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By Harry Parker

Resource and Reserve Audits Becoming Increasingly Common Types of Audits -Review of Methodology (‘Fatal Flaw’) -Due Diligence – (‘Sign Off’) -Endorsement – (‘QA-QC’) Suggested Standards in Red

Jan 1, 2003

By Maneesh Singh

During the various stages of iron & steel production a number of iron-rich by-products are generated. The traditional way to recycle them back to the blast furnace has been the balling - sintering process. These by-products can also be made into cement-bonded agglomerates for use as burden material for blast furnaces. In order to improve the quality of agglomerates the effects of various processing parameters on the properties of cement-bonded briquettes have to be controlled. This paper looks into the various aspects of producing cement-bonded agglomerates and using them as burden material for blast furnaces.

Jan 1, 2003

By Fumitaka Tsukihashi

Increasing amounts of steel scrap are being used as resources for steelmaking. Therefore, there has been a growing interest in the removal of harmful tramp elements such as antimony, zinc, tin, arsenic, bismuth, lead and copper from the molten steel. The problem that should be solved is the economic removal treatment of residual tramp elements in the steelmaking processes and the production of high quality steel by reducing the effect of the contaminated tramp elements and satisfying the environmental regulations. In this paper, the available thermodynamic data of the residual tramp elements in the molten steel arc summarized and the possibility of the removal of residual tramp elements from the molten steel is thermodynamically estimated.

Jan 1, 2003

By A. R. Miller, M. C. Bétournay, D. L. Barnes

"A number of successful proof-of-concept projects have been carried out to replace conventional power application, such as diesel and rechargeable batteries, in underground mine vehicles. This has led to the development and testing of the world’s first fuel cell production vehicle, a mine locomotive. A fuel cell loader is being built and tested.This paper provides an insight into other projects that are being carried out. Some are related to further underground applications, and some to further research, such as refueling options, power plant durability, and vehicle automation.Also outlined is an evaluation of the overall mining applications and advantages this technology can bring to underground mining, including the facilitation of automation and tele-remote operation."

Jan 1, 2003

By N Clarke, R Dineen, W Jones

The Mt Lyell copper mine in western Tasmania has discharged acid drainage (AD) into the Queen and King Rivers and Macquarie Harbour for over a century. Presently, dissolved copper loads of about 1000 tonnes per annum and dissolved aluminium loads of >2000 tonnes per annum are contained in the AD, which is derived from underground workings (~60 per cent) and historic waste rock dumps (~40 per cent). Flows vary from about 100 L/s during dry periods, to >400 L/s during the wet winter. The site is presently operated by Copper Mines of Tasmania (CMT) who are not responsible for the acid drainage generated from the mine site. Although western Tasmania is famous for its mining history, tourism and aquaculture have emerged as the new industries on the West Coast, with a major tourism railway (the Abt) recently opened along the banks of the Queen and King Rivers. The emergence of these industries in a æclean greenÆ Tasmania has resulted in a strong community and government push to remediate the acid drainage. Remediation investigations and efforts at Mt Lyell were initiated by the Department of Primary Industries, Water and Environment (DPIWE), previously known as DELM, in 1995, and have included the quantification of environmental impacts arising from the AD, and the investigation and costing of potential remediation options. A primary focus of the work has been to identify cost-neutral options which recover metals from the AD in a saleable form to help defray on going treatment costs. This paper summarises these activities in generally a chronological order, highlighting findings of the program that are potentially applicable to other acid drainage sites.

