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By B. Moudgil, M. Bogan

A bench-top centrifuge was used to study the consolidation behavior of phosphatic clays. A mathematical model (based on, first-order kinetics) was developed to describe the relationship between the void ratio (at any time) and the effective stress. The permeability of the sediment as a function of the void ratio is also described. The results of this analysis are then compared to data obtained by other consolidation testing methods. The centrifuge results indicate that consolidation data may be developed in a short period of time (hours) as compared to days or weeks when other techniques are used.

Jan 1, 1997

By F. S. Knoll

Magnetic separation employing superconducting technology is now accepted within the Kaolin processing industry, proving the value of this technology and its ability to operate reliably even at the most remote site. Developments in superconducting magnet engineering, including cryogen free operation, combined with experience in mineral processing enables new forms of Wet and Dry superconducting magnetic separation to be developed. Applying the high magnetic force advantages at 5 T else available from such magnets to other materials is now a reality. High magnetic force mineral separating system developments are reviewed allowing the mineral processor to take advantage of a technology that is no longer confined to the laboratory.

Jan 1, 1997

By M. L. Leming

Introduction In the decades since silica gel was first identified in material exuding from cracked concrete, a great deal of research has been conducted regarding the chemical reactions between the alkalies found in portland cement and silica found in aggregates. The reaction is complex and one that is not yet completely predictable, especially from the point of view of developing specifications that are appropriate to all situations. This paper is not intended to be a rigorous review of the research findings but is an attempt to provide a simplified review of the mechanisms of the alkali-silica reaction (ASR), so that one can better understand the implications of the specifications, test results and effects on structures. In addition, the contractual relationships between the aggregate supplier and one of their major clients, the concrete supplier, will be examined with regard to the ASR. ASR basics Silica. Silica (silicon oxide) may exist in naturally occurring aggregates in various forms and in combination with a number of other elements. When the silica is completely crystalline, such as in quartz, it is chemically and mechanically stable. Quartz silica is impermeable and reacts only on the surface of the crystal, where the silicon and oxygen bonds are broken. Because the surface area per unit volume of most quartz is low, the reactivity is also low. Completely amorphous (noncrystalline) silica is, on the other hand, more porous and very reactive. The less "crystalline" the silica is in the aggregate, the more reactive. Silica that has melted and cooled quickly without recrystallizing, creating a glassy material (such as in certain volcanic aggregates), has a very low state of crystallization and will be much more reactive in an alkaline solution. Crystalline silica that has been transformed by heat and pressure may have a large quantity of strain energy stored in the crystal lattice. The presence of this higher energy will make the silica more likely to react. The "strained quartz" found in many metamorphic aggregates means that these aggregates are potentially susceptible to deleterious alkali silica reactivity, although the rate of reaction is typically much slower than with aggregates composed of or containing glassy or amorphous silicas. Another problem may exist with aggregates in which the silica is primarily crystalline. In aggregates such as chert, in which the silica exists as very fine crystals (i.e., crypto- or microcrystalline), the very high surface energies between the crystals contribute to alkali sensitivity. Therefore, the potential reactivity of an aggregate is seen to be a function of both the degree of crystallization of the silica in the aggregate and the amount of energy stored in the crystal structure, whether due to a large quantity of microcrystalline silica, a high strain energy stored in the crystals or some combination of these factors. The surface area per unit volume of the reactive silica will also affect the rate of reaction, because a larger surface area of reactive silica will have more opportunity to react. Obviously, the reactivity of the aggregate is also affected by the silica content. However, in this case, the results are not quite so obvious. A discussion of the effect of silica content will be postponed until after a discussion of the contribution of the cement paste. Paste characteristics. Hydrated portland cement is a very alkaline material with a pore solution pH typically in excess of 12. The alkaline environment of moist concrete provides an ideal place for noncrystalline or cryptocrystalline silica to react. However, not all alkalies are equal in their effects. Calcium compounds react with glassy silica to form calcium silicate hydrate, commonly abbreviated C-S-H a poorly crystalline material that can occur in several forms and chemical compositions. C-S-H was at one time called tobermorite gel, because it was chemically similar to the naturally occurring crystalline mineral tobermorite and because it had a gel-like (noncrystalline) structure when viewed under an optical microscope. The formation of C-S-H is the basis for both portland cement hydration and reaction with, for example, fly ash. C-S-H is relatively stable. Although drying will cause some shrinkage and rewetting will cause some expansion, the volume stability of the C-S-H is very good compared to the volume stability of most alkali silica gels. Alkali silica gels with high sodium contents, for example, are nonstable compared to C-S-H.

