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By Mikko Ruonala, Pertti Lamberg, Olli Hyvärinen

The smelting of copper sulphide concentrate is the dominant route in copper production (Figure 1). Heap leaching of oxidized copper ores with weak sulphuric acid together with copper solvent extraction and electrowinning has gained popularity during recent decades, and it accounts for close to 20 % of primary copper production. Heap leaching offers advantages such as lower costs and consequently the construction of a production plant at a mine site is made possible. Limited resources of oxidized copper ores, the long leaching time of chalcopyrite and inability to recover gold inhibit this growth. The HydroCopperTM process developed by Outokumpu Technology at the laboratories of Outokumpu Research, Pori, Finland, is a new chloride leaching technology /1,2/, which offers an alternative to smelting and heap leaching (Figure 1). In the HydroCopperTM process sulphidic concentrates with various mineralogy and grade can be treated at the mine site to produce high-quality copper. Instead of copper cathodes the HydroCopperTM end products are copper wire rod, copper bars or copper billets. One of the advantages of HydroCopperTM technology is that gold can also be recovered in the process simultaneously /3/. To confirm the functioning of the new process and to dimension equipment Outokumpu Technology built the HydroCopperTM demonstration plant in Pori, Finland /4/. It has a capacity of 1 metric ton of copper per day. After testing with Pyhäsalmi copper concentrate in 2003, the first commercial demonstration run with Erdenet copper concentrate took place in 2004.

Jan 1, 2005

By Y Peng, D Wannas

In the fine particle flotation technologies being developed today the fine hydrophilic (gangue) particles are usually well dispersed. These highly dispersed fine particles can be recovered into the flotation froth product by mechanical entrainment. Flocculation of hydrophilic particles caused by polymer depressants could potentially reduce the mechanical entrainment of these particles. This paper reports testwork completed on fine particles of several solids, iron oxide, hydroxylapatite, galena and sphalerite, as well as on a relatively coarse quartz sample (-75+38 ¦m). Dodecylamine was used as a collector for the quartz, and several dispersants and polymer depressants, including sodium silicate, sodium metaphosphate, zinc sulfate, potassium dichromate, corn starch, corn dextrin and carboxymethyl celluloses (with molecular weights of both 700 000 and 80 000) were used as flotation modifiers. The major part of the testwork involved flotation tests in a 200 ml flotation column. Both water and solid recoveries were recorded. The degree of flocculation and dispersion was determined by settling tests in 250 ml graduated cylinders. It was observed that flocculation of the fine hydrophilic particles significantly reduced their mechanical entrainment, while dispersion severely aggravated it. Thus, in the flotation separation of artificial mixtures of the -75+38 ¦m quartz and fine iron oxide or hydroxylapatite, polymer depressants that caused flocculation were found to perform better than the ones that did not cause flocculation.

Jan 1, 2005

By T. Rasmussen, T. G. Jørgensen, T. Fischer, R. K. McLimans, C. Knudsen, D. Frei

