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By C. A. Young

Cyanide is a toxic species that is found predominantly in industrial effluents generated by metallurgical operations. Cyanide's strong affinity for metals makes it favorable as an agent for metal finishing and treatment and as a lixivant for metal leaching, particularly gold. These technologies are environmentally sound but require safeguards to prevent accidental spills. Various methods of cyanide remediation by separation and oxidation, including photolytic advanced-oxidation processes, are therefore reviewed. Reaction mechanisms are presented throughout the paper. The methods are compared in regards to their effectiveness in treating various cyanide species: free cyanide, thiocyanate, weak-acid dissociables, and strong-acid dissociables.

Jan 1, 1996

By Darrell L. Beddard

Pile driving started October 29, 1993 and was completed on January 27, 1994. Field work included driving piling from ground surface at one site and at or near proposed footing elevations for the remainder. Piles were driven to specified tip elevations or the elevations directed by the Project Manager. In an attempt to address what installation technique(s) performed the best, several methods were used, including varied predrilled depths, open ended piles, closed ended piles, and the use of both impact and vibratory hammers. Piles were driven closed ended where possible to study the feasibility of this option to reduce construction costs associated with pile cleanout. Piles were driven to different depths to measure capacity variations. The 24-inch (610 mm) diameter piling were driven in one piece while the 42-inch (1.07 m) diameter piling was driven in two segments. A total of 79 piles were driven for the four sites, 74 of the 24-inch (610 mm) diameter and 5 of the 42-inch (1.07 m) diameter. Various hammers were used to determine which hammers provided viable solutions to the potential problems anticipated in the design phase. Hammer selection was based on the driveability studies. Equipment included a 175 ton (1.56 MN) crane, support crane for pile stabilization, crane mounted auger drill, offshore leads, Delmag D30-32, D46-32, and D62-22 diesel hammers, an HPSI 2005 single acting hydraulic hammer, a Foster IHC S-90 double acting hydraulic hammer and a Kencho VM2-25000AII vibratory hammer with the weights set to produce 17,500 pound-inch (1.98 kN-m) of eccentric moment.

Jan 1, 1996

By Lanny Pasternak

"This article is directed at plant production, engineering and maintenance personnel. Seldom does any industrial operation take the time to study the costs involved in the generation of what is probably their most expensive plant utility energy source.IntroductionIn the typical industrial plant in Canada, a 200 hp, 900 cfm, air compressor costs about $60,000* per year to operate (Fig. 1). In 1989 when BC Hydro embarked on their industrial energy management program Airflow Energy Ltd. were asked to spearhead the “Efficiency Compressed Air” portion of that program with a mandate to perform onsite overview surveys and physical hands-on testing of some 300 selected industrial plants throughout British Columbia for compressor efficiencies and wasteful air leaks (Fig. 2). The program duration lasted until 1995, during which time a tremendous amount of data were amassed relating to equipment types, clients’ operating habits, end-use applications and operating costs.During the past six years, Airflow Energy also performed somewhat similar surveys but on a smaller scale in Alberta, Ontario, the United States and the Republic of China. It was no surprise to find some inherent equipment concerns related to efficiency as well as neglected energy wasteful air leaks, so British Columbia was not alone and the problems appear somewhat universal."

Jan 1, 1996

By T. P. Mucho

Strata behavior and support performance were evaluated in a longwall tailgate test area at the Eagle Nest Mine near Van, WV. The mine operates in the Eagle coalbed which ranges in height from 4 to 6 ft (1.2 to 1.8 m) on the mine property. Rugged topography results in rapid changes in overburden which ranges from 200 to 1200 ft (61 to 366 m). The immediate roof at this mine transitions from sandstone to shale. In some areas the sandstone appears to be massive while in many locations it is highly laminated, fossilized, and interspersed with coal streaks. Horizontal stress levels appear to be sufficient to create instabilities in the roof in some locations, especially where the roof is thinly laminated. Traditionally, hardwood cribs have been used at the mine to provide secondary support for longwall tailgates; Strata Products' Hercules cribs are installed on 8 ft (2.4 m) centers staggered left and right in the tailgate entry. In a 250 ft (75 m) tailgate test area, however, cable bolts were installed in lieu of cribs. The bolts were 12 ft (3.6 m) long tensionable cables anchored with 5 ft (1.5 m) of resin. Four cables were installed across the entry and rows were spaced on 6 ft (1.8 m) centers. Primary roof support was maintained in the vicinity of the test area using 42 in (1.1 m), grade 60, No. 6 (19 mm diameter) resin bolts installed on 4 ft (1.2 m) centers through T-2 channels. The cable test area was located under a stream valley in an area of relatively shallow overburden. Strata instabilities consistently had been associated with the stream valley in both the Eagle and the overlying Powellton coalbeds. In an effort to further expose the cables to the most difficult stress conditions available at the time of the test, the specific site chosen was directly beneath a barrier pillar remaining in the upper Powellton mine (approximately 150 ft (45 m) of interburden separates the two coalbeds).

