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By A. C. Fielder

It is with some diffidence that I venture to address the Montreal Section of the Society of Chemical industry on the subject of motor fuel from coal at a time when crude petroleum is produced in greater quantities than at any time in history, and at a time when the known reserves exceed all expectations, even the optimistic estimates of the Committee of Eleven of the American Petroleum Institute. Not only are new fields being discovered in America a -an embarrassing frequency but sources outside of the North American Continent show, unmistakable signs of adding materially to the world's sources of oil. Were it not for the tremendous scientific and technical importance of the work done in the past few years in transforming coal into liquid motor fuels, I should prefer to let this subject rest until a more propitious time, such as prevailed some years ago, when the gasoline consumption curve was rising rapidly and the production curve was slowing in its upward rise. That was the period which stimulated the researches which resulted in tetra ethyl lead and anti-knock gasolines on this side of the Atlantic and in methanol, synthetic gasoline and hydrogenation of coal on the other side. Some of you will recall a symposium on Motor Fuels and Oil Conservation held at the Chemists' Club n New York in September; 1925. Dr. R. L. Brown and I presented a paper at this meeting on "Complete Utilization of Coal and Motor, Fuel, in which we pointed out that coal was the most likely raw material source of gasoline substitutes if and when needed. We grouped the present and future, processes' for obtaining motor fuel from coal in three classes, namely:

Jan 1, 1928

By Nicholas J. Grant, Robert F. Wilde

TAYLOR and Floyd's"" work in establishing phase diagrams based on the elements Ni-Cr-Ti-A1 has led to an understanding of the precipitation hardening mechanism in alloys based on these elements. Nordheim and Grant4 concluded that in simple alloys, and where the aluminum to titanium atomic ratio was such that less than three out of five aluminum atoms were replaced by titanium, the precipitate on aging is the face-centered-cubic Ni 3A 1 phase, called They further found that increasing amounts of hexagonal ? phase, Ni3Ti, precipitated from these alloys when the titanium content exceeded the solid solubility of both matrix and Ni3A1. For alloys of Ni-Cr-Ti-Al, in which the titanium and aluminum contents each ranged from 0 to 4 wt pct, the titanium-rich was superior for strengthening to either pure ?' or 7. It was also noted that the combined titanium plus aluminum content (atomic pct) was a direct measure of the high temperature strength and overaging temperatures for these alloys.4 The present investigation was undertaken to extend existing data on precipitation hardening in the more complex commercial alloys containing higher titanium plus aluminum, and with significant quantities of cobalt, molybdenum, and carbon. Experimental Procedure Reforging of As-Received Bar Stock—The alloys were received as ground, forged bar stock. Chemical analyses and the as-received bar diameters are shown in Table I along with the ASTM grain size after the various treatments. All stock except the Waspaloy was reforged to % in. diam to gain material and to facilitate machining of stress-rupture specimens. Forging was carried out at 2100°F, and discontinued when the bar temperature fell to 1800°F. Heat Treatments—For experixental simplicity it was desirable to heat treat all of the alloys at, the

Jan 1, 1958

By T. B. Braun

Cathode contamination is the principal factor affecting the quality of electrorefined copper. It is commonly accepted that annealability is unfavorably affected by the following elements, in decreasing order of adverse effect: tellurium, selenium, bismuth, antimony, and arsenic. Silver in cathodes has importance as it represents a nonrecoverable loss of silver to the refinery. Mechanisms for the contamination of cathodes by these elements are examined and the effect of operating variables on contamination, including anode composition, electrolyte composition, electrolyte temperature, addition agent practice, and electrolyte discard rate, are discussed.

Jan 1, 1976

By Patrick Sullivan

Over the past few years, successful operations for processing phosphates employing the Grate-Kiln System have been achieved. Control and instrumentation philosophy followed in these installations are described and analyzed. Concepts utilizing digital techniques and computer systems appropriate for similar installations are also discussed.

