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By Nan Wang

Based on the commercial computational fluid dynamics software, Fluent, a three dimensional finite-volume model has been established, and the fluid flow and heat transfer in the super-wide slab mold (cross section 3250mm×150mm) of Nanjing Iron and Steel Company has been simulated. The basic feature of flow and temperature field in a super-wide mold has been analyzed, and the effects of mold width, the submergence depth of SEN, outlet angle of SEN, casting speed, superheat and cooling rate on the flow and temperature field have been investigated. The results by comparing several simulated calculations for 3250mm×150mm slab show that a more proper fluid flow and temperature field in the super-wide mold can be obtained with 15°outlet angle, 120~150mm submergence depth of SEN and 1.2~1.4m/min casting speed. The results through numerical simulation provide a theoretical basis for optimizing the configuration design of SEN and choosing reasonable processing parameters for the continuous casting mold of super-wide slab.

Jan 1, 2009

By S. Kelebek, J. A. Finch, Zhenghe Xu, S. R. (Ram) Rao

To improve SO2 emission compliance, pyrrhotite from Sudbury copper-nickel ores is being depressed with DETA. To understand the mechanism of depression, the role of complexing in controlling metal-ion activation of pyrrhotite was investigated. DETA was found to remove Cu and Ni ions but leave hydrophilic ferric species on the pyrrhotite surface. The metal:DETA ratio appeared to be 1:2. Cu was more readily removed than Ni, but the combination of DETA with sulphur dioxide was equally effective for both metal ions. Certain combinations of DETA, Ni ions, xanthate and dithionite (S2O4) or dithionate (S2O6), as representative derivatives of SO2 in water, produced hydrophilic precipitates. These may enhance pyrrhotite depression

Jun 19, 1905

By S. S. Chabot, S. E. James

A recent survey of CEOs from major steel companies worldwide revealed the importance of recycling zinc units from EAF dust, mill scale, blast furnace dust, and other zinc containing streams in their plants. Many processes were developed and installed in response to this challenge. The most successful approach involves the production of a crude zinc oxide and selling it to primary zinc producers to recover the metal value. The problem with this process is the high concentration of halides in the crude oxide. This type of material cannot be processed directly in an electrolytic zinc plant because of corrosion problems it will cause in electrolysis. In 1999, BRZ installed a zinc oxide receiving and washing plant to minimize the impact of halides to its circuit. A description of the washing plant and initial operating results are included.

Jan 1, 2000

During the construction of storage caverns, and during their lifetime if the use to which they are put so requires, it is necessary to provide adequate ventilation to ensure the safety and comfort of the underground workforce. An analysis of likely contaminants during construction has indicated that where a large facility is situated in a rock mass of even moderate temperature climatic conditions are likely to be the limiting factor during most of the mining operation and atmospheric pollution when blasting is undertaken. Possible options for improvement are increased air flow, cooling of intake air and reduction of the heat source by altering the number and type of haulage units employed in the cavern. Local solutions are an alternative approach where heat problems are confined to a few specific locations

Aug 1, 1994

By T. Tamagawa, N. S. Fu, I. Iwasaki, M. Kobayashi

A 3-stage fluidizing bed process of chlorination, selective oxidation and sulfur chloride conversion was tested for processing of a chalcopyrite concentrate. It was found that the use of excess oxygen was essential to a stable operation in the oxidation reactor. The oxygen-excess gas will inevitably cause the oxidation of the sulfide concentrate in the chlorination and sulfur chloride conversion reactors. A new flowsheet is proposed to separate the chlorination and the selective oxidation steps with separate flow paths of the fluidizing gases, thereby preventing the passage of oxygen-excess gas in the chlorination and sulfur chloride conversion reactors. The feasibility of the proposed flowsheet was demonstrated in a laboratory-scale fluidizing bed setup.

