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By J. E. Gosline

IN any theory of a hydrodynamic nature dealing with the vertical flow of gas-liquid mixtures in pipes, the two factors that present the greatest difficulty are the relative motion between the phases and the energy loss resulting from turbulence work. The former has generally been referred to in the literature as "slippage" and the latter as "fric-tion." A third factor of importance is the nature of admixture between liquid and gas for both the relative motion between the phases as well as the turbulence work are functions of the type of mixture. Although much work of a general nature has been performed on the vertical flow problem, there have been very few attempts made to study experimentally the factors involved in the phenomenon individually. Of these, perhaps the most notable is the work of Moore and Wilde1 on slippage. Some writers on the subject have assumed that over a wide range of operating conditions the controlling type of mixture, is one in which gas bubbles of uniform size are distributed throughout the liquid, and that the data obtained from experiments on the motion of single bubbles through various liquids may be used in evaluating the slippage. Ver-sluys2 has further assumed another controlling type of mixture in which the liquid occurs as a dispersed phase within the gas and applies data on the fall of drops of water in air to calculating the relative velocity. It was for the purpose of studying the applicability of data on single bubble motion to the slippage factor and to further observe the nature of mixtures that a research program was conducted at the University of California during 1932 and 1933. These experiments formed a basis for

Jan 1, 1935

By H. L. Ames, P. H. Jennings, R. W. Stanley

A process has been developed for leaching copper, lead and calcium from molybdenite concentrate. The leachant is a solution containing an oxidizing chloride (e. g., CuC12, FeC13) and an alkaline earth metal chloride (e. g., CaC12). Cupric chloride and ferric chloride, in the presence of 20-30% calcium chloride, are effective oxidants for chalcopyrite and galena. Calcium chloride, in addition to promoting the rate of leaching, serves to lower the solution pH and raise the boiling point. Leaching for two hours at 110'~ with a 1 % CuC12-10% FeC13- 30% CaC12 solution results in the extraction of up to 98% of the copper in molybdenite, 98% of the lead, and 79% of the calcium. Less than 0. 5% of the molybdenum is dissolved. The leach solution can be rapidly and effectively regenerated with gaseous chlorine and recycled. Build-up of copper and lead in the leach solution is controlled by discarding about 30% of the leach solution each cycle.

Jan 1, 1973

By L. H. Robinson

Triaxial compression tests on Indiana limestone indicate that chemical additives in the pore fluids can increase or decrease the strength in plastic failure but not in brittle failure. Tests using a series of the sodium salts of dicarboxylic acids show that odd-number carbon-atom chains decrease the yield strength as much as 3.0 x 10 3 psi, and even-number carbon-atom chains increase the yield strength as much as 9.0 x 102 psi. ,The most effective chemical (sodium citrate) decreased the yield strength of Indiana limestone from 16.0 x 103 to 12.0 x 103 psi. The chemical additives investigated have no influence on microbit drilling rate when drilling with zero differential pressure. However, when drilling at a 2.0 x 103-psi pressure differeniial and using an odd-number carbon chain compound as the circulating fluid, the roller bit drilling rates were slower than with water whereas the drag bit drilling rates were faster. One even-number carbon chain compound added to the circulating fluid produces the opposite effect: the roller bit drilling rate is slightly faster than with water and the drag bit slower than with water. INTRODUCTION A Russian book by Rehbinderl published in 1944 generated much interest in the possibility of aiding and accelerating the destruction of solids by the action of a liquid in which the solids are deformed. This book describes a process in which microcracks are generated during elastic deformation. To describe this process, the rock is divided into three zones: (1) the zone in which the destruction takes place, (2) the predestruc-tion zone (an affected area immediately below the destroyed zone) and (3) the undisturbed specimen. Consider a load applied normally to a surface of an infinite slab of rock. Immediately below the point of application of the load, the rock is destroyed by compression or shear forces. Below this area of destruction, because of a great number of discontinuities ranging from defects to weak points in crystals of discontinuities in crystal latices, very small cracks are created in or between the crystals (often referred to as microcracks). Upon removing the load, the broken rock in the destroyed zone could be removed. In the lower predestruction zone, however, the microcracks in and between the crystals could disappear by the process of rehealing, i.e., the molecular attraction from one side of the crack to the other side being sufficient to completely eliminate the crack. Thus, a large number of these microcracks possibly exist only for a relatively short period of time. The concept of small cracks being generated within the crystals of a rock is not unreasonable. If the rock matrix is deformed below the yield point, some of the defects present within the crystalline structure could start small cracks through the interior of the grains. Upon removal of the load, these microcracks reheal (or the newly generated surfaces come back together) so that all evidence of cracks completely disappears. Under various types of loading, and in various types of fluids, the rehealing of these cracks would be time dependent. If a liquid adhered to the surface of a rock, it could penetrate into the microcracks and thus delay or prevent the rehealing process. This suggests that the prevention of healing of the microcracks may be dependent upon the wetting characteristics of the solid. Thus, rocks which are water-wet should be more easily destroyed in water than in nonpolar hydrocarbon liquid. Adsorption of a liquid could also reduce the free surface energy which could explain the decrease in strengths of materials under nonrepetitive-type loading. Rehbinder's work prompted Boozer, Hiller and Serdengecti 2 to examine the effects of pore fluids on the deformation of rocks subjected to triaxial compression over a range of confining pressures, temperatures and strain rates. Fluids which strongly adsorbed on the rock grain surfaces decreased the strength of sandstone and limestone, which deformed plastically. For certain strain