Jan 1, 1967

By Frank E. Cash

Data on the occident experience of the pebble-phosphate industry in Florida for 1937 and 1938 are combined in this report with statistics for the 7-year period 1930-36, inclusive, which were published in Information Circulars 69174/ and 69685/. The periodic publication of such data enables the pebble-phosphate industry, as well as other industries, to consider relative hazards, compare experience, and thereby help to prevent accidents. ACKNOWLEDGMENTS Accident data ere furnished by the following; operating companies: Amalgamated Phosphate Co., Brewster; American Agricultural Chemical Co., Pierce; Coronet Phosphate Co., Plant City; International Agricultural Corporation, Mulberry; Phosphate Mining Co., Nichols; Southern Phosphate Corporation, Bartow; and Swift & Co. Fertilizer Works, Bartow.

Jan 1, 1940

By M. S. Millman

Close monitoring of performance at each process stage, from raw material through to finished product, is vital for operational consistency and the production of high quality steel. However, many of the integrated iron and steelmaking process route stages operate under such severe conditions of temperature, dust, water, thermal radiation, vibration, pressure, vacuum, extreme dynamic events, high material flows, corrosion, erosion, electrical-noise, electromagnetic-noise, or audio-noise that, in general, it is a very difficult challenge to obtain useful information for control. Thus, state-of-the-art non-contact and remote sensors are applied to help monitor and control specific process operations. Often, these sensor systems have been developed especially for the steel industry and they are based on four principal technologies: Laser, Microwave, Electro-Magnetics and Thermal Imaging with supporting technologies such as: X-ray Fluorescence, Audiometry, Digital Image Processing, Radio Telemetry, GPS and many others. These advanced sensor technologies are reviewed with respect to their application at various stages along the integrated process route.

Jan 1, 2004

By Jamey Rosen, Georgette Hlepas

"Bluestone Dam is a concrete gravity structure with an overall length of 2,060 feet and a maximum height of 165 feet above the streambed. Several major project modification designs have been implemented and additional modifications are currently in construction and design phases. Due to the various modifications since original construction was completed in 1948, detailed documentation with visualization of the project features is needed. A three-dimensional model of the internal and external features of Bluestone Dam was generated from LiDAR data, survey information, and other data sources. One of the key features of interest in this model is an accurate visualization of over 200 dam anchors based on downhole anchor surveys. The model is accessible in Microstation and Geographic Information Systems (GIS), allowing users to rotate the anchors in three dimensions; view them in the context of geology, internal dam structural features, historical construction records, site photographs, bathymetric data, and instrumentation data. Users can “click” on individual anchors to view associated construction details and open a comprehensive installation packages. The model will be used by the United States Army Corps of Engineers (USACE) as part of a larger Geospatial Data Management System as a historical accounting of the project construction data, and be a long-term living document for use by both design engineers and operations staff to assess dam safety risk and to design future project modifications.IntroductionDuring the life of any project, critical data concerning the construction and performance history are required to be collected and maintained. The data collected prior, during, and post-project construction help with the design process, ensure that the project is built to specifications and is performing as per design intent. During the Post-Implementation Evaluation (an evaluation performed after a major project modification), these data are used to visualize the repairs, verify the construction was performed per design intent, and document the history of the construction phases, associated test results, and overall effect on the project. The project described in this paper is the construction of a system of tools to effectively use these data.Data collected and maintained during the operations phase helps to ensure that the project is continuing to perform as per design and aids in advance warning of any potential failure or required maintenance. Dam Safety, Emergency Management (EM), and Operations and Maintenance personnel can use the system to verify the status of the project in preparation for a high flood event. For example, if there is repair work being performed on a critical feature of the project that would affect the operation of the dam structure during a flood event, Operations personnel would be responsible to update the status of the system such that Dam Safety and EM would be able to identify the feature that is out of service, its date of expected repair completion, and the implications during a flood. In addition, risk assessments typically require a full history of the project and its performance. Any concerns that arise concerning the safety or performance of a project will require a full documented history of the project and its components. Proper documentation and data management are key in this assessment process."

