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Based on experimental and computer simulation results from our group, we report a systematic, atomic level analysis of carbon dissolution from carbonaceous materials in molten iron. Experimental results on graphite / Fe-C-S system were obtained using carbon dissolution studies, XRD and FESEM investigations and were supplemented with Monte Carlo simulations. Three basic mechanisms, namely carbon atom dissociation rate, interfacial phenomena and mass transfer in the melt were found to be responsible for the overall dissolution process. While mass transfer in the melt is governed by the concentration gradients, melt composition and temperature; impurities present in ash play a significant role in the interfacial phenomena. For less ordered forms of carbonaceous materials, carbon atom dissociation rate depends strongly on the degree of long-range order and is an important rate controlling mechanism in the overall dissolution process. A systematic comparison of dissolution rates for a variety of coal-chars, natural and synthetic graphites has been carried out in an attempt to identify rate-controlling mechanisms. The structure of the carbonaceous material appears to be an important underlying factor in the carbon dissolution process.

Jan 1, 2003

By J. H. E. Jeffes, K. T. Jacob

The activity coefficients of oxygen in liquid Pb-Sn alloys have been measured between 550 and 1100°C by use of solid oxide galvanic cells: Pt, Ni-NiO | Zr02 Solid electrolyte | O (Pb + Sn), Cermet, Pt; and Pt, Fe-FeO | Zr02 Solid electrolyte | 0(Pb + Sn), Cermet, Pt. Alcock and Richardson's quasi-chemical equation, with the coordination number of atoms set to 2, is found to predict successfully the activity coefficients of oxygen in these alloys. The relative partial molar enthalpy and entropy of oxygen at 1 atom per cent in the alloys have been calculated from the variation of the activity coefficient with temperature. The addition of Sn to an unsaturated solution of O in Pb is shown to decrease significantly both the partial molar enthalpy and entropy of O. As the measurements were restricted to a narrow range between 750 and 1100°C in Pb-rich alloys, however, the pronounced variation of the partial molar enthalpy of O with temperature at constant alloy composition predicted by the quasi-chemical model could not be verified.

Dec 1, 1971

By Abolfazl Eslami, Fatemeh Valikhah

"Complexity in soil-foundation interaction and subsoil nonlinear behavior cause difficulties and uncertainties in evaluating the actual values of foundation design factors such as settlement. The acquired continuous records of Cone Penetration Test (CPT) can be used to determine the soil profile and characteristics those are applicable in the geotechnical design. In this paper, it has been attempted to present a new non-linear stress-strain approach to estimate the foundations settlement by using CPT data in the form of soil behavior classification charts. This new approach is based on Janbu method (1960s and also 1998). Instead of using fixed and constant values for stress exponent (j) and modulus number (m), continuous coefficient variations can be used. The proposed approach also can be used as a new method to predict pile group settlement. A data bank has been compiled containing twenty-two practical case histories to investigate the accuracy of the predictions made by the proposed and available common methods. The comparisons indicate that the proposed approach is relatively able to predict the settlement close to their real values. Therefore, it can be considered as an alternative method based on valuable CPT data and nonlinear stress-strain approach for foundations and pile groups settlement estimation.INTRODUCTIONComplexity in soil behaviour for settlement analysis is the result of non-linear and time dependent stressstrain behaviour of soils, their elasto-plastic performance under loading and unloading situation and also effects of stress history (Holtz et al., 2011; Fellenius, 2015). Hence, many relations and equations have been proposed to predict foundation settlement, where most of them are based on typical different parameters such as soil stiffness (E), foundation width (B), contact pressure (q) and pressure developing in depth (Janbu, 1967 also 1998; Briaud and Gibbens, 1999; Uzielli and Mayne, 2012).The Janbu approach for settlement estimation, proposed by Janbu in the early 1960s, combines the basic principles of linear and non-linear stress-strain behaviour of material. The method is applied to all types of soils. The relation between stress and strain is a function of two non-dimensional parameters which are unique for any soil: a stress exponent, “j”, and a modulus number, “m”. The Janbu relations are derived from the definition of tangent modulus by the following expression:"

