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By Carolina Gomes Dias Ribeiro

The modern composite materials, especially those reinforced with synthetic fibers such as glass and carbon, have been used since last century to attend the demands required by most technological fields, from home appliances to aerospace. Natural fibers composites with biodegradable polymer matrices are considered environmentally friendly materials and currently accepted as possible substitutes for synthetic composites. These green composites can be safely discarded or composted at the end of their life without harm to the environment. Another alternative for synthetic composites is to apply natural lignocellulosic fibers as reinforcement of conventional polymer matrices and already used in the automobile industry. In addition to the environmental and societal advantages of the green composites, the lignocellulosic fiber reinforced conventional polymer composite also has economical and technical advantages. In the case of a fiber collected as a waste, the price of the composite can be considerably lower than “fiberglass”. Furthermore, with high strength lignocellulosic fibers such as sisal, ramie and malva the specific strength of a composite may approach that of “fiberglass”. Therefore the objective of the present work is to investigate the mechanical behavior of polymer matrix composites reinforced with high volumes of natural malva fibers subjected to tensile stresses.

Aug 16, 2017

By Piotr Kula

Vacuum carburising with pre-nitriding (PreNitLPC® technology) involves feeding ammonia during the charge heating stage before carburising. The purpose is to restrict the growth of grain in the surface layer of the carburised steel. The article presents the influence of nitrogen on restricting austenite grain growth during vacuum carburising and on mechanical properties (fatigue strength, impact resistance) of layers that underwent such treatment in comparison with traditional carburising methods.

Aug 16, 2017

By Alberto Pesamosca

The present work analyzes the latest results achieved in scrap based EAFs in terms of application of chemical energy, starting from the observation that the general trend is a reduction of oxygen utilization. Consequently a review is needed about criteria for evaluation of melting process efficiency and equipment design. If from one side the maximization of productivity remains one of the major goals, from the other side some aspects of present market situation, included price of raw materials, are requiring the maximization of process yield. Based on achieved performance figures of selected plants and theoretical considerations, the effect of chemical energy input intensity is analyzed focusing on transformation cost, productivity and total energy input. The effect of present practices with lower oxygen utilization is considered also in terms of global CO2 emissions. Finally, the latest Danieli concepts and technological tools for optimization of chemical input are presented.

Aug 17, 2017

By Daniele Tolazzi

In today’s highly competitive market situation, it is of outmost importance for EAF steel makers to optimise their processes in order to reduce operating costs and to improve safety and reliability of the equipment. The laser based off-gas analysis technology, With laser units installed on the fix duct, downstream the combustion gap, uses the “Tuneable Diode Laser Absorption Spectroscopy” (TDLAS). The system performs real-time off-gas emissions measurements of CO, CO2, O2, H2O and temperature. A closed-loop operation is in place for dynamic control of the chemical energy package combustion/post-combustion of CO, H2 and CH4 gases into the EAF furnace shell. A statistical framework which builds on a data analysis engine, based on Danieli Automation Q3Intelligence technology, evaluates the “fingerprint” of the process represented by average and deviation trends of both gases and other process parameters. Process fingerprinting is conceived both for offline profile optimisation and on-line control of the refining process. This paper describes how the technology has been applied and the results achieved at ACCIAIERIE BERTOLI SAFAU (Italy) 100 t AC Electric Arc Furnace.

Aug 16, 2017

By Shibu John

The COREX® process is beside the FINEX® technology the only industrially realized alternative to the blast furnace route for the production of hot metal. Changes in the raw material sector in respect of decrease in quality, strictly enforced environmental laws and positive operation results of COREX® reference plants make it worth to carefully re-evaluate the COREX® technology in comparison with the traditional blast furnace technology. Integrated Plant concepts based on COREX® offer solutions for future challenges of the iron- and steelmaking industry, which include: economical hot metal production; efficient and highly economic export gas utilization (power generation, DRI production, syngas production for chemical products); lower raw material cost, higher raw material availability; environmental friendly high grade steel production. The economic evaluation of different COREX® gas based plant concepts in comparison with the traditional blast furnace route shows that the COREX® technology is highly competitive in the challenging iron and steel producing environment.