Jan 1, 2016

By H. Möller, L. Mashigo, C. Gassmann

Wire-arc additive manufacturing (WAAM) is a directed-energy deposition technology that uses arc welding procedures to produce computer-aided designed parts, such as three-dimensional printed metal components. A challenge of additive manufacturing is the anisotropy. Interstitial elements play a significant role in the mechanical properties of Ti6Al4V of different grades. In this research, the mechanical properties of Grade 5 and Grade 23 Ti6Al4V were compared for this application. Samples were extracted from WAAM-produced Ti6Al4V walls in different directions (horizontal and vertical) and at different positions (top and bottom). The samples were subjected to optical microscopy and tensile and hardness tests. Grade 5 Ti6Al4V samples were found to have greater strength, greater hardness, and lower ductility, owing to the higher content of interstitial elements compared with Grade 23. The bottom samples had higher strength than the top samples, which is attributed to thermal cycling during manufacturing, resulting in different microstructures.

Jul 1, 2021

By F. R. Joubin

MR. CHAIRMAN, Members of the C.I.M., and Friends -particularly friends, because I am not entirely a stranger in your city. I was last here some five years ago and it has given me a great deal of pleasure this evening to be able to say "Hello" again to those I had met at that time, when Bourlamaque and V al d'Or were very busy centres of intensive and successful gold exploration. My remarks this evening have to .do with Canada's Place in the Atomic Age. They will be of a general nature but I hope to tell you ?enough to whet your appetite so that you may be provoked into per-.suing the subject further. Now, atomic developments have become quite commonplace. Words like radioactivity, reactors, nuclear fission, and so on are known to everyone, even the youngsters. I re-member two or three years ago one of my office boys came to me and said "Mr. Joubin, I would like a raise." I gave the request a few seconds of serious thought and finally said "Alright, Jimmy, we'll give you a raise." However, he made no effort to leave, so after a -couple of seconds more I said, "Is there something else ?" and he said "Yes, Mr. Joubin, could you make that raise 'radioactive' to the first .of the year ?"

Jan 1, 1958

By R. Paturi

Mill liners play an important role in the operation of a mineral concentrator influencing the throughput, availability, power drawn and the efficiency of the mill in the plant. Liners protect the shell and transfer energy to the grinding charge. Metso Technology Development has conceptualized, developed and successfully implemented physics based 3D DEM simulation techniques to predict charge motion, power drawn, energy spectra and wear over the life of the liner. This paper will present a case study of shell liner optimization for a 34? SAG mill including the input data requirements, and shell liner optimization methodology using the 3D simulations that eliminates the need for the traditional expensive and lengthy proto-type testing. These simulations will cover ball and particle movement, liner wear and mill power draw, and do not cover particle breakage and slurry flow. Even the liner manufacturers lack the ability to provide this type of qualitative and quantitative information on their products. The data from these simulations provides the plant engineers a scientific basis for their decision making and thus eliminates guess work. Keywords: liner, optimization, multi-physics, 3D-DEM

Sep 1, 2012

By H. Sevim

An innovative approach in designing the haulage systems for underground coal mines is discussed in this paper. The haulage systems are formed by serially connected components. Therefore an economic and efficient design of the entire system is necessary. The computer model that uses a heuristic algorithm solves this design problem globally in a single run. It is a probabilistic model because it considers the probabilistic aspects of face operations. It is versatile because it can accommodate any type of mining and belt conveyor network configuration. The hoisting section can be used to design drum or friction hoisting systems for single or multiple level operations. These systems can have two skips in balance or a skip and a counterweight in balance. The model also has the option to internally determine the capacity of bunker(s) and shaft-bottom bin. The objective is to minimize the expected cost per ton of coal hauled from the coal faces to the surface. At the end of the paper is an example that illustrated the capabilities of the model.

