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By J. R. Dyni

The lacustrine Green River Formation of Eocene age in the Green River Basin, southwest Wyoming, contains the world's large resource of natural sodium carbonate in bedded trona (Na2CO3? NaHCO3? 2H2O). In this study, 126 billion tons are estimated to be present in 22 beds, ranging from 4 to 36 feet in thickness. These 22 beds underlie areas of about 50 to more than 775 square miles at depths ranging from about 650 to more than 3,000 feet below the surface. The total resource of trona ore in the basin for which drilling information is available is estimated to be about 149 billion short tons. The undeveloped deeper trona beds in the southern part of the basin may be exploitable by solution mining. Additional unevaluated sodium carbonate resources are present in disseminated shortite in strata interbedded with the trona and in shallow sodium carbonate brines in the northeast part of the basin.

Jan 1, 1995

By R. Hogg, R. H. Weiland, P. Bunnaul

The dewatering of flocculated clay suspensions by compression in a centrifugal field was investigated. The results were analyzed with respect to the direct applicability of centrifugal dewatering (as in solid-bowl centrifuges) and indirect applications to gravity sedimentation systems. An important objective of the study was to evaluate the self-weight effect using centrifugal forces to simulate consolidation of deep sediments. Experiments were conducted in which the sediment mass and initial structure were maintained constant while the effective sediment weight was varied by centrifuging at different speeds. The relationship between the limiting sediment density and the applied consolidation stress was found to be the same for both gravity and centrifugal consolidation, indicating that small-scale laboratory tests can be used to predict consolidation in deep beds. The effects of the initial structure were also studied using controlled variations in flocculation conditions. The results imply that, for the flocculated suspensions studied, the longterm consolidation behavior is relatively insensitive to the actual extent of flocculation.

Jan 1, 1995

By Debra W. Struhsacker

Waste characterization plays an essential role in proactive project permitting, design, reclamation, and remediation strategies. Traditional TCLP tests and chemical analyses used in many studies do not provide adequate data to predict the long-term geochemical behavior of the mineralized system. Mineralogic and geologic data are needed to assess the homogeneity of the system, the potential for acid generation or metals leachability, and the amenability of the material to traditional and unconventional closure and reclamation measures. The characterization efforts done from the evaluation stages through final closure can aid in better cost evaluations, more representative sampling, more effective neutralization and waste containment measures, and optimized reclamation designs.

Jan 1, 1995

By R. L. Amelunxen

P. T. Freeport Indonesia (PI) in conjunction with Crescent Technology Inc. has developed a method to predict the metallurgical performance of ores blends based on the behavior of their component ores. The question addressed in this paper is whether ores treated individually could be extrapolated to predict the behavior of a blend of ores. The work further investigates the use of modal analysis to establish individual mineral flotation kinetics in each of the ore zones. This information would lead to the prediction of grade-recovery curves of ores made up of those minerals. Nine samples of ore, representing various zones of FI's Grasberg ore deposit were tested metallurgically and examined microscopically. The same testwork was performed on blends depicting the 1994 mill quarterly feed. Flotation kinetics of the individual ores were then "mathematically" blended and compared to the results obtained from the quarterlies. The calculated kinetics of the actual blends of ore received by the mill were fed to the simulation program and compared to the actual mill performance.

Jan 1, 1995

By J. A. Organiscak

This paper describes the research con-ducted on bit wear and respirable dust generation conducted by the US Bureau of Mines (USBM) and West Virginia University (WVU), a member of the Generic Technology Center on Respirable Dust. The USBM investigated wear, energy and dust characteristics of various conical bit designs when cutting rock. WVU studied the functional relationships between wear, cutting force, energy, and dust of one conical bit type when cutting coal. The objective of the USBM study was to identify qualitative bit selection guidelines for cut-ting rock; WVU's research objective was to determine optimum bit replacement guidelines. These research studies both found that bit geometry (a function of bit design and wear) influences energy consumption and dust generation. Bit selection and replacement recommendations are given.