Jan 1, 1996

By Guy L. Fredrickson

A modified transpiration reactor was used to measure the composition of the equilibrium gas phase formed above compounds in the Hg-O-S system at high temperatures (600 to 900K). A thermodynamic database {(AGo°f AH°t. AS°t)} for-HgO, HgS, HgSO4, Hg2SO4, HgSO4?HgO, and HgSO4?2HgO was developed based on the experimental results. Prior to this study, only estimated data were available in the literature for the sulfates and oxysulfates at temperatures above 298K. A series of vapor pressure' stability diagrams were constructed from 473 to 973K with isobars of Hg(g), HgO(g), S2(g), and SO3(g). These diagrams were found to be significantly different than those available previously and do provide insight to the phase relations of importance during the thermal processing of Hg-containing wastes. The thermodynamic results were used to conduct a series of Gibbs energy minimization calculations for a thermal processor' afterburner system for the treatment of HgS-containing wastes. The retention of Hg in the discharge calcine was examined as a function of temperature and excess air. Hg was found to report to the calcine as HgSO4, Hg2SO4, or HgSO4 HgO depending on the process conditions, and Hg retention occurs at temperatures as high as 930K. The precipitation of Hg-containing phases from cooled afterburner discharge gas starts at approximately 900K and the cooling of the gas an additional 30K (to 870K) results in over 50% of the Hg being preCipitated as HgS04?HgO. It was also determined that for small amounts of Hg present in sulfide concentrates during roasting, the Hg will be retained as HgSO4 or HgSO4?HgO at temperatures as high as 870K.

Jan 1, 1996

By Rejane Tubino Geyer

The volume of electric arc furnace (EAF) plus oxygen (BOF) slag produced yearly in the world is about 84 million ton. Because of this, the study of recycling processes as a way to solve the storage problem of these slags rise in importance. There are, however, some inconvenients on using this byproduct: lime, which takes part of the process of steel production, remains as a non-reactive raw product in the slag. Since lime reacts in presence of humidity, forming expansive compounds, slag use is strongly limited. There are some utilizations for the electric arc furnace and oxygen slag in the Civil Construction Industry, mainly as base, subbase and asphalt covering in highways. However, independently of the type of recycling, a period of "cure" of about six months is necessary. Because of this slow cure process this byproduct may turn non-competitive in some regions if compared, for example, with the natural aggregate. The objective of this work is to present the flowsheet of the slags production as a residue both at the electric and oxygen steel plants and, through a bibliographic review, to analize the possibilities and limiting factors for the use of steelmaking slags in the Civil Construction Industry.

Jan 1, 1996

By Gunnar Persson

The borehole pressure/time history of blasting practice is simulated in a twin pendulum apparatus, where the expanding shotfiring gases force two steel slab swingers apart. A pilot installation built at SveDeFo is described. The relevant factors, that govern the use of this test method as a means of classifying explosives with respect to their toxic fume potential, are described.

Jan 1, 1996

By S. L. Karunakaran

Selection of an appropriate foundation system requires great skill and ingenuity on the part of the designer. Certain guidelines for choosing between a pile and raft foundation are presented. A number of methods are available for estimating the capacity of piles, giving a wide range of values for the theoretical load carrying capacity. A few aspects to be taken into account while arriving at an appropriate theoretical capacity are discussed. The effect of fluctuation of water table level on the pile capacity and method of accounting for this factor on the pile capacity obtained through initial load test are also discussed. A case study presents a comparison between the estimated values of capacity of piles and the values obtained through the initial load test.

Jan 1, 1996

By Jr. Chilson

This paper addresses the slurry pump industry as it exists today by touching on the business aspects, and by discussing research and development for material metallurgy and hydrodynamics for wear improvement which reduce operating and maintenance cost for the customer. It demonstrates why OEM parts give better value for cost.