Jan 1, 1987

By Miguel Reyes, Chenming Zhou, MATTHEW GIRMAN

Electromagnetic energy emitted from electronic devices has been known to interfere with other electronic systems, hindering their ability to function properly. Mines have many electronic devices critical to the health and safety of mine workers that could be negatively affected by electromagnetic interference (EMI). To ensure that devices are electromagnetically compatible, tests must first be conducted to measure emissions and check for immunity. There are many standards available across multiple industries that prescribe emission limits and test methods for electronic devices. Due to the unique environment of an underground mine, it may not be enough to simply adopt a standard from another industry to mining. A literature review has been conducted, and an overview of EMI standards in other industries will be provided in this paper. Also, an example of how a standard can be applied to mining equipment is presented. Finally, recommendations on standards which could potentially be applied to mining will also be included. This work will inform the mining industry of EMI standards in other industries so that mine workers and technology manufacturers have guidance of the steps that can be taken to investigate and reduce the impact of electromagnetic interference and potentially work toward electromagnetic compatibility. The findings and research involved in this effort can also be used to explore the need to develop mining-specific EMI recommendations and standards.

Nov 25, 2021

By Lawrence F. Johnsen, Marc J. Gallagher

"Micropiles are small diameter, bored, grouted-in-place piles incorporating steel casing and/or reinforcements. The omission of micropiles from most United States building codes has resulted in the application of varying standards for design and installation. The ADSC/DFI Micropile Committee has developed a proposed section for the 2006 edition of the International Building Code (IBC 2006) covering micropiles. The proposed IBC 2006 micropile code section is presented, along with comparisons to existing micropile codes and guidelines. A discussion section is provided to clarify sections of the proposed code. IntroductionMicropiles, defined as small diameter (typically less than 12 inches outer diameter), bored, grouted-in-place piles incorporating steel casing and/or reinforcements, are becoming common foundation elements for new construction, retrofits, and emergency repairs. Developed in Europe in the 1950's and used in United States practice since the late 1970's, micropiles are typically not addressed in building codes, particularly in the United States. As a result, micropiles are often reviewed by building officials to a variety of standards, including drilled shafts, caissons, cast-in-place bored piles, and concrete filled pipe piles. None of these adequately address the unique design and construction aspects of micropiles. Therefore, it became apparent to the foundation design and construction community that a micropile-specific code section was required.To that end, the International Association of Foundation Drilling and the Deep Foundations Institute (ADSC/DFI) Micropile Committee appointed a subcommittee in October 2003 to develop and submit a proposed micropile code section for the 2006 IBC. The subcommittee members included the two co-authors, as well as Tom Richards (Nicholson Construction Company), Tom Armour (DBM Contractors, Inc.), John Wolosick (Hayward Baker, Inc.), Allen Cadden (Schnabel Engineering) and Matt Niermann (Schnabel Foundation Company). At the time of the writing of this paper, the proposed code section has been presented at the IBC public hearing during which it was modified slightly. Final adoption (or rejection) will be determined by the IBC at the final action hearing in September 2005. The attached code section is the revised version following the public review hearings."

Jan 1, 2005

By AIME AIME

No democracy such as ours, can ever be prepared for war, because we could never conceivably be the aggressor. The aggressor prepares in secret, designs his new tactics, and invents and makes new equipment and selects the time to strike. If a democracy prepare done year and the war came later, all that it had one would have to bed one over. All that England has today in the way of effective armament has been invented, designed, made, and the crews trained since the war began, because the totalitarian aggressor introduced new types of equipment and new techniques.