Jan 1, 1995

By Billy W. Osborne

The use or primary dross as a source for aluminum ion in the manufacture of aluminum sulfate offers opportunities for an inexpensive raw material. The aluminum sulfate industry in the US is a mature market with numerous small plants operating close to major users. The majority of manufacturers use either bauxite or aluminum oxide trihydrate as a source for the alum¬inum ion.. However, using process technology developed and patented by IWC, the oxides are removed from primary dross for use in manufacturing aluminum sulfate prior to metal recovery. This process offers the benefit of reducing costs for metal recovery. This paper discusses some of the methodology used in this process.

Jan 1, 1995

By Z. Yu

The effect of particle size on coal dewatering has been well recognized However, there are no systematic studies on ultrafine coal dewatering. The results discussed last year revealed the effect of flocculant type and coal wettability on the filtration of ultrafine coal In this paper, the differences in dewatering between -25 µ m ultrafine and -500 µ m fine coal with addition of flocculants, surfactants and oil-emulsions in vacuum filtration are further investigated Significant differences were observed in the reduction of the cake moisture. The utilized emulsions were found to be very powerful and promising filtration aids for both ultrafine and fine fractions of hydrophobic and hydrophilic coal

Jan 1, 1995

By George G. Goble

In the middle of the nineteenth century, the dynamic formula appeared as a description of pile penetration during impact driving. The simplicity of use of the formula combined with the power of the energy concepts behind the formula caused it to be quickly accepted and integrated into practice. Dynamic formula had been in use for 100 years when the Wave Equation computer programs first appeared. With that long experience it is not surprising that the formula continued to be used and were only slowly abandoned. The Wave Equation offers many advantages over the various formula but it does not offer a clear sense of physical understanding of pile driving that is available with the formula. Large amounts of numbers are generated but often it is difficult or impossible to gain a physical understanding of the results or a feeling for the importance of the various parameters. The question that the Wave Equation user has is, "What will happen if I use a larger drive cap (or change any other item of equipment)?" In this paper, I will attempt to explain pile driving using elementary wave propagation theory. However, the presentation will not depend on any higher mathematics. With the use of wave mechanics, it is possible to explain driving characteristics that cannot be handled with the energy formula.

Jan 1, 1995

By Spencer R. Titley

Nearly three decades of intense research, corresponding with a period of unparalleled discovery and the advent of scientific advances and hypotheses of ore formation, has resulted in a great body process-focused research concerning how ore deposits form. The development of process models and their application has proceeded more or less in step. Discoveries have been made in mineralized regions such as provinces and districts but generally without a comparably developed understanding of why provinces and ore bodies exist and, except in general terms, where ore deposits are within districts and regions. The process of discovery is still referred to as search and exploration budgets are heavily weighted toward exploration drilling.

Jan 1, 1995

By Steve Wirch, Robert Jankowski

The issue of dust control in underground coal mines has been extensively studied by both government and industry. This research work has resulted in many techniques which control the dust or help miners avoid it. Control techniques either prevent the dust from becoming airborne or cleanse the air before it can be inhaled. Avoidance measures minimize the exposure of miners to the airborne dust by blowing the dust away from work areas or making it unnecessary for a miner to occupy a dusty region. One of several successful dust control measures in continuous miner sections is the use of a machine mounted scrubber which cleanses the air and helps to prevent the contaminated air from reaching areas frequented by mine personnel. Research on the application of scrubbers on longwall shearers began in the 1970s and continued into the 1980s. The most successful projects showed only moderate improvement when a scrubber system was mounted on a longwall shearer, and the less successful projects actually increased worker dust levels. There are many reasons that scrubbers have not been successfully applied on longwalls. The most significant of these is that longwalls have across the face ventilation and generally have high face air flows. Scrubbers tend to work best when they are the primary cause of ventilation. Therefore, their capture efficiencies on longwalls tend to suffer because of the exposure of the drums to the primary airflow. Other reasons scrubbers have not been implemented on longwall s include the successful application of an excellent water spray system, effective cutting techniques, and dispersion of dust sources. These techniques can help control drum generated dust, increase production, and limit the relative effectiveness of a scrubber.

