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By H. Jung

The microstructures and grain sizes of nanocrystalline Co and Co-1.1 wt % P alloys were characterized by X-ray diffraction. The corrosion properties of as-deposited and annealed Co-l.l wt % P alloys and pure nanocrystalline Co were studied in a deaerated 0.1M H2SO4 solution using electrochemical measurements and XPS surface analysis. Potentiodynamic polarization testing and impedance measurements revealed that an addition of P to pure nanocrystalline Co improved the anodic-corrosion resistance, however, this enhanced corrosion resistance was compromised by the heat treatment process at 350 and 800°C. The corroded surface of annealed nanocrystalline Co-1.1 wt % P at 350°C exhibited a more porous P-enriched layer compared with the as-deposited case. A sample annealed at 800°C corroded uniformly showing second-phase precipitates. The enhanced corrosion resistance of as-deposited nanocrystalline Co-1.1 wt % P was attributed to the elemental P on the surface that acted to hinder the anodic dissolution kinetics of surface Co following an initial selective dissolution of Co. However, at a higher anodic overpotential region, the superior corrosion resistance of Co-l.l wt% P alloys did not last because of the formation of a non-protective surface film consisting of mainly hypophosphite and phosphate as well as elemental P.

Jan 1, 2005

By D. D. Macdonald, G. Engelhardt

The accumulation of damage due to localized corrosion [pitting, stress corrosion cracking (SCC), corrosion fatigue (CF), crevice corrosion (CC), and erosion-corrosion (EC)] in complex industrial systems, such as power plants, refineries, desalination systems, etc., poses a threat to continued safe and economic operation, primarily because of the sudden, catastrophic nature of the resulting failures. Of particular interest in managing these forms of damage is the development of robust algorithms that can be used to predict the integrated damage as a function of time and as a function of the operating conditions of the system. Because complex systems of the same design rapidly become unique, due to differences in operating histories, and because failures are rare events, there is generally insufficient data on any given system to derive reliable empirical models that capture the impact of all (or even some) of the important independent variables. Accordingly, empirical models have generally failed to provide a robust basis for predicting the accumulation of corrosion damage in complex systems under realistic operating conditions. The alternative prediction philosophy is determinism, in which the development of damage is described in terms of valid, physico-electrochemical mechanisms with the output being constrained by the natural laws. The differential damage is then integrated along the corrosion evolutionary path for the system (i.e., over the future operating "history") to yield the desired integrated damage, which is the quantity that is most useful to an operator. In this paper, we review the theory of predicting corrosion damage within the framework of Damage Function Analysis (DFA), with particular emphasis on the pitting of aluminum in chloride solutions and on the accumulation of damage from SCC in Type 304 SS components in the primary coolant circuits of Boiling Water (Nuclear) Reactors (BWRs). These cases have been selected to illustrate the various phases through which localized corrosion damage occurs.

Jan 1, 2005

By Hee-suk Yun, Dae-jin Hwang, Jeong-woo Seok, Myoung-mo Kim

"In this paper, the accuracy of the data measured by a newly developed displacement measuring system, DPRMs (Digital Pile Penetration and Rebound Monitoring system) and its applicability as a quality control tool were verified by field measurements of pile penetration and rebound for pile driving performed at 3 construction sites and 1 test site. The DPRMs data were found to be much better than handwork data. A new dynamic formula for pile capacities is proposed uses the results of a pilot dynamic load test and the final pile penetration. The ratios of pile capacities obtained by the new formula to those by the dynamic load test were 94%±7.4% in the contrast with 123±28.3% by the 5S formula and 68±24.0% by Hiley's formula. This result shows the superiority of the new formula. The ratios of the maximum compressive stresses calculated by using DPRMs to those calculated by using PDA (Pile Driving Analyzer) were about 90-110±10%. This result confirms the applicability of DPRMs as an overdriving monitoring tool. Two sets of DPRMs were used to measure the 3-D displacement behavior of a pile head at the test site. The more the pile head moves laterally, the less the final set values were expected because of the loss of driving energy, but this trend was not obvious within the limited data obtained at the test site.INTRODUCTIONPile construction monitoring consists of two parts. In the first part, enough capacity of the pile is secured to stand the design load. In the other part, pile damage during driving is prevented. Although several methods can be applied to achieve the first part, PDA is nearly the only tool for measuring pile stress.Several methods such as a static load test, a dynamic load test, an Osterberg cell, and numerous driving equations can determine the pile capacity. Among them, the static load test and the dynamic load test are most widely used. The static load test is advantageous because it has the highest reliability. The disadvantages are as follows: it is costly and time-consuming. Also, the capacity of the pile under construction cannot be evaluated. The dynamic load test has lower reliability than the static load test, but it is cheaper than the static load test, is reliable enough to determine the pile capacity, can evaluate the capacity of a pile during construction, and can offer information about construction conditions such as the pile integrity and the pi le stress during driving. The dynamic load test takes a relatively short time and is low cost compared with the static load test. However, it is still costly, time-consuming, and unnecessary to apply to all piles in the field as a construction measurement tool. Therefore, driving resistance (blowcounts) is commonly measured to confirm the pile capacity at construction sites."

