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By Luciano R. G. Santos

Keywords: biosorption, cadmium, copper, biomass, spent zeolite. The majority of the industrial activities produce some kind of solid wastes. In this work two industrial residues (spent zeolite and wood sawdust) were chemically modified to increase their heavy metals sorption capacities. Manilkara longifolia (a Brazilian plant known as parajú) sawdust was first treated with NaOH and modified with different citric acid concentrations (0.6-1.2 mol/L) at 120°C, for 90 min. Infrared spectroscopy confirmed the presence of carboxylate groups in the wood structure as result of their mixing. Similarly, spent zeolites were also submitted to a chemical treatment (NaOH) to remove carbon deposited during oil cracking and to recover its sorption capacity. Batch experiments carried out at ambient temperature showed that both materials present sorption capacity for copper and cadmium comparable to weak acid ion exchange resins. A maximum of 78 mg-Cd/g and 59.7 mg-Cu/g as well as 29.9 mg-Cd/g and 14.6 mg-Cu/g were observed for the sawdust and the zeolite, respectively. The results were modeled according to the Freundlich and Langmuir equilibrium isotherms and compared with results of other studies.

Jan 1, 2005

By O. A. Ojo, N. Esmaeili

"The effects of brazing and use of composite powder mixture as interlayer material on hot corrosion resistance of brazed IN738 superalloy were studied. Brazing was observed to result in significant reduction in the hot corrosion resistance of the superalloy. However, application of composite powder mixture, which consists of additive superalloy powder, enhanced the hot corrosion resistance of brazed samples. It is also found that although the use of composite powder mixture increased hot corrosion resistance of brazed alloy, if the additive powder completely melts, which is possible during brazing, it can significantly reduce the hot corrosion resistance of the brazed joint. Elemental micro-segregation during solidification of the joint with completely melted powder mixture produces chromium depleted zones and consequently reduces hot corrosion resistance, since a uniform distribution and adequate chromium concentration is necessary to combat hot corrosion. This has not been previously reported in the literature and it is crucial to the use of composite powder mixture for enhancing the properties of brazed superalloys.INTRODUCTION Superalloys have been developed in response to the increasing demand for materials with higher resistance to corrosion and creep and also with higher mechanical strength at higher temperatures (Smith, 1981). Ni-base superalloys are predominantly used in manufacturing hot sections of gas turbine engine components. This is due to their high strength and corrosion resistance in extremely high temperature service environments which is typical for hot sections of gas turbine engines (Miglietti, 2009). The continuous demand for higher efficiency and output has resulted in the use of higher operating temperatures and gas pressure in modern gas turbine engines (Jahnke & Demny, 1983). Consequently, this has caused thermal and mechanical stresses which result in severe degradation and damage of gas turbine engine components due to creep, fatigue and hot corrosion (Zhang, Feng, & He, 2006). The decision to replace or repair damaged parts depends on the overall repair cost and expected life of the repaired components (Jahnke & Demny, 1983). However, in most cases, it is more cost effective to repair damaged parts rather than use a full replacement."

Jan 1, 2017

By Guilherme Bougleux Michelin Assunção

O projeto visa o estudo da reatividade e da resistência do coque, combustível tradicionalmente utilizado na siderurgia, relacionando às diversas condições presentes no alto-forno. Para a realização da pesquisa, foram utilizadas amostras de coque de uma empresa siderúrgica nacional. O coque foi analisado através dos ensaios Coke Reactivity Index (CRI) e Coke Strength After Reaction (CSR) no Laboratório de Processos Metalúrgicos da Universidade Federal de Minas Gerais (UFMG). Os testes foram realizados em tempos e temperaturas pré-determinados para simular as diversas zonas percorridas durante a descida do termo-redutor nos altos-fornos. Os resultados mostraram a viabilidade termodinâmica da gaseificação do coque a partir de 900°C, sendo possível calcular a energia de ativação da reação de Boudouard a 1100°C, e a correlação entre CRI e CSR coque.

