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Coal-derived flue gases contain CO2/SO2 and these contaminants preferably have to be captured by cheap sorbents. This remediation approach is from the standpoint of addressing issues such as global warming, acid rain and development of Advanced Power Generation Systems and to realize the economic gain as well. Conventional and existing dry scrubbing technologies use regenerable sorbents which are pollutant specific and require expensive stabilizers in order to attain versatility. This paper discusses the use a novel class of sorbents prepared from the heavy metal contaminated Berkeley Pit water (Butte, Montana) by a proprietary process developed at The University of Nevada, Reno. These sorbents are activated mixed spinel ferrite (MxFe,_X04)' Preliminary experimental results show that the sorbents have good desulfurization and CO2 decomposition capacities. The decomposition effectiveness of these mixed spinel ferrites was studied at 300°C and compared against the synthetic magnetite obtained from ferrous sulfate solution in our laboratory. The results indicated that the mixed spinel ferrite had good affinity for the adsorption and decomposition. The CO2 decomposition data of both sorbents fitted the first order reaction kinetics. Even though the surface area of the magnetite was higher than that of mixed spinel ferrite, the CO2 decomposition rate of the mixed spinel ferrite was estimated to be 2.5 times higher than that of magnetite under identical conditions. The carbon analysis deposited on the sample indicated that the CO2 was 100% decomposed into carbon and other carbon! hydrogen compounds by the mixed spinel ferrite whereas the conversion was 43% by the magnetite. In terms of specific adsorption of carbon, ferrite was 3-5 times more efficient than magnetite.

Jan 1, 1996

By M Stewart

The structural framework for the major gold deposits of the Reefton Goldfield was largely established in the 1930s after a detailed regional geological mapping programme. Recent new mapping has now substantially modified the structural framework of the Globe Hill - Devils Creek area and the Waiuta area. Using bedding-cleavage vergence as a method of establishing fold limb facing, many new fold structures have been identified, some of which conflict with long-established structures such as the Globe Hill and Waiuta anticlines. In addition, the mapping of areas of west- versus east-facing limbs constrains the position of many faults. The mineralised Globe-Progress Shear is one such fault which graphically demonstrates major structural discordance of the folds in the hangingwall compared to the footwall. Recognition of the folding is establishing the structural framework for understanding of the origin of these productive gold mining areas.

Jan 1, 1996

By William Petruk

An investigation was conducted to determine whether mineral liberation data obtained by one image analysis technique are the same as data obtained by another image analysis technique. The liberated vs non-liberated, volume % and weight % techniques for measuring mineral liberations by image analysis were tested. The results show significant differences between the values obtained by the different techniques. The lowest liberation values were obtained by the liberated vs non-liberated technique and highest by the weight % technique. It is interpreted that the weight % technique produces the most realistic results. The weight % technique also produces data that can define mineral associations for the unliberated grains. These include (1) mineral quantities in particles that contain different amounts of unliberated mineral, (2) mineral quantities in particles that have different size ranges, and (3) mineral quantities and degrees of liberation for specific minerals in particles of different size ranges.

Jan 1, 1996

By K. Sanjay

Factorial optimisation technique has been used to develop regression equations at different time intervals for extraction of manganese from precipitated manganese oxide/hydroxide in sulphuric acid using charcoal as the reductant. The three parameters chosen for a 23 full factorial design were : acid concentration, amount of carbon and temperature. The regression equations were used to predict >> 90% extractions as well as kinetic data.

Jan 1, 1996

By Zhenglong Li

A process has been developed to recover titanium from a blast-furnace slag which contains about 20-25% Ti02 and 12% Fe. In this process. "hot" slag from the blast furnace is directed to a separate furnace where it is reheated with additives to form two simple slag phases: one is titanium enriched anosovite (Ti3O5) and the other is a titanium lean non-crystal glass phase. The modified slag is then processed by conventional beneficiation techniques to produce a marketable titanium concentrate and a usable slag material. This paper focus on separating anosovite from glass by electrostatic separation and froth flotation.