By R. B. Moffitt

INTRODUCTION In recent times the continuing depletion of high grade mineral deposits and the massive increase in raw material consumption have forced the metal mining industry to exploit ore bodies of lower and lower grades. To obtain a satisfactory financial return from these deposits, there has been the concurrent and evident trend towards increasing the size of operations to obtain benefits from the economies of scale. The evaluation, planning, and design of these large scale open-pit operations, so as to yield the maximum possible return on investment, is an extremely complex, iterative procedure. With profit margins trimmed, "small" errors can become much more significant and with exploration costs spiralling, accurate and rapid evaluation is essential. It demands a sophistication and precision in the evaluation process unheard of ten years ago. What follows attempts to describe the need to thoroughly plan the overall evaluation programme such that duplication of effort is avoided and all relevant information is systematically recorded from the outset of exploration. The final section of the paper takes a realistic case study to illustrate the significance of pit slope angles on the design of the final pit and the economics of the total project. THE EVALUATION PROGRAMME The team, (for a team effort it must be), that is charged with the responsibility of conducting the evaluation exercise, has the difficult task of placing values on a multitude of independent and inter-related variables. Each variable has some economic significance; the degree of significance varying according to the metal sought, the environment in which it occurs, the vagaries of the market place, to name but a few of the problems facing the project team. From this maze of variables, the team must identify those that have the most critical influence on the overall economics of the proposed venture. Investigations must then be set in motion to quantify these controlling factors more precisely. It is important to recognize that such investigations form part of the evaluation programme and require monitoring for both timing and cost as the whole exercise of evaluating the project continues. To add to the difficulties, the economic significance of any particular variable may change during the course of the programme.

Jan 1, 1972

By Charles Weaver

DURING the past few years there has been considerable activity in prospecting for oil and gas in several parts of western Washington. From time to time seepages of oil or emanations of gas have been reported from various places. Several companies have been organized for the purpose of drilling, but only a part of these have actually begun operations. In certain localities very small seepages of oil occur, but up to the present time no oil or gas in commercial quantities has been obtained. In order to determine the conditions which may be favorable or unfavorable 'to the occurrence of petroleum it becomes necessary to know the character and extent of the geological formations in which such deposits might occur. In other regions where producing wells have been developed it is possible to know what formations contain the oil mind what structural conditions influence its concentration in reservoirs or zones. It is usually possible to determine those strata which contained the a materials from which the petroleum may have been derived and also the position and distribution of the more porous sandstone belts into which it may have collected. Detailed stratigraphic surveys, may even determine the depth at, which a certain known oil-bearing zone may be tapped at any particular place. It is also possible to recognize those formations which are presumably barren of oil, as well as those which are absolutely so.

