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By I. Iwasaki, R. Titi-Manyaka

Chlorination and chloridization behaviors of pyrite, pyrrhotite, marcasite, chalcocite, covellite, galena, sphalerite, heazlewoodite, and elemental sulfur were investigated by thermogravimetric analysis. The possible reaction mechanisms are discussed on the basis of the theoretical weight changes and thermodynamic considerations. Chlorine is a more effective chloridizing agent than hydrogen chloride. In the light of the experimental results, a scheme for producing nonferrous metal chlorides, molten sulfur, and ferric oxide from complex sulfide flotation concentrates is discussed.

Jan 1, 1974

By Frederick C. Langenberg

A method is presented for computing the solubility of nitrogen in molten alloy steels. Examples are given to illustrate the procedure, and comparisons are made between predicted and measured nitrogen solubilities. THERE is an increasing use of nitrogen as a major alloying element in steels, or as a partial substitute for other alloying elements. Nitrogen is a potent austenite stabilizer, and Cr-Mn-low Ni-N steels, or even Cr-Mn-N steels, are being considered

Jan 1, 1957

By H. F. Yancey, M. R. Geer

The importance of the size composition of coal is reflected in the difference in price of the various sizes of the same coal and in the large number of primary sizes and mixtures of sizes produced by the modern preparation plant to meet the demands of a market that in late years has grown increasingly conscious of coal size. The importance of size in the industrial and domestic uses of coal has its counterpart in the role played by size composition in the laboratory examination of coal. Investigation of many of the physical properties of coal in their relation to its uses requires an evaluation of size composition. In fact, the Standards on Coal and Coke issued by the American Socaiety for Testing Materials in 1936 contains 12 standard methods of testing that involve some use of size composition. The screen analysis is, of course, the standard method of determining size composition, whether the material is coarse run-of-mine coal or fine pulverized fuel. Custorriarily, the analysis is reported as the weight percentages retained on or passing each of a series of testing screens, the number of which may range from only two or three to as many as 20. When more than two or three sieves are used, which is usual, the number of weight percentages obtained is so great as to make the analysis difficult to comprehend. Direct comparison of analyses made 011 the same sieves is hard, and comparison of analyses covering the same range of sizes but made on different sieves is next to impossible. Consequently, a frequent purpose of sizing tests-—-correlation of size with properties and charactcristics related to size-—is rendered difficult. Less cumbersome means of expressing size composition have been attempted with various degrees of success. An average particle size, calculated by any of several formulas, is useful for some purposes, also the weight percentage retained on a single sieve finds some application as a

Jan 1, 1938

By M. R. Geer, H. F. Yancey

The importance of the size composition of coal is reflected in the difference in price of the various sizes of the same coal and in the large number of primary sizes and mixtures of sizes produced by the modern preparation plant to meet the demands of a market that in late years has grown increasingly conscious of coal size. The importance of size in the industrial and domestic uses of coal has its counterpart in the role played by size composition in the laboratory examination of coal. Investigation of many of the physical properties of coal in their relation to its uses requires an evaluation of size composition. In fact, the Standards on Coal and Coke issued by the American Socaiety for Testing Materials in 1936 contains 12 standard methods of testing that involve some use of size composition. The screen analysis is, of course, the standard method of determining size composition, whether the material is coarse run-of-mine coal or fine pulverized fuel. Custorriarily, the analysis is reported as the weight percentages retained on or passing each of a series of testing screens, the number of which may range from only two or three to as many as 20. When more than two or three sieves are used, which is usual, the number of weight percentages obtained is so great as to make the analysis difficult to comprehend. Direct comparison of analyses made 011 the same sieves is hard, and comparison of analyses covering the same range of sizes but made on different sieves is next to impossible. Consequently, a frequent purpose of sizing tests-—-correlation of size with properties and charactcristics related to size-—is rendered difficult. Less cumbersome means of expressing size composition have been attempted with various degrees of success. An average particle size, calculated by any of several formulas, is useful for some purposes, also the weight percentage retained on a single sieve finds some application as a

