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By G. Adachi, K. Machida, T. Ozaki, K. Murase

The chlorination rate with CCl4 was unexpectedly slower than carbochlorination using chlorine under the same reaction conditions. Chlorination with CCl4 was topochemical and the amount of monazite reacted after different periods suggested that the kinetic control step was the reaction between CCl4 and the monazite core at the interface. The kinetic order of the reaction was 0.5. The presence of a complex former, AlCl3, promoted the chemical vapour transport of rare-earth chlorides as complexes

Jun 18, 1905

By M. Kanefsky

Two channel polarity coincidence and polarity difference statistics are analyzed. The signal, common to both channels, consists of sinusoidal bursts where the exact frequency of the signal is nearly known, but other parameters such as amplitude, phase, and pulse starting time are unknown. The noise inputs are dependent, narrow band, Markov processes. It is shown that the performance depends not only on the signal uncertainties, but on the precise shape of the cross-correlation functions between the noise in-puts. By using two polairty difference statistics in addition to the polarity coincidence statistic, it is shown that the decrease in performance, as well as the cost of hard limiting due to correlated inputs, can be made small.

Jan 1, 1981

By Daryl E. Radcliffe

Ninety-seven roof bolts were instrumented with strain gages and resin-grouted in three areas of the Bear coal mine, Somerset, Colo., by the Bureau of Mines. Measurements taken with these instruments indicate roof support is achieved through a combination of point suspension and resistance to vertical and horizontal stresses caused by localized shearing in the roof. The localized shearing results in bending of the bolts, yielding due to high vertical stresses, and the transfer of high loads to the bolt head or plate.

Jan 1, 1980

By L. Yuan, A. C. Smith

To provide insights for the optimization of ventilation systems for U.S. underground coal mines facing both methane control and spontaneous combustion issues, a computational fluid dynamics (CFD) study was conducted to model the potential for spontaneous heating in longwall gob areas. A two longwall panel district using a bleeder ventilation system with a stationary longwall face was simulated. The permeability and porosity profiles for the longwall gob were generated from a geotechnical model and were used as inputs for the CFD modeling. In this study, the effect of methane emissions from the mined coal seam, including the longwall face and overlying rider seam reservoirs on the gob gas distribution was considered. The spontaneous heating is modeled as the low-temperature oxidation of coal in the gob using kinetic data obtained from previous laboratory-scale spontaneous-combustion studies. Unsteady state simulations were conducted, and the effects of the coal’s apparent activation energy and reaction surface area on the spontaneous heating process were also examined.1

By R A. Lynch

The state-of-the-art in cave seismic monitoring is reviewed, with the latest developments in active seismic monitoring included. Seismic monitoring systems are routinely used by most of the world’s block and panel caving mines to track the cave initiation and progression. The current best practice is to use the cloud of seismic event locations as a proxy for cave growth somewhere below. Problems with event location reliability due to seismic ray bending around the (unknown) cave are side-stepped by using sensors installed above the cave. However, the aseismic gap – the (unknown) distance between actual cave back and seismic event cloud – currently hinders reliable estimation of cave geometry.Velocity inversions using the passive seismic data are inexpensive and should be undertaken more routinely. The straight-ray methods should be used with caution, as the underlying assumptions are invalid in caving environments. The double-difference method is more correct for the caving situation, and there have been some promising results published. Constrained geometric inversions make a lot of sense, but have yet to be demonstrated successfully.Two active seismic source have recently been developed for use in the caving environment: a piezoelectric source for ranges up to a few hundred metres and a pneumatically-powered source for ranges up to a kilometre. These sources produce signals on standard mine seismic sensors that can be used to measure seismic velocity variations down to 0.01 per cent resolution. This allows the cave progression to be monitored by measuring tiny changes to seismic velocities as the rock above the cave is fractured and destressed.CITATION:Lynch, R A, 2016. Active and passive seismic monitoring of cave front evolution, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 217–224 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By J. H. Howard

The purposes of this report are to summarize the findings of the Committee on the Challenges of Modern Society Non-electrical Project (a working committee of the North Atlantic Treaty Organization) and also, thereby, to provide an introduction and review of the current situation regarding non-electrical applications to those who are interested in the subject.