Jan 1, 1996

By Hillis R

As part of BHP Iron Ore's policy and goal of achieving a high standard of environmental management within its operations, a protocol for mine closure has evolved. The need to demonstrate sound environmental management with respect to site decommissioning meant that a comprehensive, environmentally sensitive closure protocol was required. Within this framework, a four-phase protocol was developed, the first phase was the determination of objectives in relation to site rehabilitation and end land use. The second phase was the determination of the process required to achieve these objectives. The third phase was the application of this process in a site specific manner. The fourth and final phase was monitoring of the site with regard to the achievement of determined objectives. The protocol was originally developed to direct the closure and decommissioning of the Goldsworthy site in 1992. This being the first total site decommissioning for BHP Iron Ore. Since that time the protocol has been successfully utilised for the closure of the Yampi (Koolan Island) operations (in 1993/94) and the Shay Gap/Nimingarra Operations (in 1994/95).

Jan 1, 1996

By Rui-Qing Li, John G. Peacey, Peter J. Hancock

"Noranda has been investigating a pyrometallurgical process for the direct recovery of zinc from zinc concentrate and zinc and iron containing residues. The process consists of injecting dry zinc concentrate and secondary zinc materials into a molten iron oxysulphide bath, volatilizing metallic zinc into furnace off gas essentially free of sulphur or S02, fixing sulphur contained in the feed materials as iron oxysulphide matte which is disposed, and recovering metallic zinc in an ISP type lead splash condenser. Combustion of petroleum coke with air or oxygen enriched air inside the oxygen containing matte supplies part of the heat, and the products of combustion dilute the zinc-laden gas to a desired level.This paper describes the process concept, thermodynamic background, experimental tests, mass and heat balance calculation for a conceptual flowsheet, environmental stability of the residue and advantages and disadvantages of the process. Experimental tests have successfully proved the process concept and thermodynamic predictions. Direct smelting of zinc concentrate and residues inside an iron oxysulfide bath has a great potential to become a cost effective and flexible zinc smelting process.1. INTRODUCTIONZinc is mainly produced by a roast-leach-electrowinning process route, which accounts for about 80% of the world primary zinc production. This process produces high quality zinc with very high zinc recovery (>95%) but suffers from several major drawbacks such as using high cost electricity as reductant, producing environmentally problematic iron containing leach residue (jarosite or goethite) and the difficulty in treating secondary zinc feed materials containing high impurity levels, such as electric arc furnace dusts from the steel industry, and other complex sources. Also in some areas, markets for sulphuric acid are distant resulting in negative realizations on acid sales.The Imperial Smelting Furnace (ISF) process is the major pyrometallurgical process to treat zinc-lead concentrate. The advantage of this process over the electrolytic zinc process is its flexibility in treating high-lead, bulk concentrates with high recoveries of lead, copper and precious metals. However, this is a two-stage process involving sintering of Zn-Pb concentrates followed by blast furnace reduction. The process requires large amounts of high-quality coke which is a major operation cost, and the sintering process which results in serious environmental problems."

Jan 1, 1996

By Stuart Brashear, Lee Schettler

The effect of water on several ANFO/emulsion blend ratios are documented by both physical observations and analytical testing to demonstrate the effect even small quantities of water can have on water resistant blends.

