the monovalent copper containing either Cu6(antiprismatic) or Cu8(cubic) cores, were synthesised, and characterised by means of solid-state 31P CP/MAS and static 65Cu NMR. Further investigations on the crystal habits of the bulk systems were carried out by powder x-ray diffraction and SEM. A comparative analysis of the 31P chemical shift and chemical shift anisotropy (CSA) data estimated from the experimental NMR spectra of the polycrystalline bulk Cu(I) dialkyldithiophosphate complexes was used for assigning the 31P resonance lines in the NMR spectra of the collector treated Cu2S powder samples. The species formed on the synthetic Cu2S surfaces were assigned to polycrystalline phases of: Cu6L6 with L = Et2dtpû, Cu6L6 and Cu8L6(S) with L = i-Bu2dtpû, and Cu8L6(S) with L = i-Amyl2dtpû. A heterophase autocatalytic step process of both formation and growth of solid CuxLy (L = R2dtp, x = 6 or 8 and y = 6) complexes on the collector treated Cu2S surface is proposed. A possible role of the oxidised form of dithiophosphate collectors, bis[di-alkyl-thiophosphoryl]-disulfane (disulfide), is discussed in terms of a specific self-redox reaction. The second order quadrupolar lineshapes in 65Cu NMR spectra were simulated and the interaction parameters, CQ and hQ, for the bulk dialkyldithiophosphato-copper(I) complexes were obtained.

Jan 1, 2005

By Y Chung, B Choi, H Lee

Numerous studies have explored refractory corrosion in the presence of slag and/or metal, utilising the Finger Rotating Test (FRT). Recent experimental results revealed that corrosion initially increased with rising rotation velocity but was then suppressed above a critical rotating speed, under conditions involving a two-liquid solution of slag and molten steel. This phenomenon indicated that the liquid/liquid interface movement occurred during spindle rotor. However, understanding of the phenomenon, known as the rod climbing effect, remains inadequate in the case involving slag, molten steel and refractories. To gain deeper insights, a simulation experiment was conducted on the phenomenon using silicon oil/water and the phenomenon was analysed using computerised simulation software (Ansys Fluent). Experimental modelling demonstrated that interfacial movement occurs even at low rotation velocity, as low as 200 rev/min, when the viscosity of silicone oil is at 100 cP. Computational analysis utilising the Volume of Fluid (VOF) method and a realisable k-ε turbulence model elucidated that interface elevation during rotor rotation arises due to viscosity disparities between the two fluids. Furthermore, this movement is more pronounced when the viscosity difference is lower. Additionally, the study findings suggest that higher density differences between two liquids suppress the phenomenon of interface movement.

Jun 19, 2024

Australia has been an important producer of zinc minerals and metal for many years.Late in the last century Edgar A. Ashcroft, a versatile and enterprising electrical engineer proposed the treatment of zinc rich ores by roasting, followed by leaching to extract zinc, purification of the solution and electrolysis of the purified solution to produce zinc. Residues from the leaching operation were to be smelted in a lead blast furnace to recover lead, silver and gold.Ashcroft (1897-98) and (1898) has.given us a most interesting record of the attempts made at the Sulphide Corporation's plant at Cockle Creek near Newcastle, NSW, to put his ideas into practice. In spite of the best efforts of all concerned, including the use of electrolysis of aqueous chlorides and sulphates, zinc could not be deposited consistently and the project failed although lead smelting continued until 1922 (Woodward, 1965, p. 158). Based on later experience with Broken Hill materials the presence of undetected cobalt in the solutions was the likely cause of the inability to deposit zinc (Kirk and Othmer, 1956).

Jan 1, 1985

By Honey F. R, Furnell R. G, Lyon R. J P

A Joint Venture between Union Oil Development Corporation and Geoscan Proprietary Limited carried out an Airborne Multispectral Scanner Survey over approximately 15,000 square kilometres in the Charters towers area of northeastern Queensland during late 1985 and in September, 1986. The survey, using the Geoscan Mark I scanner, consisted of 50 runs each having a swath width of 5 kilometres. Twelve or thirteen spectral bands were recorded, 5 in the VNIR, 4 in the SWIR and 3 or 4 in the TIR. The results of the survey were interpreted by interactive image processing with the aim of identifying those minerals or their weathering products which are characteristically associated with hydrothermally emplaced gold mineralisation in this part of Queensland. Spectral bands in the VNIR were used to identify and discriminate the iron hydroxides, whilst the SWIR bands were used to outline the clay and carbonate rich areas. The TIR aided in identifying areas of silicification.