Jan 1, 1941

By Kirsten Corin, Belinda McFadzean, Cyril O’Connor, Jenny Wiese

The Bushveld Complex of South Africa contains almost 90% of the world’s reserves of platinum group minerals (PGMs). In the flotation of PGMs, there are significant challenges arising from the need to treat ever-decreasing grades of the relevant ore deposits. The major challenge in the flotation of these ore bodies is the control and management of the gangue minerals, particularly silicates such as orthopyroxene, plagioclase feldspar, and pyroxene which are often rimmed with talc which makes them naturally floatable. It has been shown that various polysaccharide depressants such as CMC and guar have different properties in terms of depressing the gangue minerals. Since the PGMs are often associated with sulphides, copper sulphate is widely used as an activator in PGM flotation but can inadvertently activate the gangue minerals as well as reduce the recovery of PtTe2 which accounts for up to 40% of the Pt in the Platreef ore body. Depressants also reduce the mass of solids reporting to the froth and can thus destabilise the froth. This effect on the froth can be mitigated by using higher frother dosages or water of higher ionic strength. Reducing chromite recovery is of critical importance since high levels may negatively affect the downstream smelting process. Chromite recoveries can however be reduced through the application of gravity separation or reducing entrainment through reduced water recovery. In summary, due care needs to be taken to carry out site test work to develop an optimum ratio of collector, frother, activator, and depressant to ensure that the highest grades and recoveries of the PGEs are obtained while reducing depressant dosage as much as possible.

By Y. C. Liu

An analysis is presented to show that the formation of rolling textures in fcc metals can be rationalized in terms of flow mechanisms operative during the rolling process. First, a general approach used by Calnan is followed, where the rolling process is approximated on the basis of two axes, p and Q. In this treatement there are two separate sets of slip systems, one for each axis, and it is shown that a homogeneous rotation can he achieved by restricting the slip systems for the two axes to share common slip directions Then, two criteria are used to select the active slip systems for the axis P: they must have relatively high resoloed shear stresses, and dislocations on these slip systems must interact attractively in order to lower total energy content Finally, a method of analysis is introduced to locate the end position of an axis by knowing its acti7.e slip systems. The result of the analysis indi- cates that two main flow mechanisms operate in fcc metals. The ideal orientation derived from one oj-them is (8 13 21) (21 8 13) which is very close to the (358) (523) orientation observed experimentally on the rolling texture of copper. This flow mechanism should only he operative in metals containing dislocations extended into partials separated by less than five times their lattice parameter. The ideal orientations derived from the other flow mechanism are a combination of (1 10} (112) and a spread of orientations with (110) parallel to the rolling plane. This type of ideal orientations corresponds to those observed in the rolling texture of silver 30:70 brass, and binary alloys with high alloying content. This flow mechanism should be operative in any fcc metal regardless of its stacking-fauIt energy. When a polycrystalline metal is subjected to a large amount of plastic deformation, it is generally observed that grain orientations alter and align themselves towards certain positions, eventually reach-

Jan 1, 1964

By S. S. Lau

The authors of the previous comment stated that Dorn and Rajnak33 and others34-40 concluded that "agreement with this function [(t'/tp) -f(Un/2Un) = T/Tc} may be used as a criterion for that (the Peierls) mechanism of deformation". In contrast, however, Dorn and Rajnak33 and others34-40 never made such a statement. In order to clarify the issues involved it is appropriate to recapitulate the conditions that must be satisfied in order to suggest that some deformation process might obey the Peierls mechanism: 1) Within permissible variations due to changes in the slope of the Peierls hill the T*/Tp - T/Tc relationship must be obeyed. Although some mechanisms, e.g.. solute atom stress field, recombination of dissociated partials in bcc metals, intersection of dissociated dislocations, and so forth, give about the same t* - T relationship, other mechanisms, such as cross slip, disruption of attractive junctions, climb, motion of jogged screw dislocations, and so forth, give distinctly different t*-T relationships. On this basis some distinction can be made of the various mechanisms. 2) An important feature of the Peierls mechanism concerns its physical origin based on the nucleation of pairs of kinks. The value of T* at 0°K increases with the density of dislocation (i.e. , cold work) for the intersection mechanism and it increases with the square root of the atomic fraction of solute atoms in the solute atom interaction mechanism. In contrast the value of t* at 0°k, for the Peierls mechanism which depends only on the line energy and the shape of the Peierls hills. is independent of cold working and the square root of the solute atom concentration. These differences have been employed by various investigators for elimination of a few other possible mechanisms. On the other hand it is not possible to eliminate all mechanisms, e.g., the recombination of dissociated dislocations in bcc metals, and so forth, on this basis alone. 3) Further discrimination between possible mechanisms is based on the activation volume. For the in-