Ilmenite-bearing paleo-beach deposits were discovered in Jylland, Denmark using a combination of Ground Penetrating Radar (GPR), portable X-ray fluorescence (XMET), bulk XRF analyses, Computer Controlled Scanning Electron Microscopy (CCSEM), and wire line logging. The Miocene-age paleo-beach deposits are located below a thin Quaternary cover in a region of very moderate relief and essentially no outcrop demanding unique approaches in exploration. Initially, an isopach map of the Quaternary is prepared from existing water well data. A geological model for likely occurrence of Miocene paleo-beach deposits is generated and the coincidence of thin Quaternary cover and potential paleo-beach deposits define targets for detailed exploration. The defined targets are traversed with GPR to identify paleo-beach structures which are then used to define a drilling program. This methodology located a paleo-barrier island at the Vorslunde location with more than 10% ilmenite in the sand. During the drilling process, the TiO2 and heavy mineral contents of the sand were logged every meter with a portable XRF unit (XMET) and subsequently calibrated more accurately by comparison to bulk XRF and CCSEM analyses for selected samples. The bulk XRF data also provided more complete compositional information. Insitu determination of geology, heavy mineral abundance, and corroboration of the XRF logging was done using wire line logs, a combination of spectral gamma and induction conductivity logs. Detailed characteristics (abundance, grain size, shape) and chemical composition of minerals was determined by the GEUS CCSEM methodology (Frei et al, this vol.). The average weight percent TiO2 for all Ti-minerals is 62%, 60% excluding rutile. That elevated TiO2 content (>> ilmenite stoichiometric value, ca. 50 %) indicates that ilmenite experienced an iron-leaching environment. The source of the sand deposit was investigated by dating contained zircon. The results show that the likely sources of zircon are in southern Norway and southwestern Sweden with common zircon ages of ca 1100 Ma. and 1500 Ma.

Jan 1, 2005

Folklore suggests that oxidation is detrimental to sulfide mineral flotation, and in many instances is the reason given for values reporting in the tailing. However, while a considerable body of work examining galena oxidation is available in the literature there are very few studies that investigate the consequences of galena oxidation on its subsequent flotation in base metal sulfide ores. This work clearly demonstrates that pyrite forms a galvanic couple with galena, due to the large difference in their rest potentials, and results in accelerated oxidation of galena, particularly as the pyrite content of the ore is increased. The most obvious effect of the galvanic oxidation of galena by pyrite is the release into the system of galena oxidation products, providing an ample supply of lead ions available to activate gangue minerals, most notably of which in lead/zinc ores is sphalerite. The inadvertent activation of sphalerite by lead ions inevitably leads to the recovery of liberated sphalerite into the lead concentrate, and as a consequence a reduction in the lead concentrate grade. That is, a loss of selectivity for galena against sphalerite. If galena oxidation is excessive not only is there a considerable loss in lead concentrate grade, but also a marked decreased in lead recovery as the flotation rates of the gangue minerals increase, until they rival that of galena.

Jan 1, 2005

By Emre Biringen

"Results from a small-scale laboratory experimental program show the changes in the vertical stiffness and strength of a soft clayey soil adjacent to the shaft of an inserted pile (i.e. expansion of a cylindrical cavity). The experimental program provides a realistic axi-symmetric physical model of an element of a cylindrical pile and the surrounding soil. The study interprets the improvement and assesses its magnitude in vertical stress-strain-strength properties of a normally consolidated soft cohesive soil in response to preloading impact in the radial direction. The results verify that insertion of a cylindrical pile causes densification of surrounding soil in a radial direction due to change in stress state around the pile, and thus consolidating and stiffening of the soil.The test results indicate that most improvement in modulus and strength takes place within a distance of 4 times the radius of a pile, though significant improvement is realized to a distance of 8-10 times the radius, beyond where there is negligible effect. Settlement characteristics of the surrounding soil in a zone of 12 times the pile radius improve significantly after the formation of a cylindrical cavity. The miniature vane shear strength tests show a 1.5 times increase in a zone of 4 times the pile radius compared to the strength at 10 pile radii. The results also imply that the spacing of cylindrical piles should not be more than 4 to 10 times pile radius, so that the surrounding soil matrix may improve the vertical bearing capacity under any foundation or embankment loading.INTRODUCTIONThe engineering community is familiar with different techniques to improve the bearing capacity and settlement characteristics of weak cohesive and organic soils. Some of the in situ techniques to improve the properties of soft ground (e.g. soft clays) prior to placement of foundations are vertical preloading, deep cemenUlime mixing, stone columns, and grouting (Henn 1996; Moseley 1993). In addition to these methods, researchers have recently showed interest in achieving soft ground improvement by means of applying radial compression method for which different names exist including expanding pile (Kelleher et al. 2001 ), Preload™ Pier (Biringen and Edil 2003), and sand compaction pile (Lee et al. 2004). Handy (2001) has described how preloading can also be achieved by imposition of radial loading in soft ground with an expected improvement in stiffness. The idea behind the latter method is densification and consolidation of soft soil in the radial direction by controlled displacement for which the process can be viewed as a cavity expansion problem (Vesic 1972)."