Jan 7, 1915

By W. K. Tony Seiler

Further development of mechanical boring machines for hard and abrasive rocks will be effected by the development of more efficient rock cutting tools or the evolution of entirely new rock excavating principles. Presently the cutting tools suitable for extremely hard rocks and successfully and economically used with raise and tunnel boring machines are tungsten carbide insert big hole cutters. This paper explains the design, rock cutting principles, and actual boring operations to illustrate the capabilities and applications of tungsten carbide (TC) insert cutters. While the rate of borehole advance may fall short of the rapid excavating results achieved with soft rock boring machines, the cutter described in this paper may prove to be the most suitable tool in hard rock excavation for many years to come. DEFINITION OF HARD ROCK Existing bored excavations in hard abrasive rocks are proof of the economic application of new methods and mechanical rock boring in the mining industry. Most of the experience in cutting hard to extremely hard rocks has been gained in raise boring where relatively short and small diameter openings are bored. This poses a lesser risk regarding cutter cost than a long and large diameter tunnel and has therefore promoted the testing of various cutter products. Many types of rocks and geologic conditions were en- countered and actual test data was recorded in materials of up to 100,000 psi uniaxial compressive strength. To clarify the term hard to extremely hard, a 1970 interpretation of rock strength which was recently used is adopted and expanded in this paper.

Jan 1, 1971

By W. C. Peters

From the time of its beginning in the mid-19th century, the American barite industry has had its major development in the eastern and central states. Geologic and economic factors serve to maintain Arkansas, Missouri, and the Southern Appalachian states in the lead position. In earlier days, the major markets for barite were in paint, chemical, and glass manufacturing, and the favored deposits were those which were close to eastern industrial areas; furthermore, the eastern deposits were cheaply mined and required little or no beneficiation. In the last few decades, the use of barite as a weighting medium for muds in rotary oil well drilling has caused a great expansion in the industry, but the marketing picture is still centered outside of the western states-now on the Gulf Coast area where high pressures are common in oil wells. Low cost imported barite, readily available on the East Coast and Gulf Coast, has always been a major marketing factor in the industry. The major barite producing state is Arkansas, with the industry centering about the Magnet Cove area. Missouri ranks second, with production mainly from residual deposits. Several Southestern states are actively producing from residual deposits.

Jan 9, 1958

By Sunder S. Saluja

Man had to learn to break rocks as early as the Stone Age, when they formed his main source of raw material. He started with chipping and over the years has reached a stage where he can employ atomic blasts and break, with one blast, millions of tons of rock. In between these two extremes there have been several stages of development including firesetting, use of the expansion of water on freezing in chipped cracks in cold climates, the use of low or deflagrating explosive black powder in about the 17th century, the use of high explosives with the discovery of nitroglycerine in 1846 by Sobrero, followed by the monumental discoveries of the great Swedish scientist Alfred Nobel in the latter half of the nineteenth century. The attempts to develop a stronger and still stronger explosive force were accompanied by investigations to understand the mechanism of failure of rock so that the force could be used to the best advantage; the latter, of course, have lagged far behind the former. This is mainly due to the fact that the chemical reactions involving high explosives as well as the processes resulting in the breakage of rock take place at too great a rate to be studied with the equipment that has been only recently available. Moreover, the development of stronger explosive forces was prompted by military necessities in the past and competition, at present, among highly developed nations. With the development, however, of the new techniques such as micro- second photography, microsecond flash radiography, extremely high-speed movies, strain gage assemblies, electronic chronographs and other improved electronic techniques, the investigator has in the last decade or

Jan 1, 1968

By Akira Yokoyama

Japan is composed of four main islands: Honshu, Hokkaido, Kyushu, and Shikoku (Fig. 1). Between Honshu and Kyushu, a railway tunnel and a road tunnel have been open since 1942 and 1958, respectively. Hokkaido, [ ]

Jan 1, 1970

By R. A. Ronzio, P. B. Queneau, C. A. Born

The molybdenite flotation operation of Climax Molybdenum Co., Division of AMAX Inc., near Leadville, Colo., generates a rougher tailing containing 0.03% W03 and 0.005% SnO2. This tailing is subjected to a series of mineral beneficiation steps for production of wolframite and cassiterite concentrates. However, these byproducts are contaminated by small quantities of UsOa. This paper describes application of sulfuric acid-sodium chlorate leaching for substantial elimination of the radioactive impurities, particularly the mineral brannerite. The leached residue is amenable to magnetic separation of wolframite from cassiterite.

