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By Li Chen

A new process, i.e. Ball milling--Neural leaching--Oxidation calcinations--Chloridizing distillation--Hydrolysis, was designed to recover germanium from the vacuum furnace slag produced in Shaoguan smelter. The suitable process and operational parameters were determined for the practical production.

Jan 1, 2005

By Gungor Tuncer, Ali Kahriman, Abdulkadir Karadogan, Mehmet Aksoy, Kagan Ozdemire

With increasing environmental constraints on the levels of disturbance induced by blasting operations upon nearby residents, there is an increasing need to be able to design cautious blasting with greater precision. Therefore, determination of maximum amount of explosive per delay for a certain distance especially in large blasts is of great importance for the elimination of these environmental problems. Although too many research studies had been carried out in the past in order to eliminate environmental issues produced from blasting unfortunately a general approach or formula has not been established yet because of the complexity of the matter. In addition to the wave and ground motion characteristics, the complexity of blasting parameters and site factors restrict the developing a general criterion. So experimental site-specific studies should be still done in order to predict and control blasting effects. This paper presents the results of ground vibration measurements carried out in Espey Open-Pit Boron (Colemanite) Mine located on the west side of the central Anatolia near Kütahya province in Turkey. Within the scope of this study, ground vibration components were measured for 13 shots during bench blast optimisation studies in order to predict peak particle velocity level for this site. In blasting operations; ANFO and Powergel Magnum 600 (blasting agent), Powergel Magnum (priming) and delay electric detonators (firing) were used as explosives. Parameters of scaled distance (charge quantity per delay and the distance between the source and the station) were recorded carefully and the ground vibration components were measured for all blast events using 4 different types vibration monitors (3 White Mini-Seis and 1 Instantel Minimate Plus Models). Then, the data pairs of scaled distance and particle velocity obtained from the 38 record events were analysed statistically. At the end of statistical evaluation of the data pairs, an empirical relation which gives average line at 95% confidence level and upper bound 95% prediction line with a reasonable correlation coefficient was established between peak particle velocity and scaled distance.

Jan 1, 2005

In the human body, the balance between heat production and heat loss is continuously being disturbed, either by changes in metabolic rate (work being the most influential) or by changes in the external environment (heat stress), which alters heat loss. These changes in body temperature can adversely affect the function of body systems and organs. As a result, heat production or heat loss processes are triggered in order to restore normal body temperature (36 - 37¦C). If the heat generating systems of the body are excessive or the environment hostile then the capacity of the body to maintain thermal homeostasis is exceeded and can lead to a serious threat to health, or even death. This health deficit can severely affect an individualÆs capacity to work optimally; the end result is both poor productivity and health. Strategies to minimise or eliminate this effort will benefit both the health of workers and the productivity of companies. The principal strategies to reduce the effects of the environment on workers are: engineering interventions: to improve environmental conditions and reduce heat stress; and a comprehensive working in heat protocol: with provisions to identify risk situations and procedures to be adopted in relation to these. The above points will be discussed in detail with practical and simple strategies proposed to combat the deleterious effects of heat in mining.

Jan 1, 2005

By B. Anameric, S. K. Kawatra, K. B. Rundman

The iron nugget process is an economical, environmentally friendly, cokeless, single-step pig iron making process. Residence time dependent process requirements for production of pig iron nuggets at a fixed furnace temperature (1425 C) were investigated. Three chemically and physically different products were produced after complete reduction to iron, depending on the residence time in the furnace. These products were direct reduced iron (DRI), transition direct reduced iron (TDRI), and pig iron nuggets (PIN). The increase in the carbon content of the system as a function of residence time was detected by optical microscopy and Microhardness measurements. Sufficient carbon dissolution for the production of pig iron nuggets was obtained after 40 minutes residence time. The pig iron nuggets produced had chemical and physical properties similar to blast furnace pig iron. They were liquid state products and slag was completely separated from the metal.