Jan 1, 1938

By Ihor A. Kunasz

Introduction Lithium minerals occur predominantly in pegmatites which contain mineral assemblages derived from the crystallization of postmagmatic fluids or from the metasomatic action by residual pegmatitic fluids. They have been the traditional sources of raw materials for ceramic and chemical industries. With the discovery of Searles Lake, brines became new sources of lithium. Indeed, the 1960s may well be referred to as the "brine decade" because several brine bodies of significant economic importance were discovered. In the United States, the brines of Clayton Valley, Nevada, are presently exploited by Foote Mineral Co. The brines of the Great Salt Lake of Utah, the Smackover formation, and the Imperial Valley geothermal field, have been defined as important resources of lithium. In South America, new occurrences have been identified in Bolivia and Argentina. At the Salar de Atacama, Chile, new production capacity is scheduled for 1984. Following the termination of the AEC purchase program in 1959, several companies such as Maywood Chemical Co., American Lithium Chemicals, and Quebec Lithium Corp. were forced to close their operations. Nevertheless, with the development of new applications in glass ceramics, air conditioning systems, synthetic rubber, and metallurgy (aluminum potlines), the lithium industry grew steadily, and with the potential application of lithium metal in batteries and nuclear reactors, a healthy growth can be foreseen. New products and new applications are likely to stimulate exploration for expanded, reserves as well as the search for new sources from which lithium could be extracted economically. Geochemistry of Lithium Lithium is the third element in the periodic table. It is the lightest of all the metals, having an atomic weight of 6.938, an ionic radius of 0.68Å and a charge of +1. The geochemistry of lithium has been extensively studied and has been summarized by Rankama and Sahama (1950), Goldschmidt (1937), and Hortsman (1957). The distribution of lithium in igneous rocks is controlled by its size and its charge, and by the (MgO+FeO) / Li2O ratio. In the early stages of crystallization of a magma, that ratio is very large. Consequently, both magnesium and iron are removed by ferromagnesian minerals in preference to lithium which is then concentrated in the residual magma. This results in an enrichment of lithium in silicic rocks and pegmatites (Strock, 1936). Pegmatites are coarse-grained igneous rocks formed by the crystallization of postmagmatic fluids. Minerals within pegmatites may also form by metasomatism (Jahns, 1955). Genetically, the pegmatites are associated with neighboring intrusives. Mineralogically, granitic pegmatites contain feldspar, quartz, and mica as the main constituents and a variety of exotic elements such as lithium, beryllium, tantalum, tin, and cesium, which may or may not occur in economically significant concentrations. Detailed studies by numerous investigators (Cameron et al., 1949, 1954; Hanley et al., 1950; Jahns, 1953, 1955; Page et al., 1953) indicate that pegmatites often exhibit an internal zonal arrangement, with each zone containing a specific suite of minerals. The lithium minerals are usually found in the intermediate zones, and although as many as 13 zones have been recognized by Cameron, et al. (1949), a complete zonal arrangement is rarely found. Zoning of pegmatite bodies has also been observed on a regional basis. The regionally zoned pegmatite sequences exhibit mineral assemblages and complexity according to their re-

Jan 1, 1983

By N. S. Stoloff, R. G. Davis

It is concluded from an X-ray stztdy that the formation of the hcp Mg3Cd superlattice is a nuclea-tion and growth reaction. A two-phase, ordered-plus-disordered, region is observed between 153" nnd 141"C. A maximum in the flow stress is observed both at temperature and in quenched specimens within the two-phase region. The peak arises fro112 the extra energy required to create antiphase boundary upon cutting the ordered regions. Hardening during isothermal annealing in Mg3Cd has been shown to be similar to the domain hardening in Cu3Au-type alloys in that up to the maximum the structure is ordered domains growing into a short range ordered matrix. The hardening is due to a combination of short range order strengthening and the strengthening produced when antiphase boundary has to be created. In a recent study1 of the effect of long-range order upon the mechanical properties and deformation modes of hcp Mg3Cd a comparison was made be- tween quenched (disordered) and slow-cooled (fully ordered) specimens. The most striking observations were that the disordered alloy yields at a much higher stress than the ordered alloy, and that there is a change in slip mode from primarily (_0001) ba_sal slip in the disordered state to (0001), {1010}, {1122}, and {l011} slip in the ordered state. The main purpose of the present work is to extend these observations to determine whether MgsCd exhibits a peak in flow stress at an intermediate degree of order, or at a critical domain size, as do other orderedstems. However, disagreement exists about the Mg3Cd order transformation with respect to: 1) the location of the critical temperature for order, 165°C or 153"~,' and 2) how the degree of order varies with temperature. Welber et a1.5 concluded from specific heat measurements that the formation of Mg3Cd is a second-order reaction with the degree of order a continuous function of temperature, while Moore and Raynor concluded that it is neither a first-order reaction, with the degree of order a discontinuous function of temperature, nor a second-order reaction. Consequently it was considered necessary to undertake an X-ray investigation into the change in degree of order and structure in the