Jan 1, 2003

By Y. H. Suh, H. C. Lee, D. S. Kim

A progressive karst formation and its influence upon engineered structures in the ‘phil-karst’ rock mass draw a tunnel engineer’s special attention to a long-term stability and the maintenance issues. Karst sinkholes of any size beneath the railway bed cause train wrecks or long interruptions in train traffic during rehabilitation work. The collapse of cave roof, called a ‘doline’, is in general connected to the cave by the gradual dissolving of the rock, developing into subsidence and sink-holes. The principal conclusions obtained from the field experiments are as follows: It is found that the development of karst cavity shows a relationship with a structural geological line and it is necessary to define the dominant directions of joint and geological layer (formation). The relation-ship between the water flow and joint direction can be used as an indicator of cavity presence in their direction. In addition the direction of in-situ stress can play a role in the development of karst cavities. A risk map of karst scenario is produced for the tunnel supporting systems with rock type classifications in water-soluble karstic rock mass. Eine fortschrittliche Karst-Formung und sein Einfluß auf angelegten Strukturen in der Phil-Karst-Felsenmasse wecken einem Tunnelingenieur eine besondere Aufmerksamkeit zu einer langfristigen Stabilität und der Wartungsausgaben auf. Karstensinkhöhlen in irgendeinen Größen unter dem Eisenbahnbett sind die Ursache der Zugeszerstörung oder der langen Unterbrechungen in Zugverkehr während Rehabilitationsarbeit. Der Zusammenbruch von Höhlendach, d.h. ein “doline”, ist im allgemeinen an die Höhle, die durch das allmähliche Auflösen des Felsen zu entstehen ist und sich in die Subsidence und Sinkhöhlen entwickeln, angeschlossen. Die Hauptschlüsse, die von Feldenprüfungen erhalten wurden, sind folgendermaßen: es wird gefunden, daß die Entwicklung von Karstenhöhlung eine Beziehung mit einer strukturellen geologischen Linie zeigt und es notwendig ist, die vorherrschenden Richtungen von Gelenk und geologischer Schicht (die Formung) zu definieren. Die Beziehung zwischen dem Wasserablauf und der gemeinschaftlichen Richtung kann als ein Anzeiger von Höhlungsanwesenheit in ihrer Richtung benutzt werden. Zusätzlich kann die Richtung von In-Situ-Spannung eine Rolle in der Entwicklung der Karstenhöhlungen spielen. Für das Tunnelunterstützungssystem, welches mit Felsentypenklassifizierungen in wasserlöslicher Karstic-Felsenmasse, ist eine Risikokarte von Karstenszenar hergestellt. Une formation progressive de karst et son influence sur les structures tracées dans la masse de roche "phil-karst" retiennent l'attention particulière des ingénieurs de tunnel aux problèmes de la stabilité à long terme et du maintien. Les creux de karst de toute la taille sous le chemin de fer causent les accidents de trains ou de longues interruptions pendant le travail de réhabilitaion. L'effondrement du plafond de caverne qui s'appelle "doline" s'est, en général, connecté à la caverne par dissolution progressive de la roche, en devenant l'affaissement et les creux. Les conclusions importantes venant des experimentations sur le terrain sont suivants: d'abord, le développement de la cavité de karst montre le rapport avec la ligne géologique de la structure et il est nécessaire de définir les directions dominantes du joint et la couche(formation) géologique. La relation entre l'écoulement de l'eau et la direction du joint peut être utilisé comme un indicateur de la présence de la cavité dans leur direction. De plus, la direction sur place peut contribuer au développement des cavités de karst. Le plan risqué de karst s'est produit pour le système d'appui du tunnel avec les classifications du type de roche dans la masse de roche karstique qui est soluble dans l'eau.

Jan 1, 2003

By Marlize Barkhuizen, Chris Aldrich

"Owing to environmental constraints, safety considerations and competitive pressures, the development of model-based process control and other automated systems have experienced considerable growth in the last few decades. Reliable process models are usually critical to the successful implementation of these systems. In complex processes, these models are often constructed from process data, as modelling from first principles may not be feasible or cost-effective.Even so, modelling or identification of nonlinear systems from historic plant data can be a daunting task and in the process industries the problem is complicated by the presence of noise from various sources, nonstationarity of the data, intermittence, such as observed in particulate flows, etc. Traditional methods, such as frequency analysis and linear modelling do not handle these systems well. Similar problems arise with the application of nonlinear theory developed over the last few decades, where much of the analysis depends on embedding of the data in a phase or pseudophase space, since these methods were not originally designed to deal with noisy systems.With singular spectrum analysis, the data are embedded in a high-dimensional reconstruction, followed by the introduction of a new coordinate system, where the origin is moved to the centroid of the reconstructed system states and the axes are represented by the dominant principal components of the states (points)."

Jan 1, 2003

By Steve Dillingham

The explosives business by nature is providing a specialized, valued service and associated products to a variety of customers whether mine, quarry or construction related. The level of performance demanded by the customer will typically coincide with his or her individual needs. Some will seek out the skills and knowledge of a blasting expert, while the focus of others is simply on production amounts.

Jan 1, 2003

By D. Bessinger

The present paper provides a brief overview of the thermodynamics of titania rich slags, an outline of the Multi-Phase Equilibrium (MPE) package and its application to ilmenite smelting. Through assessment of published experimental data on various systems containing TiOx, it was found that despite considerable scatter in measured phase equilibria data for the binary Ti2O3-TiO2system,the behaviour of binary and higher order titania rich slags and oxide solid solutions phases could be represented by solution models in the MPE package. Results from the applications of the MPE model on the stability of solid phases and slag-refractory interactions will be presented and discussed. Parallels will be drawn between the predictions by the model and observations made during pilot plant tests. Key words: Thermodynamics, titania slags, ilmenite smelting, phase equilibria, refractory.

