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By Yuanming Pan, Brett Rogers, Baoquan Hu, Gary Yeo, Christine Austman

The nature and distribution of radiation-induced defects (RIDs) in quartz from the Maw Zone, a yttrium- and rare-earth-element-enriched sandstone breccia complex exhibiting intense hydrothermal alteration, have been investigated by electron paramagnetic resonance (EPR) spectroscopy. EPR spectra show that detrital quartz in sandstone, from five diamond drill holes intersecting the Maw Zone and one above the crest of the so-called Quartzite Ridge, contain only background-level RIDs, indicating that Ubearing fluids were absent in this area. However, close to the sandstone-basement unconformity, in hole WR-194 immediately west of the Quartzite Ridge, the concentration of RIDs in detrital quartz is significantly above background but at least an order of magnitude lower than those at the Key Lake and McArthur River deposits. Widespread drusy quartz at the Maw Zone, which signifies intense hydrothermal alteration, is associated with hematite-, sulfide- and carbonate-bearing mineral assemblages, which exhibit complex crosscutting relationships. EPR spectra of drusy quartz in all three types of mineral assemblages are low in RIDs as well, supporting the EPR evidence that fluids at the Maw Zone did not carry significant U. These EPR results suggest that, in spite of intense hydrothermal alteration and favorable structural geology, the Maw Zone is unlikely to host any significant U mineralization. Moreover, this study shows that the EPR technique is potentially a useful exploration tool, capable of determining whether individual alteration zones in the Athabasca Basin were associated with U-bearing fluids or not.

Jan 1, 2013

By Takashi Saito

Since early 1970?s skirt suction foundations (skirted foundation / bucket foundation) have been used as support for large fixed substructures or anchors for floating structures in offshore hydrocarbon development projects. In recent years skirt suction foundations are recognized as one of the solutions in foundations applicable to bridge substructures installed in waters, because skirt foundations have a wide variety of functions such as control of settlement during service life, less impact to environments during operation at installation site. This paper introduces general features of skirt suction foundations, and then discusses design practice of them for the application to bridge substructures, with reference to experiments in both laboratory and field.

Jan 1, 2013

By D. Norman, D. J. Hughes, R. Dashwood, I. McGregor, N. D. Raath

"This paper develops a methodology for predicting spot weld fractures in automotive boron steel grades, such that fracture modes can be predicted accurately in a vehicle or sub-assembly structure. To achieve this, it was necessary to understand the range of complex fracture modes observed in boron steel spot welds and how these are linked to the Heat Affected Zone (HAZ) microstructures and hardness distributions and residual stress.Material data for the HAZ was extracted by simulating the spot welding process using a Gleeble machine; achieving specific weld microstructure in a larger volume which was used in destructive testing. Neutron diffraction was employed to accurately characterize the post-weld residual stresses found inside the weld. The constitutive relations of specific areas in the HAZ where fracture is thought to occur is being incorporated into finite element software to improve fracture prediction of boron steel welds.IntroductionWith the drive for light-weighting and improving passenger safety, lighter and stronger materials are being continuously sought in the automotive industry. The application of boron steel in the Body-In-White (BIW) meets both these criteria by down-gauging thickness of the steel and increasing the strength. As an example, when applied to crash-relevant areas in cars, components have an ultimate tensile strength of 1500 MPa, minimum springback and reduced sheet thickness.To achieve high strength and low springback, boron steel components must be formed and hardened at the same time. This is typically achieved by austenitizing the steel around 900 °C and simultaneously quenching and forming, usually with a hydraulic press and tool-set. Trace amounts of boron, typically 0.005wt%, increase the hardenability of the steel dramatically. This is attributed to the grain boundary segregation of boron, which hinders the formation of ferrite during cooling and forces the transformation of austenite to martensite at high cooling rates, a minimum of25 °C/s."