Jan 1, 1964

By K. Huessener

Discussion of the paper of K. HUESSENER, presented at the New York. meeting, February, .1916, and printed in Bulletin No. -110, February, 1916, pp. 443 to 474. KARL NIBECKER, Youngstown, O.-It has been contended that the method of measuring the operation of a blast-furnace boiler plant by means of the amount of steam generated per pound of coke used in the blast furnace is not of any value and even that it is quite misleading. It has been found, in the plant with which I am connected, that, in general, a blast furnace will operate during a month so close to average. conditions that the average monthly measure of the plant efficiency is indicated by the number of pounds of steam made per pound of coke put into the furnace, neglecting the amount of iron made and the amount of gas used for heating the stoves. For some time, it has been our custom to keep a record of this figure and use it as a general indicator of the operating practice. In comparing this figure from two different plants we have found some difficulty, due to differing conditions. It is conceivable but not altogether probable that a slight difference in burden, kind of ore or coke, would account for this difference. The method of using the gas, whether washed or unwashed, and the plant arrangement, may affect this number. For several plants on which we have worked up this number, we have found that most of the ordinary running irregularities are eliminated during a run of a month or more and that the number is, therefore, satisfactory. In connection with a plot of the number of pounds of steam generated per pound of coke, we are also plotting the production of the furnaces and the pounds of coke used per ton of production. With these three curves plotted on the same sheet, we believe that the operating man has sufficient information to judge of the efficiency of his plant' for any month.

Jan 5, 1916

By A. Werenfels

No PETROLEUM, in commercial quantities, is found in France except the small production of the Pechelbronn field (Fig. 1) in Alsace, which produced 75,000 tons in 1923; therefore the test of the petroleum prospects of the Limagne is most interesting. Under the superintendence of M. Termier, chief engineer of the French mines, a well near Crouelle (Fig. 2) was drilled in 1921 to a depth of 856.3 m. (2808 ft.); at different depths favorable showings were encountered. The well, however, was abandoned because of drilling difficulties. A second one is now being drilled near the same place.

Jan 1, 1925

By F. E. Bash

Previous to the war, this country depended on Europe for its supply of a number of alloys of great importance in the manufacture of electrical apparatus and equipment. When this source was cut off shortly after the beginning of hostilities and the small stocks in the United States were exhausted, either inferior substitutes had to be used or the manufacture of the apparatus suspended. Since electrical equipment was of primary importance in the prosecution of the war, the substitutes had to be used until the composition and processes of manufacture of the alloys could be determined. Included among these alloys was one generally known as manganin, which is composed chiefly of copper and manganese and which, beside having a low-temperature coefficient of resistance, has a low thermal electromotive force against copper. These qualities make it valuable for the manufacture of electrical instruments and machines in which it is used in the shape of wire, rod, and strip. As a result of these circumstances, an investigation was started to determine how manganin could be made on a commercial basis so that a product of uniform quality and the necessary electrical characteristics could be produced. The object was to procure an alloy with temperature coefficient of resistance not greater than 1 X 1X per " C. and a thermal e.m.f. against copper no greater than that of the imported material. It is characteristic of manganin that the temperature-resistance curve is not a straight line but has a peak, which varies in position with different samples; it is most desirable, however, to have it at a temperature of 25' C. if possible. The coefficients of manganin from all records available ranged from a large negative to a large positive value. The composition as reported by different authorities is given in Table I. Prof. Matthew A. Hunter, of Rensselaer Polytechnic Institute, made up a number of small melts of manganin in a graphite crucible and the one that he reported as having the best cocfficient gave the following analysis: Copper, 83.6 per cent.; nickel 2.5 per cent.; manganese, 13.6 per cent.; iron, 0.3 per cent. An analysis of a sample of German manganin gave the following: Copper, 82.6 per cent.; nickel, 3.8 pcr cent.; manganese, 12.8 per cent.; iron 0.7 per cent.