Aug 17, 2017

By Giuseppe Pintaude

This study aims to evaluate the effect of specimen preparation on the dry sliding wear behavior of CA-6 NM stainless steel. Two different surface finishing manufacturing processes were applied: lapping and metallographic polishing. The wear tests were conducted in reciprocating ball-on-flat system, performed for two loads: 5 or 8 N. For all test conditions, hardmetal ball was employed as counterbody. The surfaces were evaluated using 3D interferometry technique to determine their surface roughness, including texture analysis regarding isotropy. Surface characterization results indicated the presence of texturing and preferential orientation, since the parameter Str was smaller than 0.5 for samples of both the studied conditions. Two distinct levels of isotropy evaluated through Str parameter were achieved: 0.13 for lapping and 0.3 for metallographic polishing process. It is clear from wear tests that the variation of average surface roughness is the key point for tribological behavior of CA-6 NM stainless steel.

Jul 31, 2018

By Márcia Maria da Silva Monteiro Pereira

Durante o lingotamento contínuo de aço, partículas de ZrO2 adicionadas na escória de molde facilitam a nucleação heterogênea de cristais devido à sua limitada solubilidade. A adição de ZrO2 promove a cristalização da fase cuspidina, o que auxilia na redução da transferência horizontal de calor no molde, amenizando desta forma o problema das trincas longitudinais. Outro benefício da adição de ZrO2 em pós fluxantes é reduzir a taxa de desgaste da válvula submersa (SEN) na interface metal/escória; a erosão da SEN é um problema sério. Através de testes de laboratório e de testes industriais concluiu-se que a adição de ZrO2 em pós fluxantes reduz a taxa de transferência de calor horizontal no molde durante o lingotamento contínuo de aço, considerando os dois tipos de pós fluxantes que foram analisados no presente trabalho. Além disso, observou-se que a adição de ZrO2 reduz a taxa de desgaste da válvula submersa na interface metal/escória.

Aug 16, 2017

By Alberto Pesamosca

The paper presents the results obtained by the AC EAF supplied by Danieli at Kroman Çelik (Gebze-Turkey) after the planned upgrade to 150 ton. The EAF – 7,4 m diameter, based on the full platform standard design - is able to handle a maximum power of 114 MW and is equipped with the most advanced and reliable technology, including module injection system and the Hireg electrodes regulation system. Excellent results were already obtained with 120 heat size in terms of fast start-up and excellent performance figures. After the upgrade, productivity was increased up to 212 t/h, maintaining high process efficiency (365 kWh/t with 32,1 Nm3/t O2).

Jul 30, 2018

By Alexandre Rizek Schultz

Silat, Siderúrgica Latino-americana, selected Russula as the main engineering contractor for their 700,000 tpy Greenfield steel plant dedicated to long and flat steel production. The project is currently under construction in the district Guararu in Caucaia in the metropolitan region of Fortaleza. The project will be developed in two phases. First phase: 600,000 tons per year rebar mill and 60,000 tpy steel mesh line; Second phase: 700,000 tpy melt shop (90 ton/hr EAF and 4 strand continuous caster for billets up to 180 mm x 180 mm).

Aug 16, 2017

By Eddy Dierckx

Modernization of flat rolling plants is essential to sustainably fulfill increasing market demands and to improve competitiveness. Intelligent modernizations ensure getting maximum prime yield of existing mills, even if they have gone through half a century of operation. Existing mills were designed based on former production, consumption and quality targets. Ever increasing requirements such as increase of productivity, change of product mix (e.g. new steel grades), reduction of energy consumption and improvement of product quality lead to the necessity to adapt the existing equipment to the new target. SMS group provides, besides the reliable equipment and automation solutions to successful upgrades of existing mills, also a systematic approach to develop technical and economical solutions together with our customers (conceptual engineering). This paper describes the SMS group approach to modernizations / upgrades, introduces powerful performance modules and provides a number of successful examples that have been implemented recently.

