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Almost from the beginning of civilisation the inhabitants hadlearned the art of recovering and working copper to produceitems which were of use to society.From the early beginnings of the use of copper which can betraced back 6000 years and more, there has been an evolutionaryprocess accentuated in more recent times in which the art ofproducing alloys particularly with tin and latterly zinc and otherelements, has given society a wide range of useful alloys for usein industrial, domestic and architectural applications.

Jan 1, 1995

By Daniel S. Gwinner

The tolling, or processing for a fixed fee, of aluminum drosses to recover the metal units is a common practice in the Aluminum Industry. The Dross Toller is acting for the owner, and since most dross processes result in material going to landfill, it is important for the owner of the dross to insure that the toiler is processing the material and handling waste disposal in an environmentally responsible manner. The paper discusses the Dross Toiler Audit Program, first from the Reynolds Metals Company perspective. Included are the reasons the company deems it necessary to audit and a description of the items covered during the audit. Finally, there will be a discussion of the audit from the Tollers perspective - what the Toiler can expect when the auditor arrives.

Jan 1, 1995

By M. R. Yalamanchili

The in-situ FTIR/IRS technique has been used to spectroscopically characterize interfacial water near a hydrophilic surface. Interfacial water was examined spectroscopically over known distances from the surface of a silicon single crystal by appropriate design of the geometry and optics of the internal reflection system. The in-situ FTIR/IRS spectra of interfacial water were examined by consideration of the 0 -H stretching region (3000 -3800 cm-1) associated with the vibrational spectra of water. The broad peak: in this region which describes the interfacial water structure was deconvoluted in order to isolate the overlapping spectral features of the interfacial water. Preliminary spectral results indicate the prevalence of an ice-like water structure (-3200 cm-!) at the silicon surface. Importantly, it appears that the interfacial water structure may extend a considerable distance (several tens of molecular layers) from the surface as established from the spectroscopic depth profile measurements which show that the free OH stretch at 3600 cm-1 becomes very significant at distances from the surface exceeding 400 nm.

Jan 1, 1995

By D. A. Meyer

The long and arduous process of bringing aggregate produced in Mexico to the Gulf Coast of the United States really began in the 1970s when the first exploratory trips were taken by Vulcan's geologists. It was not until the middle of the 1980s that all of the elements of the project seemed favorable and the largest capital investment in Vulcan's history was given the green light. The history of the project will be covered along with a discussion of the role that market forecasting played in the process. Is this the first of many or a once in a lifetime project? In July 1987, Vulcan and its joint venture partner broke ground in Mexico for a world-class limestone quarry and crushed stone production facility. This project is the largest ever undertaken by Vulcan's Construction Materials Group, with a total cost of over 200 million dollars -a cost shared equally by Vulcan and its joint venture partner, Ingenieros Civiles Associados, or ICA, a diversified Mexican company which is also the largest construction firm in Latin America.

Jan 1, 1995

By Alan G. Galley

"Advances in our knowledge of the petrochemical attributes of deposit environments and of the character and extent of hydrothermal systems associated with certain deposit types has resulted in increased application of lithogeochemistry to exploration programs. Lithogeochemistry can be used to vector an exploration program toward an area of high potential through the use of a series of collapsing scales of analysis from a tectonic subprovince down to a particular stratigraphic segment. In the case of volcanogenic massive sulphide (VMS) deposits this involves the recognition ofsuitable volcanic domains, and the identification of subvolcanic intrusions and cogenetic felsic extrusive complexes. The recognition of chemical vectors within regional-scale alteration zones and associated chemical sedimentary rocks allows the geologist to identify the stratigraphic units with the most potential for hosting a base metal deposit.An integrated lithogeochemical program requires the judicious use of major, trace and rare-earth element and isotopic analysis. Standard discriminant plots may be employed to identify suitable tectonic and lithologic environments. Analysis of the chemical and mineralogical variations in broad-scale, semi-comfortable alteration zones provides a useful set of vectors to VMS mineralization. These may include contouring raw data, element ratios on XY plots, normalizing data against known rock values, or calculating mass changes in alteration zones."