Jan 1, 2000

In 1950, about a third of the world?s population lived in cities. That figure has steadily risen throughout the following decades. Now it is believed that about 60 percent of the estimated 8.1 billion people in 2030 will be living in urban areas. The strain on infrastructure in cities in the developed world is already showing. And the rapid growth in developing nations today is adding to the shortage of materials, equipment and labor needed to keep up with this growth. So, while materials and labor may be in short supply, there is no shortage of work for the underground tunneling and space industry. In June, 718 of those professionals from around the world were in San Francisco, CA for the North American Tunneling (NAT) conference, put on by the Underground Construction Association (UCA) of SME. The attendees spent the three days of technical sessions listening to international authors discuss the state of the industry, new technologies that have become available and updates on major tunneling projects throughout the world. The accompanying exhibit attracted 79 vendors, who displayed the latest in tunneling and underground space equipment and services. In addition to the technical sessions and the exhibit, the NAT featured three short courses ? ?DRB Process Update Workshop,? ?Soft Ground Tunneling Technologies? and ?Underground Blasting Technology and Risk Management.? And the post-meeting field trip to the Devils Slide tunneling project near San Francisco was sold out.

Jan 1, 2008

Near-Infrared Spectroscopy (NIRS) Sorting in the Upgrading and Processing of Skorpion Non-Sulfide Zinc Ore In 2008 Anglo American sponsored a research project at RWTH Aachen University to assess the feasibility of the use of near-infrared spectroscopy (NIRS) for ore waste discrimination at the Skorpion zinc mine. The Skorpion mine is an open pit zinc mine located in Namibia, owned by Anglo American with an annual production of 150 000 t/a of super high grade pure zinc. Opportunities for the implementation of NIRS sorting for the Skorpion process exist to upgrade currently subeconomic material, including the marginal dump (over 2000 000 tonnes, av grade of 2.5 per cent Zn). NIRS sorting is not yet implemented or established in the minerals industry however it is a proven technology in the plastics recycling industry, where more than 2000 NIRS sorters have already been installed. NIRS sorting, a type of sensor-based sorting, is a single particle sorting technique which classifies the particles based on the absorbed/reflected radiation in the near-infrared (NIR) region. A disadvantage of NIRS is that it is a surface measurement technique, but NIRS sorting shows overall great potential for the minerals industry. Skorpion ore minerals include zinc bearing phases such as sauconite, hemimorphite, smithsonite, and hydrozincite. These display diagnostic responses in the near-infrared. There are three major absorption features that characterise the reflectance spectra of the ore bearing minerals. These are due to OH and H2O molecular bonds. The spectral response of the waste material is caused by other minerals such as non-zinc-bearing clay minerals, calcite and impure quartz. Test work showed that it is theoretically possible to separate ore material from most waste material based on spectral response in the NIR region. In addition to upgrading material by removal of waste it is also potentially feasible to classify the material based on zinc grade. A tentative correlation between zinc grade and spectral response seems to exist for the sample test suite in the NIR region.

Sep 13, 2010

By Carsten Rühlemann, David Friedmann, Bernd Friedrich, Thomas Kuhn

"This paper explores the option of direct reduction smelting of the nodules from the German license area in the equatorial NE Pacific in a submerged arc furnace (SAF). An optimized slag design is proposed to separate the larger Mn-bearing stream from the valuable metals (i.e. Ni, Cu, Co, Mo). The slag optimization allows a maximum of Mn to be retained in the manganese-silicate slag on the one hand and a maximized metal recovery in a FeNiCuCo alloy on the other. This way, the goal is to make use of the complete nodules (“zero-waste”) instead of extracting only the metals Ni, Cu, and Co, which make up about 3 wt%. The process closely relates to the “Inco Process” by the Ocean Management Inc. (OMI) of the late 1970s, which was a consortium of INCO (International Nickel Company, CAN; today Vale Canada), Preussag AG & Metallgesellschaft AG (GER), DOMCO (JPN), and Sedco (USA). However, the manganese containing slag is investigated in more detail to recover FeMn, FeMnSi and/or SiMn. To optimize the process modern tools such as thermo-chemical modeling in FactSage™ have been used. [1,2]Polymetallic deep-sea manganese nodules may offer a decreased dependency of raw material imports for Germany and the EU. Currently, four European countries (United Kingdom, Belgium, Germany, and France and an Eastern European consortium (InterOcean Metal)) hold exploration licences for these nodules in international waters in the equatorial NE-Pacific. The license areas each cover 75 000 km2 of the seafloor and are located in the Clarion Clipperton Fracture Zone (CCZ) south east off Hawaii at water-depths between 4000 and 6000 m. The nodules may be used as a resource for industrially important metals such as Cu, Ni, Mn as well as for technology metals like Co, Mo, V and Zn. The average chemical composition of nodules from the German license area is presented in Table 1. [3,4]"