Aug 17, 2017

By Douglas Glenn Stalheim

Hot strip structural steel coil used in construction, engineering, transport, structural applications and other applications are widely used in yield strengths from 300 – 700 MPa. However, structural design engineers are now not only requiring various strength levels but also other mechanical properties, primarily good formability, toughness and weldability. To produce a balanced approach to a cost effective structural steel, hot strip coil requires an understanding of utilization of an optimized alloy composition designed for the layout/equipment capabilities of a given hot strip mill to produce the desired metallurgy for optimum mechanical property performance. The term “cost effective” does not just focus on alloy design, but also ease of overall processing from steelmaking, casting, rolling and cooling, stable mechanical properties with a statistically normal distribution, no downgrades/rejections and a product that the end user recognizes as being superior to others. The desired metallurgy is simply understanding what will be the optimum microstructure and cross sectional grain size/distribution needed to meet the mechanical property requirements. This paper is a follow up paper that previously described optimum base alloy designs along with steelmaking/casting processing considerations and will focus on proper reheating, rolling and cooling metallurgy/processing strategies to produce quality cost effective hot strip structural steel coil.

Aug 17, 2017

By Moisés Paulo Teixeira

The use of tailings for the synthesis of new materials is a worldwide concern today. This paper approaches the utilization of tailings of soapstone (steatite) in order to produce ceramics. The results show that the addition of soapstone in a ratio over 20% in the ceramic mass has enhanced the bending resistance of the ceramic samples when they were fired at temperatures of 900°C or 1000°C.

Oct 30, 2017

By Nigel Marx

In order to understand (and ultimately to predict) the friction reduction resulting from the use of polymer solutions, the rheological properties of model polymer solutions have been measured over a wide range of shear rates. Both temporary and permanent shear thinning have been observed. By using base fluids of different viscosities it has been shown that permanent shear thinning depends more closely on the shear stress experienced by the fluid than on the strain rate. Hydrodynamic measurements have been made on the polymer solutions using a compliant ball on flat lubricated contact that operates in isoviscous-elastic conditions. The measured friction values can only be predicted with reasonable accuracy if the measured shear thinning properties of the lubricant are taken into account in the hydrodynamic model.

Jul 31, 2018

By Kermit Reins

The most recent modernization phase of the wire rod mill at Sterling Steel involved installation of a pre-finishing mill, using a Morgan Vee Mini-Block, a new water box and shear with utility systems and automation. The new mill configuration adds more stands to the mill for better drafting and is designed to improve finished product quality by providing a more uniform entry temperature, better control of the feed section into the No-Twist® mill as well as enhanced surface quality. The new shear improves cut length accuracy as well as decreases the amount of trimming to reduce yield loss. This paper explains the changes made in the mill and the features of the new equipment and automation.

Aug 17, 2017

By Paul Pugsley

The EMSpec sensor employs the principle of measuring the complex impedance of the target steel over a range of frequencies these impedance values in turn varies with transformation fraction of the steel. A full scale implementation of the Real Time Transformation Monitoring has been installed at a quality large European steel producer to show the benefits of such a system. A total of three EMSpec sensor heads have been installed between the exit Finishing Mill and the Down Coiler on a HSM. For the successful production of Dual Phase, TRIP and TWIP steels increased control of the cooling regime is demanded; the use of surface temperature measurements alone cannot guarantee to achieve the desired mechanical properties. The EMSpec sensor, which is engineered to withstand this harsh environment, in real time directly measures the percentage transformation of the steel in the cooling area, typically in the accelerated water cooling zone. Using the information from the sensors integrated into the mill model enhances the models ability to predict the transformation profile.

Aug 17, 2017

By Márcia Maria da Silva Monteiro Pereira

Tundish is the last reactor where significant metallurgical operations can still be done. Calcium aluminate slags are able to positively contribute to metallurgy considering oxide separation, protection against reoxidation and preclusion of resulphurisation. However, these are poor insulators. When using low melting point slags it is necessary to use another covering material. The deviation from saturation can be used as a measure of absorption capacity. By utilizing computerized construction of ternary and quaternary diagrams it is possible to compare different slags and to find proper slag compositions with reasonable capacity to dissolve inclusions. Objective of the present technical contribution is to evaluate tundish slag capacity to absorb inclusions, considering a particular tundish industrial slag and the changes in its chemical composition during continuous casting of steel. It was observed that slag composition changed during the continuous casting process; this variation is possibly related to interaction between the CaO-Al2O3 liquid slag and the rice hull ash layer which is used above it. Computational thermodynamics was used to determine activity of alumina dissolved in liquid slag; it was observed that the variation in slag composition did not change slag capacity to absorb inclusions, since precipitation of Al2O3 solid phases is not predicted.