Jan 1, 2005

By Monica Prezzi

"Auger cast-in-place (ACIP} piles and drilled displacement piles are being increasingly used as foundation elements for structures, particularly in projects requiring accelerated construction or involving the rehabilitation of foundations of existing, overstressed structures. Auger cast-in-place piles (also referred to as continuous-flight-auger piles) are widely used to construct the foundations of all types of structures. There are many different types of drilled displacement piles, with the installation methods varying according to the equipment used. Depending on the specific rotary piling technology used, responses ranging from those associated with non-displacement to those associated with full-displacement piles are obtained. Conventional pile design methods do not account for how the various construction techniques involved in auger piling change the soil state around the pile during installation and, hence, cannot accurately estimate the pile resistance in a consistent way. Research on this subject, identifying the different variables that must be accounted for in design and linking these variables to installation methods, is lacking. This paper describes the different piling methods available for auger cast-in-place and drilled displacement piles, the equipment used to install them and the quality control processes typically used. It also reviews some of the design methods currently used.IntroductionDeep foundations are extensively used in geotechnical engineering practice. The wide spectrum of piling methods results in a variety of pile types. Each type behaves differently, depending on the installation or construction methods. On one end of the spectrum are non-displacement piles, the classicql examples of which are bored piles or drilled · shafts. These piles are constructed by removing a cylinder of soil from the ground and replacing it with concrete and reinforcement. On the other end are full-displacement piles, such as closed-ended pipe piles or precast reinforced concrete piles, which are typically driven into the ground. Driven piles preload the materials below the toe of the pile and displace the soil surrounding the pile shaft laterally during the installation process. Therefore, displacement piles are, in general, more likely to have a stiffer response than non-displacement piles. This is true particularly in the case of sandy soils where displacement causes densification."

Jan 1, 2005

By C. -S. Xie, J. -H. Kong

The microstructure and mechanical properties of X80 hot-rolled thick steel strips with a thickness of 17.5mm produced in Wuhan Iron & Steel Company (WISCO) are introduced in the paper. The steel strips as fabricated through proper thermomechanical processing (TMP)/ on-line accelerated cooling (OLAC) processing have shown high strength and toughness, low brittle transition temperature, good weldability, and high Shear Area (SA) percentage in Drop Weight Tear Test (DWTT). The microstructure of the steel strips is characterized with mainly acicular ferrite, and fine dispersed Martensitc-Austenite (M-A) phases. It is determined that the mechanical properties are improved due to the presence of the fine M-A phases and precipitates, which could be formed by reducing the finish rolling and coiling temperatures.

Jan 1, 2005

By Ji-He Wei

Keywords: stainless steel, AOD refining, side and top combined blowing, mixing characteristics, water modeling The fluid mixing characteristics in the bath during the side and top combined blowing AOD (argon-oxygen decarburization) refining process of stainless steel have preliminarily been studied on a water model unit of a 120 t AOD converter. The geometric similarity ratio between the model and its prototype (including the side tuyeres and the top lances) was 1:4. On the basis of the theoretical calculations for the parameters of the gas streams in the side tuyeres and the top lances, the gas blowing rates used for the model have more reasonably been determined. The influence of the tuyere number and position arrangement, and the gas flow rates for side and top blowing on the characteristics has been examined. The results demonstrated that the liquid in the bath underwent vigorous circulatory motion during gas blowing, without obvious dead zone in the bath, resulting in a well mixing effectiveness. The gas flow rate of the main tuyere had a governing role on the characteristics, a suitable increase in the gas flow rate of the subtuyere could improve mixing efficiency, and the gas jet from top lance could make the mixing time prolong. Corresponding to the oxygen top blowing rate specified by the technology, a roughly equivalent and good mixing effectiveness could be reached by using six side tuyeres with an angle of 27° between each tuyere, and five side tuyeres with an angular separation of 22.5° or 27° between each tuyere. The relationships of the mixing time with the gas blowing rates of main-tuyeres and sub-tuyeres and top lance, the angle between each tuyere, and the tuyere number have been obtained.