Aug 17, 2017

By Thomas A. Simpson

Heretofore, underground coal mines in Alabama have operated under only 60 to 360 meters of cover: however, new mines (at least 5 in the early opening or development stages) will be operating under cover ranging from 600 to 660 meters. With increased rock confining pressures, roof stability problems will become more critical. Initial studies in two 7 ½ -minute quadrangle areas in the Warrior coal basin of Alabama indicate that the orientation of certain lineament and fracture-trace modes mapped from ERTS-1 (Earth Resources Technology Satellite) imagery correlate closely with the strike of joint and fault modes. High altitude (118,000 m) U-2 aircraft data were used to support these findings. In addition, over 50 percent of the normal faults mapped in the study area could be directly correlated with ERTS and U-2 lineaments and fracture traces. These correlations provide clues to the structural development of the Warrior coal basin and may, in turn, be used as a guide to the prediction of roof-stability conditions in advance of mining.

Jan 1, 1975

By S. Mishra, C. Shon, D. Saylak

Only 40% of fly ash generated by the power plants in US are recycled and used for commercial applications. Of these, the high lime, Class C ash had been preferred. Systematic laboratory and field-scale studies have shown that, by including calcium chloride in the mix design of stabilization of roadbed materials, both Class C and Class F fly ashes can be effectively utilized. Test data reveal that the addition of calcium chloride to the system accelerates its curing rate, thereby increasing early strength and long term durability of the constructed road. For road construction, a preblended Class F fly ash–CaCl2 system tends to be more forgiving than the Class C fly ash–CaCl2 system. The former system produces more durable roads. The role of calcium chloride as an accelerator in these systems is discussed along with a mathematical model developed for fly ash- CaCl2 stabilized roadbed systems.

Jan 1, 2007

By Rosiane Mary Rezende Faleiro

O carvão vegetal, CV, é o componente individual com maior impacto no custo final de uma usina integrada. Diante desta realidade, foi desenvolvido um processo de carbonização contínua, uma tecnologia moderna que a diferencia das carbonizações tradicionais, permitindo que o CV produzido tenha melhores características físicoquímicas. Sendo assim, o desafio agora é encontrar condições operacionais adequadas para produzir em larga escala a um custo competitivo. Com base nisso, desenvolveu-se este trabalho com o objetivo de avaliar o desempenho de um altoforno, em condições reais de operação e em escala industrial, utilizando dois tipos de carvões (CVs): CV Referência e CV produzido por carbonização contínua (Carboval). Os principais parâmetros operacionais foram monitorados. O CV Carboval apresentou melhores resultados para as análises químicas e granulométrica, melhor permeabilidade no alto-forno e menor consumo bruto, demonstrando sua viabilidade técnica.

Aug 17, 2017

By Manuel Cabrera M

Dado que la actividad minera aurífera representa un aporte de divisas para el desarrollo económico en el Perú, el presente texto revisa los principios del uso del carbón activado como medio de recuperación del oro, asi como analiza los principales detalles de la planta de Cianuración Pison Mning y la aplicación del Head Leaching a nivel planta piloto industrial como sistema de beneficio de minerales de oro baja ley.

Nov 8, 1982

By T. T. Campbell

Although secondary recovery of lead and lead-tin alloys has been common practice in the United States during recent years, there is little published in-formation concerning recovery techniques. Available information does not cover metal recovery from wet dross skimmings. This investigation by the Bureau of Mines was undertaken to develop techniques that would allow lead-tin alloys to be recovered from wet dross skimmings containing large amounts of zinc chloride. A process was developed, on a laboratory scale, for recovering lead-tin alloys from wet solder dross skimmings. Straight water leaching, either with or without a second leaching operation carried out with a Na2C03 addition for removing chloride, produced a dross that could be smelted without further treatment. Overall recoveries averaging 92 percent of the metal values in the dross were obtained in the form of lead-tin alloys, which had an average tin content of 16 percent and lead content of 84 percent. The recovered alloy contained less than 0.02 percent zinc, as determined by both chemical and spectrographic analyses.