Jan 1, 1996

By A. B. Cecala, G. W. Klinowski

Introduction The US Bureau of Mines has designed and evaluated total mill ventilation systems (TMVS) at two mineral-processing operations. Both systems have proven proficient at cost-effectively reducing respirable dust levels throughout the mills. An 11.8-m3/sec (25,000-cfm) system installed at a clay-processing mill provided about 10 air changes per hour (acph). This system reduced respirable dust concentrations by about 40% throughout the mill building. The second evaluation was performed at a silica sand operation. Tests were performed with 23.6 and 47.2 m3/sec (50,000 and 100,000 cfm) of ventilation to the mill building, corresponding to 17 and 34 acph. Average millwide respirable dust reductions were 36% and 64%, respectively. This work was done to determine general guidelines and design criteria for operations that may be interested in implementing TMVS. TMVS should be designed to draw clean make-up air in near the base of the mill. This air provides general purging and may clear some dust-laden areas throughout the mill structure. It is discharged at or near the top of the structure. Without the TMVS, dust can exit the building through open doors, windows, etc. and contaminate outside plant workers. This dust can also be recirculated back into the mill building causing additional contamination problems. TMVS is not a stand-alone system. It is a supplemental technique to assist other localized dust control systems (Mody et al., 1987). Testing Total mill ventilation systems were evaluated at two processing operations. For both tests, the primary goal was to determine the reduction in respirable dust throughout the structure. Test site No. 1. The first evaluation was performed at a clay-crushing and screening mill in New York. The mill's base dimensions were 39.6 x 9.8 m (130 x 32 ft), giving a volumetric capacity of 4250 m3 (150,000 cu ft). The TMVS was designed to provide 12 m3/sec (25,430 cfm) of ventilation air to the mill, representing about 10 acph. This was accomplished by three 4 m3/sec (8475 cfm) roof-powered exhaustors that were evenly spaced across the roof. Three wall louvers provided inlets for make-up air at the mill's base. Two evaluations were performed at this mill. The first occurred for two days in December when outside air temperatures ranged from -12.2° to 4.4° C (10° to 40° F). Temperatures with the wind chill factor dropped as low as -34° to -40° C (-29 to -40° F) during the early morning. The second evaluation was in April when outside air temperatures ranged between 10° to 26.7° C (50° to 80° F). These two evaluations verified the effectiveness of TMVS in lowering respirable-dust concentrations throughout the mill. Gravimetric-sampler respirable-dust concentrations in December ranged from 0.22 to 2.39 mg/m3 under normal conditions, compared to 0.13 to 1.55 mg/m3 with TMVS. In April, respirable dust concentrations ranged from 0.29 to 4.84 mg/m3 under normal conditions compared to 0.21 to 2.37 mg/m3 with the system on. TMVS also increased visibility throughout the mill building. Dust reductions for gravimetric and RAM-I instruments are listed in Table 1. Each value was determined by comparing the average concentration for the entire day of testing for normal and TMVS values. The mean/standard deviation values for gravimetric and RAM-1 results were 42.5/17.6 and 37.1/16.8, respectively.

Jan 1, 1996

By D. V. Karandikar

Contiguous bored piles have been used in the past for retaining the sides of deep excavation. An innovative version of this method was adopted successfully in two prestigeous projects in Bombay in which in a very constricted and congested locality, adjoining seashore at Walkeshwar, 14 m deep excavations with vertical sides were required. 600 mm dia bored cast-in-situ piles were first installed at 1.2 m c/c and subsequently as the excavation proceeded, they were tied to cast-in-situ RCC waling beams. The shear connectors to the beams were pre-fixed to the pile reinforcing cage at specified depths. The pile / waling beam system was anchored into the ground by installing inclined prestressed cable anchors at the designed depths. The waling beams were also used to support the brickwalls, which formed the required backup wall for fixing the tiled water proofing system. Catch-drains were installed behind the brickwalls for relieving the ground water pressure and thus ensuring a very economic design. The adequacy of the system was proven in that where the system was not installed in time, failure of the sides occurred during monsoon. Whereas in the areas where the above retaining system was installed, there were no problems inspite of heavy monsoon and surcharge of construction materials and equipment. The system became a very effective and economic alternative to an anchored diaphragm wall. The paper presents the case studies of these two projects.