Jan 1, 2013

By Douglas A. Anderson

Much progress has been made in understanding the forward process for blast vibration simulation: that is, how to create a resultant seismogram from an empirically determined seed waveform. What has not been successfully investigated to date is the reverse process: Determining the contribution of each borehole to the resultant seismogram. It might seem that these should be two sides of the same coin, but the reverse process is much more complicated. That is because the source, geological path, and receiver contributions must be unraveled and then dissected. If that can be done, a relationship can be developed between the seismic source properties and the explosive interaction with the surrounding rock. This paper presents a first step in the unraveling process, through analysis of blast seismograms using wavelet transforms.

Jan 1, 2013

By Joshua Hoffman, Philip Mulligan, Braden Lusk, Tristan Worsey

Blasters rely upon detonators to achieve the designed timing sequence to move material where it needs to go, minimize vibration, or optimize fragmentation. At times detonator inventory on seldom used delays may be slow moving. This can lead to detonators being used long after they were manufactured. This paper addresses the potential shelf life concern as it relates to timing accuracy of shock tube detonators. A recent study was conducted to study the timing accuracy of non electric shock tube detonator systems. A follow up study was then conducted to determine the degradation of the non electric shock tube systems accuracy with time. The follow up study is presented in this paper. Samples of detonators from the initial study were set aside for approximately one year and then tested. The results from the aged detonators were compared to those of the detonators that were tested in the original study. As an extreme case a third set of shock tube detonators was tested using detonators that were between eight and nine years old. The results from these tests are presented as well. Each system was tested at a short medium and long delay time. Statistical analysis was conducted to determine the effect of time on the detonators accuracy. This paper quantifies the importance of regular inventory cycling to help preserve manufactured timing when using non electric shock tube detonator systems.

Jan 1, 2013

By Sam X. Yao

The underwater concrete technology has historically evolved largely through a trial-and-error process of constructing marine works. Many outstanding examples exist of high quality concrete placed underwater. However, failures also occurred and led to excessive cost and/or schedule overruns. These failures were largely due to improper concrete mix design or improper placement. The problems may have occurred because proper underwater concrete construction techniques and experience have not been widely disseminated. This section focuses on technical issues of underwater concrete mix design, concrete production and placement, and quality control.

Jan 1, 2013

By F. Malek

An extensive blast monitoring program has been carried out to study explosive performance and the effectiveness of blast designs in production blasts in a deep underground mine. Comprehensive monitoring of blasting vibrations through multi-station high-capacity high-frequency accelerometers, and borehole deformation history have been the main tools of such analysis. The mining activity involves relatively unstressed stopes as well as highly stressed stopes. More than 30 production blasts have been monitored, and the respective vibrations from close-range as well as distant seismic stations have been analyzed, and the vibration parameters (amplitude and frequency) have been correlated with explosive charge weight in the holes. It is found that the correlation between blasting rounds and the corresponding vibration amplitudes often have poor correlation for a very significant portion of the blasts. These point to either explosive charge malfunction in those specific blast holes, or inadequate blast design, or the effect of high in-situ stresses, or any combination thereof. This paper analyzes these variables and their effect on the overall blasting operation at the mine.