Jan 1, 2005

By J. F. T. Agapito

Overcore measurements at the North Fork Valley (NFV) coal mines in western Colorado have shown that horizontal stresses are highly anisotropic. Measurements have been made in four mines at various depths. In many measurements, the maximum horizontal stress is three to four times higher than the minor horizontal stress. At the West Elk Mine, maximum and minimum horizontal stresses of 24 MPa and 6 MPa, respectively, have been measured at depths of 640 meters (m). Under highly anisotropic stress conditions, ground control problems associated with both high and low horizontal stresses can develop. While high horizontal stresses can produce cutter failures and floor heave, low horizontal stresses can allow block fallouts. This paper summarizes the horizontal stress measurements in NFV mines and, in particular, in the West Elk Mine where their role in roof fall and floor heave failures is discussed. This experience has led to an improved use of ground support and safer mining operations at depths of 640 to 700 m.

Jan 1, 2005

By Bob King

Jan 1, 2005

By A. Nivala, S. Ulgiati, M. Canino

Mining and processing of bastnaesite ore, (Ln)CO3F, for lanthanides extraction is investigated in this paper. This series of elements proved to be applicable for a wide range of high-tech uses. In spite of the strategic importance of lanthanides, no LCA and energy analyses of their extraction have ever been published. We perform in this paper a Life Cycle Assessment of the Lanthanide production cycle, based on available database and literature data from Mountain Pass mine (USA) and other worldwide mining and processing sites, most of which in China. We investigated three main steps: mining, milling (including transport, grinding and drying), and flotation (for lanthanide chloride extraction). We do not investigate here the separation of pure oxides from lanthanide chloride, a compound which is also marketed as such. The conventional LCA was integrated by means of energy and emergy evaluations, aimed at investigating respectively the global energy cost and the environmental sustainability of the process. Indicators of material intensity, thermodynamic efficiency, and environmental impact (including LCA and ecological footprint impact categories) are calculated and discussed.

Jan 1, 2005

The Snap Lake Phase I project initiated a subsampling campaign on the material (kimberlite/metavolcanic/granite) mined and treated for diamonds. The campaign was aimed at determining the optimum subsampling program to subsample the feed to the bulk sample plant (BSP) for the duration of a sampling campaign. This paper describes the application of GyÆs formula for determining the subsample size and other good sampling practices to determine this subsampling campaign. Three main issues are discussed: the use of a hammer sampler to sample off a moving conveyor and the practical experiment to determine the optimum subsampling program; bias introduced by laboratory equipment including two sizes rotary splitters; and variability of the feed material to the BSP over time.

Jan 1, 2005

By P. M. Soupios

A near geophysical surface investigation of a landfill area close to the Hania city, in Crete Island, Greece, was conducted as inextricable phase of a preliminary geotechnical, geological and hydrogeological study of the area under investigation. Electrical Resistivity Tomography (ERT), one of the most promising prospecting techniques mainly concerning its effective contribution to resolve several environmental problems, was applied for the geophysical modelling. ERT is a robust imaging method the theory and implementation of which are well documented in geophysical research literature. The survey site is located in Akrotirion Peninsula, about 7km east of Hania city in Crete I. The geological setting comprises Trypalion limestones, marly limestones and a clayed weathered layer. Cavities are also identified at various scales which are recent tectono-karstic voids resulted from the combined actions of karstic erosion and tectonic stress on the Trypalion limestones where they are located. Due to the above-mentioned geological singularity and in the light of the requirement for an environmentally safe construction of the landfill, an ERT survey was carried out by deploying the dipole?dipole electrode configuration. Specifically, seven geoelectrical tomographies were conducted reaching the prospecting depth of 36m. The resulted images conduced, a) to overcome geotechnical problems, b) to plan the future sites for waste disposal and c) to reliably estimate the thickness of the already deposited wastes.