Jan 1, 1996

By J. F. White

An experimental study was undertaken to evaluate the feasibility of a selective chloridizing roasting pre?treatment process for the elimination of impurities from zinc feed?stocks prior to recovering zinc by conventional unit operations. In this investigation, a number of chemistries that might serve as a basis for such a pre? treatment process were examined. A variety of chloridizing agents were admixed with EAF dust to promote the selective removal of lead and cadmium by the formation of volatile metal chlorides, he results of the experimentation firmly establish that selective chloridizing roasting is a technically feasible means of eliminating lead and cadmium from EAF dust. Excellent extraction efficiencies were accomplished with a number of chloride additives; as high as 98 percent lead extraction and 88 percent cadmium extraction were attained with minimal zinc losses, Continuous pilot?scale tests reinforced the trends established by laboratory?scale experimentation, Attempts of chlorine elimination using pyrohydrolysis were less successful. The extent of chlorine elimination was found to be highly dependent upon EAF dust sample type and treatment temperature.

Jan 1, 1996

By D. M. Morrison

"The most important factor in Canadian mining is not the operating cost of current projects but the availability of capital for future projects. The future of mining at depth will be producing ore from the top of the orebody working downward with very effective, tightly controlled mining methods, i.e. either selective mining or bulk mining with well controlled dilution and fragmentation. The key characteristics of future mines will be smaller access excavations, more effective ground support, very precise blasting techniques and more efficient and reliable materials handling systems. Equipment will be smaller and designed for high efficiency and low maintenance, reducing both the capital and operating cost. This means there will be fewer scoops, more continuous mucking machines and conveyor belts, both lateral and vertical.Orepass failures have become accepted and the resultant redevelopment and retramming has become common. The capital investment in so-called permanent ore passes and crusher stations becomes questionable, particularly when crushers are only necessary for less than 10% of the ore going through the system. The best way to solve the chronic instability of ore passes is, as with all of the stability problems at depth, by reducing the excavation size rather than increasing ground support. Smaller access drifts would reduce the capital cost and increase the rate of development as well as reduce the amount of waste to be handled, reducing the ground support and the ventilation requirements. Large drifts and ore passes are essential only for the equipment needed to handle large pieces of ore and the productivity of scoops is very expensive when the requirements for ventilation and large access drifts are taken into account. The key issue is the fragmentation generated by primary blasting.The future of mining in Canada will depend on simple and robust technology geared to the environment in which it will have to operate. Its survival will depend on some-thing much more fundamental and difficult to accomplish than a technological advance — it will require a dramatic change in the way the mining process is managed, how work is organized, how effort is rewarded and how costs are measured — a complete change in mind-set."

Jan 1, 1996

By J. Bostjancic

As wastewater discharge regulations become more stringent, power plants, manufacturing plants and other industrial sites are looking for ways to reduce makeup water requirements and to recycle and reuse as much wastewater as possible. In some cases, environmental regulations require zero liquid discharge, meaning all wastewater must either be retained on site or reduced to solids for disposal off site. Zero liquid discharge or "closed-loop" wastewater treatment systems using evaporators and other process equipment have been well-accepted in recent years. Often overlooked is the fact that zero discharge is not just the latest fashion--many commercial zero liquid discharge systems have been in operation since the mid-70's. This paper will give specific examples of zero liquid discharge operations from 1974 to the present, showing how evaporation equipment and processes have changed to meet the requirements of industry and environmental regulations.