Jan 1, 2017

By John A. Franklin, Tom C. Palangio, Norbert H. Maerz

WipFrag systems I and II have become the world standard in photoanalysis systems to measure fragmentation. Mines, quarries and excavating contractors can now easily measure blast results and track the progress of optimization efforts. This technology was developed and evolved to allow automatic measurements of the size distribution of patiicles on moving conveyors, in truck boxes and on crusher feeds. Production machinery can now be controlled by photoanalysis results and multiple cameras allow various locations to be monitored by a single system. Blast designs can be monitored on a shot by shot basis. Changes in delay times, explosives, patterns and hole sizes can be quickly evaluated. Along with this measurement capability has come a heightened awareness of the importance of “optimum size” and uniformity of particles for lowest cost production and material handling efficiency. In the past, savings in the “drill / blast” cycle of the operation were sometimes overshadowed by downstream production costs related to fragmentation. Now total production costs can be compared with fragmentation sizes which will immediately show the trend towards optimum size for economical production. No cost reduction program can be complete without this critical information.

Jan 1, 1997

Several Approaches to Enhance the Bioleaching of Enargite Some approaches were investigated to enhance the recovery of Cu from enargite by bioleaching with Acidithiobacillus ferrooxidans using the galvanic interaction with pyrite and activated carbon, and with thermophilic bacteria, Acidianus brierleyi. Addition of pyrite initially enhanced Cu leaching by the Galvanic effect, but after that the formation of secondary minerals passivated the surface of enargite in inoculated batches. Activated carbon improved Cu recovery from enargite much better than pyrite, when it is contacted with enargite. Recovery of Cu from enargite has been recorded to at largest 2.4 per cent within 30 days in the presence of activated carbon when mesophilic bacteria were inoculated at 25¦C. The recovery of Cu from enargite was drastically enhanced by inoculation of thermophilic bacteria, Acidianus brierleyi, up to 60 per cent within 40 days at 70¦C and still not leveled off after 40 days unless the formation of Fe(III) precipitates occurred. After 40 days dissolved molar ratio of Cu/As is around 5.2, suggesting that metal-deficient sulfides and/or ferric arsenate might be formed on the surface of enargite.

Sep 13, 2010

By Christopher Mark

Successful longwall gate entry design requires control of both vertical and horizontal stresses. Vertical, or overburden, stresses are most severe in the tailgate where they are concentrated by longwall panel extraction. Horizontal stresses, which are generally tectonic in origin, can be highly destructive during the development and headgate phases of longwall mining. The goal of this paper is to present the current state-of-the-art in detecting and controlling horizontal stresses. The information presented was collected through site investigations at 45 U.S. longwalls and an international literature review. The paper begins with a discussion of the present knowledge of regional in situ stress fields in the U.S. A review of available underground stress measurements from coal mines is presented, along with data collected by structural and petroleum geologists. The combined evidence indicates that a persistent ENE-EW trending stressfield is present throughout the eastern coalfields. Experience with horizontal stress in longwall mines is addressed next. The paper focuses on the northern Appalachian region, where the effects of horizontal stress have been most evident. Three case histories are discussed in detail, and the solutions each developed are highlighted. Observations made in the Southern Appalachian, Alabama, and Illinois coalfields are also described.