Jan 1, 2005

By H. Kose

In this research, a model quarry with an annual production capacity of 1 000 000 tonnes has been studied for both pit and hillside quarry cases with constant overall slope angle and variable bench slope angle, considering road grades of 8 per cent and 10 per cent. First, technical requirements have been determined and then the effect of production parameters, such as hole diameter, type of quarrying (pit or hillside) and road grade, on the cost has been investigated to determine bench height. Based on the results, it has been concluded that hole diameter has to be kept large in both pit and hillside quarrying to reduce drilling unit costs. In addition, in order to take advantage of gravity and reduce transportation cost, it has been suggested that bench height and road grade have to be kept high and low respectively in the case of hillside quarrying (downhill transportation) while, in the case of pit quarrying (uphill transportation), bench height and road grade have to be kept low and high respectively, in order to transport the blasted material to a lower height and distance, to save energy, thus decreasing the transport cost. Keywords: Quarry, pit, hillside, road grade, bench height

Jan 1, 2005

By F. Khomamizadeh

In this study the effect of solidification rate, T6 and T7 heat treatments on thermal fatigue resistance of A319 aluminum was investigated. Increasing of the solidification rate improved the thermal fatigue resistance of the alloy by refinement of the microstructure. The most sensible areas for thermal fatigue crack growth were the eutectic zones, T6 and T7 heat treatments improved the thermal fatigue resistance of the alloy by enhancing of the matrix resistance against the crack propagation. The slight reduction of the thermal fatigue resistance after T7 heat treatment is attributed to coarsening of the precipitates which reduces the matrix resistance.

Jan 1, 2005

Sishen uses a state-of-the-art tracking system to track material from its position in blast blocks through various stockpiles and crushers. Qualities are blended directly to the crusher as opposed to blending from stockpiles. This poses an interesting challenge to the planning department to simulate these conditions. The software used in these simulations are Whittle 4X and Maximiser for long-term planning, Xpac for medium-term planning and Mine Works Planner for short-term planning. Geological models and mine design layouts utilise Surpac. Sishen introduced Xpac a number of years ago; the system has developed and changed over the years. With the Sishen Expansion Project (SEP), which aims to utilise low-grade material, major changes to the planning process have to occur. SEP requires that the mine have two different plants, which utilise two different ROM feeds and have different beneficiation curves. Xpac is used to produce a rolling 18-month plan, which is as close to actual operations as possible. In order to do this, the simulations have to take into account the plants beneficiation curves, stockpile movements, hauling distance and equipment needs. On top of this, the schedule has to continually consider specifications for Fe and the contaminants. Plant yields also have to be kept within a certain bandwidth. Xpac is used to simulate the above parameters, as well as generate the raw data required to produce a mine budget. The paper will also show how the 18-month planning process and subsequent planning processes are measured and aligned. Xpac has proved to be an excellent tool to achieve these goals.

Jan 1, 2005

By Goudschaal Mark R.

"The Museum of Science and Industry U-505 Submarine Relocation project in Chicago, IL consisted of building an underground reinforced concrete vault (37' deep) for the Museum's new U-505 exhibit. This WWII submarine was captured in 1944, had been located outdoors at the Museum since 1954 and was lowered into its new exhibit area in 2004. A unique combination of earth retention, water cut-off and underpinning systems allowed a forty-two foot (42') deep excavation underneath th is historic museum. The museum - originally built in 1893 for the Chicago World's Fair - was closely monitored for building movements throughout construction. The underpinning systems, construction activities and monitoring results are presented herein. IntroductionThe historic U-505 German submarine at the Museum of Science & Industry was restored, moved approximately 1,000' and then lowered into its new indoor home (Figures 1, 2 and 3). The new underground exhibit opened this year celebrating the 61st anniversary of the German submarine's capture on June 4, 1944. On this historic day, Captain Daniel V. Gallery, a Chicago native, led the Navy in the siege of this submarine near the coast of Africa. This U-boat was the only German sub captured by the United States Navy in WWII and the Enigma machines, codebooks and publications recovered from the sub helped the war effort."