Jan 1, 1996

By John L. Watson

The dewatering of steel industry waste sludges prior to discard or recycling often presents significant problems due to the fineness of the sludge particles, which may blind the filter medium and/or produce a cake with limited porosity, Several steel plant wastes, such as sludges from BOF and EAF gas cleaning operations exhibit not only a very fine particle size, but also some degree of magnetic character, A novel process has been developed to utilize the magnetic character of such sludges to enhance dewatering through a multi-force operation involving magnetic, chemical and vacuum forces, The process consists essentially of undertaking vacuum filtration of a flocculated sludge in a magnetic field, This is achieved by installing a permanent magnetic in a fixed position on the axis of a vacuum drum filter, thus effecting filtration of magnetic and non- magnetic particles, bound together in flocs, in a magnetic field, Previous tests using a modified laboratory vacuum drum filter treating artificial (magnetite) and industry waste (BF sludge) feeds have demonstrated that filtration capacity may be enhanced significantly with increases of up to 3000/0, An explanation of the mechanisms associated with the enhanced filtration was not obvious, and this research was undertaken to permit the cake formation in the magnetic field to be monitored to provide an insight into the manner in which particles agglomerate to form the cake. These tests revealed that the magnetic field caused magnetic particles to be aligned perpendicular to the filter surface and to form channels through which filtrate could freely pass thus increasing capacity, The effects of various magnetic fields and field strengths on the filtration process were also investigated. A simple computer model was constructed to demonstrate the proposed theory of multi-force dewatering, The model output graphically illustrated the suggested mechanism and confirmed the enhanced capacity of the novel dewatering process,

Jan 1, 1996

By A. K. Kyllo, G. G. Richards

"The formation and control of accretions is an important aspect of process operation for gas injection. The nature of the accretion formed can have a considerable effect on a process, especially on the life of the lance or the refractories in the tuyere region. There are three basic shapes of accretion formed on tuyeres; pipes, hemispheres and hollow-cored hemispheres. However, there are wide variations within these shapes. Generally, the type of accretion formed will depend on the injector design, certain operating parameters and the physical properties of the bath materials. This paper seeks to collect the results of previous and current physical and mathematical modelling together with data gathered from operating furnaces, to obtain a better understanding of the effects of process design and operating variables on accretion formation.IntroductionAn important consideration in the design of a gas injection process is the possible freezing of the bath either around the tuyere or on the lance. With proper design, freezing may be controlled to provide protection of the lance or refractory, and to avoid blockage. Improper design may lead to tuyere blockage and significant refractory or lance erosion. In view of this, a good understanding of the heat transfer in the injection region is essential.While tuyere blockage has been a persistent problem since the inception of submerged gas injection processes, the problem of accretion formation was not studied in detail until the development of the shrouded tuyere by Savard and Lee. A number of studies relating to accretion formation have been carried out since then, but there is still little information available relating the nature of the accretion formed to the design of the injection system.The build up of materials on lances is a similar problem, and may also be either beneficial or detrimental, depending on circumstances. Unfortunately, there is even less information available regarding build up on lances than there is relating to tuyere accretions. While the form of build up on lances is generally a simple coating of the lance, accretions on tuyeres tend to be more complex. Tuyere accretions tend to occur in one of three basic forms: pipe, hemispherical and hollow-cored hemispherical (Figure 1). However, there appears to be a considerable variation within these forms."

Jan 1, 1996

By D. M. Jones

Dust generation data have been obtained from 19 industrial Outokumpu flash furnaces. Statistical analyses of the data have been carried out and the most significant factors affecting dust generation evaluated. The results indicate that dust production may most effectively be minimized by: 1) Minimizing the distance between the molten slag and the furnace roof 2) Optimizing burner design and combustion parameters.

Jan 1, 1996

By V. D. Jalevsky

A new methodology of an experimental-analytical approach has been developed. It is used in building an information geomechanic monitoring system for the modeling of geomechanic processes during coal seam working. The approach synthesizes experimental (in-situ) measurements of rock pressure manifestation in separate points, methods of numerical modeling of processes on rock boundaries with coal, and a seam analytical calculation of rock mass in a spatial strained state. One of the realizations of this approach is the developed theory and calculation method of adjoining rock surface shift (overhang) formation during underground working of sheet deposits and of rock mass geomechanic state determination. There are description algorithms of cavity configurations with broken lengths of faces during underground working of useful mineral sheet deposits. These algorithms have been used in computer modeling of formations of adjoining rock surface overhangs and abutment pressure upon rock mass in the area of coal faces with irrectilinear longwalls. Peculiarities of surfaces shifts and stress allocation are established for different face schemes. The use of theory and methods alloww working out techniques of automatic control to receive processing algorithms of RPM measurement results and calculate geomechanic situations within panels in the process of planning and development as well as during mining, i.e., to carry out long-term prediction, in-line control, and short-term prediction of rock pressure manifestations.