Jan 1, 1991

By Michael Arnold, Bob Faulhaber, Joe Nichols

"Center Hill Dam is a critical part of the infrastructure controlling floods at the Caney Fork River and reducing flood levels at the Cumberland, lower Ohio and Mississippi Rivers. The Center Hill Dam Foundation Remediation Project was necessary to address Karst features in the foundation rocks and observed signs of distress of the dam. From 2011 to 2014 BAUER Foundation Corp. (BFC) performed deep foundation works for this project. The executed features of work include the installation of two walls. The first wall extends throughout the clay embankment into the underlying rock to provide encasement during the construction of the second wall. Its width of 7.4 feet makes it the widest diaphragm wall ever installed. The second wall is the actual seepage barrier and provides a continuous 2- feet wide wall. It extends through the first wall into the underlying rock and is up to 300 feet deep. The paper introduces the project, the requirements specified by United States Army Corps of Engineers (USACE) for encasement and barrier wall and the approaches taken by BFC. It discusses the ground conditions and describes the excavation equipment as well as the excavation methods used. A special focus is put on the steering capabilities of the hydrocutter equipment and the verticality performance.PROJECTBeginning in 2011, BFC was tasked by the USACE with the installation of a seepage barrier/cutoff wall at the Center Hill Dam Foundation Remediation project under a partially performance based specification. The remediation was necessary due to karst features in the foundation rocks and observed signs of distress, which led USACE to rate the dam with the most critical dam safety action classification (DSAC I). The executed features of work include the installation of two walls. The first wall, an encasement wall, extends vertically through the clay embankment and is embedded minimally into the underlying bedrock to provide embankment stability during the construction of the second wall, the barrier wall. The encasement wall is constructed of overlapping panels 7.4 feet (2.25 m) wide, which is the widest diaphragm wall ever installed, and up to 210 feet (64 m) deep. The second wall is the seepage barrier and provides a continuous 2 feet (0.6 m) wide wall consisting of overlapping panels. It extends through the encasement wall into the underlying bedrock and is up to 307 feet (93 m) deep. BAUER BC40 and BC50 hydrocutters mounted on MC96 and MC128 foundation cranes were used to perform the majority of the works (Figure 1). Excavations were performed under bentonite slurry (encasement wall) and water (barrier wall) and concrete was poured with the tremie method. Adding to the challenges, the project had to be executed in an environmentally sensitive area. Based on the high risk, a special focus was put on monitoring, quality control and geometric accuracy. The WallTracker information management system was used to share all relevant data between BFC and USACE (Roff et al. 2014)."

Jan 1, 2017

By L. G. Billington

"The Agnew nickel deposit occurs in a major linear greenstone belt in the Archaean Eastern Goldfields Province of Western Australia, and has been subjected to mid-amphibolite facies nietamorphism of dynamic style. The largest dunitic ultramafic body in the Perseverance Block is host to the bulk of the nickel mineralization. The Perseverance Ultramafic is mineralogically zoned and has an embayed western margin against a mixed metasedimentarv-metavolcanic wallrock sequence.Three categories of nickel sulphide mineralization are concentrated on this western margin at the thickest part of the ultramafic exposure. Massive sulphides characteristically occur as contact mineralization, internal mineralization and as remobilized concentrations in vein form structures. Disseminated ore constitutes the largest volume of mineralized materials in the deposit and occurs in three separate shoots in en-echelon relation. Weakly mineralized 'cloud sulphide' zones surround and envelop the shoots and persist much further along strike. In the upper mine levels the shoots are truncated by a shear or crush zone, which inhibits geological knowledge to the south but marks a major fundamental structural break.Most of the ore types have suffered supergene alteration and there is a complex variable distribution of the mineralogical facies. The ore types have been metamorphically retextured, but the oreshoots can be characterized by their Ni tenor and some chemical ratios. S/Se values, PGF. and precious metal values are distinctly different from those of other nickel sulphide ores extracted.Despite intense structural and metamorphic modification of the mineralizations, some features support an original magmatic derivation for the sulphides. These include the localization of massive sulphide ore types on one marginal contact within an emhayment structure, the general distribution of disseminated mineralizations located immediately above the massive sulphides and the Ni/Cu, Ni/Co, Fe/Ni ratios of the oreshoots being similar to those of deposits that typify the intrusive dunite- associated class of nickel sulphide deposit. Varying S/Ni ratios between different shoots suggest a revision of the single magmatic intrusion model in favour of a changing composition between successive magmatic episodes."