Jan 1, 1997

By D. Pacey

"This paper reviews the installation, start-up, and operation of a comprehensive monitoring and targeting management technique in which all plant utilities (i.e., electricity, natural gas, compressed air, and water) are managed as controllable resources in the same way that raw materials, mined ore, personnel and capital are managed.The essential elements of monitoring and targeting (M&T) include:•gathering in a systematic, disciplined way the utility information by energy account centres;•closely monitoring the utilities used in each centre and comparing them with production on a common time base (e.g., kWh/ton per day);•bench marking and target setting to pro-vide attainable energy reduction goals which can be further refined as they are achieved; and•establishing an implementation plant that may provide efficiency enhancing benefits to various operating areas within the plant.The M&T system will reduce utility consumption per unit of production on a continuing basis.This would translate into sustained operating cost and waste. M&T will also provide better information for assessing the plant operation and progressively implementing further enhancements."

Jan 1, 1997

By Bernard Woolley

The history of the use of calcium aluminates in mining is discussed including a review of very rapid hardening concretes, anchoring using cement capsules and pumped ground control systems. Specific reference is made to the long term performance of highly abrasion resistant orepass lining in South Africa and the use of rapid hardening materials for a range of applications in Australian coal mine where water infiltration creates difficulties or where rapid repair or return to service is required. The topics covered in detail are, high strength abrasion resistant concretes with a 20 year, 30 million ton ore pass life. Rapid reinstatement of wet and worn roadways using mineral dewatering and rapid roadway rebuild solutions, all in I maintenance shift. The different applications are illustrated using examples from operating mines.

Jan 1, 1997

By Douglas R. Burns

In New England, an area of the country where 3 ½" holes are considered large diameter,we are starting to experiment with 5" and 6" holes. The results are excellent in some areas and poor in others. The geology of rock is the major consideration to account for the blasting results.

Jan 1, 1997

The National Mining Hall of Fame and Museum in Leadville, CO seized the opportunity to show off during its 10th anniversary induction banquet on Sept. 6. "We wanted to make people more aware of the mining hall of fame and museum," said Carl Miller, its executive director. The annual event honors inductees into the Mining Hall of Fame. This year, the inductees included Paul Wheeler Allen, Joseph Rosenblatt, Arthur Fay Taggart, Joseph Toy, Joseph Wharton and John Benjamin Zadra (ME, August, pp. 60-63). Allen, of Pasadena, CA and Rosenblatt, of Salt Lake City, are both living. Only Allen was able to attend. This year's induction banquet was the first held in Leadville, North America's highest incorporated city, at 3,094 m (10,152 ft) above sea level. The banquet gave attendees an opportunity to see the museum in its century-old 6,500-m2 (70,000-sq ft) Victorian schoolhouse. Many of the 350 guests came in 1890s dress to the black-tie affair. The evening included a cocktail reception and an open house along with a catered, prime rib dinner. During the open house, attendees had the opportunity to tour the museum's 12 rooms of exhibits and displays. Among items of interest, it was noted that a framed directory of inductees now enhances the entrance to the hall of fame. The directory is organized by the inductees' names and the location of their plaques, allowing visitors to quickly find hall of fame members. Noted mining historian and author Duane Smith delivered the keynote address at the banquet. After the induction of the six honorees, attendees danced to the big-band era music of the Leadville 17-piece band BandAge. Karl Elers was the master ceremonies for the evening's program. He is a member of the hall of fame's board of directors and is chairman of Battle Mountain Gold Co. Allen was honored by the presence of 26 former colleagues and associates. He told the audience that he originally thought the museum should have been located in Denver. "But I have been proven wrong," he said. For many years, Allen was the operational executive of Cyprus Mines Corp. and a key participant in the company's growth. Allen received a replica of his mining hall of fame plaque from Thomas Falkie, chairman of the hall of fame's board of governors and president of Berwind Natural Resources Co.