Jan 1, 1975

By Ken-ichi Machida

"Surface modification of R-Fe-N intermetallic compounds was made to improve their magnetic property and nitrogenabsorbing ability, arid high-performance resin-bonded magnets and nitrogen storage materials were developed: Surface coating for Sm2Fe11Nx by the zinc metal produced via photodecomposition of Zn(C2Hs)2 was effective to avoid the further oxidation in the molding process of the fine powders for bonded magnets and the resulting (BH)max values were improved to -186 kJm-3. Meanwhile, R2Fe17 as the mother compounds for RzFe11Nx was highly active for decomposition of NH3 molecule and subsequent nitrogen absorption as metal nitrides. Furthermore, even inert Nz molecule was dissociated on them by impregnating Ru metal and the resulting nitrogen atoms were absorbed in the crystal lattice of R2Fe17. These results demonstrated that the nitrogen storage system was established by cycling the nitrogenation and hydrogenation of RzFe11/R2Fe11Nx materials.IntroductionProcessing for rare earth metals and intermetallic compounds requires well-controlled conditions in order to avoid the oxygen contamination involved in it due to their high reactivity, as causes the serious damage for materials such as magnets, metal hydride for hydrogen storage, and so on. Rare earth-iron intermetallic compounds, R2Fe17, provide the corresponding metal nitrides (R2Fe11Nx) by heating in N2 or a mixed gas stream ofNH3-H2 [l] and, among them, Sm2Fe11N3 has been particularly noted as one of the promising materials for high-performance permanent magnets such as bonded ones [2- 6]. Usually, the nitrogenation for Sm2Fe17 is made in Nz, but it needs the much more hard conditions of reaction pressure (-10 MPa), temperature (-550°C) and time (-72 h) than the nitrogenation in the NH3-H2 mixture [l]. In the latter case, a significant amount of nitrogen can be interstitial introduced in· the R2Fe17 crystal lattice (x=-7) under the more moderate conditions than in N2 (at 0.1 MPa and -450°C for -3 h) [3-6] and then, in a similar manner as metal hydride systems [7], the excess nitrogen in RzFe1 7Nx (x>3) is reversibly desorbed by heating at a temperature around 500°C in Ar to form the RzFe11N3 compounds. This behavior of nitrogen absorption and desorption has a close relation to the sites for nitrogen in the crystal lattices."

Jan 1, 2000

By H. Kinilakodi

In 2008, the authors developed a methodology for assessing underground coal mines for high risk for major-hazard events. It focused on major hazard-related violations of safety standards associated with high-risk conditions. Later using a sample of 103 mines with 2008 and 2009 data, injury measures and MSHA citation data were combined into a Safe Performance Index (SPI). The SPI was used to assess the relative safety-related risk of mines, including by mine-size category. In this paper, comparisons are made of SPI-associated, normalized safety performance measures across mine-size categories, with emphasis on small-mine safety performances as compared to large and medium-sized mines.

Jan 1, 2011

By R. E. Wilmot

The problem of corrosion of reinforcement in concrete structures is internationally recognized and represents the single biggest expenditure in the preservation of steel reinforced concrete structures. While the corrosion protection of the reinforcing steel is no substitute for design and the placement of good quality concrete, it does provide for a viable and economical extension of structural integrity and service life in the day-to-day and practical environment in which concrete structures are constructed. The mechanism of corrosion attack and consequent deterioration of reinforced concrete structures is well understood and documented. New structures can be designed and built to withstand corrosion. However, due to short-term economic restraints, many new reinforced concrete structures continue to suffer as a result of corrosion damage, which results from the corrosion of the steel reinforcing. This paper explores the economic and practical benefits offered by the application of hot dip galvanizing as a viable means of protecting reinforcing steel concrete structures. The paper also discusses technical misconceptions that exist about application and performance provided by the use of hot dip galvanized reinforcing steel.