Jan 1, 1996

By J. A. Organiscak

Longwall mining technological improvements have provided significant increases in productivity over the last 15 years. Longwall productivity is anticipated to continue to escalate with expanded application of automated equipment. Automation technology that will likely be adopted over the next 5 years is memory cut with shearer initiation of shield movement supervised by a couple of face workers. Operations using this technology will most likely relocate many production workers from the face to the outby gate entries and position several face workers outby the shearer, exposing workers to different health and safety risks. These changing risks are primarily related to worker relocation and expected increased production levels. Workers outby the face will most likely have less dust and noise exposure, but will be exposed to other safety hazards associated with outby equipment movement, materials handling, and gate entry ground movements. The face workers will most likely be exposed to higher respirable dust and noise levels generated by the equipment at elevated production rates. Methane gas emission is also expected to increase with faster mining rates. These operational changes and the control technologies needed to reduce redefined longwall worker hazards at semiautonomous longwall operations require examination to maintain the health and safety of mine workers.

Jan 1, 1996

By Lyle Dennis

Emphasis on increased production while maintaining rigid quality standards has necessitated a change in blasting technology at Dacotah Cement's limestone and gypsum quarries. The following three methods implemented during the past three years have yielded an increase in production through improved fragmentation.

Jan 1, 1996

By A. K. Bakshi

Slurry rheology affects autogenous grinding performance by changing the rock's breakage characteristics. In this study pilot scale batch autogenous grinding was carried out to observe the effect of viscosity on the breakage characteristics of the rocks (the media), and on the overall specific energy consumption. Clay/fines content, and temperature of the initial charge, were varied to alter the viscosity of the slurry. Results showed that at higher slurry viscosity, rocks became more difficult to break, resulting in an overall increase in the specific energy consumption of the mill. Also, it was observed that viscosity had a significant effect on the amount of critical size material present in the grinding circuit, where the critical size material is the material which is too large to be effectively ground in the mill, and too fine to act as grinding media.

Jan 1, 1996

By D. J. McCracken

During 1995, the estimated consumption of lithium minerals in the western world was 139 kt (153,000 st).This amounted to 18 kt (20,000 st) of lithium carbonate equivalent (LCE). Overall tonnage demand for lithium minerals increased by 10.8 kt (11,900 st) during 1995from 1994. From 1992 to 1995, overall tonnage demand has increased 62%, from 85.5 to 139 kt (94,240 st). There are four major producers of lithium minerals. Gwalia Consolidated in Western Australia is the largest producer of spodumene. It supplies high-grade spodumene concentrate, fine-spodumene concentrate, glass-grade spodumene and chemical-grade spodumene.Tantalum Mining (Tanco) of Manitoba, Canada, produces high-grade spodumene concentrate, fine-spodumene, concentrate and montebrasite. Bikita Minerals in Zimbabwe is the largest manufacturer of petalite. It supplies high-grade and container-glass petalite.

Jan 1, 1996

How do you think the US Bureau of Mines closing will affect SME? The demise of the bureau represents a challenge, an opportunity and, above all, new responsibilities for our profession. A lot of good professionals are seeking new positions. A lot of worthwhile research is available for transfer to the private sector. Logic dictates that worthwhile projects of any defunded government activities should find support in the private sector. The bureau may be gone but its legacy is deeply rooted in the profession. The bureau’s contributions will be remembered as long as there are mines and miners. Its1994 research program was divided into three major areas: environ-mental technology; health, safety and mining technology; and minerals and materials science. There must be a place in either the government or private sector to continue these worthwhile activities.

Jan 1, 1996

By Ronald W. Roberts

For years, blasters have experienced near-misses, injuries, and yes, even fatalities as a result of the dangerous nature of our business. Yet, some blasters continue to portray the immortal attitude: nothing-would-or-could-ever-happened-to me syndrome. As we all know, that attitude can become disastrous to yourself or colleague(s).