Jan 1, 2003

By Ch. Schroeder, F. Collin, R. Charlier, Y. J. Cui

The paper proposes two numerical models ot the mechanical behaviour of chalk. First, an elasto-plastic constitutive law reproduces the different plastic mechanisms of the chalk and the influence of pore fluids by introducing the concept of suction. Secondly, a model able to reproduce time dependence behaviour. Eventually, the paper gives a simulation of an academic reservoir during depletion and waterflooding phase. Der Artikel stellt zwei numerische Modelle des mechanischen Verhaltens der Kreide vor. Das erste ist ein elasto-plastisches Modell, das verschiedene plastische Mechanismen der Kreide und den Einfluss von Porenflüssigkeit, unter dem Begriff der Suktion, reproduziert. Das zweite Modell berücksichtigt darüberhinaus das zeitabhängige Verhalten. Schliesslich zeigt die Veröffentlichung eine Simulation einer theoretischen Lagerstätte während der Entleerung und der Wasserinjektion. L'article propose deux modèles numériques du comportement mécanique de la craie. Le premier est une loi élasto-plastique qui reproduit les différents mécanismes plastiques de la craie et l'influence du fluide interstitiel par l'introduction de la notion de succion. Le second est un modèle prenant en compte les effets différés. Enfin, l'article présente une simulation d'un réservoir académique durant les phases de déplétion et d'injection d'eau.

Jan 1, 2003

By Bora Derin

The partial pressure ratios of sulfur and oxygen for several copper flash smelting plants were derived using the Reddy-Blander (RB) model and predicted dissolved sulfur contents available in the literature. The sulfide capacities (Cs) of six different flash smelting plants (FeO-CuOo.5- CaO-MgO-FeOu-AlO15-SiO2) slags were calculated. The log (PO2/PS2) versus matte grades of various industrial processes was determined. The PO2/PS2 ratio increased with an increase of copper grade. The calculated partial pressure ratios for the copper flash smelting are in good agreement with those of the experimental data.

Jan 1, 2003

By R Carreau

The results of a detailed acid rock drainage (ARD) prediction program were used to revise the waste rock segregation criteria at the Restigouche open pit mine. Waste rock at the site was predominately derived from altered volcanic rocks that hosted a massive sulfide lead/zinc orebody. The program assessed the five years of drainage chemistry from both the potentially acid generating and the non-acid generating waste rock storage facilities in addition to laboratory-based kinetic test results. Material-specific leaching characteristics including relative metal-release rates and neutralisation potential depletion rates were determined from 12 laboratory-based kinetic tests. Solid-phase analyses indicated that, although pyrite was typically the most abundant sulfide mineral in the waste rock, its abundance varied significantly as documented by total sulfur contents ranging from 4.0 per cent. Kinetic test results were used to establish revised waste rock segregation criteria based on total sulfur content and neutralisation potential. The revised criteria maintain that waste material with a total sulfur content 4.0 per cent as potentially acid generating. When present in sufficient quantities, ankerite provided an effective source of neutralisation potential for the range of observed sulfide oxidation rates. Kinetic testing documented that up to 6 kg CaCO3/t was ineffective at neutralising acidity in samples that contained >4 per cent S. The carbonate molar ratio measured from the humidity cells was adjusted to reflect the stoichiometry of the ankerite and applied as an NP/AP criteria for waste rock containing 0.1 <S per cent <4.0.

Jan 1, 2003

By J. H. Huang

In this investigation, the selective precipitation of cobalt and molybdenum from Co-Mo aqueous solutions was studied in order to recover efficiently valuable elements from industrial effluents generated from a novel electrodeposition of nanocrystalline Co-based alloys process and reduce the effluent impact on environment. It was found that the behavior of cobalt in aqueous solutions was substantially affected by the presence of molybdenum. When adding 11.6 to 46.6g/L molybdenum to a 50g/L cobalt solution, the co-precipitation of molybdenum and cobalt started to occur at pH value of 3-4. However, without the presence of molybdenum, cobalt could only be precipitated out of the solution at about pH 6. Most of the molybdenum was found in the solid phase when the solution pH reached 5. After further increasing pH to greater than 7, the molybdenum dissolved back into the solution. Cobalt kept precipitating as the pH increased. When the pH was greater than 7, most of the cobalt was present in the solid phase. The chemical and physical characteristics of the precipitated materials were investigated by SEM, XRD, AAS and EDX. It was revealed that the precipitate was initially present as cobalt molybdate oxide hydrate and subsequently transformed as sodium cobalt molybdenum oxide. With further increasing the solution pH, the precipitate was transformed into cobalt hydroxide. Further investigation implied that most of molybdenum was chemically tied to the precipitate produced at the low pH, yet at the same time, physically entrapped at the high pH. The paper also presents the influence of reaction temperature and time on the precipitation process and kinetics.