Jan 1, 2007

By I. Ciabatti

Inorganic salts of hexavalent iron (ferrate (VI)) are versatile reagents for water and industrial effluent treatment because of the strong oxidising effect of the ferrate ion (FeO42-) and the well-known coagulation properties of the resulting ferric ion. Among other applications, ferrate can effectively remove arsenic, cyanide and phenols from industrial effluents. Furthermore, ferrate salts can be prepared from ferrous sulphate, a common byproduct of the steel and titanium industries, and possibly from other iron wastes. Notwithstanding their many potential advantages, the industrial-scale application of ferrate salts, such as potassium ferrate (K2FeO4), for effluent treatment has been hindered by the difficulties inherent in their synthesis and stabilisation. Within a project co-funded by the European Commission, the large-scale synthesis of stabilised potassium ferrate was realised through a new synthesis process, and different applications of the resulting ferrate to effluent and wastewater treatment are under investigation. This paper reports the results of the application of stabilised potassium ferrate for the purification of textile effluents. Laboratory and pilot-scale tests were carried out and the performance of the ferrate was compared to that of chemicals currently used in wastewater treatment. According to these experiments, potassium ferrate is a promising reagent for an effective treatment of textile and other industrial effluents.

Jan 1, 2006

By M. F. Corcoran

Rapid advances have been made in the past few years in the application of automatic controls and instrumentation to iron ore pelletizing plants. Present practice in applying instrumentation and control to the Grate-Kiln system of iron ore pelletizing is described. Major control points and loops are tabulated. Future trends in the application of digital control including computer data logging systems are described.

Jan 1, 1965

By Charles R. Simcoe

The stress-strain curves in the microyield region for various Fe-C solid solutions shown by Davies and Ku are typical examples of parabolic curves defined by the expression a = kEn 111 These data, when replotted on log-log coordinates, as shown in Fig. 9, exhibit three essentially parallel straight lines. It is apparent that carbon increases the flow stresses, but does not affect the exponent n. In other words, the only factor in Eq. [1] affected by in in carbon content is the constant k. As Eq. [1] is written k is the stress at a strain of 1.0. This is unsatisfactory for examining data in the microyield region. Therefore, the equation can be altered to the form: to permit the use of the authors' microyield stress at a strain of 10-6 as k. Extrapolating the curves in Fig. 9 to a strain of 10-6 gives stress values of 2000, 3200, and 5400 psi for 0.008, 0.014, and 0.02 pct C, respectively. These values do not agree exactly with the authors' measured values, but this will not affect the following discussion. The effect of carbon content on the slopes of the stress-strain curves shown in Fig. 2 of the paper by Davies and Ku can be analyzed by differentiating Eq. [2] with respect to strain. Thus: where n is always less than 1.0. Since n is essen- tially constant as a function of carbon content for the data under discussion, the slopes of the stress-strain curves depend only on k and E. If the slopes are examined at various selected Plastic strains. i.e., 10-6, 10-5, and so forth, it follows from Eq. [3] that the dif-ferent slopes for the different carbon contents depend only on the different values of ke=10-6. Thus, the larger ke=10-6, the steeper the linear stress-strain curve will rise with increasing plastic strain. This

Jan 1, 1969

A method is presented for calculating the number of cycles of stress to failure of a drill rod from operating variables; a mathematical analysis by Cooper of the stresses present in drill steels is applied to the forged collar, i1i-in. hexagonal hollow drill steel in common use in Australia; and an estimation is made of the dry fatigue limits at various points along a drill rod.It is shown that these calculations predict failure at a 'point where failure rarely occurs, and do not predict that failure should occur where it does in practice. The reasons for this anomaly lie in the neglect of bending stresses in the stress calculations, and in failuredue to corrosion fatigue at a preferred section rather than to simpler fatigue under non-corrosive conditions.INTRODUCTIONIt has long been recognized that failure of metal sections by fatigue is influenced both by the number of cycles of stress imparted to the section (N) and by the magnitude of this cyclic stress (8). In this paper, both Nand Shave been calculated for rods which have failed in service, and whose operating history is known. While the calculation of the number of cycles to failure is·simple, the calculation of stress is more complex. The results of stress caIculations predict that failure should occur only hi short rods, and then preferentially at the tip end rather than the shank end.However, in actual fatigue failures of steel rock drill rods, approximately 75 per cent. of such failures are close to the shank end, and failures near the tip end are rare.The usual explanation given for this high incidence of shank-end failures is that at the point of failure there exists, in forged collar steels of the type common in Australia "hardness valley" or. "m'etallurgical notch". This narrow valley in hardness is a weakness, and failure is expected to occur at the weakest point at the bottom of...