Jan 1, 2017

By F J. Kelly

A chemical process, based on laboratory investigations, is proposed for the production of high-purity niobium oxide from a pyrochlore-perovsk1te flotation concentrate produced from ore obtained at the Oka, Quebec property of Columbium Mining Products Limited. The method developed included the decomposition and dissolution of the flotation concentrate with hot, concentrated sulphuric acid. The dissolved niobium was purified and concentrated by a solvent extraction step, using methyl isobutyl ketone as the extractant. The niobium was recovered from the extractant with ammonium fluoride solution from which niobium oxide was precipitated with ammonia. Finally, the filtered and washed precipitate was calcined. Ninety-six per cent of the niobium was recovered in a product analysing 99.9 per cent Nzo.. The reagent cost was in the range of $1.00 to $1.25 per pound of niobium recovered. Introduction OVER the past few years, Columbium Mining Products Limited has been engaged in the development of a niobium-bearing mineral deposit in the vicinity of Oka, Quebec. One phase of this program resulted in a flotation process capable of producing concentrates containing up to 50 per cent Nb205? Flotation pilot-plant

Jan 1, 1965

By Michael Fehler, Hidenshi Kaieda, Leigh House

Hydraulic fracturing has gained in popularity in recent years as a way to determine the orientations and magnitudes of tectonic stresses. By augmenting conventional hydraulic fracturing measurements with detection and mapping of the microearthquakes induced by fracturing, we can supplement and independent1 y confirm information obtained from conventional analysis. Important information obtained from seismic monitoring includes: the state of stress of the rock, orientation and spacing of the major joint sets, and measurements of rock elastic parameters at locations distant from the wellbore. While conventional we1l 1ogging operations can provide information about several of these parameters, the zone of interrogation is usually limited to the immediate proximity of the borehole. The seismic waveforms of the microearthquakes contain a wealth of information about the rock in regions that are otherwise inaccessible for study. By reliably locating the hypocenters of many microearthquakes, we have inferred the joint patterns in the rock. We observed that microearthquake locations do not define a simple, thin, planar distribution, that the fault plane solutions are consistent with shear slippage, and that spectral analysis indicates that the source dimensions and slip along the faults are small. Hence we be1 ieve that the microearthquakes result from slip along preexisting joints, and not from tensile extension at the tip of the fracture. Orientations of the principal stresses can be estimated by using fault plane solutions of the larger microearthquakes. By using a joint earthquake location scheme, and/or calibrations with downhole detonators, rock velocities and heterogeneities thereof can be investigated in rock volumes that are far enough from the borehole to be representative of intrinsic rock properties.

Jan 1, 1986

By L. K. ARMSTRING

ANYONE doubting prosperity in the mining industry should visit the Kootenays of British Columbia where the West Kootenay Power & Light Co. is kept busy running new power lines and connecting mines and mills with lines already in service. Quoting from an inspired statement "The four hydro-electric plants of the West Kootenay Power & Light Co. on Kootenay River have been in continuous operation." At the recent 35th annual meeting of the Eastern' British Columbia Boards of Trade held in Nelson, a two-day session indicated unusual activity. The following information was obtained through personal contact, through the press, and by hearsay. Much of it has been checked and proved accurate. Reversing the order of the flowsheet. Secretary J. R. Hunter reported as fol¬lows regarding the value of the 1934 production of the Consolidated Mining & . Smelting Company's metallurgical, plants at Trail and Tadanac:

Jan 1, 1935

By Arthur E. Focke

IF a metallurgist employed in an industry producing mechanical parts or assemblies wishes to make the most of his opportunities he will be concerned with every use of metals in that industry. He will not only take part in the testing and treating of the metals used but will assist in their selection and study their behavior in processing and in service. In addition, he will attempt to develop an understanding of the problems involved in the use of the metals in all plant tools and equipment. Metallurgists that follow this course will soon recognize that frequently too little thought is given to the effect of the design of parts on the way the metal in them is expected to behave in service. He will come to realize that changes in the design of a part will often be much more useful than changes in the hardness, strength, composition, or structure of the metals used in them. Does this mean that a metallurgist is out of place in these industries and that he should leave the field to others or be content to fill only a minor role?

