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By Heinz Giegerich

This paper deals with a new development in recycling second generation catalytic converters, namely metal substrate converters (MSC). It describes a patented dismantling process, whereby the MSC is segregated into it's three components outer steel shell, metal substrate carrier foil and ceramic W8shcoat with embedded precious metals.

Jan 1, 1995

By R. J. Kuczynski

The U.S. Bureau of Mines Reno Research Center operated a batch pilot plant to demonstrate high-temperature cyanide leaching for recovering platinum group metals (PGM) from automobile catalysts. Approximately 1,600 kg of used pellet, monolith, and metal support catalyst containing 1,680 g (54 tr oz) of PGM were processed. Forty-five-kilogram batches of used catalyst were leached with sodium cyanide solution at 160° C for 1 h under basic conditions in a countercurrent processing sequence to dissolve the PGM. Extractions from the used pellet catalyst ranged from 94 to 95 pct for Pd, 95 to 97 pct for Pt, and 64 to 81 pct for Rh. Extractions from the used monolith catalyst ranged from 7B to BB pct for Pd, 75 to 90 pct for Pt, and 43 to 71 pct for Rh. Heating the pregnant leach solutions to 275' C for 4 h destroyed the PGM-cyanide complexes, resulting in over 99.7 pct of the PGM precipitating from solution. The PGM precipitate was predominantly a powder metallic concentrate, typically analyzing greater than 50 pct PGM. Heating destroyed cyanide to less than 0.2 mg/L. Both the pellet and monolith residues were evaluated for disposal using the EPA Toxicity Characteristic Leaching Procedure.

Jan 1, 1995

By J. Kalynchuk, R. Poulin, R. Pakalnis, D. Peterson

"A market survey of all underground mines in Canada (Fig. 1) was completed to determine the ex1ent to which cable bolts are being used as ground support. One hundred and nine questionnaires were distributed with 65% of them being returned completed. As a result, the quantity, types and locations of cable bolt installations have been determined. In addition, the grout pumps used, time required and cost of installations have been addressed. The popularity of other support types used in underground mines is summarized.IntroductionRock reinforcement consists of installing support within the rock mass (internal) or within the excavation (external). Within the past twenty-five years several new types of ground support have been introduced within the mining industry. Cable bolts were first introduced to the Canadian mining industry in the 19605 (Gramoli, 1975).Cable bolts have gained increased acceptance as a method of ground support during the past decade. The cable bolt is comprised of one central wire surrounded by six slightly smaller outside wires and typically having an over-all diameter of 15.2 nun to 15.9 nun (0.6 in. to 0.625 in.). The cable wires are made from high-strength steel with an ultimate strength of 26 tonnes (58 000 Ibs) (Goris, 1990). Current cable bolting practice consists of cement grouting one or more steel cables within a drill hole in order to reinforce the surrounding rock mass. Cable bolts are a form of internal support and are generally used in open stoping and cut-and-fill mining methods (Fig. 2).They can be either tensioned (active support) or untensioned (passive support) and may be of any length, though for underground mining applications, they are generally less than 20 m (65.5 ft) and are untensioned. A major advantage compared to previously used ground support is that the cables are flexible and can be coiled to approximately 1 m (3.3 ft) diameter coils allowing relatively long support to be installed in areas with limited head room (1.8 m).With the advent of bulk mining methods which require comparatively large stopes, it has necessitated the use of relatively long support tendons to stabilize the large spans being created. As a result, the use of cable bolts for ground support in mines has increased significantly within the past decade."

Jan 1, 1995

By John F. Papp

International and U.S. chromium material flow, losses, and environmental releases and transfers from mining through industrial processing, end use, and recycling are identified and quantified. Average (1983-92) U.S. consumption has been: metallurgical industry, 87 pct; chemical industry, 10 pet; and refractory industry, 3 pct. Average chromium content of aluminum, cobalt, copper, nickel, and titanium alloys and alloy, carbon, and stainless steel alloys was estimated. Anthropogenic chromium consumption was estimated for the cement and copper industries. N on-commodity cycle anthropogenic chromium mobilization resulting from U.S. fuel and fertilizer use was estimated. Commodity cycle anthropogenic world chromium loss from mining and primary consumer industry was estimated to be equivalent to about 56 pct of chromium contained in chromite ore production and represented a loss rate of 181 kt-Cr/Mt-CrOre. Chromium released to the atmosphere from natural and from anthropogenic sources were comparable in magnitude. Chromium released to soil was mostly from anthropogenic sources, and aquatic releases were all anthropogenic. Domestic product chromium losses exceed process losses by more than a factor of 10 showing the importance and potential environmental impact of post-consumer recycling. The location of historical and current domestic chromium industry processing sites in 23 States were reported. Chromium releases and transfers to the environment were estimated from 1973 through 2002 by primary consumer industry. A decrease in chromium releases and transfers to the environment was anticipated.