Jan 1, 1995

By J. E. Dutrizac

A mineralogical study of a weak acid leach residue from the Clarksville zinc plant of Savage Zinc Inc. was carried out. The study focused on Pb and Cd as these elements most significantly impact on the environmentally acceptable disposal of the residue. The residue consists of major amounts of bassanite, zinc ferrite and various Zn-Pb-Fe-Cd silicate species. Also present are lesser quantities of PbSO4, sphalerite, Fe2O3 quartz, Mn-Pb-Fe oxides, SrS04, (Pb,Sr)SO4 iron gel-silica gel, jarosite and Ti oxide. The principal Cd carriers are the zinc ferrite, which contains up to 9.00% Cd and likely accounts for -45% of the total Cd content of the residue, and the various silicate species which contain up to 6.97% Cd and account for about 45 % of the total Cd. The sphalerite is a minor Cd carrier containing an average of 0.35 % Cd and accounting for -5 % of the total Cd; the other carriers contribute only trace amounts to the total Cd content. The major Pb carriers are PbS04, Pb-bearing silicates and Mn-Pb-Fe oxides. Minor proportions of the total 1.09% Pb content of the residue are carried by SrS04 and (pb,Sr)S04' Trace Ph carriers include the iron gel-silica gel, Fe-Zn-AI oxide and bassanite. The residue after the toxicity characteristic leaching procedure (TCLP) is mineralogically very similar to the initial weak acid leach residue; the amounts of calcium sulphate are approximately the same in the two products. The principal Cd and Pb carriers are also the same as those noted in the initial residue, except that some dissolution and reprecipitation of Pb-Sr sulphate takes place. That the residue fails the TCLP test is likely a consequence of the superficial dissolution of Pb and Cd from species such as PbS04 or Zn-Pb-Fe-Cd silicate.

Jan 1, 1995

By Faustino G. Prado

In the, quest for an economical and environmentally friendly reclamation of metallurgical dusts generated during pyrometallurgical operations, our goal has been the separation and recovery of most of the components, as well as the complete recycle of all the reagents. Effluents have been avoided, within acceptable economic parameters. This presentation, which can be applied to a large spectrum of dusts and other residual-materials-, has focused on the dusts generated by the operation of Secondary Copper Smelters. Those dusts show a wide range of components, including zinc, lead-, copper, cadmium, tin, chlorine and-alkalies. Our present work deals with the use of ammonium salts in the separation and recovery of-the above mentioned elements in a marketable form. Most of the chemistry and techniques involved have teen already confirmed in commercial scale operations. Others have gone through pilot scale tests or bench scale tests. The recycle of reagents has also been- confirmed at the same operating levels. A preliminary evaluation indicates that the chosen route, in addition to a viable economy, offers a complete and safe reclamation within the most strict environmental regulations.

Jan 1, 1995

By Kaby K. Kabongo

The paper is drawn from a project intended to explore a technique of prediction, control and optimization of fracture in coal induced by blasting. It evaluates the fines generated in coal submitted to dynamic loading stresses in an impact stamp mortar. The aim is to analyze a complex phenomenon of coal response to blast-generated stresses from a series of discrete simulations of shock and gas actions in controllable processes.

Jan 1, 1995

By Greg Hendon

Longwall developments in the UK have historically consisted of single entry gate roads. Adjacent developments were separated from existing panels by large barrier pillars (designed of sufficient width to get away from the longwall abutments of the previous panel) or by small barriers driven in the shadow, or de-stressed zone, of the previous panel. Some 2nd panel tailgates were also driven skin to skin leaving no coal barrier between the newly driven entry and the heavily supported existing gateroad. With the developement and wide acceptance of fully bolted entries and the pressure to reduce production costs, alternatives to single entry drivage, particularly yield pillar developments, were examined. Through the Rock Mechanics Branch of British Coal, a cooperative study was begun with Jim Walter Resources, Inc., USA, (JWR) to look at the yield pillar alternative in detail. This study was to determine the feasibility of utilizing yield pillars in the UK and to determine, through monitoring, the possibility of reducing stable pillar widths at JWR. The study has included extensive monitoring of the yield-stable-yield pillar system at JWR No. 7 Mine and an underground trial of a two entry yield pillar test area at Welbeck Colliery in the UK. This paper describes results from the JWR study and the subsequent results of the first advancing yield pillar development in the UK at Welbeck Colliery.