Jan 1, 1955

By A. W. Khair, S. S. Peng

Discussion by J. Parker Gentlemen; Rainy day in Upper Michigan, a good time to catch up on reading. Am doing that, and have a couple of questions concerning the K and P paper on roof problems and supports. I wonder if the authors can enlighten me. The compressive strength of the coal was reported as 4.4 MPa (633 psi) and compressive stresses measured in the coal seam were reported at around 27.6 and 48.2 MPa(4000 and 7000psi ). Can such a soft coal actually contain such a high level of stress? Can it be measured as if the material were elastic, or does the coal behave plastically? Can that stress level be confirmed with hydraulic load cells? And if the coal is so soft, and if it is plastic, why is the stress field not hydrostatic'? The intact roofrock appears to be unusually strong, with compressive strength reported at around 145 MPa (21,000 psi), and some failures were noted as soon as the rock was exposed. Were tests run to find out how that rock responded to the addition of moisture, from sprays or from humid air? Did moisture weaken the rock? Did it cause the rock to expand quickly, thus to induce internal compressive stress? How can the near-vertical cutters, as shown in the photographs, be attributed to primarily horizontal stresses? Did the cutters follow any particular pattern in the development panels, which might be related to a particular stress pattern? For example, did they always appear alongside the stiffest pillar? Or always along the northwest rib? Was there any evidence of the pillars and entries "rotating" under the influence of differential horizontal stresses? How much did the entries and pillars rotate as the longwall face approached and passed? After rooffalls, did the openings assume shapes which would indicate a preferred shape in that stressfield and geology? Did crosscuts always survive without damage, as shown in the sketch?

Jan 1, 1992

By Jaeheon Lee, Junmo Ahn, Isabel F. Barton

"Newmont’s Mike prospect, currently undeveloped, is a blind Cu-Au(-Zn) deposit on the Carlin Trend, containing >8.5 M oz. Au, 1027 M lbs. Cu, and 809 M lbs. Zn as Carlin-type gold and polymetallic Cu-Zn minerals in Paleozoic lower-plate carbonates and shales. This project was undertaken 1) to examine the effectiveness of different lixiviants for leaching the Mike supergene Cu-Au ores via bottle roll tests, and 2) to determine what ore minerals resist dissolution in each leaching agent by comparing the mineralogy and chemistry of head and tail samples. Sulfuric and sulfurous acids were used to leach copper and cyanide was used to leach gold. Thiourea, glycine, and other lixiviants were used to leach both base metals and precious metal. QEMSCAN and SEM study of six samples of different ore types and grades indicate that the Au occurs as varieties of native gold, including auricupride and electrum. Major Cu minerals are native Cu, cuprite, malachite, chrysocolla, and conichalcite (Ca-Cu arsenate), with locally significant Cu in jarosite and goethite. Gangue mineralogy is dominated by quartz, sericite, chlorite, alunite, smectite and kaolinite, K-feldspar, and iron oxides (sensu lato). Results of bottle roll tests and leach residue mineralogy will be presented and discussed at the conference.INTRODUCTION Resource and Geologic Setting The Mike deposit is a large, blind Cu-Au(-Zn) deposit in the Maggie Creek district of the Carlin Trend of Nevada, USA, near the Gold Quarry mine (Figure 1). The mineral inventory, based on drilling, is 8.568 Moz. Au, 1027 M lbs. Cu, and 809 M lbs. Zn at average grades of 0.72 g/t Au, 0.34 wt% Cu, and 2.13 wt% Zn (inventory for a cone at $400/oz Au and $0.80/lb Cu by Norby and Orobona, 2002)."