Jan 1, 1995

Various influences determine how an Environmental Management System (EMS) for a mining or petroleum project is developed and administered. These influences include the environmental and resource legislation applying to the project, the culture of the organisation, the environmental sensitivity of the area, and the administrative policies of the regulatory agencies involved. While financial penalties and even imprisonment may be imposed for non-compliance with environmental legislation, there are other compelling reasons for the establishment of an effective EMS. If a company wishes to be considered by Governments for the grant of exploration or mining rights, it is important that it can demonstrate environmentally responsible operations at existing facilities. The development of an effective EMS requires commitment from the Board of the company and the issue of an Environmental Policy to empower all levels of the staff and workforce to achieve environmentally responsible operations. This must be supported by the provision of appropriate human and financial resources, and environmental training of staff at all levels from the Board to the mine site, workshop and office. A regular environmental auditing programme is essential to ensure that the EMS is in place and is effective in achieving compliance with regulatory requirements, corporate policies and protection of the environment. An EMS can be developed on the basis of existing management systems, quality management systems, existing and emerging environmental management standards (such as BS7750 and ISOI4000), or sophisticated computerised systems which may incorporate international experience, standards, and codes of practice.

Jan 1, 1995

By G. T. Austin

This is an overview of the gemstone industry with special attention on particular states within the united states. The U.S. Bureau of Mines, Department of the Interior compiled and analyzed the information contained in this report. The report should be viewed as a current "still photograph" of a dynamic system. The information presented on a specific gemstone or for a specific state can and will change with time. This overview presents historical and reference information on the principal gemstones and their production in certain states. The report is not a definitive work on gemstones within the select states or United states.

Jan 1, 1995

By H. Hoberg, M. Langen, B. Hamacher

Since the term "abandoned hazardous sites" was first coined in the 1978 environmental report of the Council of Environmental Specialists, a number of different types of technology has been developed in the Federal Republic of Germany for the remediation of contaminated soils /l/. At former sites of the mining industry, such as metallurgical and coking plants whose soil has been contaminated by organic and inorganic pollutants over decades of industrial activity, there is an exceeding necessity for soil remediation. Also, many former locations of metal processing works, battery factories or scrap yards have been contaminated in particular by heavy metals. Wet mechanical soil decontamination has proven successful over the past 10-15 years in the purification of these soils The process goal is the enrichment of the pollutants in certain plant products and the separation of a pollutant concentrate from the decontaminated soil. Table 1 lists the steps of the highly advanced wet mechanical soil decontamination process to achieve this process goal. Table 1 lists both the name of each process step and its goal in terms of a direct separation of the pollutant or the preparation of the soil for subsequent separation steps. For the separation of heavy metals, density sorting and separation techniques utilising flotation were specifically used. The use of chemical auxiliaries such as acids and lye is limited to special cases because these in themselves produce additional environmental impact and the economical effficiency of these techniques compared to conventional methods is lowered by supplementary process steps for water purification. The subject of this presentation is to consider how soil decontamination processes can be effectively improved through a description of the material properties of soils contaminated by heavy metals, and through carrying out basic investigations about the adsorption of heavy metals. Soils of different origins, especially those from former mining and metallurgical sites, were used for the experiments.

Jan 1, 1995

By R. Reeves

Coal producers and utilities depend on automated coal blending systems to reduce costs and meet stringent environmental regulations. Over 30 systems installed in the United States since 1987 use on-line PGNAA (Prompt Gamma Neutron Activation Analysis) analyzers to accurately control the blending process. Experience and detailed engineering are required to integrate real-time data produced by the coal analyzer with a control system to meet demanding performance specifications. This article reviews successful installations and lists important features including interfacing analyzers with plant control systems, specifying feeders and weigh scales, and managing data.