Jan 1, 1956

By O. F. Brown

The use of quality materials (aggregates and asphalt binder) in optimal proportions is the key to producing optimally performing hot mix asphalt (HMA). The Superpave mix design standard in the US introduced specific volumetric and binder property requirements in HMA design. Different methods for HMA constituent proportioning have been proposed in various guidelines. The design process to determine the HMA blend is currently iterative and engineers rely almost exclusively on experience. This approach is time consuming and often does not result in cost-optimal HMA mixtures. This paper introduces a mixed integer linear programming (MILP) optimization model for hot-mix asphalt constituent proportioning. The MILP model minimizes the total mix cost while satisfying all the volumetric, binder and mix property specification requirements. The model has been successfully validated with real-life example. The aggregates and binder ratios from the model were in close agreement with those from the contractor. The Bailey ratios and the gradation constraints were also satisfied. The cost of the optimal mix was $0.804/Mg less than that of the contractors?. This marginal reduction might make all the difference in an industry that is highly competitive. The MILP model also demonstrated that adding RAP to the contractor?s design would reduce the cost of the blend by $5.74/Mg. The virgin binder content was reduced by 1% because of the recycled asphalt contained in the RAP. This work represents the first successful attempt in incorporating both aggregate and asphalt performance requirements into the optimization formulation. Applying these models will ensure the minimum cost mix that meets all constraints and will increase profit margins for plant operators.

Jan 1, 2012

By W. Timothy Adams

The production of natural abrasives varied in quantity and value compared with 1976. Output of tripoli-type materials was approximately the same in both quantity and value. Special silica stone products decreased in quantity and increased in value. Garnet production decreased both in quantity and value. The production of emery increased and the production and value of manufactured abrasive material was approximately the same. Foreign Trade Imports of abrasive materials were 23% more in value than in 1976, and exports plus reexports increased in value 10%. Net imports, the excess of imports over exports and reexports, were $35.3 million. The volume and value of all abrasive materials exported varied.

Jan 1, 1980

By Musa D. Manzi, Raymond J. Durrheim, Richard T. Masethe

Large mining-induced seismic events and their aftershocks cause hazardous working conditions, damage infrastructure, delay production and pose a risk to miners in the deep-level gold mines of South Africa. Stress changes affecting pre-existing zones of weakness are the main drivers of large mining-induced seismic events, which are often followed by aftershocks triggered by quasi-static stress transfer within the rockmass. A better understanding of seismic source mechanisms is important if the seismic data is to be used more effectively for mine planning and to reduce the rockburst risk. Four large seismic events (ML≥2.0) associated with the mining of the Ventersdorp Contact Reef (VCR) at Kloof Gold Mine occurred on 13 June 2017. The events and their fore- and aftershocks were studied in detail to establish the circumstances and the cause of the incidents. The local magnitudes ranged from ML 2.3 to ML 3.0, the seismic moment from 0.69 to 2.25 x 1013 Nm and the source radius from 92 – 150 m. The main shocks were preceded by foreshock sequences, which were especially vigorous in the four hours before the main shock. Seismicity was recorded by in-mine arrays of three-component 4.5Hz geophones (detection threshold approx. ML -2.9). Following all four main seismic events, ML 2.3, ML 2.3, ML 2.9 and ML 3.0, the network detected a total number of 300 aftershocks ranging from ML -2.9 to ML 1.6 spread within a 1300 m radius from the centre of the seismic network. The statistical properties of the aftershocks were analysed using three scaling relationships: (i) Gutenberg–Richter frequency magnitude relationship; (ii) modified Omori’s law; and (iii) Båth’s law for the magnitude of the largest aftershock. The geological or mining feature that controlled the failure (e.g., fault, dyke, pillar, abutment) was determined by calculating the orientation of the nodal planes of the large seismic events using moment tensor analysis and studying the aftershock distributions.