Jan 1, 1947

By David Bequette, Ray D. Peterson, Cynthia K. Belt

"With a need to cut production costs in the metals industry, cost savings from energy efficiency improvements are critical. Opportunities can be found by reviewing furnace systems and practices so that the melting and holding processes operate at the highest energy efficiency. Many of the changes can be implemented with a minimum of expense or capital investment. This paper will review several low cost methods to optimize energy efficiency on reverberatory melting or holding furnaces. These five methods (furnace utilization, idle procedures, fire rate, controls, furnace pressure) will be explained and information given to implement these changes. Included are several rules-of-thumb and benchmarks for aluminum reverb furnaces.IntroductionEnergy can be a significant portion of the total manufacturing costs for metals and materials manufacturing involving thermal processing such as heat treating, melting, and high temperature processing. Natural gas prices have dramatically varied over the last few years. While no one can foresee the future, prices are expected to increase from the current low prices. More recently, emphasis is being put on the reduction of greenhouse gases with the potential of additional costs to industry.One of the first steps in an energy management program is to measure the energy usage of the process [1]. The results are typically understood in relation to the mass melted in kWh / mT [BTU / lb]. For the purposes of this paper, furnace energy efficiency is calculated over a month or even a year and thus includes hold times. This efficiency is typically different from the values quoted by furnace manufacturers. Those values are for limited short term tests at highutilization.Once you know the performance for your furnaces, these should be compared to industry benchmarks. For aluminum melt furnaces with cold air burner systems, a benchmark value or goal is 1800-2000 BTU/lb [1160-1290 kWh/mt], though some of the best have reached 1600 BTU/lb [1030 kWh/mt]. Furnaces with regenerative burners can attain 1100-1200 BTU/lb [710- 775 kWh/mt]. There are some designs of multi-chamber furnaces or oxygen furnaces that have improved on these numbers, perhaps as low as 950 BTU/lb [615 kWh/mt]. Typically, as the degree of sophistication and energy efficiency of the furnace increases, so does the cost."

Jan 1, 2010

By Tim Siegel, III Fondren, Billy Camp

"INTRODUCTIONThe new $650 million power block at Santee Cooper’s Cross Generating Station in Cross, South Carolina is being constructed on driven pre-stressed concrete (PSC) piles. S&ME, as geotechnical subconsultant to Parsons Energy and Chemical Group, was responsible for pile analysis and design to meet the site’s geotechnical and seismic challenges. Selection, analysis and design of the PSC piles included consideration of the following:• Column and equipment support loads ranging up to 500 to 1000 kips (2224 to 4448 kN).• Incorporation of the 2000 International Building Code seismic provisions.• A thick upper soft clay and loose, liquefiable sand.• Potential for karst-related features in the calcareous Santee Limestone.GEOTECHNICAL CHARACTERIZATIONThe near-surface site geology consists of (in order of increasing depth): (1) Pleistocene sediments, (2) the Santee Limestone (considered part of the Orangeburg Group) of Eocene age, and (3) the Black Mingo Formation of the Eocene/Paleocene age (refer to the shear-wave profile in Figure 4). Pleistocene clays and silts are generally soft and will settle significantly if subjected to loading by heavy grade-supported structures while the interbedded sands are generally loose. Where submerged below the shallow groundwater table, the sands were determined to be liquefiable during a strong earthquake.The Santee Limestone is a nearly white to yellow fossiliferous and partly glauconitic rock consisting chiefly of calcium carbonate. Observations of the rock core samples from the site indicate that it can range from hard crystalline limestone (primarily in thin layers) to a lightly cemented sand. In terms of rock strength, the Santee Limestone is generally very soft to soft, depending on the cementation and other depositional characteristics."