Jan 1, 1995

By E Castelli, M Fomaro, R Mancini, M Cardu

The economic return of rock blasting is not provided by brute volume of broken rock, rather by the amount of marketable product. That is the case of the porphyry quarries of Trento district, whose output is mainly absorbed by road paving and building facing elements production.

Jan 1, 1995

By Roy EI. Durr, Glen R. Davidge

"This paper presents the results of structural analyses and full-scale destructive tests conducted on liner plate culverts. The purpose of this work was to establish a design method and evaluate the suitability of using these structures in potential roof-fall areas for a rehabilitation application in lower stress and relaxed mining environments. Field evaluation of the design is currently in progress.Theoretical ultimate resistance functions were established for two different culvert shapes and were found to be representative of their experimental behaviour. The ultimate resistance function was used to determine their plastic behaviour to a rapidly increasing deflection condition, to determine the energy absorption capacity of these structures, and to predict their response to impact loading.IntroductionThe Kidd Creek mine of Falconbridge Limited is located justnorth of Timmins, Ontario. The area under rehabilitation for which this program was developed is the 2600 level of the No. I mine. The problem of effectively securing selected drifts at the 2600 level in NO.1 mine, for access to a high-grade ore block, is key to the economics of the operation. Diamond drill test holes had indicated a loosened rock mass above the 2600 level of about 7.5 m thick in response to the extensive mining operation below this level. This level forms the arbitrary boundary between the No. I and No. 2 mines, and has extensive volumes of cemented rock fill below it and largely untouched ore above it to the 2000 level in the North orebody. The walls at that level were showing relaxed ground conditions typical of de-stress: sub-horizontal joints opening up, and peeling.Due to the ground conditions, the consequent safety risks, the high grade of the ore, the potential production delays, and the likelihood of several phases of rehabilitation, regularly used drift rehabilitation employing rock bolts, cable bolting, or shotcrete was not practical. Two options were deemed possible alternatives to suit these conditions, steel sets with blocking and lagging, and liner plate culverts with backfill. Culverts were chosen."

Jan 1, 1995

By Jan W. Merks

"The settlements between mines and smelters are based on the mass of metal contained in concentrate lots. The mass of contained metal is a function of the wet mass of a lot, and its moisture content and metal grade while the variance of the mass of contained metal is a function of the same variables and their variances. Uncertainties in the measurement procedure applied to estimate each variable are quantified in terms of precision and bias. The absence of bias and an acceptable degree of precision are the keys to effective risk analysis and loss control.ISO Technical Committee 183-Copper, Lead and Zinc Sulfide Concentrates, has developed standard methods for sampling and weighing, estimating precision and testing for bias, the determination of mass loss on drying, the calculation of the mass of contained metal and its variance, and various analytical methods for major and minor metals. The variance for wet mass is calculated from the precision of the scale while the total variances of moisture and grade are estimated from pairs of interpenetrating primary samples. The variance of contained metal can be calculated either from mine data or from smelter data but the risk associated with the settlement is largely determined by the absence or presence of bias and the variance of differences between exchange assays.ISO/TC 183 does not deal with precision and bias for exchange assays but is developing guidelines to determine realistic splitting limits. Given that the exchange of assays between mines and smelters accounts for a large part of the risk associated with the settlement, precision and bias for exchange assays should be measured and monitored. The need for umpire services can be reduced by applying statistical quality control (SQC).Calibrating static scales, moisture balances and analytical balances, bias testing of sampling methods and sample preparation procedures, estimating the variance of a single variable or the variance of a function that a set of variables defines, and monitoring precision and bias for exchange assays, are the quintessence of metrology, the science of measurement, when applied in mining and metallurgy."