Jan 1, 2005

By Sayavur Bakhtiyarov

Keywords: Rheology, Viscoelastic, Oil In this paper we present the results of the rheological property measurements on viscoelastic composite materials used in oil industry. Laboratory experiments were carried out to determine important thermophysical, rheological and mechanical properties of the test materials using both the standard commercial and in-house made equipment. The composites with the paramagnetic particles (?-iron oxide) are exhibited a significant magnetic memory after magnetic treatment. The measured value of the yield stress after the magnetic treatment increased almost twice in comparison with the yield stress value of the magnetically untreated composite. The yield stress of the composite material exponentially decreases with time and reaches its magnetically untreated value after 15 hours. The yield stress also increases with the amount of the paramagnetic powder additive, and it reaches a maximum value at 8 wt-% of this additive. The obtained results provide valuable information for computer modeling of the viscoelastic fluid flow in pipes of complex geometry.

Jan 1, 2005

By Marco Antonio Falquete

A novel spark-generating tube, containing no explosive in its composition, is evaluated and compared with conventional shock tube. The product overcomes a series of problems found in conventional shock tube technology. The technologic development had multiple aims: to avoid transport and storage costs associated with explosives, to be more environmental-friendly, to obtain a high-velocity, hightemperature spark whose thermal performance could overcome poor heat transfer to the delay charge by gas convection at shock tube end, and that could cross barriers such as tight kinks, close knots, cuts, extreme environmental conditions, and long-term hot explosive emulsion exposure. The product of this development is evaluated and compared with conventional shock tube in a series of aspects and performance tests, including spark thermal performance (ignition of tougher, low sensitive delay columns, spark gap test), propagation in critical conditions of use (kinks, knots, cuttings), extreme environmental conditions (long-term exposure to hot emulsion explosive, extremes of cold, heat, moisture, underwater exposure), safety features (ignition through flame, open fire), and security against terrorist acts. Due to the safe characteristics of the tube, a series of demonstrations will be performed during the presentation. In nearly all tests and aspects, the spark-generating tube exceeds conventional shock tube, and in the rest equals shock tube, making it a more reliable alternative.

Jan 1, 2005

The fracture behavior of second phase particles and the role of matrix material on the wear resistances of the three Al-Si alloys containing 8, 17, and 19% Si were investigated using single pass scratch testing technique by applying normal loads between 0,15 and 5,00 N, in ambient air, Optical microscopy and SEM with EDS were used to analyze microstructures and morphologies of scratch tracks of the Al-Si alloys, The results showed that needle-like Si particles fractured under a load of 0.50 N, while block-like Si particles fractured at loads above 3,00 N, The Al-17% Si alloy with large number of needle-like particles (area fraction 16,4%) exhibited the highest coefficient of friction (0,8) and the widest scratch track, The Al-19%Si alloy containing high Si percentage and larger number of block-like particles (area fraction 16%) exhibited the lowest coefficient of friction (0,37) and the narrowest scratch track width. Presence of block-like particles was effective in reducing the amount of material transfer from Al-Si alloy surfaces to the counterface.

Jan 1, 2005

By Paul D. Tomlingson

Modern production equipment has been designed with greater productive capacity and higher reliability to meet the rigorous operating demands of the mining industry. These improvements have also made the equipment more complex and challenging to maintain. Whether these equipment enhancements contribute to more effective mining operations depends on the overall quality of maintenance. Maintenance is not a stand-alone activity. Although its quality depends primarily on maintenance, cooperation and support from other departments, coupled with the skillful guidance of mining managers, greatly influence maintenance success. Therefore, maintenance risk management must look beyond maintenance itself. Successful maintenance risk management begins with an assessment of the maintenance-related interactions of all mining departments within the mine’s stated operating strategy.