Jan 1, 2004

By Umberto Cassará de Castellammare Scott Siciliano

A proposta desta pesquisa foi desenvolver uma metodologia que empregasse radiação gamae a técnica de “Cross-Correlation” para medir a velocidade das pelotas de minério no duto. Uma unidade experimental foi projetada e construída para realizar simulações de fluxos de duas fases, usando um medidor de fluxo, instalado externamente ao tubo, consistindo em dois sistemas independentes, cada um composto por uma fonte 241Am de radiação gama (59,62 keV de energia) e um detector cintilador NaI (1 x 1 "). Estes sistemas estavam localizados no mesmo plano vertical e separados por uma distância de cerca de 18,0 cm. Como Pelotas, foram produzidos corpos de prova de composição distinta a fim de obter um espectro de densidades para verificar a validade da metodologia. Os resultados mostraram que o uso da densitometria gama associado com a medição do coeficiente de "Cross- Correlation” permitiu calcular o tempo transiente entre dois sinais e assim, calcular a velocidade da pelota.

Aug 16, 2017

By Ródnei Abbade Abreu

A UPV é abastecida basicamente por duas fontes de energia elétrica de 60 Hz (maioria das cargas da usina): LIGHT (concessionária - externa) e CTE#2 (interna). A energia externa chega a UPV via sistema de transmissão e distribuição da LIGHT, por esse transporte paga-se uma tarifa de uso do sistema para a concessionária, vale ressaltar que não é comprado energia da LIGHT e sim o transporte da mesma, a energia é comprada de unidades geradoras distantes da UPV. O valor pago pelo transporte da energia é baseado em um contrato de Demanda [MW], que representa um valor máximo que o sistema deve ser capaz de suportar, caso seja solicitado. O objetivo desse trabalho é identificar qual a melhor (menor) demanda a ser contratada pela UPV, de forma a atender os processos produtivos e não ultrapassar o valor contratado (pagamento de multa), para tal foi criado um simulador com base em dados históricos para estimação de demanda a ser contratada pela usina.

Jul 31, 2018

By Mateus Augusto Martins de Paiva

Este estudo tem como objetivo avaliar a possibilidade de remediação de águas e áreas contaminadas com Arsênio(V) e Crômio(VI) em pH levemente ácido pela biomassa Polygonum punctatum Elliot, planta presente na imediação da lagoa da Pampulha em Belo Horizonte e em várias regiões do estado de Minas Gerais. Todos os ensaios de adsorção foram realizados em pH 5 por 24h a 25°C. A biomassa foi caracterizada por espectroscopia de infravermelho e o ponto de carga zero (PCZ) foi determinado por titulação potenciométrica. A concentração inicial e remanescente após adsorção para As(V) e Cr(VI) foram obtidas por espectrometria de absorção atômica (AAS). A capacidade de remoção para As(V) foi de 1,14 mg por grama de biomassa enquanto para Cr(VI) foi de 7,4 mg por grama de biomassa. A biomassa apresentou excelente resultado de adsorção para a espécie Cr(VI), portanto um bom potencial para aplicação para descontaminação de efluentes contendo este contaminante.

Aug 16, 2017

By Fremont T. Johnson

Credited with production of more than 164,000 flasks Of quicksilver from 1876 to 1944, the Oat Hill mine has ranked third in output in the United States. During World War II, when the demand for mercury was high, this property was selected for diamond drill with the purpose of increasing ore reserves so that production could be maintained or, if necessary, increased. Although the existence of marginal-grade ore (fill material) left in the stapes and possibly of virgin ore of good grade had suspected in certain parts of the Oat Hill mine, no factual information to tonnage, grade, or location was available. In close cooperation with the Federal Geological Survey, the Bureau of Mines studied old records and the few available incomplete maps. Diamond drilling began in November 1943 and was completed in December 1944. Twenty-eight holes aggregating 8,121 feet were drilled, in only parts of the promising areas disclosed by the study of the data available. Detailed data on the work done by the Bureau as well as a brief history of the property and some operating details are described in this report.