Jan 1, 1984

By F. Calizaya

The Western Mining Training and Translation Center is a consortium of four universities devoted to developing educational and training projects to reduce the incidence/accident rates in the mining industry. The center consists of Missouri University of Science and Technology, Montana Tech, the Colorado School of Mines and the University of Utah. It is fully funded by the National Institute for Occupational Safety and Health (NIOSH). The center manages 15 educational projects and one translation project. Hazard Identification and Risk Assessment (HIRA) for Small Mines is an educational project managed by the University of Utah. The objectives of this project are to identify critical mine hazards, assess risks; outline procedures to reduce accident/incident rates in small mines in the western United States and to train mine workers and super-visors on HIRA in each participating mine. To accomplish these objectives, the HIRA personnel visited 15 small mines in Utah, Colorado, Nevada and California. At these mines, most operators were employing independent contractors to perform several tasks ranging from drilling, blasting and mucking of rock at the work site to hauling ore to a processing plant. The operation of diesel-powered equipment was one of the major tasks performed by the contractors. This article presents three case studies in which contract workers performed a number of tasks with no reportable incidents but did so unsafely. It also highlights the training received by most contractors, the constraints imposed upon them and the safety hazards to which they are exposed most frequently.

Jan 1, 2008

By Carolina Passanante

Aços Inoxidáveis Supermartensíticos surgiram na indústria petroquímica como um material alternativo para confecção de dutos, devido principalmente ao sinergismo de suas propriedades mecânicas e de corrosão. Com esta nova demanda, tornou-se necessária a caracterização deste material em suas diversas propriedades, destacando-se neste trabalho o efeito da microestrutura na resistência à corrosão. Objetivou-se, portanto, o estudo da resistência à corrosão por pite de um aço inoxidável supermartensítico 13Cr-5Ni-2Mo-Nb em função da fração volumétrica de ferrita-delta (d) presente na microestrutura. A variação da ferrita-delta foi alcançada através de tratamentos de recozimento, a 1.050°C, durante diferentes tempos (de 0,5h a 48h). As amostras foram submetidas a ensaios de polarização potenciodinâmica em eletrólito contendo 3,5% NaCl, naturalmente aerado. Quantificou-se, ainda, a porcentagem de ferrita em cada uma das condições através de ataque eletrolítico com solução 20% NaOH. Os resultados obtidos evidenciaram a diminuição desta fase com o aumento do tempo de recozimento, chegando praticamente à sua eliminação com tratamento de 48h. Paralelamente, a resistência à corrosão por pite deste aço foi melhorada de modo proporcional à diminuição da fase ferrita, resultando em um aumento de aproximadamente 115 mV da pior para a melhor condição, comprovando que, de fato, a presença de ferrita-delta prejudica as propriedades de resistência à corrosão localizada.

Aug 7, 2018

By B. P. Faulkner, M. Weinecke

Svedala started a development program in 1997 to develop a process to convert waste tires into valuable commodities. A review of numerous approaches revealed short-comings in the various approaches either process, mechanical, combination of factors, or trying to emphasis the production of low value products. A market study revealed that a process that could produce a good grade of carbon black would be economically feasible. This paper discusses the laboratory and pilot plant development and commercial plant design.

Jan 1, 2001

By Gislan William Guimarães

Neste trabalho avaliou-se o efeito de diferentes ciclos térmicos na microestrutura e propriedades mecânicas de um aço Dual Phase revestido por imersão a quente, da classe de resistência de 800 MPa, a partir de simulações em escala piloto no equipamento HDPS (Hot Dip Process Simulator), ensaios dilatométricos, tração à temperatura ambiente e flangeamento. Nas simulações de recozimento contínuo foram experimentadas duas temperaturas de encharque no recozimento intercrítico (740°C e 780°C) e três temperaturas de patamar isotérmico no resfriamento rápido (610°C, 560°C e 510°C). A caracterização microestrutural evidenciou que a temperatura de encharque de 740°C não foi suficiente para dissolução completa dos carbonetos formados na laminação a quente, resultando em frações reduzidas de segundo constituinte. Com isso, o limite de resistência mínimo de 800 MPa não foi alcançado. Além disso, os resultados de ductilidade e flangeamento se mostraram aquém dos obtidos nas simulações com encharque a 780°C. Nas simulações com temperatura de encharque a 780°C e isotérmicas de 510°C e 560°C no resfriamento rápido foi atendido o limite de resistência mínimo, com capacidade de expansão de furo ligeiramente superior à obtida nas simulações com encharque a 740°C.