Jan 1, 2005

By Bruce Hebblewhite

This paper focuses on the recent achievements and practices developed through the Minerals Tertiary Education Council (MTEC) initiative of the Minerals Council of Australia (MCA), in conjunction with the three partner universities involved in mining engineering education – University of New South Wales (UNSW), West Australian School of Mines, Curtin University (WASM), and University of Queensland (UQ). The collaboration between these partner universities and industry has led to the development of shared course material, cross-institutional teaching arrangements, and development of a number of flexible, distance-based delivery programs. The paper will then move on to future initiatives. Importantly, the exciting challenge is the future initiative planned to cement this collaboration by the formation of a “virtual” national school of mining engineering – Mining Education Australia (MEA). This will provide a common 3rd and 4th year program to all three universities from 2007, involving innovative teaching and learning arrangements, greater student exchange potential and a more significant input by industry into the education process. Such an initiative is not without its challenges, and has a long way to go, before becoming a reality. However, it offers greater attractiveness and marketing potential to prospective students, as well as economic efficiencies, whilst delivering a better quality, and hopefully greater quantity of graduates to industry. It can also form a launching platform for a much greater level of international collaboration, through a proposed International Mining Education Network (IMEN) which is currently being floated amongst a number of international educators.

Jan 1, 2005

By C. S. Kucukkaragoz

An ilmenite concentrate was reduced in the solid state with carbon under argon atmosphere at temperatures between 1000oC and 1400oC. The ilmenite concentrate and 50% excess carbon were reacted to achieve the highest attainable degree of reduction at each temperature and the reaction products were subjected to a series of analytical work by optical microscopy, X-ray diffraction analysis and SEM ( EDS) analysis. The ilmenite remained unaltered at 1000oC and had a slight change in its composition at 1050oC. A secondary oxide phase containing metallic nuclei was detectable at 12% reduction at 1100oC. The reduction of TixOy took place in a sequence changing the y/x ratio from 2.0 to a value less than 1.0 at 84% reduction at 1400oC. Metallic phase consisted of Fe and C initially and started to include Ti at the later stages. Complete reduction of TixOy to metallic Ti was not possible at these temperatures.

Jan 1, 2005

By Randall M. Wheeler, Kenneth K. Eltschlager

Blasting Seismographs use microphones to measure air overpressure from blasting. The microphone height above the ground has been the object of some controversy. The current ISEE “Field Practice Guidelines for Blasting Seismographs” specify microphone placement within 1.2 inches of the ground or over 3 feet above the ground. In this study, air overpressure measurements were taken at different height intervals and compared. Blasting seismographs constructed to the ISEE “Performance Standards for Blasting Seismographs” were used to monitor construction, quarry, and coal mine blasting. Near and far field measurements were taken to obtain representative spectral and amplitude ranges. The comparative analysis shows that microphone height has negligible impact on air overpressure measurements.1

Jan 1, 2005

By V Ser, I Smit, C Robertson

Anglo American has been researching the potential benefits of inter-particle comminution techniques for several years. Inter-particle comminution has additional benefits in terms of milling circuit performance such as energy consumption and stability. This paper focuses on the flotation benefits. Inter-particle comminution leads to selective breakage, mineralogical analysis has shown that this leads to improved liberation of the valuable minerals. In addition to selective breakage, the relatively short residence time experienced in typical inter-particle comminution machines allows more efficient classification which contributes to a æsharperÆ product size distribution. The effect of particle size in flotation has been well documented in literature. In general, it is has been shown that there is an optimal particle size range for flotation, and that both above and below this range, flotation recovery is adversely affected. Results show that the narrow size distribution which results from inter-particle comminution improves flotation recovery. Furthermore, the absence of excessive fine gangue material which typically results from conventional fine (-75 ¦m) milling of talcaceous ores, can lead to 100 per cent savings in depressant consumption when such ores are subjected to inter-particle comminution. To-date, this technology has been evaluated on more than ten ores. This paper will focus on one set of results which demonstrates a number of common differences that exist between material that has been milled conventionally and using inter-particle comminution technologies, with emphasis on what the impact of these differences is on flotation performance. A pilot scale (200 kg/h) vertical roller mill (VRM) was used to produce the material, and the results shown will describe conventional laboratory batch, locked cycle and pilot plant flotation testwork.