Jan 1, 2005

By P. -Q. Wu

A modified electrochemical noise (EN) technique has been applied to monitor corrosion wear of TiN-coated ASP23 steel and TiN-coated AISI 316 stainless steel sliding against corundum in 0.5 M H2SO4. Experimental results show that the EN technique can sensitively detect potential and current variations during a corrosion-wear process. Corrosion-wear mechanisms of TiN coatings depend on their substrate properties. If the substrate is passive, such as AISI 316 stainless steel, the potential and current variations reflect the properties of the coating. Depassivation and repassivation alternately take place on the tribo-activated wear area during the steady-state phase. If the substrate is active, such as ASP23 tool steel, the electrochemical noise is dominated by dissolution of the substrate at the pinholes and the hydrogen evolution all over the exposed surface.

Jan 1, 2005

By Peter Shuttleworth, Chris Fesq, Eddie Woods

Precast concrete segmental linings for tunnels have traditionally been designed with conventional steel bar reinforcement. In many cases, this has been satisfactory in service, but in others, major problems have occurred with the durability of the linings. Commonly this has resulted from corrosion of the reinforcement, mainly from chloridesin ground water, causing spalling of the concrete and leading to very expensive and disruptive repair programs. This paper discusses the relative merits of designing tunnel linings with steel fiber reinforcement to provide long-term durability, improved impact resistance and toughness for greater load capacity across joints, enhanced robustness during transportation and erection, plus improved fire resistance with the addition of polypropylene fibers. Guidance is also given in the selection of the correct fiber type, mix design and testing methods to establish the optimum dosage required and production techniques to ensure even distribution and compaction.

Jan 1, 2005

By David Heydon

NAUTILUS MINERALS is a leader in the commercial exploration for and evaluation of seafloor massive sulfide (?SMS?) deposits. Nautilus has exploration licences covering 15,000 sq km of seafloor in Papua New Guinea and is evaluating other areas in the Western Pacific. The Nautilus Western Pacific Gold-Copper project is an interesting case study of the interaction of the disciplines of Science, Engineering and Environmental Science to solve and attend to the challenges of a project without precedence. The Science books of geology and marine biology with respect to seafloor massive sulfides are still being written or at best are thin volumes with recognition still we know very little at this time. Science?s early discoveries and study of these mineral processes on the seafloor provided invaluable data from which to develop an exploration strategy and the genesis of Nautilus itself. The Engineering required for development of such deposits is a combination of yet to be tested ?theory and engineering principles? and adaptation of best practice from other fields such as oil/gas and telecommunication cable laying. The Environmental guidelines for exploring these deposits, let alone mining them, is at the moment still being debated by a panel of experts chosen by the International Seabed Authority.