Jan 1, 1995

By K S. Smith

Mineral-deposit geology, geochemical processes, and biogeochemical processes are fundamental controls on the environmental conditions that exist naturally in mineralised areas prior to mining, and that result from mining and mineral processing. Input from economic geologists and geochemists is therefore crucial to effectively predict, assess, mitigate, and remediate the environmental effects of mineral-resource development. Recent open pit gold mining at Summitville, Colorado , has received intense public scrutiny for a variety of environmental problems, most important of which has been extreme acid drainage. Now a Superfund environmental cleanup site, Summitville exemplifies how economic geology and geochemistry principles: 1. could have been better utilized to first predict and minimise the environmental problems, and 2. can now be used to optimize the environmental cleanup.

Jan 1, 1995

By Jinxing Ji

Several fundamental aspects related to the nickel electrowinning from chloride electrolytes have been addressed in this paper. The thermodynamic study includes the activity coefficient of the hydrogen ion and the speciation diagram of NiCI2 solutions. The activity coefficient of the hydrogen ion (YH+) was calculated and estimated experimentally using a combination glass pH electrode. It was found that YH+ was greater than one in concentrated NiCl2 solutions and increased significantly with increasing NiCl2 concentration. The speciation diagram for NiCl2 solutions was plotted with YH+ and the effect of the ionic strength on the equilibrium constants being taken into account. It was discovered that the predominant nickel species in the acidic region were Ni2+ and NiCI+ in 0.937 M NiCl2 solution at 25°C. Electrodeposition tests demonstrated that higher Nit' concentration in the electrolyte improved the current efficiency of nickel electrodeposition (CENi). The additions of H3BO3, and NH4Cl increased very little the current efficiency of nickel electrodeposition at pH 1.5 and temperature 60°C. However, the addition of sulfate decreased the current efficiency of nickel electrodeposition. Nickel electrodeposition was also found to be a steady-state process since the amount of acid added to the electrolyte at a constant pH increased linearly with time during galvanostatic electrodeposition. The cathode surface pH during nickel electrodeposition was measured using a flat-bottom combination glass pH electrode and a 500-mesh gold gauze as cathode. The cathode surface pH was found always to be higher than the pH in the bulk electrolyte, and if the current density was sufficiently large, it would eventually reach a level causing precipitation of insoluble Ni(OH)2(s) on the cathode surface. Rotating disc electrode studies revealed that the rate of nickel electrodeposition was first order with respect to the activity of nickel ion and zero order with respect to the activities of chloride and hydrogen ions. The rate of hydrogen evolution was found to be first order with respect to the activity of hydrogen ion and to be zero order with respect to the activities of nickel and chloride ions. These findings indicate that nickel deposition and hydrogen evolution proceed independently.

Jan 1, 1995

By Pr-Anders Persson

This chapter deals with the concepts of shock waves and detonation waves together, because a detonation wave is really a shock wave, supported by the explosive reaction that the shock wave ignites and propagates as it travels through the explosive material. In the c.ootext of rock blasting, furthermore, there is justification for treating shock waves and detonation waves together, because the mechanical effect of the detonation in an explosive in a drillhole in rock is propagated and its effects are spread throughout the surrounding rock by means of a shock wave. The overall performance of sn explosive in rock blasting or any other application is of course dependent on how much thermal energy is released in the chemical reaction that occurs when the material detonates, and on how much useful mechanical work the reaction products can do as they expand. A major portion of this chapter deals with the prediction and measurement of explosive performance, a subject which is now still in a process of rapid development.

Jan 1, 1995

By L. A. Cornish, B. Eatwell

Austempered ductile iron (ADI) is a ductile iron which has had its matrix toughened by an austempering process. The alloy exhibits remarkable properties, which it owes to a unique microstructure comprising graphite nodules embedded in a matrix of acicular ferrite and carbon-enriched austenite. The properties include high strength combined with high toughness and ductility. Excellent wear resistance is also exhibited because, under strain, the austenite is transformed locally to martensite. Samples of ductile iron were austempered to produce grades I and IV AD!, and were tested at various strain rates. The grade IV ADI exhibited higher strengths and lower difficulties, and the strengths were found to be more dependent on strain rate. Transformation to martensite was more prevalent at the lower strain rates. A mechanism of increased flow stress and work hardening in the austenite of the matrix is proposed to explain the higher strength of the samples at high strain rates, where significantly less martensite is formed in the matrix.