Jan 1, 1968

By Sean Gallagher, William S. Marras, Alan S. Litsky, Deborah Burr

This paper describes a comparison of the fatigue failure responses of older versus younger lumbar spine cadaver motion segment specimens. These specimens were repeatedly subjected to loads simulating those experienced by the spine in lifting a 9 kg load in different torso flexion postures (0, 22.5, and 45 degrees of flexion). An older sample of 36 motion segments (average age 81 years + 8 SD) is compared with a younger sample of 18 motion segments (average age: 47 years + 9 SD) with respect to the number of cycles to failure and results of survival analyses evaluating the effects of flexion and bone mineral content with and without the younger data set. Compared to the older sample of spines, the younger sample exhibited many more cycles to fatigue failure in all the torso flexion conditions (10020 versus 8267 average cycles to failure in 0 degrees flexion, 7124 versus 3262 in 22.5 degrees flexion, and 3229 versus 263 cycles to failure in 45 degrees flexion). The increased cycles to failure in young specimens is likely due to the increased bone mineral content (BMC) in younger motion segments (30.7 g + 11.1 g per motion segment versus 27.8 + 9.4 g). Cox regression analyses modeling both flexion effects and BMC indicate that betas are similar when just older spines are modeled and when younger specimens are included in the analysis. Betas for survival analysis models with and without younger specimens generally show little change for flexion (2.716 versus 2.756 for 22.5 degrees [0 degrees referent], 3.926 versus 3.380 for 45 degrees [0 degrees referent]). Bone mineral content shows a similar protective effect in both models (Betas: -0.127 versus -0.087). Overall, comparison of the models indicate that risk ratios are similar for 22.5 degrees flexion, slightly increased for 45 degrees flexion and slightly more protective influence predicted for BMC in the combined sample versus the older sample alone.

By R. D. Groves

Techniques were developed for preparing metallurgical-grade copper powder from industrially produced cement copper. Flotation was used for rejecting discrete gangue particles, acid leaching to remove residual iron and aluminum, hydrogen reduction to eliminate oxygen, sintering to consolidate the fine-sized copper, and grinding to obtain copper powder. Powders prepared from six different cement copper samples contained, in percent, 98.5 to 99.0 Cu, 0.10 to 0.05 Fe, 0.10 to 0.08 insoluble material and the remaining individual impurities less than 0.15 percent. The apparent density, flow characteristics, and other physical properties were suitable for powder metallurgy applications. An economic evaluation showed that this process was economically feasible. Processing costs appeared modest when considering that copper powder commands a price normally about 17.5 cents per pound over that of electrolytic copper.

Jan 1, 1971

By CHENGLONG XU, HAORAN LI, YALI FENG, JINRONG JU, Shunliang Liu

In order to realize the resource utilization of spent hydrodesulfurization catalyst, a solvent extraction-oxalic acid precipitation process is studied in this paper for efficiently recovering vanadium, nickel, and aluminum from the acid leaching solution of spent hydrodesulfurization catalyst. The process conditions for extracting vanadium with Cyanex 272 and precipitating nickel using oxalic acid as a precipitation agent were explored in detail. The results show that vanadium (IV) in the sulfuric acid medium containing nickel and aluminum was efficiently and selectively extracted by Cyanex 272. After three-stage countercurrent extraction, the extraction efficiency of vanadium was 99.76%, and the co-extraction efficiencies of nickel and aluminum were only 2.47% and 1.87%, respectively. Thermodynamic calculation shows that the extraction of vanadium (IV) from the sulfuric acid medium with Cyanex 272 is an endothermic reaction. The innovative method of oxalic acid precipitation was used to recover nickel from the raffinate, achieving selective extraction of nickel from the solution containing a high concentration of aluminum. The precipitation efficiency of nickel was 98.58%, while that of aluminum was only 0.75% under optimal conditions. The proposed flowsheet for the separation of vanadium, nickel, and aluminum from acid leaching solution may provide a new idea for the comprehensive recovery of valuable metals from spent hydrodesulfurization catalyst.

Nov 30, 2022