Jan 1, 1995

The sedimentary basins of this region developed in the collision zone of thePacific Ocean plate and the continent. Stresses were transmitted thorough wedge-like lithospheric blocks, such as the Okotsk Sea, East Kamchatka, Aleutian and other smaller blocks. Compression and inversion were more active at the boundaries: ***INSERT EQ*** and ***INSERT EQ*** in places. Tension, rifting and the increase in the rate of sedimentation were marked in P1-2, P3, N12, and also in N2 û Q in places. Structural plan changes of the sedimentary basins and possible oil, gas and fluid migration occurred more actively at the boundaries: ***INSERT EQ***.

Jan 1, 1995

By C Ross

This paper uses the results of research trials by Landcare Research and Forest Research Institute and assessments of reclamation plantings at mines and other drastically disturbed sites to describe methods of enhancing restoration of native forests. The characteristics of mine and forest environments are compared to highlight the difficulties facing restoration and techniques which result in successful restoration are described. Selection of the most appropriate technique is illustrated by describing restoration of lowland beech-podocarp forest at a West Coast coal mine. The key to successful reclamation is to understand the factors controlling and limiting plant establishment and growth, then to design rooting media, surfaces and management regimes to create a favourable environment. This paper concludes with a summary of the planning and technical factors which are critical for successful restoration of native forest.

Jan 1, 1995

By S. M. Robinson

Wollastonite is recognized as one of the most unique, non-metallic minerals in the world. Its history for use in industrial applications is recent compared to other minerals, however, its distinctive physical properties, such as acicular particle shape, and alkaline pH creates incorporation possibilities ranging from bowling balls to automotive fascia, from ceramic tiles to automotive brakes, and from thermal insulation board to industrial and trade sale coatings. Its future use will be impacted by the exploitation of deposits which will ensure maintenance of the acicularity and purity of this naturally occurring mineral. Additionally, closely held surface treatment technology will open up additional niches requiring highly engineered performance.

Jan 1, 1995

By G J. Fleming

The Miwah prospect lies on the dilational 070¦ trending Miwah Lineament near its intersection with northerly oriented fractures within Pliocene volcanic rocks exposed between a NW trending segment of the dextral transcurrent Sumatra Fault, and the more northerly trending Samalanga-Sipopok Fault to the east. These faults reflect the continued interaction between stresses from the India-Australia plate located to the southwest, and spreading within theAndaman Sea to the north of Sumatra. A system of deep seated faults is believed to have facilitated emplacement of post-Miocene magmas and Quaternary volcanic centres at shallow crustal levels throughout northern Sumatra. Miwah mineralisation is associated with variably dipping structurally and lithologically controlled argillic and advanced argillic alteration. An oxidised supergene leached zone and a recent, thin, unaltered tuff blanket partly overlie the mineralisation. Mineralised zones are commonly brecciated and veined, and display quartz, quartz-alunite, quartz-alunite¦pyrophyllite¦kaolinite replacement assemblages, surrounded by more weakly mineralised, often vugghy quartzalunite¦pyrophyllite¦kaolinite advanced argillic, and argillic zones of quartz-kaolinite, quartz¦pyrophyllite¦kaolinite and smectite-illite-quartz. Propylitic assemblages are marginal to more intensely altered zones. Hypogene copper mineralisation is typified by enargite, luzonite, and covellite. The host mineral to gold is uncertain at present. Rare barite, native sulfur, and ?telluride also occur. Bornite and chalcopyrite have been observed in transported altered rocks in faults. Generally the mineralisation is anomalous in precious metals, locally enriched in Cu, erratic in Pb, and depleted in Zn, with a good correlation between Cu-As-Ag.