Jan 1, 1996

By Frank Sames

A recently developed model is used as a tool to optimize blast designs based on the continuing combination of full scale blast assessment and performance prediction. The use of this tool has allowed to evaluate present blasting practices and proposed designs through a better under-standing of the influence of the various blast parameters. The empirical model has a modular structure covering all aspects of blast performance including 30 fragmentation, potential rock damage and 30 muckpile profile prediction. The modules are assisted by a terrain model which is compatible to most mine mapping systems, and a blast design editor. The evaluation is summarized in a blast management module. Various studies have recently been undertaken using the model to qualify and improve blast designs with respect to wall stability, optimized fragmentation and muckpile distribution, as well as to the control of the environmental effects such as blast vibration and airblast overpressure. To verify the predictions of the modeling, full scale blast assessment techniques were used to qualify blast geometry, explosives and initiation performance, rock movement, muckpile distribution, near- and far-field vibration levels and airblast ovepressures. The model provides a tool to gain an improved understanding of blasting and blast control. The modeling results are presented in a visual form which allows simple comparisons of proposed blast designs. Additionally, the model can be used for detailed analysis and blast management.

Jan 1, 1996

By N. B. Gray, I. F. Taylor

"Gas injection to promote chemical reactions or mixing is a feature of many metallurgical processes. Often the aim of gas injection is to bring about a chemical reaction between the gas and liquid but most of the past physical and mathematical modelling work has ignored the influence of such reactions. In the work reported here, cold model studies have been conducted in which gas reacts with the liquid into which it was injected. The rate of liquid mixing has been measured as an indication of the mechanical energy transfer. It has been found that gas generated chemically within the liquid is significantly less effective at promoting mixing than the equivalent volume of inert gas. The relative ineffectiveness of chemically produced gas is thought to be due to smaller bubble sizes in comparison to the inert gas case. Small bubbles characteristic of chemically generated gas move with low slip velocities relative to the liquid and lead to different turbulence generation mechanisms.IntroductionIn processes such as steelmaking, copper conversion, bath smelting and ladle steel finishing gas is injected into liquid metal where it reacts chemically or simply serves as a source of agitation. An understanding of fluid flow phenomena in such situations is an essential pre-requisite to the calculation of process intensity and the optimisation of vessel productivity. Traditional physical cold modelling approaches to prediction of liquid flow in such situations are now often augmented by the techniques of computational fluid dynamics. Even with the availability of numerical modelling techniques cold physical models continue to have an important role for validation because it is generally difficult to obtain quantitative data from high temperature processes.Almost all previous cold modelling work has been based on the injection of an inert gas into water or some other non-reactive liquid. Such models do not include the significant increase in gas volume inherent in some processes. For example the oxidation of carbon in steelmaking leads to a twofold increase in molar gas flux through the reaction:"

Jan 1, 1996

By F. Patisson

During exothermic gas-solid reactions, heat generation makes temperature rise and modifies the rate of the various mass transfer processes, namely the chemical reaction itself, the pore diffusion and the external transfer. We have investigated this thermal effect during the oxidation of zinc sulfide porous pellets in a thermo balance furnace, between 550 and 900°C-and under O2-N2 atmosphere. The results have been' analyzed by using, firstly, the law of additive reaction times derived from the isothermal Grainy Pellet Model, and, secondly, a new numerical model taking into account non-isothermal conditions. Both the models can satisfactorily simulate conversion versus time, but the numerical model also depicts the temperature evolution within the pellet. Finally it is shown that owing to the heat generation the zinc sulfide oxidation takes place under diffusion control (3/4 internal, 114 external) in all the cases studied. During the course of reaction, the. pellet undergoes strong temperature variations, with thermal gradients confined to a shell oxide layer.

Jan 1, 1996