Jan 1, 1995

By A. M. Girodo

"Dorbyl Heavy Engineering has been manufacturing winders since 1949 mostly for the South African mining industry.Table 1 shows that the vast majority of winders have been double drum winders. At the greater depths with larger ropes being employed, it became apparent that multi-rope winders would be needed. The high stress variation in Koepe winder ropes at great depths especially beyond 2000 m, ruled out this possibility. Thus the original concept was borne for the Blair multi-rope winder where the stress level variations in the rope would be as per the well known, tried and tested double drum winder. The Blair multi-rope was also devised to increase payload by using multiple ropes.With the increasing costs of transporting men and material coupled with fact that orebodies are getting deeper, various feasibility studies have been carried out by South African mining houses. For this reason Dorbyl Heavy Engineering has done conceptual design work of both double drum and Blair multi-rope winders with diameters up to 8.5 m dia (still well within our manufacturing capabilities). These feasibility studies have looked at depths approaching 4000 m*.This paper covers the typical duties leading to the choice of single drum, double drum, Koepe and Blair multi-rope hoists on South African gold mines. A brief synopsis of Dorbyl hoists in use in the South African mining industry, with some indications of future trends, will be discussed.With current installed depths of wind approaching 2500 m, the Blair multi-rope hoist has been used extensively for the heavier payloads.Some of the main considerations pertinent to the design of the Blair multi-rope hoist are illustrated together with the implications of using this type of hoist to winding depths of3000 m to 4000 m in the foreseeable future."

Jan 1, 1995

Longhole stope overbreak has always been a source of unwanted cost within the underground mining industry, and efforts to control it using various rock reinforcement systems have long been a rock engineering challenge. At the Pasminco Mining Broken Hill Operations trials have been carried out using an innovative cable bolt reinforcement system known as Rib-Roc. The system, based loosely on the Swedish Rib-in-Roc concept, utilises zones or ribs of heavily reinforced rock in the troublesome hangingwall and back areas of longhole stoping. The trials were carried out under a strict qualitative and quantitative scientific stope measurement program utilising rock mechanics instrumentation. Not only did the trial demonstrate the success of the system but data obtained was useful in implementing the system virtually as standard practice throughout the operation.

Jan 1, 1995

By J M. Laboz Bernard

Among the numerous technical evolutions in the blasting environment we are going to describe below the concep

Jan 1, 1995

By T. G. Hawkins, T. M. Naciuk

"The Katie Cu-Au deposit is situated in southeastern British Columbia, 425 km east of Vancouver. The deposit is a member of the alkaline group of porphyry Cu-Au deposits associated with potassically and propylitically altered andesitic volcanic rocks.The Katie porphyry system occurs in mafic to intermediate alkaline volcanic rocks of the Lower Jurassic Elise Formation of the Ross/and Group. Host metavolcanic rocks include andesitic to basaltic flows, flow breccia, massive fine tuff and crystal tuff Gabbroic intrusions alternate with the volcanic rocks in drill core. The lack of chilled margins and shear contacts, as well as their similar composition to the volcanic rocks, suggest that the gabbro was synvolcanic.Alteration exhibits a zonal pattern spatially related to zoned porphyry-style mineralization. Propylitic alteration is common and assemblages consist of epidote, chlorite, sericite and calcite. Potassic alteration zones are accompanied by elevated copper-gold grades and are composed of K-feldspar, plagioclase, quartz, biotite and chlorite. Narrow drillhole intervals of secondary magnetite, generally less than 2 m across, occur above the potassic alteration zones. A thick oxidized cap lies above the mineralized zones, although only local supergene enrichment has been identified. The lack of supergene enrichment is perhaps due to intense near-surface fracturing and leaching from a high energy groundwater environment.Sulphide mineralization consists mainly of pyrite within the propylitic halo, and pyrite and chalcopyrite with trace pyrrhotite, sphalerite, tetrahedrite, bornite and molybdenite within the potassic alteration core. Malachite, azurite and traces of chalcocite occur within the oxidized cap.Discovery and exploration techniques have included airborne geophysics, regional stream sediment sampling, prospecting, geological mapping, ground geophysical surveys, soil sampling surveys, and diamond drilling. Two primary targets of porphyry copper-gold mineralization have been identified by exploration. The Main zone strikes northwest, has an apparent true thickness ranging from 70 m to 135 m, and is a minimum of 500 m in length. The 17 zone strikes northwest, has an apparent true thickness of 90 m, and is a minimum of 300 m in length. The two zones are defined by grades that generally exceed 0.2% Cu and 0.25 g/t Au. Both zones are open along strike and to depth."