Jan 1, 1995

By S. Shankar

Available literature on the effect of re-entrainment on overall airborne dust concentration in mine airways or the fundamental mechanisms of coal dust re-entrainment in mine atmosphere is scant. Therefore, as part of the Respirable Dust Center's ongoing research, a three part study was envisaged: study of the re-entrainment phenomena of anthracite and bituminous coal dust particles in a wind tunnel under the influence of varying air velocities; study of the same in the Lake Lynn Laboratory Mine of the USBM with both airflow and walking by personnel causing re-entrainment; and mathematical modeling and computer simulation of the re-entrainment phenomenon. In this paper, results from the re-entrainment studies in the wind tunnel and the Lake Lynn Laboratory Mine are presented. Further, the results from the wind tunnel studies are compared with the results from in-mine studies conducted at the Lake Lynn Laboratory Mine of the USBM. Comparing the results from the two studies it was observed that increasing air velocity increased the rate of re-entrainment, but increased time of exposure decreased the airborne dust concentration. Compared to same size particles, a mixture of sizes created more airborne dust concentration when re-entrained. It was also observed that contribution of airborne dust concentration due to airflow was negligible compared to the contribution due to walking.

Jan 1, 1995

By D. B. Sikka, R. B. Bhappu

Porphyry-type copper-molybdenum (Cu-Mo) deposits typically occur in the Phanerozoic rocks and have been well-documented. During the past two decades, a number of porphyry-type Cu-Mo deposits that range in age from 1055 Ma to 2970 Ma have been identified in the Precambrian rocks of Australia, Canada, China, Finland, India. Namibia and Zambia. The Malanjkhand porphyry copper deposit M.P., India is estimated to contain 789 Mt (870 million st) averaging 0.83% copper (mill headgrade); 0.004% molybdenum; 0.2 g/t (0.006 oz/st) gold; 6 g/t (0.175 oz/st) silver and a cap of 7.5 Mt (8.2 million st) of oxide ore averaging 0.8% copper. The economic potential of the expanded copper mining milling, smelting and refining complex is expected to yield cathode copper 118.6 kt (130,700 st); molybdic oxide 830 t (914 st); gold 1.9 t (61,732 oz); silver 46.6 t (1.5 million oz); sulfuric acid 240 kt (264,500 st), copper from leach dumps 11.5 kt (12,600 st); nickel 24 t (26,400 st); cobalt 84 t (92,600 st); bismuth 16 t (17.6 st); selenium 48 t (53 st), tellurium 4.8 t (5.3 st).

Jan 1, 1995

By Theophili CN, Kapenis AP

Seismic tomographic imaging has been applied to determine the blast induced damage zones in bauxite pillars in underground mining. At the retreating stage, when pillar dimensions are reduced from 8 x 8 m to approximately 5 x 5 m, the' seismic tomographies reveal, through measurements of the P-wave velocities which is a measure of the degree of fracturation of the pillar rock mass, the presence of three zones within each pillar. In the external zone, where velocities recorded are below 750 m/s. extensive pillar damage occurs which is attributed to both the growth and coalescence of pre-existing cracks and even the creation of new cracks in the rock mass. This effect is in agreement with literature, when considering the peak particle velocity as a criterion for rock failure in tunnels. In the intermediate zone, where velocities range between 7S0-1000 m/s, damage to a much lesser extent occurs which is due mostly to growth of pre-existing cracks and widening of their apertures. The inner zone, where velocities exceed 1000 m/s, is considered to be unaffected by blasting. Simple remedial measures of low cost, which are based on blasting mechanics are proposed to minimise the blast induced damage zone and consequently the transition zone.

Jan 1, 1995