Jan 1, 1995

Industry and regulatory agencies have requested guidance on safe blasting near transmission pipelines. The US Bureau of Mines (USBM) and Amax Coal Co. studied surface coal mine overburden blasting near four steel and one PVC pipeline of 15 to 51 cm-diam (6-20 in.-diam), monitoring vibration, strain and pressure. Unlike tests of small blasts simulating construction, these were up to 1 t (2200lbs) per delay in 31-cm (12-in.) blastholes. Worst-case comparisons showed that 12.7 cm/sec (5 in./s) blasting vibrations produced strains about one fourth that of pressurization and 10% to 18% of the ultimate tensile strength. No failures occurred from blasting as close as 15 m (50 ft), which produced vibrations over 60 cm/sec (24 in./s).

Jan 1, 1995

By Sukru Sumer

East Pit Lake is an artificially created lake that resulted from the remediation and reclamation of surface coal mining operations at TransAlta Utilities' Whitewood Mine in the Wabamun area west of Edmonton, Alberta. The original excavation resulted from the creation of a mine end cut at the northern extent of the mining operation. The area of the surficial drainage basin that feeds East Pit Lake was relatively small. Therefore, most of the inflow and outflow from the lake would result from regional ground water flow. There was a concern about the lake's ability to provide a suitable habitat for a sportfish population. To determine the final recovered water level and rates of recovery, a two-dimensional ground water flow model was used. Data supplied by nested piezometers in and around the mine were used to calibrate the computer simulation and assess predicted recovery.

Jan 1, 1995

By Jr. Gabler

Because of concern over the availability and reliability of an uninterrupted supply of manganese and other materials, the U.S. Congress requested that the U.S. Bureau of Mines (USBM) study the /low of strategic and critical materials in the economy to delineate and quantify the production areas where metal values are lost. As a result, the USBM developed a generic computerized commodity flow model that is readily amenable to updating. The original model developed for cobalt, with slight modifications, was used to track the flow of manganese. This report follows the flow of manganese through its metallurgical and chemical applications and highlights areas where significant losses occur owing to downgrading, export, or disposal. The study indicates that materials containing 695,000 short tons (st) of manganese were consumed domestically in 1990. Scrap recovery specifically for manganese recycling was insignificant. However, considerable manganese was recycled through processing operations as a minor component of ferrous and nonferrous scrap and steel slag. The major loss category is manganese lost in steel processing, 323,156 st or 46 pet of the 1990 apparent consumption. Most of this loss reports to steelmaking slags. Recovery from slags is technically feasible, but is not economically feasible.

Jan 1, 1995

By S. Mathur

The southern Florida phosphate deposits that will be mined in the future contain significant amounts of dolomite. Because high MgO levels are undesirable in phosphoric acid production, several flotation schemes for the removal of the dolomite have been attempted. Alternatively, selective flocculation has been suggested as a potential process. A high MgO rock was simulated with a 30:10:60 mixture of apatite, dolomite and silica, respectively. Single mineral selectivity was observed in the apatite-silica and dolomite- silica systems using Polyacrylic acid (PAA) and Poly(ethylene oxide) (PEO) flocculants, respectively. However, no single mineral selectivity was observed in the apatite-dolomite system using PEO. Heteroflocculation, suspected to be the major reason for the loss of selectivity, was minimized by the addition of a site blocking agent (SBA), consisting of a lower- molecular-weight fraction of PEO. Process parameters such as size reduction schemes, flocculant/SBA dosage and pH were investigated to achieve the desired separation. The selectivity obtained in binary mixed-mineral tests was also achieved in the ternary mixed-mineral system, namely, the apatite-dolomite-silica system. In this report, surface chemical characterization of the samples and their flocculation behavior are discussed.