Apr 26, 2022

By Stefano Trevisani

Abstract The FIEC Sustainability Vision states that “risks should be identified and allocated in a fair manner across the project team from the early stages of the design phase. A partnering approach, where objectives and timescales are agreed in advance together with all relevant partners in the value chain, offers a useful solution to improve on site efficiency and reduce disputes”. An alliance or collaborative form of contract involving all parties is the best way to ensure fair contract conditions and proper risk allocation in construction projects. Collaborative contracts are particularly useful where there is uncertainty or undefined information or in the event of technical difficulties and other risks difficult to allocate among the parties involved in the project. Owners sometimes require even special output in terms of innovative technical solutions or special performance. In addition, this particular form of cooperation has been construed and developed with the intention of avoiding and mitigating another great risk associated with the construction industry (especially in complex projects): disputes and conflicts, which are often a major cause of delays, increased costs, loss of reputation and opportunities. In contrast, Alliances are a way to increase and strengthen business relationships, technical and economic innovation and effectiveness, in a worldwide global context where the waste of resources must be avoided in order to guarantee future recovery and growth. Of course, the total cost of a project is usually a key factor and the main driver for the Owner and the Contractors in deciding the type of relationship between them as well as the subsequent relationship with subcontractors and lower-tiers. This paper and presentation, will explain the main features and the principle benefits that the use of collaborative contracts can bring to all parties involved in the construction project, including the sustainable financial return that might be achieved if costly and time consuming disputes can be avoided.

Jan 1, 2014

By Jerald E. Harris

"Often taken for granted, drill accuracy plays a major role in the relative success or failure of a blast.Expensive technological advances in equipment capabilities, drilling tools, communications, explosives, and timing can quickly be nullified by poor drilling."

Jan 1, 1999

By Tom Rutkowski

Los excesivos niveles de selenio son capaces de producir trastornos de desarrollo para la vida acuática. Por tanto, es difícil eliminarlo mediante los métodos convencionales de tratamiento físico/químico en los emplazamientos mineros, tales como plantas de tratamiento de precipitación química. En ese sentido, el presente texto señala el tratamiento biológico del selenio como el método adecuado que permite una descarga mínima de selenio total de 4.1 microgramos por litro (µg) en el efluente minero. Así también se describe el programa, presupuesto y costo del proyecto diseño- construcción.

Aug 1, 2015

By Hugh Douglas

In the past two years recent increases in silver prices over levels that prevailed for many years have changed supply/demand patterns. On the supply side, a silver mining boom is in progress in the United States and elsewhere. On the demand side, traditional uses of silver by individuals are dropping while industry is conserving. These changes will alter the supply/demand balance and bring about more moderate rises in silver prices, which in turn will impact the mining industry.

Jan 1, 1981

By F. E. Brantley, D. M. Yergensen, D. A. Martin

Fluidized - bed roasting was investigated as a means of decomposing gypsum and gypsum mixtures to produce a gas rich in sulfur dioxide and a lime or portland cement residue . Ninety- eight percent desulfurization of gypsum in a 10 - inch fluidized- bed reactor took 1.5 hours at an operating temperature between 1,200 ° and 1,225 ° C. A cement- type residue was obtained but had to be refired at 1,450 ° C before mortar prepared from it met the physical specifications for cement .

Jan 1, 1963

By Sailesh S. Author

The current design method for soil-cement (SC) columns improved soft clayey ground under the highway embankments assumes a slip circle failure surface shearing through the columns and the soils using a weighted average shear strength. However, the results from the laboratory centrifuge model test and numerical analysis indicate that in many cases, the SC columns fail by bending. Some researchers have proposed methods for estimating the maximum embankment loading for bending failure of SC columns, but those methods have limitations in correctly considering the internal shear stresses or not applicable for the group SC column improvement. Numerous model embankments on SC columns have been simulated by three-dimensional (3D) finite element analysis (FEA) and the mechanism of bending failure and the magnitude of the bending moment in the SC columns under embankment load has been investigated. Based on the simulated results, the design method for the estimation of the bending failure of floating SC columns has been proposed. The predicted results from the proposed method agreed with the existing field condition of one embankment in Saga, Japan reported in the literature in terms of the stability of columns. Hence the proposed method can be used for the design of floating SC columns in the soft ground.