Jan 1, 2013

By Jinqian Zhao, Jiarong Li, Shizhong Liu

"Creep cavitation of in single crystal (SX) superalloy was investigated. The constant load creep tests, in single crystal superalloys DD6, were conducted at the conditions of 800°C/700MPa, 850°C/550MPa and 900°C/450MPa, respectively. It was found that there were square facets on the stress fracture surface, and microscopic cavities in the ruptured specimens in the vicinity of the fracture surface. Both the square facets on the fracture surface and microscopic cavities in the section of the ruptured specimens show the morphology of the same thing at the different views, namely creep cavities, which are take the form of flatten cuboid. In fact, creep cavities are the longitudinally tensiled creep cracks slowly growing during the stress tensiling. The factors of creep cracks nucleation and growth conditions include: (a) enough high temperature to activate diffusion (b) casting pores as nucleation origination (c) high strains and strain rates. Eventually, the instantaneous fracture mechanism of creep specimen is cleavage fracture.IntroductionFor the materials used in elevated temperature service, creep behavior has to be accounted for. It is well recognized that creep rupture in polycrystalline materials at high temperature occurs principally by the nucleation and growth of microscopic cavities at grain boundaries, followed by microscopic cavities linkage to form micro- and eventually macro-intergranular cracks[l,2]. Without the usual grain boundaries, SX superalloys have superior capabilities at high temperatures to polycrystalline superalloys, and have become an established feature of gas turbine technology where they are commonly employed in the manufacture of high performance blades[3]. A considerable amount of work has been done over the past tens of years, and many models for nucleation and growth of creep cavities have been proposed, however, those are mainly for polycrystalline materials.In order to improve creep resistance that single crystal superalloys, in which grain boundaries are removed, have been developed. Because there don't exist grain boundaries in SX superalloy, the mechanism of nucleation and growth of creep cavities must be different from that in polycrystalline materials.Understanding the formation and characteristics of creep cavitation is crucial to model the lives of single crystal superalloys.M. Marchionni and L.G. Zhao et al. found that there were square facets on the stress fracture surface [4,5]. Roger C. Reed pointed out creep cavities lie in the necked region[6]. In this paper, the effects on the formation of creep cavities are discussed, as well as the morphology of creep cavities and fracture mechanism of SX superalloys."

Jan 1, 2013

By Takashi Sasaoka

A great deal of coal will be left under the final end-walls in Chinese surface coal mines because of lower slope angle in shoveltruck mining systems and larger mining depths. In traditional surface mining systems, the coal under the end-walls will be buried by the inner dumping site, and these coal resources are generally abandoned. Considering these situations, the application of end-wall mining systems was considered in order to recover the residual coal around the end-wall. This mining system can improve economic benefits by exploiting haulage and ventilation roadways from end-walls and utilizing the existing transportation systems. In order to develop the appropriate pillar design methodology for the end-wall mining system, several empirical formulas and methods were discussed based on the formulas developed so far and the mechanics properties of coal and rocks in the Chinese coal mine. From the results of a series of theoretical and numerical analyses, it can be concluded that the coal pillar width calculated by the Mark- Bieniawski formula may serve as an important reference for pillar design in end-wall mining systems, and the end-wall mining system can increase the coal recovery from residual coal resources around highwall and reduce the effect of underground mining operation on slope stability

Jan 1, 2013

By K. Lascelles

ABSTRACT Nickel compounds vary significantly in their toxicological properties, so it is critical that continuing studies to accurately quantify worker exposures consider the processing that accompanies refining nickel-containing materials. The Clydach nickel refinery, which has operated for more than 100 years, was the first nickel-producing facility to show a high risk for lung and nasal-sinus cancers among workers employed since it opened in 1902. Process chemistry and equipment have changed dramatically over Clydach’s history. This paper describes the processing evolution at Clydach with a focus on the propensity for aerosol formation and the forms of nickel in airborne dusts.

Jan 1, 2013

By Zach G. Agioutantis

The prediction of ground movements due to underground mining using the influence function method is a mature technology, widely used by researchers and planning engineers around the world. Surface strain, either tensile or compressive, is an important indicator of potential impacts on structures such as buildings, bodies of water, pipelines, railway and power lines, and tailings dams. Calculation of static or dynamic surface strains, for varying surface terrains and slopes, should be accurately predicted and be independent of the methodology applied for the calculation. This paper discusses and compares the development of horizontal and ground strains on the surface due to underground mining for different surface topologies (sloping terrain, monitoring lines, etc.) and presents the steps needed to ensure accurate calculations. Examples are given to demonstrate how ground strains can be calculated for one- and two-dimensional gridded surfaces.