Jan 1, 1995

By G. Lee, E. T. C. Spooner

"Molybdenum mineralization at Boss Mountain is hosted by the Triassic Takomkane quartz monzodiorite batholith and is associated with a Cretaceous monzogranite stock. Ore has been mined from a sheeted vein system that describes a partial annulus centred upon the apical region of the stock and from subvertical breccia pipes that emanate from the stock. Molybdenite precipitation is coincident with CO2 effervescence from a dilute (1.9 mole o/o NaC/ equivalent) hydrothermal fluid over a temperature range of 250°C to 370°C at a pressure of approximately 350 bars, interpreted to be greater than or equal to the lithostatic load and equivalent to a depth of 1.3 km or less.IntroductionThe chemical and thermal constraints on molybdenum transport and deposition to form molybdenum ore deposits are not well understood. To address this problem, the Boss Mountain mine in central British Columbia, operated by Noranda Mines Ltd., was chosen as a well-described (Soregaroli and Nelson, 1976), relatively small and simple example of a Cordilleran Mo~ deposit. It is situated on the northeast slope of Takornkane Mountain, 10 km west of the community of Hendrix Lake (N.T.S. 93A/2W; latitude 52°06'N, longtitude 120°56'W). Access is from 100 Mile House by nearly 90 km of road, the first 50 km of which are paved."

Jan 1, 1995

"The Crescent, DM, and Pothook zones are copper-gold porphyry deposits which formed in association with alkalic intrusions of the early Jurassic Iron Mask batholith. The characteristics of the Crescent and DM deposits are nearly identical. Both formed along the contact between the Cherry Creek monzodiorite and Pothook diorite phases of the batholith. Permeable intrusion breccias along the contact concentrated the flow of hydrothermal fluids. Early, pre-ore alteration is represented by pervasive, sulphide-barren potassium metasomatism. The precipitation of copper-gold ore occurred during subsequent fracture-controlled potassic alteration, and is most strongly developed in chlorite-sulphide veins and their alteration envelopes. A central zone of potassic alteration is surrounded by a propylitic, pyritic halo in both deposits. The DM zone is unique among alkalic porphyry deposits in its high abundance of quartz-sulphide veins.The Pothook deposit formed at the westernmost contact of the Iron Mask batholith with enclosing Nicola Group volcanic rocks. Pervasive potassium metasomatism, similar in style to that at Crescent and DM, is associated with intrusion of the Cherry Creek monzonite. Pervasive and fracture-controlled albitic alteration is associated with intrusion of the Sugarloaf diorite and introduced minor copper-gold mineralization. Most of the copper-gold mineralization was introduced during formation of veins and breccia matrices dominated by magnetite/hematite and sulphide. Late-stage chlorite veining may have remobilized or introduced additional gold mineralization.Copper and gold assays in the Crescent deposit are well-correlated and have a nearly constant Cu:Au ratio, suggesting that the metals coprecipitated during a single hydrothermal event. In the Pothook deposit, copper and gold do not correlate closely, lack spatial correspondence, and suggest that transport and/or deposition of the two metals were not identically controlled and that they may have been introduced at different times by separate hydrothermal events."

Jan 1, 1995

By Roger A. Bullivant

The introduction of this size and type of piling rig is intended to address a multipurpose foundation activity. The 8000 denotes the size of equipment that is attached to the mast, namely 8000 Kg. Larger equipment can be carried subject to adjustment of rig geometry. The 8000 series rig will easily accept hydraulic piling hammers and CFA equipment, but for the purpose of this discussion it will be equipped with an auxiliary power pack that is matched to twin vibrators. The design of the siamesed vibrators allows long tube equipment or piles to be driven with a short mast configuration that provides a lower overturning risk. It is easily adapted within minutes to carry out other foundation requirements that are required on the same contract. The piling and ground consolidation activities that can be undertaken by the 800 series machine are:-

Jan 1, 1995