Jan 1, 2005

By B. T. Lu

The corrosion and wear properties of a series of chrome white iron (CWI) castings were study using electrochemical and low-stress sliding abrasion tests. The results confirm that the corrosion resistance of these materials is largely dependant on the quantity of chromium in the matrix, while the wear resistance is mainly controlled by the volume fraction of chromium carbides. A pseudo-wear/corrosion map is developed to identify alloy compositions that may be suited for erosion/corrosion conditions.

Jan 1, 2005

By Clyde Sitterud

Presentation Agenda ?Global Mining Tire Demand ?What is driving it? ?Latest Situation ?How long it will last? ?Michelin?s Response to Increase Supply ?New plant ?Additional presses ?Recommendations for Mining Users ?Treat tires as your major assets ?Areas of attention that will produce immediate results

Jan 1, 2005

By A. J. Romeo

The Old Hickory heavy mineral ore body, which lies within the Fall Zone of south central Virginia, has been mined since 1997. There are many differences in this deposit when compared to humate-laden mineral sands mines of southern Georgia and Florida. These differences include an abundance of kaolin-rich clayey sands, highly concentrated and iron-colored heavy mineral sand units, and a base of mineralization that is undulating. For these reasons, the selective approach of dry mining with track excavators is ideal. Grade control in this deposit uses traditional panning techniques and requires an intimate working knowledge of near-by drilling data. Mine geologists train equipment operators to recognize the base of mineralization by such characteristics as a stark color change, significant changes in grain size, and/or considerable, recognizable shifts in the concentration of heavy minerals. The regular pattern of mine site drilling does not always prepare the geologist and digging crews for occurrences of near-vertical contacts between the saprolite basement and the ore sands. These deformed areas, combined with undulating and pinching ore zones, require close monitoring and flexibility by the geologist and the mine operators.

Jan 1, 2005

By Pinai Mungsantisuk

Keywords: Pd-Ni alloys, Pd-Fe alloys, Pd-Co alloys, Magnetostriction, Magnetic Properties The presence of congruent melting minima, the occurrence of ferromagnetic transition over a large composition range, and FCC type crystal structure make Pd-Ni, Pd-Co, and Pd-Fe based systems attractive candidates in our search for materials with no rare-earths, large low-field magnetostriction, and good mechanical properties. The presence of paramagnetic-ferromagnetic transition over a broad range of composition also provides opportunity for fundamental studies. In this work, we have examined the magnetic and magnetostrictive behavior of Pd-Ni, Pd-Co, and Pd-Fe alloys over the entire composition range. Alloy sample rods were prepared by arc melting and casting. X-ray diffractometer was used to obtain lattice parameter data. Magnetostriction was measured along the rod axis using strain gages. Magnetic properties were measured using a vibrating sample magnetometer.

Jan 1, 2005

By G Forbes, D J. Bradshaw, G S. Heinrich, D

Traditionally, operators on mineral flotation plants have relied on visual inspection of the froth surface when making adjustments to process set-points. Machine vision systems are being developed to relate froth surface descriptors, which can be consistently measured in real time, to flotation performance. By investigating the impact of various selected operating variables on both froth surface characteristics and metallurgical performance it is possible to develop a management strategy for the control and optimisation of the process. This paper presents the results of testwork conducted at Kennecott copper mine which investigates the relationship between the froth colour and the concentrate grade and discusses the factors which affect the froth colour. This work shows that the main factors that influence the froth colour in this system are molybdenum, copper and iron concentrate grade, pulp and concentrate per cent solids and pulp iron grade.It goes on to develop models to predict the concentrate grade based on colour information and velocity and stability information. It also shows that the most accurate prediction is made with combined colour and stability information.