Jan 1, 1949

By L. Archambeault

This paper describes preliminary research on the application of Markov Decision Processes (MDP) to Real Option Valuation (ROV) and the optimisation of mine scheduling. The MDP framework is a novel approach to option valuation and scheduling in mining operations. A learning agent is introduced into the valuation process of an open pit, where prices and block ore grades have probabilistic values. The prices are modelled using a mean reverting diffusion process and the block grades using sequential Gaussian simulation. The agent is asked to learn which production parameters should be used in order to maximise the overall value of the project. The introduction of the agent permits a real option approach to mine valuation, such that the value associated with the robustness of a design to uncertainty can be measured. A simulated example is used in which there are ten blocks to be extracted under conditions of grade and price uncertainty. Using policy iteration, an optimal policy is generated and the value of production options is found. The potential financial gains from applying MDPs to mine valuation and optimisation are substantial and warrant further investigation.

Jan 1, 2007

By Raquel de Carvalho Reis

A fosfatização é um pré-tratamento superficial que tem como principais funções: a lubrificação, proteção contra corrosão e proteção contra abrasão. Os metais fosfatizantes mais comumente utilizados são o zinco, manganês e o ferro, sendo o zinco o mais aplicado nas indústrias siderúrgicas, automobilísticas e de linha branca. Atualmente, grande parte das pesquisas relacionadas aos processos de fosfatização é referente ao fosfato de zinco, sendo escasso o estudo sobre fosfato de manganês. O objetivo deste trabalho foi estudar a cinética de formação da camada de fosfato de manganês em aços baixo carbono, analisando a influência do substrato na formação da camada fosfatizada. As análises foram baseadas na obtenção das curvas de ganho de massa, sendo caracterizadas por microscopia eletrônica de varredura. Os resultados indicaram que para o substrato constituído essencialmente de martensita revenida, uma maior quantidade de carbonetos resultou em uma menor taxa de ganho de massa, pois estes funcionam como sítios ativos no processo de fosfatização, fazendo com que exista uma maior densidade de núcleos.

Aug 16, 2017

By Eric G. Zahl

Researchers at the Spokane Research Laboratory of the National institute for Occupational Safety and health are evaluating stress and displacement measurements in a longwall coal mine. The objective is to determine the best indicators of coal bump hazards during operations so that mine foremen and technical stall can make more informed intervention decisions to protect miners from coal bumps. Instruments were clustered in two panels, a yield pillar, and the immediate roof and floor of a two-entry longwall coal mine. Data were gathered continuously from a variety of instruments as mining proceeded toward and past the instrument cluster. Researchers and the mine's technical staff evaluated these data with respect to coal bumps and bump mechanisms. Selected graphs were then presented to mine foremen on a periodic basis to test their usefulness in identifying hazards. Of particular interest was the use of horizontal stress data from the immediate roof. To measure changes in horizontal stress, a new technique was devel¬oped for installing a grouted biaxial stressmeter in the roof. An evaluation of the development of this stress monitoring system in producing data beneficial to mine foremen is presented.

Jan 1, 2000

By J Temos

This paper outlines a number of immediate practical approaches to continuous improvement in environmental management in the minerals industry. It puts these into context with longer time-frame step-change approaches whose gestation may take a decade. Examples of improvements and approaches are drawn from WMC operations.