Jan 1, 1989

Fluid circulation occurs in oceanic crust of all ages, at the seafloor spreading axis, on mid-ocean ridge flanks, in the ocean basins, and in subduction zones. In the first three settings the fluid originates as seawater. At the axis and on the ridge flanks, the circulating seawater produces a major chemical exchange between the oceans and the crust. Based on heat budget constraints, between 10 and 40% of the river flux of Mg can be taken up during high-temperature alteration of the basaltic crust along the mid-ocean ridge axis. Most of the hydrothermal -heat loss, however, occurs on the mid-ocean ridge flanks, where the temperatures are lower and the seawater flux correspondingly larger. The estimated heat loss on the flanks is so large that upwelling must occur over a large fraction (5-30%) of the seafloor less than 65 Ma in age, at seepage velocities on the order of 10 to 100 cm/yr. The circulating seawater need lose less than 1 to 2% of its Mg content in order to solve the Mg mass balance for the oceans. Fluids in subduction zones are commonly less saline than seawater and are rich in methane and other light hydrocarbons. These fluids may originate by dewatering of the downgoing slab. If so, they may close the geochemical cycle of H2O that began with hydration of the basaltic crust at the ridge axis.

Jan 1, 1990

Coal seam methane (CSM) is an æunconventionalÆ gas resource that is becoming an important energy resource for Australia, especially along the eastern seaboard. It has been conventionally believed that methane in high rank coals was exclusively derived from thermocatalytic processes during decomposition of coal at elevated temperatures. However, recent re-interpretations of gas composition and isotope data have indicated that microbial methane generation may be one of the main processes responsible for the accumulation of commercially producible methane in some coals. In low rank (æbrownÆ and sub-bituminous) coals, methane (CH4) is mainly generated by microbial activity at low temperatures. The amount of this biogenic gas generated and accumulated in low rank coals depends largely on the rate of burial and depth. Most low rank coals are æunder-saturatedÆ with respect to their maximum gas sorption capacity. In contrast, high rank coals may be highly saturated due to extensive gas generation from both thermogenic and secondary biogenic processes. However, in basins where secondary biogenic gases have not replenished the thermogenic gas lost during basin uplift, the coals will be æunder-saturatedÆ. In many basins around the world, high CSM producing zones appear to contain secondary biogenic CH4 generated by microbes transported in meteoric water recharge through permeable coal seams. Biogenic CH4 generation requires the activity of a consortium of anaerobic respiring microorganisms, fermentative bacteria and acetogenic bacteria to break down complex organic molecules to simpler molecules having one or two carbon atoms, which enables methanogenic archaea to generate CH4. The two main methanogenic pathways in the generation of secondary biogenic gas from coal are aceticlastic reaction and carbon dioxide (CO2) reduction. In eastern Australian coals CO2 reduction appears to be the main process. The types of microbes that are directly involved in these processes are unknown because they have not yet been isolated from the coal seams. The CSIRO is currently investigating the processes of biogenic gas generation in Australian coals. Potential may exist to introduce appropriate microbes into deep coal seams to enhance methane saturation levels, gas sorption capacities and permeabilities.

Jan 1, 2004

Between, 1980 and 1984, the demand for non- ferrous metals in the free world grew annually by 1.5 per cent for copper, 0.4 per cent for lead, 1.4 per cent for zinc, and 2.5 per cent for nickel. The growth rate decreased substantially compared to the rate experienced before 1980, and was far lower than the GNP growth during the corresponding period. The main reasons for this are considered to be 1. resource-saving efforts by industrialized countries resulting from the first and the second oil crises, 2. saturated demand for durable consumer goods, and 3. substitution of non-ferrous metals by new materials such as optical fibers.

Jan 1, 1986

By R Berry, J Hunt, T Kojovic

Geometallurgy aids the understanding of orebody variability through the integration of geological and processing information, thereby enabling spatial mapping of processing (eg comminution or separation) performance across a deposit. In order to do this, estimates of quantitative geometallurgical attributes are needed so that continuous downhole profiles can be generated for each attribute, providing vital data for the development of processing domains through geostatistical modelling. However, as traditional comminution tests are high cost and/or require large samples, current practice typically results in insufficient data density and distribution of comminution indices making it difficult to model and map deposit scale variability. The aim of this work was to find a method to estimate comminution indices based on data that is widely available at mine sites. This data includes mineralogy and chemistry of drill core samples, plus logging information such as lithology and alteration. Work to date indicates that comminution parameters such as semi-autogenous grinding (SAG) Power Index (SPI), Bond Work Index (BWI) and A*b (Julius Kruttschnitt Mineral Research Centre (JKMRC) drop weight test (DWT) Index) can be modelled using chemical and/or mineralogical data. The estimated hardness indices can then be propagated into the mine site database and used in the definition of processing domains that map inherent variability across a deposit. The estimates can thus provide geometallurgical inputs for spatial modelling, mine planning and optimisation initiatives.CITATION:Hunt, J, Kojovic, T and Berry, R, 2013. Estimating comminution indices from ore mineralogy, chemistry and drill core logging, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 173-176 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By C J. Moran

The Gladstone region, as one of the most industrially intense regions in Australia, uses significant quantities of fresh water. Awoonga Dam, situated on the Boyne River, is the only major source of water in the region. The current typical annual usage is 53 GL (Porteous, 2006) and approximately 80 per cent of the water is used by heavy industry (Gladstone Area Water Board, 2004). Until relatively recently, there has been ready and easy access to raw water for industrial use. The recent drought, which resulted in severe water restrictions in 2002 and 2003, emphasised the importance of water for a dominant industrial region like Gladstone. Although now in the process of changing, the typical contractual arrangements in the past have provided little financial incentive for efficient water use. From research undertaken on potential water reuse opportunities, several key questions have emerged related to water management in an industrial region such as Gladstone. This paper highlights these key questions, presents findings from recent regional strategies and assesses the potential for water reuse. Even though there is no clear-cut financial incentive for reusing water, there could be stronger regional and risk mitigation drivers for doing so. Initiatives to incorporate adaptive capacity through collaborative industrial synergies would allow for robustness and resilience in water security, leading to long-term sustainable water management across the Gladstone region.