Jan 1, 1995

By B. J. Timmons

Depending upon which of two letters describing the theme of the session I chose to honor, the subject choices because either one or three. They were: "Applied Research and Exploration and Discovery" or "Applied Research in Exploration and Discovery." The final choice; to partially ignore both of them. That minor difference in meaning may be appropriate here, inasmuch as very minor research/exploration differences may also have profound impacts on discovery. To further set the stage, I consider myself an Industrial Minerals geologist, and more specifically primarily associated with basic construction materials crushed stone and sand & gravel. My remarks will apply primarily to those materials. Therefore, when the discussion instructions included emphasis on beneficial aspects (to name a few): "drill target definition; elimination of ore potential; ore forming environments; alteration studies, and isotope analysis," problems became apparent. Evidently, and although this was a form letter, the drafters of that letter had no idea what was involved in research for a construction materials source. My task may be great.

Jan 1, 1995

By C. H. B. Leitch, T. N. MacAuley, R. L. Linnen, A. E. Williams-Jones

"The Trout Lake stockwork molybdenum deposit is temporally and spatially related to the emplacement of a late Cretaceous granodiorite-tonalite stock in southeastern British Columbia and contains an estimated 49 million tonnes grading O.I9% MoS2- No metal zonation patterns are apparent, with the exception of peripheral tungsten skarn, and exploration was guided largely by geological interpretation. It is typical of the granodiorite, or fluorine-poor type of molybdenum deposit. Molybdenite is contained within a quartz-feldspar vein stockwork and coeval dissemination in igneous (and less commonly metasedimentary) hosts. In general, molybdenite is strongly associated with alkali feldspars, but in detail it is intimately associated with incipient muscovite replacement of albite and K-feldspar; veins that lack feldspars are also typically barren of molybdenite. These textures suggest that fe/dspathic alteration (and precipitation in veins) was an important precursor to mineralization, and the occurrence of similar textures elsewhere (e.g. Henderson) suggest that early feldspathic alteration is important to the genesis of molybdenum deposits in general. Molybdenite deposition at Trout Lake was preceded by contact metamorphism, skarn and potassic alteration, and was overprinted by muscovite-ankerite (phyllic) alteration. Only moderate temperature changes are recorded by the metamorphic and alteration mineral assemblages (350°C to 450°C}; however, with time, fluids became increasingly more acidic and enriched in C02- In light of the intimate molybdenitemuscovite intergrowths, the decrease of pH probably exerted a major control on mineralization.IntroductionGranite-hosted molybdenum deposits can be classified in terms of the composition of the related intrusion, e.g., the granodiorite and granite types of Mutschler et a!. (1981), or the calc-alkaline, alkali-calcic, and alkalic types of Westra and Keith (1981). They have also been classified on the basis of their fluorine contents (Theodore and Menzie, 1984) with the fluorine-rich and -poor varieties roughly corresponding to granite- and granodiorite-type deposits, respectively. For economic reasons, most exploration and research has concentrated on the high-grade/large tonnage granite-type of deposit, exemplified by Climax. F1uorine-poor, granodiorite-type deposits are, however, the most common type in Canada and have been mined in the past (e.g., Endako). In this paper, the authors summarize the research that has been carried out on the fluorinepoor Trout Lake deposit (Boyle and Leitch, 1983; Linnen, 1985; Linnen and Williams-Jones, 1987; 1990) and use what has been learned to develop guidelines for the future exploration of fluorinepoor, granodiorite-type molybdenum deposits."

Jan 1, 1995

By K. Gum, W. C. Hirt, D. A. Rice

Selective flocculation was used to produce a superclean zinc concentrate by minimizing silica contamination. Research was carried out on a flotation concentrate from the Jersey Miniere Zinc Company (JMZ) in Gordonsville, TN. The material was first dispersed with sodium silicate and then causticized tapioca starch was used to selectively flocculate the sphalerite, leaving the silica in suspension. This technique has been applied commercially to iron ore beneficiation but never to zinc processing. The feed material assayed 0.45% SiO2. The use of 0.56 kg/ t (1.13 lb/st) sodium silicate and 0.070 kg/t (0.141 lb/st) causticized tapioca starch resulted in a 98.2% zinc recovery and produced a purified zinc concentrate assaying 66.0% Zn and 0.24% silica. The target level for silica contamination in JMZ zinc concentrates is currently 0.30% Si02. This work demonstrated that selective flocculation is a potential method for cleaning flotation concentrates, particularly where low silica products are required.