Jan 1, 2013

By Andrea Francioso, Roberto Folchi

In order to comply with the latest European Highway Standards, the highway Salerno - Reggio Calabria, in southern Italy, had do be widened and upgraded to reduce its vulnerability to earthquakes. Reinforced concrete viaducts, no longer needed for the new road, had to be demolished. Many bridges still to be used for the highway required refurbishment due to 50 years of wind, frost and salt corrosion. This re-furbishment and new construction had to be carried out simultaneously. To keep the highway open dur-ing the renewal process, all traffic was directed to one side of the road. Demolition was conducted ex-tremely close to operational roadways and viaducts, as close as only 2 cm (0.8 in). Care had to be taken to ensure that the stresses (vibration levels), resulting from the demolished pylons and decks hitting the ground, were below the no-damage thresholds for the nearby acceptors (structures receiving the vibra-tion stresses). These structures included bridges, houses and buried pipelines (water, oil and gas). In some cases, care also had to be taken to preserve the existing pylons supporting decks that were being demolished; since the same pylons were going to be used for the new viaducts (bridges). New continu-ous decks in weathering steel replaced the old reinforced concrete decks.

Jan 1, 2013

By Marco Lombard, Paulus Kapolo, Christopher J. Greet

"The conversion of a concentrator from one grinding media type to another is a major undertaking in terms of both financial and technical risk. So, a strategy of completing sufficient laboratory and field tests to mitigate this risk, and give the operation confidence that advancing to plant trial will give a high probability for success.The objectives of this paper are twofold: to provide the reader with a strategy for mitigating risk prior to undertaking a plant trial; and to provide a statistical basis for analysing plant trial data. That is, when employing an electrochemically inert grinding media in the primary grinding circuit it is possible to change the pulp chemistry of the system and improve the metallurgical response of the ore.This paper tracks the changes in pulp chemistry and metallurgical performance of Rosh Pinah Zinc Corporation’s silver/lead/zinc concentrator as the primary ball mill was converted from forged steel grinding media to high chrome grinding media. The changed in metallurgical performance are correlated to the shift in pulp chemistry.INTRODUCTIONTheoryBruckard et al (2011) recently published an article describe the effect of the grinding environment on the flotation of copper sulphides. While this paper confined its discussion to copper sulphides the arguments presented apply equally to other sulphide mineral systems. Broadly, these studies indicate that most sulphide minerals are more noble than the grinding media used during comminution. Therefore, the sulphide minerals are cathodic with respect to the forged steel grinding media, and the following reactions apply:Cathode (sulphide mineral): ½O2 + H2O + 2e- ? 2OH- (1)Anode (grinding media): Fe ? Fe2+ + 2e- (2)A galvanic couple between the grinding media and the sulphide mineral(s) exists, which increases the corrosion rate of the forged steel media. The corrosion products of the grinding media, iron oxy-hydroxide species, invariably precipitate on to the surfaces of the sulphide minerals thereby affecting their floatability (Johnson, 2002).The application of more electrochemically inert grinding media to “real” ore systems at an industrial level to improve metallurgical performance has not gained universal acceptance. The aim of this paper is to provide a protocol for conducting laboratory and plant test work that clearly demonstrate that metallurgical benefits are not only possible, but measureable, by way of example. In this case, the work conducted at Rosh Pinah Zinc Corporation in Namibia is described."

Jan 1, 2013

By L. Shoke

The aim of this study was to develop an in-house tensile testing procedure that would yield accurate and reproducible parameters as input material properties into computational models for numerical simulations of the mechanical behaviour of TM380 mild steel. To achieve this objective, we reviewed the ISO 6892:2009 tensile testing standard along with reported good practice guidelines. Tensile tests were conducted on a dog-bone shaped TM380 mild steel specimen with strain gauges attached on either side, to monitor alignment and measure strain, using three different types of tensile testing machines. Parameters quantified included yield stress, ultimate tensile strength, and modulus of elasticity. The values of these parameters were found to be in agreement with the values supplied by the manufacturer's specification and showed minimal variations between laboratories. Thus it can be concluded that the tensile test procedure used resulted in accurate and reproducible results. The strain values calculated as per standard were in disagreement with those determined from extensometer and strain gauges and resulted in lower elastic modulus values. This confirms that the current testing procedures require the use of long-range strain gauges or extensometer to determine the strain. A chemical analysis was conducted to verify the specification by the manufacturer. The specimen was found to be fairly homogeneous with minor sulphide inclusions. The micrographs reveal a pearlite and ferrite structure typical of mild steel, and the fractographs show a dimpled surface typical of ductile fracture, which is an attribute of mild steel.