Jan 1, 1976

By Francis L. Vinton

THE eccentric theodolite I exhibit is one constructed by the Stack-poles of New York, from drawings, considerably modified, of Combes's theodolite. The telescope is on one side of the horizontal limb, and the vertical circle is opposite to the telescope; thus they nearly balance each other, making already the construction lighter than in the instrument of Combes, where the telescope and vertical circle are together on the same side, and are both balanced by a considerable weight. The instrument stands upon three levelling screws or feet, an improvement upon the old or general style of mounting a transit on four feet-for indeed the instrument is easier levelled, and, more-over, stands more stable on three than on four points of support. The general advantage of an eccentric theodolite is evident, namely, that it can measure any and all vertical angles, from 0 to 360, without being interfered with by the horizontal limb as is the transit; besides this advantage, it needs no preparatory adjustment or correction for eccentricity ; on the other hand, however, that correction

Jan 1, 1873

By Francis L. Vinton

THE eccentric theodolite I exhibit is one constructed by the Stack poles of New York, from drawings, considerably modified, of Combes's theodolite. The telescope is on one side of the horizontal limb, and the vertical circle is opposite to the telescope ; thus they nearly balance each other, making already the construction lighter than in the instrument of Combes, where the telescope and vertical circle are together on the same side, and are both balanced by a considerable weight. The instrument stands upon three levelling screws or feet, an improvement upon the old or general style of mounting a transit on four feet for indeed the instrument is easier levelled, and, moreover, stands more stable on three than on four points of support. The general advantage of an eccentric theodolite is evident, namely, that it can measure Any and all vertical angles, from 0 to 360, without being interfered with by the horizontal limb as is the transit; besides this advantage, it needs no preparatory adjustment or correction for eccentricity; on the other hand, however, that correction

By J. Federico Price, Joseph E. Aparicio

This paper describes the production of a specific iron oxide pellet that has given very good and consistent results as feedstock for HYC-Process Direct Reduction Plants. The sponge iron originated from these pellets has been used for the economic production of almost 15 Mt of low carbon steel via electric arc furnace meltshops. An overview of mining, beneficiation, pelletizing, direct reduction and steelmaking for this case is given with emphasis on the charactertitics of the self-fluxing oxide pellets.

Jan 1, 1982

By C. Jackson, J. J. Harrington

The pH control system at Kennecott Copper Corporation's Nevada Mines Division concentrator consists of two independent systems, lime dilution and lime addition. Lime dilution is accomplished in a mixing tank where slaked lime and water are introduced proportionately. The desired dilution of the milk of lime is determined by the electrical inputs provided by eight pH probes, one per grinding section. The inputs are averaged and applied to a time base generator. The summation output of the time base generator determines the proportion of lime and water that are to be mixed and applies this input to a voltage sensitive switching device. The switching device provides a signal to one of two relays which will add either slaked lime or water, dependent upon the summation output. The entire cycle is based on a 2-min repetition rate to allow for sufficient mix time. Responsivity is controlled by maintaing a limited maximum solution level in the mix tank. Lime addition is controlled independently within each grinding section. The electrical input from the pH probe in a given section controls the solenoid valves which provide lime to each of the ball mills. The valves remain open within a time range capable of maintaining the pH of flotation feed at a given set point.