Jan 1, 1995

By S. Guo

In this paper, a model for the resin anchor bolt system is developed in which the smooth bar is modeled by using one-dimensional truss elements and the resin annulus is modeled by using axisymmetric elements. These two submodels are combined together and then incorporated into the' existing computer code ROOFBOLT. After this development, all of the components in the resin anchor bolt system including smooth bar, bearing plate and resin annulus can be correctly modeled.

Jan 1, 1995

By E. A. Barrett, K. M. Kowalski

The U.S. Bureau of Mines (USBM) conducted experiments to determine if training using a latent- image, three-dimensional (3-D) slide simulation exercise improved miners' ability to recognize roof and rib hazards. The effectiveness of this innovative type of classroom training was investigated by measuring workers' performance on a hazard recognition task. The study was unique in that hazard recognition skills were assessed in the workplace using actual coal mine roof and rib hazards. Results showed that training with a latent-image, 3- D slide simulation exercise significantly improved each subject's performance on the in-mine hazard recognition task. Further, the USBM researchers concluded that transfer of learning from the classroom to the workplace occurred.

Jan 1, 1995

By H. EI-shall

In this paper, the results of bench scale testing of five different flotation processes to separate dolomite from phosphate are discussed. The effectiveness of each process interms of phosphate recovery and MgO content in the concentrate is used together with the reagent consumption as the basis of comparison. The water quality is found to play a major role in the performance of these processes. Effect of water hardness as well as other parameters are discussed.

Jan 1, 1995

By V Morand, W R. H Ramsay

Structural, mineralogical, and textural data from the Tarnagulla Goldfield demonstrate that the area has undergone three significant phases of deformation. The first phase of deformation (D1) predates the intrusion of the Tarnagulla pluton, which has been dated using K/Ar as 391 ¦ 5MY. We regard this pre-granite deformational event as the major regional deformation. Gold-bearing quartz veins have been deposited in dilational sites on west-dipping reverse faults. These sites demonstrate a geometry related both to faulting associated with D1 and the plunge of the F1 fold axes. This evidence, together with chronology of unmineralised ? D2 and D3 faults, the absence of quartz veining associated with D3 events, and the deformation of carbonate-quartz-biotite-sulphide aggregates within Sl by later S2, lead us to conclude that the bulk of the mineralisation was essentially syn- or late D1 . d18O values for fluids in equilibrium with vein quartz from Central Victoria have indicated equivocal support for either a magmatic or metamorphic origin. Our evidence supports a pre-magmatic origin for mineralisation at Tarnagulla and hence tends to favour a metamorphic fluid source.

Jan 1, 1995

By Glenn S. Dobby, Glenn A. Kosick

"Column flotation circuit engineering has matured to a good level of understanding regarding testing, scale-up and design. Some of the factors important to the process of implementing columns are addressed in this paper, highlighting the following issues• operating bias and the maximum achievable solids carrying rate for a column application.• internal circulating loads of full scale and pilot plant flotation columns• short-circuiting oflarge scale columns and the impact on separation selectivity• the number of stages in a column circuit and the impact on selectivity.The paper uses several case studies, from pilot plant to full scale implementation, to illustrate these design issues.1. IntroductionTen years ago, in 1984, there were very few column flotation installations world wide and the largest columns were about I . 5 to 2 m diameter or square. During the following decade there have been in the heighbourhood of 80 column installations that have been successful and profitable, as both retrofits and green-fields plants. Now, columns as large as 3 to 4 m are not uncommon. Examples of installations with many large columns include Escondida, with ten columns each at 4 m square, and P T Freeport Indonesia, with 21 columns: nine 3 m diameter columns, four 2.4 m diameter columns and, starting up in April I 995, eight 3.6 m diameter columns.During this growth period there have also been column installations that can be considered as failures. In the majority of these cases, the reason for their failure has been an insufficient installed capacity for applications where there is a high weight recovery of solids to the froth product These include zinc cleaning, copper cleaning and iron ore flotation (silica flotation from a feed that is 15 to 30 %Si02) An application with high weight recovery to the froth product makes column scale-up and circuit design more complicated. This is particularly so if a high degree of selectivity is also required while attaining a high weight recovery, which can happen with iron ore flotation in columns."

Jan 1, 1995