Jan 1, 2003

By G. C. Yao

Iron and silicon impurities can form needle and branch shape intermetallie compounds in molten aluminum when there is no manganese. It is difficult to separate them from molten aluminum by electromagnetic separation. The Fe-Si-AI and Fe-AI intcrmetallic compounds were transformed into Mn-Fe-Si-AI and Mn-Fe-AI compounds by the addition of manganesc into molten aluminum, In molten aluminum the morphology of these intermetallic compound particles is lumpish and spherical. Migration resistance of these impurity particles is small, which is beneficial to separation. FeSiMnAl4 and FeMnAl6 arc paramagnetic. These impurity particles can be moved by magnetic force and can be separated from the molten aluminum.

Jan 1, 2003

By R C. Cox

The Brukunga pyrite mine was operated from 1955 to 1972 to supply feedstock for sulfuric acid production in the South Australian fertilizer industry. Iron sulfide ore, mined by Nairne Pyrite Ltd, was finely crushed and concentrated onsite with the concentrates being sent by road and rail to Port Adelaide for roasting. Waste rock was dumped at two locations on the western side of Dawesley Creek and the tailings pumped to a valley-fill storage facility on the eastern side. Production of 1.5 Mt concentrate resulted in 3.5 Mt tailings and 8 Mt waste rock. The site has been administered by the South Australian Government since August 1977 and a lime treatment plant has been operated on the site since September 1980. Environmental issues arising from these operations included: diversion of Dawesley Creek to accommodate the waste rock dumps; dumping of low-grade sulfidic ore in waste rock dumps at the angle of repose immediately adjacent to Dawesley Creek; exposed fresh sulfide mineralisation in the quarry floor; tailings storage facility dam wall constructed by upstream up-lift using tailings and waste rock; an acid water pond sited on the tailings; and pollution of natural drainage. As a result, the minesite rapidly became a source of acid drainage and potential contaminants (sulfate, Al, Fe, Mn, Cd, Zn, and Ni). Various Government bodies have been responsible for considerable effort and expenditure in reducing the flow of acid seepage and contaminants into Dawesley Creek. Presently an estimated 60 per cent of seepage from the waste rock dumps, tailings storage facility and quarry is collected and neutralised prior to discharge into the creek. Tailings have been covered with waste rock, biosolids, neutralisation sludge and soil and planted with grasses, shrubs and trees to reduce rainfall infiltration. Monitoring of water flows, water quality and riparian ecosystems is on-going. Consultants have been engaged to develop cost-effective remediation techniques and a five-member Brukunga Mine Site Remediation Board was appointed to oversee remediation of the site and liaise with the community. Construction has commenced on the diversion of Dawesley Creek, and plans are being developed for the relocation of waste rock back to the quarry benches and upgrading of the neutralisation plant. The paper examines operations, environmental monitoring, remediation, research and community involvement with respect to current best practice.

Jan 1, 2003

By John Frostiak

"Kahama Mining Corporation Limited, a wholly owned subsidiary of Barrick Gold Corporation, poured the first dore bar and filtered the first concentrate produced at the Bulyanhulu mine on February 28, 2001. This event marked the completion of the initial development of the Bulyanhulu Mine – Barrick’s first mine located outside of the Americas.Bulyanhulu is a 2,500 tpd underground mine located in the Lake Victoria gold belt of northern Tanzania. Gold is recovered as a gravity concentrate and smelted on site to produce dore bars or collected in copper concentrate that is shipped to offshore smelters. The facilities were constructed to meet Canadian standards. Unit operations include single stage crushing, SAG milling, gravity recovery, flotation, thickening and dewatering. Tailings are converted to paste and returned underground as paste backfill or pumped to the surface tailing site. The surface paste tailing disposal system is believed to be first of its kind in the gold industry. Paste disposal has several advantages over slurry, including lower dam construction costs, reduced water losses, and lower reclamation costs. This paper describes the facilities and discusses the challenges faced during development and construction including logistics, lack of infrastructure, recruiting and training, security, and social issues as well as initial operating results.INTRODUCTIONBarrick Gold Corporation completed the Bulyanhulu mine development in 2001. Capital cost of the project was US$280 million. The mine produced 241,575 ounces from start of milling to year end at a total cash cost of $197 per ounce. Numerous challenges were overcome in the mine’s development due to the general lack of infrastructure in Tanzania and the mine’s location some 1200 km inland by road from the port of Dar es Salaam."