Jan 1, 1996

By Jan Vrestal, Josef Tomiska, Pavel Broz

"Thermodynamic investigations on fcc solid ternary Fe-Ni-Cr alloys have been performed by means of the computer-aided Knudsen cell mass spectrometry. Ternary T.AP.-series (Thermodynamically adapted power series) are used for the algebraic representation of the thermodynamic excess properties. At 1650 K the molar excess Gibbs energy GE is negative over the whole field of stable fcc phase. The molar heat of mixing HE is exothermic in the predominant part of the fcc phase field. Only between the section with a constant ratio of mole fraction Xcr/XNi = 0.64 and the fcc phase field boundary the HE values are slightly endothermic. The results of this work can be used successfully for phase diagram calculations.IntroductionThermodynamic investigations on multicomponent alloy systems such as the Fe-Ni-Cr ternary system including the three binary boundary systems are very time-wasting and usually beset with considerable experimental difficulties. Additionally, the required experimental equipment is very expansive and the obtained results are not always satistying. Therefore it is understandable that many phase diagram calculations are based only on few experimental values of the molar excess free Gibbs energy GE. Consequently, Kundrat and Elliott [1] as well as Hillert and Qiu [2] used in their reassessments of the phase diagram of the Fe-Ni-Cr system thermodynamic data mainly assumed and/or optimized by means of various reasoning.Lee [3] reported recently, a revision of the used thermodynamic description of the Fe-Ni liquid phase is necessary to obtain a better agreement with the experimental data on the bcc/liquid or fcc/liquid tie lines and liquidus temperatures in the Fe-rich region of the Fe-Ni-Cr ternary system than in the previous assessments. This is 'in full agreement with mass spectrometric investigations of Fe-Ni alloys in the liquid and in the fcc solid phase, published earlier [4,5]. Indeed, phase diagram calculations based upon the molar excess free Gibbs energies GE obtained in these studies yield liquidus and solidus lines in excellent agreement with experimental phase diagram data [5]. Nevertheless, these experimental data have not been considered later on any more, not even in the revision by Lee [3]."

Jan 1, 1996

By H. K. Lin

During slow-cooling crystallization of iron-making blast furnace slags, most rare-earth elements in the feed recrystallize as cerite-calcium while scandium and europium concentrate in a sheet-like "mineral". The mineralogy of this "mineral" is studied with one of the objectives being the extraction of the "mineral" from the slag for recovery of Sc and Eu. This "mineral" has been identified as one of the mica group minerals and can be named as rare-earth-bearing barium fluorophlogopite. The mineralogical characteristics of this "mineral" are investigated and discussed. This "mineral" can be effectively recovered from the slag by flotation with dodecylammonium acetate or a combination of dodecylammonium acetate and sodium oleate as a collector.

Jan 1, 1996

By A. A. Campoli

The U. S Bureau of Mines is conducting research to develop improved guidelines for selecting the type and pattern of roof support in different geologic environments (Mucho, et al., 1995). As a part of this wider research effort, a multifaceted ground control investigation was conducted at the Diamond TB Mine of RoxCoal, Inc. The study included statistical analysis of mine-wide roof bolt performance, instrumented bolt test areas, stress damage mapping, and pillar design analysis. The mine employs state-of-the-art continuous miner technology, including mobile roof supports and continuous haulage, to retreat mine the Lower Kittanning Coalbed. A herringbone section design makes the stability of the center belt entry critical to efficient retreat mining. Roof cutters formed during section development sometimes set up unstable immediate roof conditions in advance of the belt entry mobile roof supports during retreat mining.

Jan 1, 1996

At the Nikkel og Olivin nickel mine near Narvik, Norway, Outokumpu has been the operator since 1993. The mine was opened in 1989 and in 1992 Outokumpu commenced operations to secure concentrate deliveries to Harjavalta's nickel smelter in Finland. Annual production is about 740 000 tonnes of nickel ore grading 0.5 per cent Ni, about 25 000 tonnes of nickel concentrate and about 2800 tonnes of nickel metal. All production comes from underground operations which makes Nikkel og Olivin AS perhaps the lowest grade underground nickel mine in the world today. Production is currently from one of two orebodies, which is known as the Western orebody. The Eastern orebody was worked out by 1995. During Outokumpu's operational period the Western orebody has been delineated and taken to production. The underground exploration and definition drilling involved about 15 000 in of diamond drilling, which was carried out during a nine-month period. Following this a feasibility study was undertaken and production commenced. Improvements were made to the mining methods. Previously the mine utilised open pit equipment underground and this resulted in an enormous amount of additional tunnelling. Grade control and ore delineation were previously based on sparse diamond drilling and all geological information was processed manually. The improvements included the use of underground sludge drilling to increase the amount of geological information, the of a new computer system for grade control and mine planning, new automated underground longhole drilling equipment and the of underground mining equipment which reduced the size of the drives. These changes produced a marked increase in the efficiency of the underground Mine.

Jan 1, 1996

By Jr. Wilkinson

In today's work environment a tremendous amount of data is required to provide the regulatory agencies justification to issue a mining permit. The demands for data, specifically environmental characterization data, grow and the mine plans must address the issues raised by the interpretation of that data. Computers and computer software can provide operators and consultants with the tools necessary to assimilate, digest and interpret these seemingly unmanageable data sets. This paper presents some examples of how Mincom's MineScape software can be applied to the task of developing coal mine permits in an electronic format.

Jan 1, 1996