Jan 1, 1978

By E. C. Dominguez, H. B. Scharf

THE Sparrows Point plant of Bethlehem Steel Co., southeast of Baltimore, is the largest Bethlehem plant, with an annual rated capacity of 6.2 million ingot tons. There is considerable diversity of product, but a high percentage is sheet, tin plate, galvanized sheets, and rod and wire. The large amount of light-weight end product requires a number of pickling installations that necessarily consume large quantities of sulfuric acid. In the coking operations sulfuric acid is also consumed in recovery of ammonia as ammonium sulfate and in treatment of recovered light oil derivatives. Total sulfuric acid consumption in the plant is currently approaching 10,000 tons per month, of which 55 to 60 pct is required for pickling. In 1951 the acute sulfur shortage caused grave concern as to future sulfuric acid supply for the Sparrows Point plant. Raw materials for acid making were already at hand in the form of hydrogen sulfide and pyrites sufficient to produce nearly half the sulfuric acid required at that time. It was also known that the Bethlehem mining activities would produce additional pyrites in the future. Late in 1951 Bethlehem management decided to build a 250-ton sulfuric acid plant at Sparrows Point to utilize these raw materials. The plant was built and put in operation in May 1953. The steel plant has expanded considerably since 1951, and it is now necessary to operate the acid plant far over rated capacity in order to supply plant demand. Production of acid in 1954 amounted to 93,000 tons. Raw Materials for Acid Making: Coking operations at Sparrows Point produce a residual fuel gas in large quantity which has a net heating value of 525 to 545 Btu. Prior to 1950, plant surplus coke oven gas was sold to the local utility company. In

Jan 1, 1957

By F. E. Bash

About three years ago, the writer presented a paper1 on the rate of heating and cooling of a 24-in. round ingot. The present paper deals with work done on larger ingots at the plant of the Allis Chalmers Mfg. Co., Milwaukee, Wis., in August, 1919. Sufficient data on ingots of all sizes were desired to enable one to calculate in advance the rate at which any ingot could be raised to a forging temperature without injury to the steel, determining also the temperature gradient between different sections of the ingot and the length of time necessary to heat to the center. This has now been experimentally determined for 24-in. and 45-in. ignots by the writer and for a 18-in. cube by E. F. Law.2 J. F. Harper has also made tests on heat-treating temperatures on 30-in, ingots; which data are included in this paper. No attempt is made here to work out a formula for the heat penetration of steel, for too many factors are involved concerning which we have not sufficient information, as for instance, the specific heat of steel up to 2300' F. It is hoped that eventually a set of formulas will be developed so that one may calculate maximum allowable temperature differences within an ingot for any particular kind of steel and the rate of absorption of heat and temperature gradient within the ingot for a definite temperature head. EXPEEIMENTAL INGOT The ingot tested was 45 in. in diameter, having been forged into the shape shown in Fig. 1 from 54 in. diameter. Seven -in. holes were

Jan 1, 1923

By F. E. Bash

About three years ago, the writer presented a paper1 on the rate of heating and cooling of a 24-in. round ingot. The present paper deals with work done on larger ingots at the plant of the Allis Chalmers Mfg. Co., Milwaukee, Wis., in August, 1919. Sufficient data on ingots of all sizes were desired to enable one to calculate in advance the rate at which any ingot could be raised to a forging temperature without injury to the steel, determining also the temperature gradient between different sections of the ingot and the length of time necessary to heat to the center. This has now been experimentally determined for 24-in. and 45-in. ignots by the writer and for a 18-in. cube by E. F. Law.2 J. F. Harper has also made tests on heat-treating temperatures on 30-in, ingots; which data are included in this paper. No attempt is made here to work out a formula for the heat penetration of steel, for too many factors are involved concerning which we have not sufficient information, as for instance, the specific heat of steel up to 2300' F. It is hoped that eventually a set of formulas will be developed so that one may calculate maximum allowable temperature differences within an ingot for any particular kind of steel and the rate of absorption of heat and temperature gradient within the ingot for a definite temperature head. EXPEEIMENTAL INGOT The ingot tested was 45 in. in diameter, having been forged into the shape shown in Fig. 1 from 54 in. diameter. Seven -in. holes were