Jan 1, 2002

By J. C. Gathje

Newmont&apos;s Phoenix Project is located near Battle Mountain, Nevada and is scheduled to produce copper concentrates containing high precious metal values. High temperature pressure oxidation (PDX) of the concentrates was considered as a treatment option during process development. The metals content in Phoenix concentrates range from: 15-25% for Cu, 1-10% for Zn, 0-2% for Pb and ?27% Fe. The precious metals content of the Phoenix concentrates can range up to ?300 g/t Au and >3,000 g/t Ag. As a consequence it was necessary that any process for consideration should have the capability of recovering both the copper and precious metal values. Typically, gold can easily be leached from the autoclave discharge solids, but silver is chemically bound with the jarosite formed and cannot be directly leached. Laboratory investigations led to the development of a patented PDX process that minimizes the formation of jarosite so that the silver can be leached easily along with the gold. The process was confirmed with extensive pilot plant testing. Excellent solution extraction of copper and zinc was achieved, and both iron and lead were precipitated in the PDX residue. The process produces clean PDX discharge liquors with very low iron concentrations. As an example, conventional PDX techniques resulted in pregnant liquors containing ?5 g/L Fe. However, the Newmont process, which controls the iron and sulfate species, achieved high iron precipitation in the PDX solids and pregnant liquors containing <0.5 g/L Fe. High gold and silver recoveries were achieved by direct cyanidation of the PDX solids. This process has the added benefit of producing PDX solids that demonstrate superior settling and filtration characteristics.

Jan 1, 2006

By R. V. Ramani, W. Miola

"A relationship exists between the quartz contents in the underground coal nine airborne dust samples and those in the coal and host rocks that are mined [17, 18, 19] The prescribed method for quartz analysis in respirable airborne coal dust samples is the MSHA P-7 method. Accurate quartz analysis procedures are needed for bulk samples in order to predict the potential quartz content in airborne nine dust, which in turn will aid the design of quartz dust control procedures during mining. thereby reducing the airborne quartz dust in underground atmospheres. The requirements of this method are that the amount of quartz is the sample be less than 250ug, and the total sample weight less than 2,500 ug. Unlike with airborne dust samples, there are no limitations to the available mass of bulk samples. However, these are no standard procedures for the preparation of bulk samples for scanning or prescribed methods for quartz analysis. The NIOSH and MSHA methods are certified for roped* dust and the acceptance of these methods for bulk samples assumes that the bulk samples will be reduced to the conditions specified for respirable dust samples. An alternative method is X-ray diffraction, which provides higher average quartz values than those obtained from P-7 method for the same samples.An investigation was carried out to determine the optimal procedure for preparing the bulk samples for the IR and XRD analyses. In this paper, the investigations on the effects of calibration, particle sizes, matrix composition, interferrous, and behavior of the filter substances on IR, XRD and FTIR results are presented. The error introduced by the presence of kaolinite and a new sample asking procedure to reduce it are discussed. The problems experienced with conventional sample holders for scanning were eliminated with the design and development of a new hollow sample holder. Quantitative comparison of quartz determinations by IR, XRD and MR methods on coal, roof and floor rocks, and airborne dust samples are presented. The important factors affecting the results of quartz analysis methods are: 1) bulk sample preparation for obtaining representative and homogeneous analysis samples: 2) particle size distributions of the analysis samples and calibration standards; 3) qualitative matrix composition of the analysis sample; 4) matching calibration standards to analysis sample; 5) substrates for sample deposition during analysis sample preparation; 6) procedures for analysis sample mounting; 7) selection of proper portions of she response profile for insanity measurement; and 8) interferences of spurious phases with the critical analyses. The recommendations of this study are important to enable comparisons and interpretations of analysis and research results."

Nov 1, 1995

By Dennis A. Fenton

This paper presents some techniques and data required to design large ball mills. The advent of larger size mills leads to consideration of the gearless drive as a practical solution to utilize large horsepowwers. The particular shell structure under consideration is subjected to thermal as well as magnetic loads. The magnitude of the inertia, magnetic and shell temperature characteristics have a very significant effect on the design and performance of the hydrodynamic pivoted shoe bearing. Particularly since these bearings have lower frictional resistance properties than hydrostatic trunnion tee rings. The structure of the mill is designed for long life. Parameters involved with the fatigue life of the structure are discussed together with some of the more important aspects of the design.

Jan 1, 1975