Jan 1, 2005

By G. Hangone

Paper written on project work carried out in partial fulfilment of MSc thesis This paper investigates the effects of thiol collectors: xanthates, dithiophosphates, dithiocarbamates and mixtures of these on the froth flotation performance obtained with a bornite-rich copper sulphide ore from Okiep Copper Mine with a feed grade of 1.8%copper. Batch flotation tests were used to assess the performance in terms of mass-water recovery, sulphur grade-recovery and copper grade-recovery relationships and the Klimpel rate constant for copper recovery. The results showed that the di-ethyl-dithiocar-bamate (di C2-DTC) was the weakest collector of copper sulphide minerals. Highest copper recoveries were obtained with the di-ethyl-dithiophosphate (di C2-DTP), which were accompanied with more watery froths and lower copper grades demonstrating frothing properties in addition to collector action. Superior copper recoveries were obtained with the 90% ethyl xanthate (C2-X):10% di-ethyl-dithiophosphate (di C2-DTP) and 90% ethyl xanthate (C2-X):10%di-ethyl-dithiocarbamate (di C2-DTC) collector mixtures compared to that obtained with ethyl xanthate at an equivalent collector dosage of 0.139 mol/ton ore (a dosage equivalent to 20 g sodium ethyl xanthate per ton ore). A superior copper grade was obtained with the 90% ethyl xanthate: 10% di-ethyl-dithiocarbamate collector mixture at a dosage of 0.0695 mol/ton ore compared to that obtained with ethyl xanthate at the same equivalent dosage. Keywords: flotation, collector mixtures, copper sulphide ore

Jan 1, 2005

Following the Moura No 2 Wardens Court of Inquiry and subsequent changes to the Queensland Mining Legislation there is a requirement in Queensland coal mines for: a person with the recognised competencies to be appointed at each underground coal mine to the position Ventilation Officer; and the person is directly responsible for the implementation of the mine ventilation system and for the establishment of effective standards of ventilation for the mine. The Regulations require that an underground mine must have principal hazard management plans that provide for at the least the following: emergency response, gas management, methane drainage, mine ventilation, spontaneous combustion, and strata control. Other than strata control all the plans require the ventilation officer to have roles and responsibilities to develop, control, monitor and undertake actions in relation to these plans.There are also another 34 Regulations that either directly or indirectly requires the Ventilation Officer to take actions.The purpose of this paper is to outline the information that the regulators look for in sealing plans and the actions the regulators will take if the sealing does not go to plan (TARPs being exceeded).

Jan 1, 2005

By C Katongo

Ground condition at No1. Shaft varies across the mine. The different ground conditions arise as a result of the differences in the rock strength and structure, seismicity and induced stresses in abutments areas. Apart from being a major cause of Fall of Ground incidents/accidents, adverse ground conditions where encountered has affected the rate of development advance as well as production. This implies that for support to be cost effective Geotechnical section has to ensure that support is designed to prevailing ground demand to ensure the safety of personnel and minimize loss of production. We have also seen changes in mining methods as a result of change in ground conditions. To avoid incurring unnecessary costs through remedial works resulting from ground deterioration and collapses of development openings due to inadequate support, the principle in engineering design is ?Do it right the First Time?, and this can only be achieved through good understanding of Geotechnical environment. The paper discusses the different ground conditions encountered in various development ends at No.1 Shaft. It also discusses the principles of ground support, failure mechanisms, types of ground support systems employed, and the different techniques used to select support systems, and quality control techniques in underground support installation.

Jan 1, 2005

Through the use of structural analysis programs such as Unwedge and considering the shear strength of applied fibrecrete it can be shown that fibrecrete can provide a higher factor of safety in a ætypicalÆ underground development excavation than standard rock bolts. This paper describes the progression of ground support from an æas requiredÆ component of mining to the use of bolts and surface support as a mandatory requirement. With the mandatory requirement for surface support, fibrecrete has been considered and applied as a secondary feature but simple analysis and practical observations indicate that it may be considered as primary support. The key elements to its implementation are: When is it safe to work under fresh fibrecrete and how do we practically determine this? How much ground support does fibrecrete provide? How can we reduce the cost of fibrecrete? An examination of these questions indicates fibrecrete can be much safer,less expensive and quicker to install than normal ground support elements. This paper explores practical examples from sites where significant benefits have been achieved by mine operators.