Jan 1, 1921

By George A. Packard

WHEN, in April, 1892, the writer began experimenting with the cyanide-process, it had already proved a success in the treatment of tailings, but had not become an important factor as a primary method of ore-treatment. The Livingston, Colorado, mill was running a few small agitators; the Mercur mill, in Utah, was said to be a success, but was " closed down to increase capacity; " and Mr. A. B. Paul, in Shasta county, California, was running ore'through a stamp-mill into leachingvats, using a weak cyanide solution in the battery. Mills had been, or were being, erected in Arizona; on the Comstock lode; and in South Dakota. Some of these never started, and several were shut down or remodelled for other processes. Altogether, the outlook was anything but favorable. Many of these mills were planned to make use of agits tion, and a cyanide solution containing at least 1 per cent. of potassium cyanide was employed. Since then the improvement of the process, both chemically and mechanically, has placed it among the recognized successful methods of oretreatment. Within the past year I have visited a large number of cyanide-mills, and have collected considerable data, of which I publish enough herewith to give an idea of the development of the process and of the methods followed in the principal mills. I would say, however, that nearly all of these plants are experimenting, most of them employing experienced chemists,

Jan 1, 1897

By Fred A. Krafft

The time allotted to this paper will permit only the sketching of general principles and practice as generally employed in the industry to maintain and preserve the physical well-being of the miner and his family. Let it be emphasized on behalf of the industry that coal opera- . tors, individually and collectively, have given primary consideration to the appointment of a mine or community physician who is charged with the responsibility of caring for the sick and injured. However, it too frequently happens that with the selection or appointment of the camp doctor many operators wash their hands of further responsibility toward the health and the working efficiency of their employees. The coal industry is so organized in most of the coal-producing areas that not only is the health of the individual miner an important production problem but the collective health of the entire mining community is a fundamental operating problem. This is particularly demonstrated when epidemics of communicable diseases attack entire communities, with resultant loss of life and production and general community distress. The problem and responsibility of maintaining high health standards among miners and their families should be given as much consideration as safety, economical production and efficient distribution are given in the successful operation of coal mines. Company Policy In the inauguration or administration of a medical program for a large mining operation or for an individual mine, the first question to be solved is what the company policy is to be with respect to the following factors pertinent to a medical program: 1. On what basis will the company and the employees finance the program ? 2. Should a contract doctor or a full-time doctor on salary be employed ? 3. What measure of service is to be rendered the employee and his family in return for his monthly contribution to the medical program?

Jan 1, 1936

By Fred A. Krafft

The time allotted to this paper will permit only the sketching of general principles and practice as generally employed in the industry to maintain and preserve the physical well-being of the miner and his family. Let it be emphasized on behalf of the industry that coal opera- . tors, individually and collectively, have given primary consideration to the appointment of a mine or community physician who is charged with the responsibility of caring for the sick and injured. However, it too frequently happens that with the selection or appointment of the camp doctor many operators wash their hands of further responsibility toward the health and the working efficiency of their employees. The coal industry is so organized in most of the coal-producing areas that not only is the health of the individual miner an important production problem but the collective health of the entire mining community is a fundamental operating problem. This is particularly demonstrated when epidemics of communicable diseases attack entire communities, with resultant loss of life and production and general community distress. The problem and responsibility of maintaining high health standards among miners and their families should be given as much consideration as safety, economical production and efficient distribution are given in the successful operation of coal mines. Company Policy In the inauguration or administration of a medical program for a large mining operation or for an individual mine, the first question to be solved is what the company policy is to be with respect to the following factors pertinent to a medical program: 1. On what basis will the company and the employees finance the program ? 2. Should a contract doctor or a full-time doctor on salary be employed ? 3. What measure of service is to be rendered the employee and his family in return for his monthly contribution to the medical program?