Jan 1, 2013

By Frank Schmidt

Due to changing geology, rib bolting is an ever-changing problem in ground control. With the economic status of the coal market, the need for safely increasing productivity in rib bolting is at an all-time high. The current solutions used in the market often require a long installation time (e.g. if collapsed holes have to be redrilled) or result in poor quality installations that can lead to insufficient ground control. A new bolting product based on the simple screw principle has been developed to bolt ribs faster and with a more repeatable, higher level of installation quality. The paper covers the product invention and development, the fastening principle and its advantages over current systems and first experiences in the market. The first underground trials have shown that the screw anchors can be installed safely and efficiently, often faster than traditional methods. The screw anchor does not suffer from conventional bolting issues such as collapsed holes due to bad ribs. The screw anchors are designed to obtain steel failure and load testing underground shows consistent fastening in all types of conditions.

Jan 1, 2013

By Marisa Di Sabatino, Michael Phan Knudson, Mari Juel, Eivind Øvrelid

"A p-type Czochralski silicon ingot doped with boron was characterized for resistivity, minority carrier lifetime, interstitial oxygen, and metallic impurities. Analyses show a peak in resistivity and a dip in lifetime both occur 5 cm from the top of the ingot crown. This peak in resistivity deviates from the expected trend based on Scheil's equation for boron distribution. High concentration of interstitial oxygen in this area suggests that other oxygen-related defects, such as thermal donors and precipitates, may also be present here, and the observed peak in resistivity and dip in lifetime could be attributed to such defects. The low lifetime of 15-30 µs at minority carrier density of 7.5 x 1014 cm-3 is likely due to copper contamination.IntroductionSolar energy resources vastly exceed all other alternative energy resources, ensuring that solar power must play a crucial role in the evolving energy market. The economic viability of solar power in competition with other energy resources depends upon finding efficient, cost-effective, reliable, and controlled methods for solar cell production. In this regard, minimizing waste (such as material with unsuitable electrical properties that hinder solar cell performance) is a vital component of making solar cell manufacturing cost-effective. Impurities affect electrical properties of solar cell silicon in different ways (i.e. [1, 2, 3, 4, 5, 6]). In this work we focus on the role of oxygen and metallic impurities. Understanding oxygen impurities in silicon is critical to solar cell development because oxygen has been attributed with influencing critical electrical properties including resistivity and minority carrier lifetime and thereby potentially hindering solar cell performance or rendering material unsuitable for solar cells.[1, 2] Furthermore, oxygen is a common impurity in the standard type of solar cell silicon, Czochralski (CZ) silicon, due to diffusion of oxygen from the silica crucible into the melt during crystallization. [7] This study investigates the effects oxygen impurities have on the electrical properties of p-type CZ silicon."

Jan 1, 2013

By Walter Voglauer

On May 14, 2011 a chimney blast took place in Vienna, Austria. The blasting operation was part of the demolition works at a former railway fabrication. The demolition works on this ground were done under the leadership of the Austrian construction and demolition company PORR. In agreement with the civil organizations which were involved, the commander of the Regional Military Command of Vienna, Brigadier general Dr. Karl SCHMIDSEDER ordered a reserve force engineer company to demolish the chimney. The concrete planning of the chimney blasting was done by specialist Markus SEWALD who belongs to the HEERESTRUPPENSCHULE (combined armed force school) of the Austrian armed forces.