Jan 1, 2017

By Francis C. Lincoln

"INTRODUCTION As part of a general investigation of the zinc-producing area of southwestern Wisconsin, the Bureau of Mines undertook a limited amount of exploratory drilling in the immediate vicinity of the New Dale Rundell mine, in the Mifflin District of Iowa County, Wisc.The work was carried out during the early part of 1945, at a time when all effort was being directed toward increasing production of metals important to the Nation's war program. Bureau of Mines engineers decided to conduct exploration at the New Dale Rundell mine after a preliminary study of available data showed a reasonable possibility of indicating an important deposit. Before the Bureau of Mines investigation, 50 holes had been drilled in the vicinity. Of this number, 18 encountered ore of minable grade. Subsequently the mine was developed and operated for a brief period; however, work was stopped before all of the ore disclosed by drilling had been mined. There appeared to be a correlation between the ore shown by the drilling in the New Dale Rundell mine and another disclosure some 1,500 feet to the northwest. The Bureau of Mines exploration was pinned to explore this possible correlation. Of the 7 holes drilled by the Bureau of Mines, 3 disclosed minable ore beyond the limits of previous drilling."

Aug 1, 1946

By D. W. Hayley

The rapid expansion of exploration drilling with anticipated production facilities for oil and gas in the Mackenzie Delta region of the Northwest Territories has created a demand for granular construction materials. This paper discusses the technique adopted and experience gained by the authors from several major resource evaluation programs in this remote area. The first part of the paper describes a methodology for deposit identification, logistics of helicopter and ground-based drilling operations and the sampling difficulties which are unique to permafrost: soils. The second part describes the exploitation of a large glaciofluvial deposit at YaYa Lake on Richards Island. Granular construction material is sparse in the delta region relative to projected demand. Exploitable sources of granular materials for aggregates or construction borrow are found in glaciofluvial deposits of Pleistocene age or in outcrops of Paleozoic bedrock. Glaciofluvial landforms can be located by reference to published surficial geology maps coupled with airphoto interpretation. Preliminary assessment of these features in a large region is most economically carried out during the summer months with a drill that is transportable by helicopter. Once prospective borrow pit sites are identified, a detailed ground-based winter drilling program must be undertaken to establish aggregate quality and quantity, and to provide information on natural features which could affect development. The glaciofluvial terrain has been highly modified by the formation of massive ground ice within the gravel deposits. This presents some unique pit development problems which are not encountered in a normal bedrock quarry operation.

Jan 1, 1977

By Reinhard Bott

The Companhia Mineira de Metais (Brazil) runs a Zn-recovery plant in Tres Marias, federal state Minas Gerais, Brazil. The Zn-production is about 65,000 t/a, This corresponds to a concentrate throughput of about 255,000 t/a with a Zncontent of about 29.5 % at an output of 85 %, The plant is run continuously 360 d/a and 24 h/d, respectively. From this it can be concluded that: Input: approx. 650 - 700 t/d ore-concentrate and approx. 29 t/h ore-concentrate, respectively.

Jan 1, 1990

By G S. Beros

In 2019 the Chinese Ministry of Ecology and Environment issued guidelines promoting the implementation of ultra-low emissions in the iron and steelmaking industry. These guidelines aim to drive improvements in air quality through the reduction of particulate matter (PM), sulfur dioxide (SO2) and nitrogen oxide (NOx). Secondly, it also represents an initial means to commence decarbonisation of the industry. The ultra-low emissions guidelines propose that well over 80 per cent of China’s production capacity will achieve these targets by 2025. In response, many sintering operations have implemented numerous improvements to the process that result in significant efficiency gains. Of note is the adoption of deep bed sintering where, with some modifications to equipment, the sintering bed depth is increased resulting in sizable reductions of SO2 and NOx emissions. This paper will also provide an overview of the requirements to introduce deep-bed sintering into an operation and highlight test work completed which quantifies the resultant reduction in emissions.

Nov 8, 2021

By Y. A. Attia, M. Elzeky

Thiobacillus ferrooxidans bacteria were used in this work to study the effect of bacterial adaptation on the bioleaching of three iron-bearing sulfide minerals, namely, pyrite, chalcopyrite and arsenopyrite. The change in the pH during the bioleaching process was observed and the mechanism of the bacterial action were discussed. It was found that bacterial adaptation prior to bioleaching, enhanced the degree of sulfide leaching by 2-4 folds over that of non-adapted bacteria. A1 so the bacterial activity was enhanced by 2-4.8 folds. The pH of leaching solutions was decreased by the increase in both adaptation period and bioleaching time. It was also concluded that the mechanisms of bioleaching of iron-bearing sulfide minerals involved both the direct and indirect bacterial action simultaneously.

Jan 1, 1989