Jan 1, 2006

By T B. T Nguyen, L Matthews, D O’Dea, T Honeyands, T Harvey

Productivity and fuel consumption of the blast furnace is driven by the quality of the iron ore sinter, which in turn is related to the sinter mineralogy. The sintering conditions including temperature and gas composition have a significant influence on the formation of melt and finally the mineralogy of the sinter. In this work, analogue sinter tablets were produced from iron ore fines in a laboratory furnace with tightly controlled temperature profile and oxygen partial pressure in the gas. The mineralogy of the sinters was analysed using reflected light microscopy. The results showed that increasing thermal enclosed area (area enclosed by heating and cooling curve above a reference temperature) reduces primary hematite and platy silico-ferrite of calcium and aluminium (SFCA) contents. This is attributed to increasing melt formation, leading to greater assimilation of the iron ore particles. Lower magnetite was found for tablets with greater median pore size, which is thought to be due to greater oxidation of magnetite to hematite during cooling in air. It was also found that higher alumina content was found to result in more SFCA formation under the same heating/cooling conditions, whereas tablets with higher goethite had higher assimilation and produced more secondary hematite on cooling. Finally, it is necessary to relate the enclosed area to the temperature at which the melt formation becomes significant which strongly depends on chemical composition of the ore studied.

Nov 8, 2021

By W Y. Kim, Y B. Kang, Y J. Park

The phase equilibria in the Al2O3–TiOx system were investigated in wide ranges of temperature and oxygen partial pressure: 1300~1600°C and 10-16.6~10-8 atm, respectively. The equilibrium phases and their compositions were identified using X-ray diffraction (XRD) and electron probe microanalysis (EPMA), respectively. Most noticeably, a wide range of pseudobrookite solid solution was found in equilibrium with almost pure alumina. At each temperature, the cationic ratio expressed as RTi = nTi/(nAl + nTi)) of the pseudobrookite solid solution showed a noteworthy dependency on the oxygen partial pressure. This resulted in the formation of a broad range of pseudobrookite solid solutions, ranging from Al2TiO5 (RTi = 1/3) to Ti3O5 (RTi = 1.0). Complete miscibility within the pseudobrookite solid solution was observed at 1600°C, with only a minor miscibility gap becoming evident below 1500°C. Based on the results obtained in the present study, the behaviours of Al2TiO5 pseudobrookite have implications in two key domains: (1) understanding changes in the physical properties of the materials, and (2) elucidating the evolution of Al–Ti complex oxide inclusions in liquid steel which can deteriorate the steel cleanliness.

Aug 21, 2024

The seam gas content at Westcliff Colliery is 12-15m3/tonne of coal.Composition ranges from 99% CH4 to 52% C02 in one area. Desorption rates are proportional to gas contents and CH4 is preferentially desorbed. A crushed zone of reduced permeability advances with the face - at Westcliff ribside crushed zones are 2.5 to 6.5m wide. Poor strata control widens crushed zones. 12 months of pre-drainage allowed 2 heading development and longer pillars to be used in a virgin area instead of 3 or more headings without drainage. Machined coal may lose as much as 1.6m3/tonne being conveyed out of Westcliff Colliery. Experience differs from mine to mine. Permeation is affected by time, strata movements, changing water content, and changing stress. Permeabilities vary from lOmd for Pittsburgh Seam to less than 1 and for the Bulli Seam. All these data and differences await further investigation.

Jan 1, 1982

A study of the bacterial oxidation of naturally occurring high-purity sulphide minerals (FeS2, Fel_xS, CuFeS2, Cu2S) has been conducted using a mesophilic strain of T. 6ejtAooLcdcth4. As well as metal analyses and solution pH, partitioning of sulphide sulphur into elemental sulphur and sulphate ion has been monitored. Partially oxidised sulphide substrates have been characterised at regular time intervals by X-ray diffraction methods and extra-cellular organic compounds reporting into leach solution have been identified by'thin layer chromatography. The results indicate that the S¦/SO4 2 partitioning of the sulphide substrates is independent of cell inoculum size and initial pulp density and varies with solution pH, Eh, leaching time and mineralogical properties of the individual sulphide minerals. The signifi- cance of results for applications in selective flotation, coal desulphurisation and agglomera- tion has been outlined.

Jan 1, 1984