Aug 16, 2017

By M. F. Trice

PYROPHYLLITE is a hydrous aluminum silicate (A12Si4010(OH)2)1 that occurs in both the foliated and the massive forms. The foliated variety resembles talc in that it has a greasy feel, a pearly luster, perfect basal cleavage, and usually is white, although in some deposits apple green, gray, brown, russet, and nearly black specimens may be found. The massive deposits of pyrophyllite yield pearl gray to light tan aggregates, some of which are so friable that they may be crushed with the hands into a fine gritty powder. Frequently specimens of the massive variety are studded with crystals of radial structure. The mineral has a specific gravity of about 2.7 and a hardness of 1 on Mobs' scale.1 The chemical composition of commercial pyrophyllite reflects the mineralogy of the deposits, which, according to Stuckey,2 contain pyro-phyllite and quartz, together with chloritoid, sericite, and a few other minerals of negligible importance. The latter, he says, "are noticed in but small quantities to the extent they might occur as accessory constitu-ents of an igneous rock or as products of regional metamorphism or weathering. . . . Quartz is abundant everywhere except in the very best grades of pyrophyllite." Analyses of specimens from several deposits are listed in Table 1, showing that the silica content varies from 57 to 73 percent and the alumina from 22 to 33 percent. Oxides of iron and the alkaline metals are collectively present, with one exception, to an extent of about 1 to 1.5 per cent.

Jan 1, 1940

By Carolina Person Maschio

Pelotas compostas de minério de ferro, aglomerante e coque foram analisadas quanto à resistência à compressão (a frio e após aqueciemento) e porosidade. Para isso, três lotes de pelotas foram confeccionados, com diferentes teores de redutor, até a quantidade necessária para reação completa com os óxidos de ferro. Após seu preparo, as pelotas passaram por diferentes tempos de cura ao ar. Ensaios de resistência à compressão à frio e porosidade foram realizados em pelotas verdes e com 3, 7, 14, 21 e 28 dias de cura. Após 28 dias, uma série de pelotas foram secas e submetidas a testes de resistência à compressão após serem aquecidas a temperaturas entre 200ºC a 900º. Analisou-se, também, a perda de massa em cada patamar de temperatura. Entre os principais resultados, verificou-se que o comportamento mecânico de pelotas autorredutoras é melhorado com o aumento do tempo de cura e prejudicado pelo aumento do teor de coque e aumento da temperatura. Após 600ºC, a resistência das pelotas cai potencialmente. Além disso, lotes com maiores teores de coque apresentaram maiores valores de porosidade, sendo que este aumento foi mais significativo nos primeiros dias de cura.

Oct 30, 2017

By J. O. Marsden

Over the past eight years, Phelps Dodge (a subsidiary of Freeport-McMoRan Copper & Gold, Inc.) devoted a significant amount of effort to the development of a suite of processes for the effective hydrometallurgical treatment of copper sulfide concentrates. This effort resulted in the development of high-temperature (>200ºC) and medium-temperature (150° to 165ºC) pressure leaching processes. Specific configurations of both processes have been commercially demonstrated at Phelps Dodge?s facility in Bagdad, Arizona. This paper reviews in detail the chemistry of medium-temperature pressure leaching of copper concentrates and reports on the process development work conducted by Phelps Dodge and others for this technology. This paper is Part I of a four-part series on this technology. Part II covers the development of medium-temperature pressure leaching and direct electrowinning technology; Part III considers the large-scale demonstration of the MT-DEW-SX process at Bagdad, Arizona; and Part IV addresses the development and design of a full-scale commercial application at Morenci, Arizona.

Jan 1, 2007