By T. A. Grammatikopoulos, B. Vasily, A. H. Clark

"The St. Lawrence deposit is a large wollastonite skarn (ca. 9 Mt @ 41.3% wollastonite) adjoining the gabbroic-to-syenitic Leo Lake pluton in the granulite facies Frontenac Terrane of the Grenvillian Central Metasedimentary Belt. It occurs within a horseshoeshaped horizon of quartzite, open to the east. The skarn extends over 1.2 km2, and comprises wollastonite-dominant, wollastonite-clinopyroxene, and diverse quartz-feldspar-sulphide (-titanite) layers, interbanded with, and strongly folded within, the quartzite. As in the world-class wollastonite deposits of the Willsboro district, New York, no carbonate protolith is preserved, and calcite is a negligible constituent of the mineralized zones. Wollastonite development is nonetheless ascribed to metasomatism of a metacarbonate unit by magmatogene, silica-rich, CO2-poor (XCO2 < 0.05) fluids, at P = 350 MPa and ca. 560°C, or, alternatively, 550 MPa and ca. 630°C.Several high-grade zones, averaging >40% but locally exceeding 80%, of translucent, white, tabular wollastonite grains, with lengths of 0.2 cm to 5 cm, have been delimited by drilling. Preliminary beneficiation studies yield high aspect-ratio and high-purity (low Fe and Mn) concentrates.St. Lawrence compares favourably to other known prospects and operating wollastonite deposits: having good chemical and physical properties, low iron content, and high aspect ratios (>20:1). In addition, the deposit has a favourable size and location, and will benefit from a low Canadian dollar. Canada currently has no wollastonite production."

Jan 1, 2003

By Almon F. Robertson

"INTRODUCTION At various times, North Carolina has supplied small quantities of brown-iron ore to the furnace o the South. Between 1917 and 1920, the quantity reported to the Federal Geological Survey was 126,000 tons. Most of this came from Cherokee County. 3/In furtherance of the program initiated by the Bureau of Mines to develop additional reserve of iron ore during the emergency, the Cherokee County deposits were examined by an engineer 4/ of the Bureau of Mines, and work was recommended on,12 properties.The project was begun in April 1944 and continued intermittently until April 1945, when work was stopped. During this period, eight properties were explored, and an additional property was mapped.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch; Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision of Dr. R. S. Dean, assistant director."

Nov 1, 1946

By S. Janisko

Studies have linked long-term inhalation of diesel exhaust with adverse health effects such as cardiovascular disease, cardiopulmonary disease, and lung cancer. Diesel exhaust levels in underground mines can approach 100 times the environmental level and are therefore monitored closely in the mining industry. Elemental carbon (EC) (a product of diesel combustion commonly referred to as ?soot?) has proven to be a good indicator of diesel exhaust levels. The current procedure for measuring EC levels involves taking personal samples from a mine worker?s breathing zone and/or stationary samples in various parts of the mine and subsequently sending these samples to a lab for analysis by NIOSH 5040 method. Unfortunately, the whole process can take up to several weeks to complete. To address the problem of waiting weeks for results, NIOSH?s Pittsburgh Research Laboratory is developing a portable device for measuring levels of elemental carbon. This optical device takes a continuous sample of air in the surrounding environment and measures the absorbance of light passing through a filter that collects diesel exhaust particulates within the instrument. This technology can provide a near real time measurement of EC with accuracy within 10% error. The ability to take near real time measurements, combined with the instrument?s portability (currently small enough to be worn on a miner?s belt), makes this device extremely useful in the mining industry.

Jan 1, 2009