Aug 17, 2017

By Kyle T. Chomyn

Multi-disciplinary engineering analysis and advanced modeling techniques were used to identify and develop low cost design modifications to improve a blast furnace hot blast air distribution main that experienced frequent refractory failures. Piping flexibility analysis helped identify the root causes of refractory damage and determine the need for new expansion joints. Finite element analysis was used to optimize a custom-designed elbow-to-elbow tie-rod system, which ensures thermal expansion loads are not placed on connecting piping. Heat transfer coefficients through the elbows were estimated using computational fluid dynamics (CFD) flow modeling. The cast refractory design was changed to a more reliable brick refractory design. Excessive draft was occurring during furnace back-drafting, so the system was assessed using CFD, and a passive flow-reduction spool was designed. This firstprinciples engineering design approach allowed for optimization and verification, ensuring that the new design addressed the root cause of the previous deficiencies.

Aug 17, 2017

By Amilton Feliciano Castro

In this work, activated carbons (ACs) were prepared using Sewage sludge as starting material. The ACs were pyrolyzed in an inert atmosphere at 550 °C after independent chemical treatment with ZnCl2 or KOH with ratio of 1:1. The materials were used as adsorbents for removal of Cu(II) from aqueous solutions. The adsorbents were characterized using adsorption/desorption nitrogen isotherm, SEM (scanning electron microscopy). The results showed that copper removal could be linked to surface pH and compounds present on the surface of adsorbent. KOH-treated adsorbent has smaller surface area (186 m2 g-1) than ZnCl2-treated adsorbent (192 m2 g-1), however, KOH-treated adsorbent exhibited higher removal of Cu(II). The performance of KOH-treated adsorbent could be attributed to the presence of basic groups on the adsorbent surface. Liu isotherm model gave the best description of the equilibrium data. From the Liu isotherm, the maximum adsorption capacities at 298 K for KOH-treated, ZnCl2-treated and sewage sludge (without inorganic activation) adsorbents are 31.85, 19.79 and 3.513 mg g-1, respectively. The best desorption experiment was obtained using 1.50 mol L-1 of HNO3 as eluent. Recoveries of Cu(II) from Cu(II)-loaded adsorbents are 98.9% (ZnCl2-treated) and 95.5% (KOH-treated.

Aug 17, 2017

By Ryoma Fujiyoshi

In this article, the technologies of highly durable MgO-C bricks for the scrap impact zone and bottom blowing tuyere of converters are demonstrated. On the bases of our recent investigations, wear of scrap impact zone and bottom tuyere are explainable in terms of crack initiation and propagation. Theoretically, crack propagation in brittle material is regarded as generation of new crack surface area. It occurs when the elastic strain energy stored in the material exceeds the energy required to generate a new crack surface area. Since the overall energy consumed for crack propagation until fracture is evaluated by fracture energy, materials exhibiting high fracture energy can be regarded as materials with high fracture resistance. Therefore, two fracture energy-improving technologies for MgO-C bricks were developed. One is matrix reinforcement and the other is carbon bond enhancement. These technologies were applied to bricks for the scrap impact zone and bottom tuyere. As a result of commercial applications, notable decreases in wear rates were recognized for high fracture energy materials for the scrap impact zone and bottom blowing tuyere of converters.

Oct 30, 2017

By Qingwen Dai

The Marangoni effect is an important phenomenon where a surface tension gradient drives liquid towards high surface tension regions. Temperature gradient, evaporation, disparity of viscosity, and surface roughness and topography are all significant factors that can affect this thermo-capillary migration. The purpose of this study was to investigate the influence of micro-groove patterns on the migration of paraffin oil, and obtain a well-designed texture of micro-grooves to prevent the thermo-capillary migration. Patterns of micro-grooves with differing orientations and geometric parameters were fabricated on the surface of SUS 316 stainless steel substrates. Experiments on the migration behavior with different viscosities of paraffin oils were carried out various temperature gradients. The experimental phenomena indicated that the surface with the micro-grooves perpendicular or parallel to the temperature gradient have a strong impact on the migration performance of paraffin oil. Micro-grooves perpendicular to the temperature gradient exhibited extraordinary slower migration velocity than that of the parallel one. Width and depth of micro-grooves had an obvious influence on the behavior of temperature-driven migration and detail discussions on the effects of these geometric parameters were carried out.

Jul 31, 2018