Jan 1, 1923

By K. C. Li

ARSENIC and antimony are always grouped together by chemists, since they are both members of group V of the periodic table of elements and exhibit a general similarity in the formation of compounds. Metallurgists generally think of them as less closely related because they do not have similar uses. In metallurgical operations, especially lead and copper smelting, arsenic tends to go off as a vapor phase and collect as fume in the flues, while antimony tends to remain with the bullion. Broadly speaking, the frequency of occurrence, practical utility and the effects on associated metals of arsenic and antimony are such that the metallurgist is inclined to think of arsenic as a troublesome impurity in ores, but of antimony as a valuable constituent that is recovered either as a byproduct or through the metallurgical treatment of antimony ores. Estimating the world production of arsenic as about 40,000 tons annually, probably not more than about 200 tons yearly is produced and used in metallic form, whereas one half of the approximately 40,000 tons of antimony produced annually is metallic. ARSENIC The modern uses of arsenic differ little from ancient ones. Though it has been known from early times, its poisonous quality is almost the only one that yet finds extensive use. The shift in the past century from its utilization in poisoning people to the poisoning of insects, beginning in 1860, has not only led to a considerable increase in

Jan 1, 1953

By J. M. Clark

For some years past, those interested in the development of the increasingly important mining industry of Canada, havc urged the adoptioi~ by the Dominion Parliament of a federal mining-law, which would have the force and stability of statutory enactment. At present, placer-mining in the Yukon Territory is governed by the Yukon Placer Mining Act. All other mining under federal jurisdiction is governed by Orders in Council and Ministerial Iiegulations. In the earlier stages of development, it is perhaps a matter of neces~ity that these important matters should be so dealt with; but it is now felt that the time has come when mining-rights in the extensive regions under federal control should be put on a permanent basis, and that any changes required from timc to time should be made only after full and open discu~sioii in Parliament. A short sketch will suffice to indicate how vast and varied the interests affected really are. When the Dominion of Canada mas constituted by the Inlperial Statute known as the British North America Act of 1867 (which into force by proclamation on July 1 of that year), it comprised only the present Provinces of Ontario, Quebec, Nora Scotia, and New Brunswick; but provision was made for the inclusion of Newfoundland, Prince Edward Island, British Columbia, Rupert's Land, and the North West Territories. Subsequently Rupert's Land and the North West Territories were acquired, the Crown Colonies of British Columbia and

Jan 1, 1912

By Helmut Thielsch

During the last three decades a great many arguments have been presented on the subject of "mosaicJ' or "blockJJ structures of metals. Apparently because of insufficient evidence, the "block-structure" theories have never been widely understood among the physical metallurgists in this country, and most investigators among the few that have tried to demonstrate the existence of such an inner strutture Of crystals or grains have failed to recognize also the existence of a lamellar structure. Moreover, little thought has been given to justify the existence of such "lamellar" or "mosaic-block" structures on a theoretical basis. Since properties such as Plasticity; ferro-magnetism, hardness, diffusion, and others may be explained by structural faults in the lattice network of the crystals: the great importance of a more detailed knowledge of the structure within crystals or grains becomes now evident. Because Of the vast extent of the field Of submicroscopic structures, it shall be the purpose Of this paper only to review the more important of the results obtained by other investigators, especially in Germany, where a great deal of attention has been given to mosaic structure during the last three years. The origin of this mosaic patternt and effects of cold reduction and recrystallization will be shown in further studies later on. Imperfections in Crystals The many terms used in the literature to denote structural types of crystals are often not clearly defined. To clear up some of the confusion, the meaning of the more important terms will be given here. ideal, or perfect without any structural imperfections are called "ideal crystals,,or ''Perfect'' crystals,n meaning a Homogeneous interior structure of atoms, ions or molecules, as the case may be. In other words, at every point in the interior of the crystal exactly the same orientation of the crystallographic axes of the coordinate system would exist. The Surface of such a body, if etched with an appropriate etching reagent, would reflect light with perfect uniformity. Crystals of this type are almost nonexistent. Real Crystals.—L'Real crystals"' may contain various types of structural defects, which can be classified into: (I) lineage structure, (2) mosaic-block structure, (3) lamellar structure. The inhomogeneities many,in these groups mean that the orientation of the crystallographic aies will not be the same at every point within the interior of a crystal (or grain of a poly crystalline body). 'Perjecl Real Crystals.—The term "perfect real crystals " is generally used to describe crystals with minute structural or thermo-dynamical inhomogeneities. The former

Jan 1, 1946