Jan 1, 2005

By William W. Edgerton, Calvin Locke

INTRODUCTION King County, Washington operates a regions wastewater treatment system that provides treatment to 18 cities and 16 sewer districts in the greater Seattle metropolitan area. The system serves 1.4 million people and currently includes two regional treatment plants. In 1999, a long-range planning study identified the need for a third regional treatment plant, now known as Brightwater. Prior to this project, the county has almost exclusively used the traditional design-bid-build delivery process for its capital projects. However, with the adoption of the RWSP, the county began to study the potential application of innovative project delivery methods. This paper looks at the project delivery methods used for the Brightwater project, based on the specific needs of this large, complex, and multi-faceted project. THE KING COUNTY WASTEWATER TREATMENT SYSTEM In 1958, voters approved the formation of a regional agency called the Municipality of Metropolitan Seattle, or Metro, to build and operate a regional wastewater collection and treatment system. Prior to the formation of Metro, there were no regional wastewater treatment facilities and pollution of Lake Washington and Puget Sound from untreated sewage was a concern for many residents. In 1994, King County merged with Metro. The county’s 1,087 square kilometer (420 square miles) wastewater service area covers most of urban King County and extends into portions of two neighboring counties. The system includes two regional treatment plants, a local plant, 61 pump and regulator stations, and 571 kilometers (355 miles) of conveyance pipeline which convey wastewater from local districts to the treatment plants. As with other areas, the greater Seattle/King County region has seen rapid population growth. The RWSP estimates that the current system would soon reach capacity, and called for the construction of a new third regional treatment plant, called Brightwater, to be operational by 2010.

Jan 1, 2005

By R. Baker

A novel electrochemical half-cell and corresponding working electrode were designed to evaluate the electro-catalytic activities of catalysts in an environment close to that of an operating proton exchange or polymer electrolyte fuel cell (PEMFC). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques were employed using the novel cell to characterize various methanol electro-oxidation parameters that contribute to the overall reaction on a fuel cell anode. The effect of temperature on methanol oxidation kinetics was examined in the potential range of 0.31 to 0.65V (vs. NHE). The data was collected in the temperature range of 20 to 80°C. Based on the experimental analysis and literature data, an equivalent circuit model (ECM) for methanol oxidation was proposed and was used to fit the EIS experimental data. The experimental data and ECM electrochemical data was used to extract electrochemical kinetic parameters for methanol oxidation such as the exchange current density, Tafel slope, and energy of activation for the reaction. Kinetic data, especially at different temperatures, is very limited in the literature.

Jan 1, 2005

By P. N. Psarropoulos

During many strong earthquakes in the past, a significant number of tailings dams failures has been recorded, leading in some cases to human life losses. However, over the last decades, seismic design of tailings dams has drawn much attention mainly due to the high environmental hazard. Although the stability of such geostructures under dynamic loading is mainly related to their liquefaction potential, there exist several technical issues that have not been adequately investigated. One of these issues is the impact of local site conditions on the dynamic earthquake stresses developed, and therefore on the inertial instability of these dams. Based on the models examined in the first part of the present study (Stability of Tailings Dams ? Part I: Static Loading), two-dimensional numerical simulations are performed in order to examine the effects of local site conditions in the dynamic response of tailings dams. Imposing dynamic loading via characteristic pulses and real earthquake records, the most commonly used types of construction methods are studied at their final stage. Emphasis is given on the special characteristics of the ground motion, while the material nonlinearity of both soil and tailings is taken into account by an equivalent-linear procedure. The results obtained indicate that local site conditions may have a significant impact on the seismic response of a tailings dam.

Jan 1, 2005

By Vijenac Quarry, A. Iljazagic, t. Knezicek, T. Omeragic

Limestone quarry Vijenac, is one of the key limestone producers in B&H. Conventional massive drilling and blasting is the technique applied for limestone exploitation. Utilized blasting scheme causes appearance of large oversize stone pieces, uncontrolled flying stone and undesirable seismic effects. In order to reduce or eliminate exposed disadvantages and to improve environment in the area of Vijenac quarry, an innovative blasting scheme was tested. Conventional blasting scheme was changed from single row, deep inclined blast holes combined with two lines short horizontal holes to multi row, inclined blast holes combined with a single line short horizontal blastholes. Applied innovative blasting scheme reduces negative blasting impact on the environment through safer working conditions, reduced amount of dust after blasting, reduced explosive and energy consumption, reduced appearance of explosive gasses and reduced earth and air vibrations as the result of seismic effects.

Jan 1, 2005