Jan 1, 1997

The recent mine disasters in Australian coal mines have initiated an introduction of Self-Contained Self-Rescuer (SCSR) as component in the development of new escape strategies for miners. These self-contained self-rescuers are closed circuit, demand sensitive breathing apparatus that make oxygen available to the wearer for a nominal period of time. Their operation is completely independent of the surrounding atmosphere. Once properly donned, the SCSR can assist a miner to escape from an area containing smoke, toxic gases or an oxygen deficient atmosphere. The duration of a typical SCSR is usually taken at the point of complete collapse of the breathing bag which is accompanied by an increase in breathing resistance and inhaled levels of carbon dioxide. Because the oxygen consumption (V02) and the heart rate are correlated, a prediction of V02 and consequently the duration of an SCSR can be made by monitoring the heart rate. Thirty-seven volunteers participated in field simulated escape trials at four underground coal mines. The results from the field trials suggested that oxygen consumption depends on the heart rate, the body weight and exercise rating of the miner. All the volunteers were asked to fill out the questionnaires to evaluate the performance of the units. The miners indicated that they could tolerate the inhaled temperature without any difficulty to breathing resistance. A complete statistical analysis of the field results is also presented.

Jan 1, 1997

Large-scale shear apparatus is designed to investigate the shear hehaviour of simulated soft rock joints under constant normal stifmess condition. Regular saw-teeth profiles having inclinations between 9.5" and 26.5" have been tested. The strength envelope based on these test results indicates that predictions made by Panon (1966) are accurate for the lower asperity angles. However, for higher asperity angles, Patton's model overestimates the shear strength especially in the low to medium normal stress range. In contrast, while Barton's model (1973) is realistic for Constant Normal Load (CNL) condition, it seems to be inappropriate for modelling the shear behaviour of soft joints under Constant Normal Stiffness (CNS) condition. An empirical strength envelope for the prediction of peak shear strength of joints is proposed in this study to account for the change in normal stress and surface degradation during CNS shearing.

Jan 1, 1997

By Tom Treleaven

The widening of the Panama Canal to approximately 130 feet (40 m) for its entire length began just a few years ago. The original expansion program was slated for completion in 18 to 20 years, but has recently been reduced for completion within the next four years. This means that a tremendous amount of blasting at simultaneous points along the canal, by both the Panama Canal Commission (PCC) and many subcontractors, is necessary to achieve the new completion deadline. The accelerated program also imposed many logistical concerns, since marine trafIic is always heavy and cannot be stopped for blasting. Because some of the large and heavy cargo vessels clear the bottom of the canal by only about 6 feet ( 2 m), the blasting cannot result in any large boulders into the center of the canal, for fear of grounding and damaging a vessel, not to mention the traffic delays and lost income of approximately 1 to 2 million dollars per day.

Jan 1, 1997

By T. Malterer, R. Adams

Peat has unique physical, chemical and biological properties. These include high porosity and water retention, high absorption and adsorption properties, and high buffering capacity. In addition, peat is a rich medium for microorganism activity. Peat has traditionally been used for horticultural purposes. However, in recent years, peat is increasingly being used for waste- treatment purposes. This paper reviews North American literature on the use of peat for waste-treatment applications. The literature indicated that peat has potential for use in the treatment of municipal and on-site effluents, for the removal of low concentrations of heavy metals and for the adsorption of liquid and gaseous hydrocarbon pollutants.

Jan 1, 1997

By G. Simmons

Santa Fe Pacific Gold Corporation (SFPGC) conducted pressure oxidation pilot plant studies at Hazen Research, Inc. on the Twin Creeks refractory carbonaceous gold ores during 1993 and 1994. Previous laboratory investigations demonstrated very good gold recoveries of 90 to 95%, using CIL cyanidation after batch pressure oxidation. However, results from the pilot plant showed that several ore types responded very poorly, with gold extractions of only 45 to 75%. Since these poor recoveries were unexpected, pilot plant testing was suspended for approximately four months while extensive research activities were conducted to determine the cause(s) and identify potential solutions. This paper describes the batch and pilot plant test results, the research activities that eventually identified the cause of the gold recovery problem, and the final semicontinuous and continuous pilot plant operations that confirmed possible solutions.