Jan 1, 1936

By J. H. Henderson, L. A. Wilson, R. L. Gergins, R. J. Wygal, D. W. Reed

This paper presents a method of predicting the production history of an underground combustion recovery process. A rigorous solution of the thermodynamics and hydrodynamics involved is beyond the scope of this report. However, a practical scheme to appraise combustion recovery performance has been Worked out. By prudent assumptions, regarding the attainment of steady-state conditions, a trial-and-error solution, which satisfies both material balance and three-phase relative permeability requirements has been evolved and tested. As a combustion zone moves through a formation the interstitial water, the water of combustion and a portion of the oil wil1 be vaporized. These vapors will move downstream to a cooler region of the formation where they will condense. Part of the remaining oil will be displaced by the imposed gas drive and what remains behind will be consumed as fuel. The fluids will distribute themselves downstrean? in a manner which will satisfy the three-phase relative permeability characteristics of the formation. Three distinct zones will exist ahead of the combustion zone: (I) a zone termed a water bank which contains three mobile phases, oil, water and gas; (2) a region containing two mobile phases, oil and gas, called the oil bank; and (3) a zone having the fluid saturution distribution which existed prior to combustion. The mobile water will impose a water flood on the oil in the region containing three flowing phases. The process can be visualized as a simultaneous water .flood and combustion-supported gas drive. It is possible to estimate the saturation distributions in the water bank and oil bank as well as the production history for any combustion temperuture if the porosity, three-phase relative permeability characteristics, oil viscosity and initial saturations are known. This has been done for injection pressures ranging from I to 100 atm, oil viscosities of 10 to 1,000 cp and porosities from 20 to 40 per cent. Several of these calculations have been checked in the laboratory, with the result indicating rather good agreement between the predicted and observed production histories. The analytical and experimental techniques are described and the comparison of predicted and observed performance presented. INTRODUCTION Considerable research by the oil industry during the past 10 years has been directed toward the thermal recovery of crude oil. Of all schemes considered, the one receiving the most attention is in situ combustion. This is a process in which part of the oil is actually burned within the reservoir rock. The uniqueness of the process lies in its potential. Theoretically, this potential generates from the following: (1) it may open the door to vast reserves previously not economically producible, (2) it may induce increased production rates where low rates are now realized and (3) it may give high over-all recovery efficiency. The general idea of the process has received considerable attention in the literature '-' and the following brief description is intended for orientation only. In situ combustion can be visualized by considering a linear system, one end of which represents the injection well and the other the producing well. The formation at the inlet end is raised to ignition temperature by placing a gas or electric heater at the face of the formation or by the ignition of thermite, charcoal or similar material. While heating, the water and part of the oil in the heated region is vaporized and moved out into the reservoir by the injection of gas containing oxygen. In addition, part of the oil is displaced as liquid by the imposed gas drive. The oil not displaced is modified to an immobile, coke-like material (hereafter referred to as coke) by the high temperatures existing immediately ahead of the combustion zone. This coke is used as fuel, and the combustion front advances through the formation at a temperature which is probably in excess of 800°F. As the combustion front advancek it will drive ahead all interstitial oil not rendered immobile and all interstitial water plus the water formed by the combustion of hydrogen. As a result the sand behind the combustion zone is freed of all oil and water. Although the general description of the process has been outlined in the literature, there has been no consideration of the behavior of the fluids moving downstream from the combustion front. It is the purpose of this paper to present a technique

By M. F. COOLBAUGH

WHEN I was asked to speak on the subject of leaching, I did not realize that a complete summary of recent progress in leaching had been given by Stuart Croasdale. I shall try to give some other phases of the subject that were not touched by Mr. Croasdale. Not all metallurgists are in harmony as to their methods of treating metals. If they were it would probably mean lack of progress. They can be divided into two classes-the pyrometallurgists, using fire means, and the hydrometallurgists, or those using leaching methods. Conflict is always good for progress; we have it in politics, and in religion there are fundamentalists, and those who are not fundamentalists. As representing pyrometallurgy, may I hope not to be classed among the fundamentalists. The leaching of ores is not new. The leaching of ores for the recovery of metals, however, is quite new. The older leaching was simply to recover the salts. Agricola, back in 1555, I think it was, outlined a great many methods of leaching for the recovery of salts. They called them solid juices at that time. There was no real competition, however, between leaching meth-

Jan 1, 1926

By D. G. Osborne

Transportation cost is a key factor in both the profitability and competitiveness of coal marketing. With coal exportation growing rapidly, moisture control is important. Although in some cases, too much moisture reduction can lead to losses in transportation and pollution problems, there is normally justification for reducing moisture by mechanical means as much as possible. This paper reviews current technology of dewatering coal fines and examines the comparative capabilities of screens, filters, and centrifuges. Financial considerations are stated and implications of capital and operating costs on selection are discussed.