Jan 1, 2003

By Heinrich Hutchison, Thomas von Moltke, Roelof F. Sandenbergh, Katarina P. Cerovic

In the leaching of gold in aqueous cyanide solutions the rate of gold leaching may be decreased by the passivation of the gold, that may however be prevented or reversed in the presence of lead species in solution. In the present study potentiostatic, potentiodyanamic and XPS (X-ray photoelectron spectroscopy) analysis were used to further clarify the action of lead ions on the anodic activity of gold in alkaline cyanide solutions. It was found that lead increased the gold dissolution rate as it deposited on the gold surface at potentials more positive than its reversible Nernst potential for bulk metal deposition, i.e. by underpotential deposition mechanism, but that it decreased gold activity if present as bulk plated lead on the gold.

Jan 1, 2003

By B. Solar Menéndez, M. B. Díaz Aguado, I. Á. Fernández, C. González Nicieza

The analysis of subsidence due to the opening of an underground void (mining, water exploitation or civil works hole) is a problem usually hard to solve. First of all, it requires a predictive model, in order to define both the displacement magnitude and area affected by subsidence. Such model should be validated with measurements of the actual movements sustained on the surface, in order to adjust it properly and enable influence of future behaviour in a reliable way. Two different kinds of problems might arise. On one side, it is necessary to control and measure surface movements in a very exhaustive way during a long period of time, beginning before underground works take place and finishing years after they are over. Furthermore, three factors bring in errors, some times of magnitudes higher than the displacement magnitudes measured. These include: the fact that reliable and long-term information cannot always be achieved; the precision of measuring devices; and the design of the topographical network itself. In addition, the predictive models more widely used only apply to certain excavation geometries, mainly to horizontal holes. In light of this background, the Group of Rock Engineering, of the University of Oviedo Mining Department, has developed a working methodology and a specific software tool, Subsidence 3D, to estimate ground displacements and strains. The program will allow for predictive models to be defined and also allows the treatment of data related with topographical marks and its comparative analysis with calculated results. The software has been programmed using Visual C++. Graphical outputs however are generated using AutoCAD 2000. This paper mainly refers to a practical situation, an underground coalmine, remarking the main difficulties arisen during the study of the available information and proposing how to solve them. A predictive model in subsidence 3D was established and validated. The actual behaviour of the ground was that in the model.

Jan 1, 2003

By Markus A. Reuter, Yongxiang Yang, James R. Post

The packed coke bed in the lower part of an iron making blast furnace, the dead man, dissolves slowly in a pool of hot metal, which is tapped regularly. The coke particles of the dead man not only exhibit a size distribution, but also their size distribution is non-uniform throughout the dead man and as a result, the porosity of the dead man is non-uniform. This causes the flow of hot metal through the dead man to be irregular and non-uniform, bringing about channelling in the coke bed. Channelling is detrimental to the refractory lining life of the hearth of a blast furnace. Using population balance modelling and a porosity model it is possible to keep track of the local changes in size distribution and bed porosity during dissolution of coke particles. Numerical simulations show that carbon dissolution from a packed coke bed (with particles which exhibit a size distribution) increases the average porosity, decreases the mean particle size and changes the size distribution to a distribution with a smaller size range. Influence of the type of initial size distribution (mean, variance) is investigated. The calculated changes in porosity are used to dynamically adapt the flow and the mass transfer (kinetics) during calculations. This approach provides the possibility to implement dynamic porosity calculations for CFD applications, and thus simulate the results of various coke types and particle size distributions on dissolution and flow behaviour.

Jan 1, 2003

By Yi Luo

The severity of disturbances caused by longwall mining subsidence to various residential structures can be re¬duced. The success of such mitigation efforts depends on accurate subsidence prediction, correct assessments of the subsidence influences, and careful design and implementa¬tion of the proper mitigation measures. This paper presents the systematic approach involved in the subsidence mitiga¬tion efforts with a case demonstration.

Jan 1, 2003