Jan 1, 2013

By Jose Antonio Silva Souza, Emanuel Negrao Macedo, Iara Ferreira Santos, Otacilio Dias, Luis C. A. Venancio

"The Bayer process alumina production generates 0.7 to 2.0 ton of bauxite residue (BR) and an average of 1.0 ton of C02 per ton of alumina produced. The direct reaction of exhaust gases to reduce the alkalinity of the BR may allow a triple gain: improve the storage conditions, open a range of new applications for BR and sequester from 16 to 102 kg of C02 per ton of alumina. This paper shows the measurement of C02 captured during a pilot scale reaction of a suspension of BR in water with flue gas, produced from direct oil burning. Three different types of reactors were used: one spray tower and two packed columns. The inlet and exhaust gases were analyzed using electrochemical and non dispersive infrared sensors. The pH of the suspension was monitored during and after the reaction to evaluate the buffer effect.IntroductionAlumina is mainly produced from refining bauxite using the Bayer process. This process consists of extracting the aluminum oxide through its dissolution in caustic soda and the separation of insoluble residues. The remaining bauxite residue (BR) although not particularly toxic, poses risks to the environment due to the large volume and its reactivity. According to the latest technology it is stacked on sealed deposits specially constructed. To date the vast majority of the bauxite residue that has been produced was stored and were not incorporated into any existing production processes to significant amount with exception to some extent of the sintering process residue at Russia and China [l]. On the other hand, a strategic goal was set in 2010 by the Bauxite and Alumina Committee of the International Aluminium Institute (formed by the majority of the industries) to reuse 20% of BR in 2025 [2]. China has established the same objective for 2015[1].This paper is a sequel of two others presented at TMS 2010/2012 [3-4] and describes:• A pilot plant assembled for testing the carbonation process of BR with gaseous effluents similar of the refining process.• The methodology used to measure the amount of C02 captured during the carbonation process.• The results of the carbonation process, the C02 capture and the buffering effect of the pH.This process is studied in order to consume minimal power and use the effluent as efficiently as possible in different reactors from low cost to ultra high performance. The process is designed for minimizing the power consumption and equipment investment."

Jan 1, 2013

By Kyle A. Perry

Pillar design formulae have existed for decades, and the guidelines for design stability factors are generally accepted by regulatory agencies and broadly used within the coal industry. Nearly all design pillar formulae are based on geometrical parameters of pillars resulting from empirical investigations, with primary focus on the pillar width-to-height (W/H) ratio and associated shaping constants from regression. The most widely used modern pillar design formula in the coal industry, the Mark- Bieniawski equation, also adheres to this principle. Common practice when applying Mark-Bieniawski equation is to use a coal compressive strength of 900 psi. This reduces the design equation to sole dependence upon geometry. However, recent studies have shown that pillar strength is highly dependent on roof and floor properties, particularly the interfaces between the roof-pillar and pillar-floor. This study utilized numerical modeling using FLAC3D to evaluate the relative effects of varying roof and floor interface and mechanical properties. The results confirm that pillar strength is significantly influenced by the properties of the coal pillar interfaces with roof and floor. The mechanical properties of the roof and floor material have only a minor impact on pillar strength when compared with interface effects. These results were used to formulate design recommendations for existing pillar design methods.

Jan 1, 2013

By D. Yuan, L. Yan, M. J. Collins, P. Kalanchey, I. M. Masters

ABSTRACT Pressure oxidation tests have been conducted by Sherritt for a refractory gold-silver project in China. The feed contained 39 g/t Au and 970 g/t Ag; the major gold-bearing minerals were pyrite and arsenopyrite. Because the feed contained a significant amount of silver, which can be refractory to cyanide leaching after pressure oxidation due to the formation of argentojarosite, the test program included investigation of methods to enhance silver recovery. The “lime boil” process proved successful and was incorporated into the flowsheet. Gold extraction from the lime boil product solids was 95–98%; silver extraction was up to 94%.

Jan 1, 2013