Jan 1, 2005

By T Gartner

This paper describes the design, manufacture and site services associated with the supply of mine hoists for the new mine under construction by Falconbridge Limited in Ontario, Canada. Two new shafts are being sunk, and the hoisting equipment at each shaft can be summarised as follows: Ventilation shaft:4.66 m diameter double-drum second-hand hoist, originally in operation at San Manuel Mine, Arizona, to be used as the shaft sinking hoist. The second-hand hoist presented a challenge in that during its previous life, the hoist had been intensively operated during service at San Manuel Mine, and this paper describes the scope of refurbishment work undertaken, both electrically and mechanically, to ensure future reliable operation, together with the requirement to meet Canadian and Ontario regulations and codes of practice. 3.05 m diameter new single drum auxiliary hoist to be used as a second means of egress. Main shaft:4.57 m diameter new double-drum hoist to be used initially as the shaft sinking hoist, and subsequently to be converted to the equivalent of a single-drum multi-rope hoist for service duties during the production phase; 5.49 m diameter new double-drum hoist to be used for skip hoisting during the production phase; and 3.05 m diameter new single drum auxiliary hoist.The new hoists are all designed to comply with SABS requirements such that hoisting with reduced rope safety factors will be possible in the future. This paper describes the principles involved both mechanically and electrically. Particular attention is paid to the conversion of the main shaft service hoist from a double-drum sinking hoist to a multi-rope hoist.This paper describes the ac electrical powertrains (drives and motors) used that eliminate the need for harmonic filters and reactive power compensation equipment since they exhibit no negative effects on the utility electrical network system. This paper describes the logistical challenges of installing, commissioning and setting to work a series of five hoists in a short time frame.

Jan 1, 2005

This paper outlines the role of commissioning in the project cycle, shows how to get organised for commissioning and describes the principal commissioning activities. Emphasis is placed on appointing key commissioning staff early in the project to coordinate the preparations for commissioning and on detailed planning and tracking to ensure that the required commissioning activities are performed satisfactorily. The management of safety during commissioning is reviewed.

Jan 1, 2005

By James T. Ludwiczak

Drilling and blasting in a Karst (sinkholes and mud seams) environment has long been a problem for blasters, miners, quarry operators, contractors, and developers. While one cannot change the geological conditions, one can take some measures during the bidding process and the initial preparation of the blasting program to help reduce some of the problems. During the geotechnical investigation and developing the test/core drilling grid, the owner/developer needs to take some additional measures that will provide important data to the blaster to help reduce the problems associated with blasting this type of geology. The owner/developer must also understand that, due to the geologic conditions, the results of the blasting will not be ideal and there may be additional blast-related costs. If provided the proper geologic data, the blaster can develop drilling patterns and blast designs that will help reduce some of the more problematic areas.

Jan 1, 2005

By Cathleen J. Webb, Arden D. Davis

The Homestake Gold Mine at Lead, South Dakota, has been proposed as the host site for the Deep Underground Science and Engineering Laboratory. The laboratory will house neutrino experiments in mine workings at the 7400-foot depth, as well as research in geomicrobiology, rock mechanics, and ground-water flow. Initial plans for the laboratory were developed in 2000 after Homestake Mining Company announced the closing of the underground gold mine. Homestake’s owner, Barrick Gold Corporation, had agreed to donate the mine for a laboratory if it could be protected from environmental liability. That initial agreement was delayed, and Barrick turned off the mine’s pumps in 2003, allowing lower levels of workings to begin to flood with water. In early 2004, the Governor of South Dakota signed an agreement with Barrick that would indemnify the company and eventually transfer ownership of the mine to a state laboratory authority. South Dakota’s governor also announced plans to ask the state legislature for funds to help in the initial construction of the laboratory. A consortium of scientists from several states is currently preparing a detailed laboratory proposal for the National Science Foundation.

Jan 1, 2005

By D McInnes

Rather than look at the problems associated with sampling, this paper deals with the issue of sampling and blending to optimise revenue û predominantly in the mining industry. An example of the use of this methodology in the agriculture industry is also presented. Mining companies, in particular, are experiencing a boom in commodity prices and many believe the industry is in the middle of a æsuper cycleÆ. Production levels are being escalated dramatically to meet the demand coming from China and India. This in turn has further stretched the capacity of our rail and port infrastructure û resulting in significant shipping queues around most Australian commercial ports and increased demurrage costs for the producers. Mining companies are now looking for effective scheduling, planning and blending to maximise production and reduce demurrage charges û given the current infrastructure constraints. Mining companies can no longer use spreadsheets to run their business. This paper further looks at how these outcomes can be met by optimised blending using an integrated supply chain management system such as MineTrak together with effective sampling and analysis.

Jan 1, 2005