Jan 1, 1997

By Chas. E. Shumate

There is assembled here this morning in Chicago the heartland of America, what is undoubtedly the greatest concentration of Technical, Scientific and "CAN DO" knowledge ever assembled in America. The participation in this Conference by the representatives of so many nations is particularly impressive and is a further indication of the importance of the subject matter of this conference which you will be discussing in much detail during the next few days. Another impressive feature of this Conference is the participation of a large segment of the construction industry in whose hands fall the job of building what others design. Also strongly represented is the manufacturing industry whose capability is well known throughout the world. They have the resources to design, develop and manufacture the machines and specialized equipment needed to do any job which the world requires. You should not expect to gain any knowledge from my few remarks this morning as I am undoubtedly the least qualified individual in this room on the highly technical and scientific subjects you will be discussing during these next few days. However, I shall offer a few broad suggestions on subject matter which I trust may generate serious thought during your discussions.

Jan 1, 1997

By A. Desbiens, R. del Villar

"This two-part paper summarizes the design and implementation of a distributed PIbased control strategy installed at the B grinding circuit, at the Kidd Creek Division of Falconbridge Ltd. Part I details the design of the control strategy using a grinding circuit dynamic simulator (DYNAFRAG). The first step consisted of sampling campaigns and data processing to calibrate DYNAFRAG. Then, several control alternatives were designed and tested with the simulator. The main feature of these strategies is their ability to regulate or keep within an upper and lower limit five output variables (circulating load, rod mill density, cyclone feed and overflow densities and pump box level) with only three manipulated variables (rod mill water, pump box water and rod mill tonnage). By simulation on DYNAFRAG, it was possible to discriminate among several control structures. The preferred control strategy uses a saturation algorithm, which allows the adequate regulation of two measured variables with only one actuator. Controllers located in interacting loops are appropriately tuned, taking into account the existing process coupling. Part II will present the implementation of the selected control strategy.IntroductionSteady state simulators are used to predict the stationary state of a given process under specific operating conditions. Tradi - tionally, steady state simulation has been applied for process flowsheet design, for evaluating process modification benefits or for determining key operating parameters in process operation optimization. Dynamic simulators add a new dimension to process simulation since they allow the prediction of the process transient behaviour, resulting from the application of a different set of operating conditions and/or from natural disturbances or equipment failure. Dynamic simulators can also be used for the training of new operators or for the design of control strategies."

Jan 1, 1997

Geostatistical literature has been dealing with recoverable reserve estimation techniques for the last 30 years. There have been well established support correction techniques (Le. affine correction, indirect log-normal correction, etc.) to deal with volume -variance relationship globally in determining what will be the reserves above a cutoff grade during mining. Kriging has become the accepted technique in the mining industry for ore reserve estimation. Many large companies are using this method for gold and copper deposit modeling. In general, the estimates coming from kriging are smooth. The variances of the block grades estimated by kriging are often lower than the material that will be mined selectively. As a result, kriging tends to under estimate reserves at high cutoff grades and overestimates them in low cutoff grades. It is necessary to perform additional steps after kriging if the goal is to determine recoverable reserves at some cutoff and not the in situ resources. In the mining industry, it is becoming more and more common for the low grade heap leach projects to consider whether the higher grade portion of a deposit may be processed by a mill at higher profits. Similarly, a concentrator -refinery operations are implementing heap leach -SX-EW option for the lower grade portion of their deposit. These options are making it very critical to estimate the low and high end of the grade distributions more accurately. Ore reserve estimation is normally done by using widely spaced exploration data which has very small size support (Le. core samples). Selective mining is carried out on ore control that is based on closely spaced blasthole data normally averaged into larger polygons based on some cutoff grade. Estimated grades from exploration data need to reflect the variability of the grades of the selectively mined units if they are used without further adjustments to predict recoverable reserves.