Jan 1, 1985

By T. E. Brower

SHORTLY after our previous paper on this subject was printed,1 we located a source of uncertainty in the results arising from the unexpected fact that hydrogen slowly reduces silica at 1100° C. in presence of iron, even when the iron nowhere touches the silica, although in absence of iron it does not do so. This difficulty has been completely obviated by the use of a small high-frequency furnace, which enables us to heat the specimen for analysis without raising the temperature of the silica vessel to a point at which any appreciable reduction of the silica glass occurs. We now describe this modification of procedure, and present some typical results obtained with it. For any given specimen of steel, the results are entirely definite and. reproducible, but their precise significance is still open to some question, as indeed is true of all methods of oxygen determination so far developed. Further elucidation of this question is to be expected from the cooperative comparison of the several methods now under way under the auspices of the Bureau of Standards at the instance of the Iron and Steel Division of the A.I.M.E.

Jan 1, 1934

By G. J. Saulnier, K. E. Goddard

The US Geological Survey has developed mathematical modeling techniques to assess potential impacts on the hydrologic system resulting from mining of coal and oil shale in northwestern Colorado. Potential impacts of oil shale mining on groundwater hydrology have been simulated using a quasi-three-dimensional, finite-difference model. The model has been used to simulate hypothetical mine dewatering operations at two proposed oil shale mines. Dissolved-solids distribution and solute transport were simulated with a three-dimensional, finite-difference model that was used to evaluate the effects of flooding in hypothetical abandoned mines. The potential impacts of coal and oil shale mining on water-sheds were investigated using a digital watershed model. This deterministic physical-process model predicts responses of the hydrologic system to modifications resulting from mining in basins having snow as the major source of runoff and recharge. Potential impacts of coal development on surface water quality were investigated using a river quality assessment model. The models developed by the US Geological Survey have been useful in defining the potential effects of mining in northwestern Colorado. They are an important first step in analyzing the existing data base and in predicting impacts and new data needs. The models may not be totally applicable on the local scale but are very meaningful on the regional level.

Jan 1, 1983

By Arvid Holst Mortensen

The rational exploitation of deposits for cement manufacture requires evaluation of the material, the planning of the quarrying and the right choice of quarry machinery. By using a computer for all evaluations and planning work the optimal recovery of material is arrived at and a quarry layout - and machinery is decided upon. The result will be uniform production throughout the lift of the deposits using a rationally chosen quarry equipment.

Jan 1, 1977

By Allan Gibb

The ores of copper are usually associated with minerals containing arsenic, antimony and bismuth. Whatever the means adopted for extracting the copper, these metals are usually found, to a greater or less extent, in the product. There is, however, usually some elimination in the various metallurgical operations to which the ores are subjected, and some attempt is made here to determine the degree to which this elimination is effected.

Jan 1, 1903

By B. H. Bergstrom, Will Mitchell, T. G. Kirkland, C. L. Sollenberger

SEVERAL constructive and fundamental studies have been made in the analysis of data obtained from experiments carried on with batch ball and rod mills. The operating characteristics of ball milling in small continuous circuits have also been appraised. It is from these analyses that some of the theories of comminution have been developed. Relatively few studies of continuous rod milling have added significantly to the fundamental concepts, because seldom have they yielded sufficiently consistent results. Perhaps they have been too limited in their scope. Careful control of the variables in batch grinding is simple compared with that encountered in a continuous operation. This factor alone has discouraged many investigators. Occasionally results of systematic changes made in industrial rod mill circuits have been published, but usually the data are sketchy and are restricted because -of the unwieldiness of the equipment used. The work, in general, has not been comprehensive; nevertheless it has provided empirical relationships that have bridged the gap between postulate and practice so that by proper manipulation of formulae, a mill designer can anticipate mill size and power requirements.1-3 Although operating variables of a small continuous mill are not so easy to control as with the batch mill, with present day devices, and with careful experimental work, consistent results can be obtained.

Jan 10, 1954