Jan 1, 1997

By Espi J

The Nena high sulphidation deposit, located in the Sandaun Province, PNG, contains a measured and indicated resource of 51 Mt of copper ore grading 0.5% Cu and 0.6 g/t Au at a 0.5% Cu cut-off. The copper orebody is overlain by an 18Mt oxide gold resource grading 0.1 % Cu and 1.4 g/t Au at a 0.6 g/t Au cut-off. The deposit is hosted in advanced argillic altered pyroclastics interstratified with lavas, volcanoclastics, epiclastics and sediments of the Debom Volcanics within the Frieda River Intrusive Complex. Foraminiferal sediments indicate the Debom Volcanics to be Early-Middle Miocene in age. Alteration is elongated along, and concentric about a northwest trending structure (Nena Structural Corridor) which is about 7km in length. The inner two alteration types, residual and massive silica-alunite are strongly brecciated and host the bulk of later hypogene Cu-Au mineralisation. Weakly mineralised weak silica- alunite and barren peripherally zoned clay alteration surround the inner mineralised alterations. The hypogene sulphide deposition was polyphasal, episodic and is zoned from north to south from covellite-enargite ¦ chalcocite (5600N to 5200N) to a mixed enargite-luzonite (5200N to 4700N) to luzonite-stibioluzonite (4700N to 4400N) in the south within a 1200m long by 300m diameter sub horizontal pipe like body. Paragenesis studies indicate that pyrite ¦ marcasite were introduced early with barite and black native sulphur before deposition of banded pyrite (melnicovite) with barite during a period of brecciation. Continued brecciation allowed bladed covellite ¦ chalcocite followed by enargite-luzonite-stibioluzonite ¦ pyrite (brassy) and minor acicular covellite deposition. Yellow native sulphur and trace amounts of galena were deposited in remaining pores. Pre-acid alteration intrusives domed the mainly volcanic stratigraphy in the southwest and post-mineralisation porphyries in the northeast truncate mineralisation. Supergene processes and erosion have modified the top of the deposit, creating a 45m thick goethitic-scoroditic-haematitic gold cap above a 40m thick (on average) chalcocite rich supergene blanket. Lesser amounts of digenite, covellite native copper and rarely seen malachite occur in the supergene copper zone.

Jan 1, 1997

By Batric Pesic

Solvent extraction of nickel and cobalt from the real leach solutions was studied by using a novel extraction system. The extraction system was a mixture of 2,6-bis-[5-n-nonylpyrazol-3¬y]] pyridine (BNPP) and dinonylnaphthalene sulfonic acid (DNSSA). The BNPP represents a novel molecule, which was designed and synthesized in our laboratory. Real solutions for the study were prepared by leaching of two different cobalt-nickel bearing concentrates, cobaltite [CoAsS] concentrate from Blackbird Mine, Idaho, and siegenite [(Ni,Co)3S4] concentrate from Missouri Lead-Belt. The major strength of the system was the selectivity of extraction toward nickel and cobalt from iron containing solutions. Other metals such as Mn, Mg, Ca, Al and As were not extracted. Due to the irreversibility of copper extraction, its removal from solution was required prior to the extraction of nickel and cobalt. Zinc was not as strongly extracted (i.e. its stripping was readily achieved) as was copper . Flowsheets for the recovery of nickel and cobalt were also developed.

Jan 1, 1997

By Y. Akin

The floatability of a typical boron mineral, colemanite (Ca2B6O11.5H2O), is shown to be hindered by the presence of montmorillonite type clay minerals. The clay is found to act in the form of slime coating. The mechanism of slime coating is investigated using pure colemanite and clay and their mixtures with an anionic reagent in a microflotation cell. Adsorption, flotation, solubility, zeta potential and scanning electron microscope studies reveal that slime coating occurs through electrostatic attraction. It is possible to minimize the effect of slime coating either at high surfactant concentration or at high pH values.

Jan 1, 1997

Water contact angles in the air/water/francolite, fuel oil/water/francolite and fuel oil/water/quartz systems were measured to describe the wetting characteristics of these minerals. It was found that white francolite is more hydrophilic than black and tan francolite both in the absence and presence of fatty acid addition. The contact angle measurement results do not correlate very well with the flotation response and it appears that kinetic aspects of the bubble attachment process play an important role in the francolite-fatty acid flotation system.

Jan 1, 1997

By H. J. Ilgner

The paper reviews the results to date of an integrated research programme currently being conducted by CSIR Mining Technology, aimed at impacting significantly on concentrated mining with face advance rates of up to 20 times faster than presently achieved. Consideration is given to the interplay between innovative technologies for continuous non-explosive mining or rock comminution underground and lateral hydraulic transportation in cross cuts, haulages and eventually hydro hoisting. Novel technologies for underground comminution of reef and development waste and an innovative pumping system suitable for the hydraulic transportation of coarse comminuted rock are reviewed. Emphasis is placed on South African gold mine reef and waste samples comminuted by electric shock wave comminution technology. The innovative TORE® pump system appears to be well suited for the successful hydraulic transportation of rock, produced by electric shock wave comminution, at solids concentrations between 45 % and 67 % by mass.

Jan 1, 1997