Jan 1, 2005

By A Holmgren, W Forsling

In the present study infrared attenuated total reflection (IR-ATR) was used to monitor the rate of in situ adsorption of heptyl xanthate on a layer of zinc sulfide synthesised on a germanium ATR crystal. The zinc sulfide surface was characterised using x-ray photoelectron spectroscopy (XPS). The absorbance of heptyl xanthate measured increased with increasing bulk concentration of the adsorbate up to an equilibrium plateau value corresponding to a fractional coverage of the surface sites of the substrate. For the adsorption from solutions of concentrations between 10-3 and 10-5 M, the rate of adsorption increased with increasing bulk concentration. At higher concentrations the measured absorbance should be corrected for the absorbance due to the concentration of xanthate in bulk solution. The present work provides a discussion of this correction. Assuming the adsorption stage to be rate-controlling and proportional both to the concentration of the adsorbing species in solution and unreacted surface area, a rate law governing this type of transient adsorption kinetics was derived. By means of absorbance data for the concentrations 0.1 and 0.01 mM, the rate constant of adsorption was calculated. From the initial part of a Langmuir adsorption isotherm, the absorbance at monolayer coverage and the equilibrium constant of adsorption could be estimated.

Jan 1, 2005

By P. Klaus

"KfW IPEX-Bank is the commercial arm of KfW Bankengruppe, responsible for international project and export finance.KfW was one of the first banks in Germany to promulgate environmental guidelines for its commercial business activities. These guidelines were first made public in 2000 and updated for the second time in 2004. They now include specific reference not only to environmental but also to social concerns. The guidelines specify the procedures to be followed in assessing credit risks related to environmental or social hazards.The bank considers sustainability as an interdependent framework of economic, ecological and social factors. In its efforts to contribute to sustainable development worldwide the bank uses its influence as far as possible to improve a project’s performance if such improvement is deemed necessary."

Jan 1, 2005

By J Arola, B Kettunen, W M. Bond

Separation of fine and coarse particles as separate streams prior to flotation, and their differential treatments, could substantially increase recovery and reduce collector consumption. A series of simulations was carried out to quantify the benefits from plant scale implementation of such a treatment at the Ispat Inland flotation circuit (Minorca mine). The study involved detailed plant sampling and sample analysis to generate the data needed for simulation studies. Samples were taken from all the streams from flotation feed to final concentrate, as well as cell lips and cell pulp. Sampling was repeated for the second ore blend that was processed by the plant during different periods of a year. Sample analysis involved sieve analysis and size by size chemical analysis for total iron, magnetic iron and silica. Raw data were mass balanced, and flow rates within the circuit were calculated. Mass balanced data were used to calculate model parameters representing the existing conditions. Usim Pac was used for both mass balancing and simulation studies. Available pilot and bench scale data were utilised to define the modified flow sheet and expected performance. The simulated flow sheet included classification of flotation circuit feed by hydrocyclones. While the coarse fraction followed the existing flow sheet, the fine fraction was sent to a magnetic separator. Magnetic and rougher flotation concentrates were combined to form the final concentrate. Two simulations for each blend were carried out. The first one assumed that there would be no change in size by size kinetic behaviours of both gangue and magnetite due to this modification. This was named as the worst case scenario, in which particles had a longer residence time due to reduced flow rates within the flotation cells. The second scenario anticipated that there would be an increase in recoveries of gangue and magnetite going into froth launder due to more efficient use of collector in absence of fines. Results showed that pre-classification of flotation feed could improve the flotation recovery by 0.3 - 0.5 per cent, with the major benefit being significant reduction (40 - 60 per cent) in the amount of collector used.

Jan 1, 2005

By Yuanbo Zhang

Keywords: Complex Iron Ores, Roasting, Tin, Zinc, Pellets, Comprehensive Recovery. The complex iron ores containing tin, zinc are typical refractory ores. Large reserves of the ores are found in China and have not been utilized efficiently so far. A new process of tin and zinc recovery and pellet preparation from iron concentrate containing tin and zinc by controlled atmosphere roasting is developed in this investigation. The results of 2573 N/P compression strength of product pellets, the 91.49% and 82.22% volatilization of tin and zinc respectively, are achieved for a concentrate containing 0.39% tin and 0.28% zinc. The strength and chemical compositions of the pellets meet the requirement of blast furnace ironmaking. Volatilization mechanism of tin and zinc are investigated. Thermodynamic study shows that the reduction balance curves of SnO2(s) and SnO(g) are proximate in the presence of carbon, and the standard formation free enthalpy of FeO and SnO2 is also approachable. Therefore, it is difficult to realize the complete volatilization of tin in the form of SnO(g) by selective reduction. But SnO2(s) and SnO(g) will form SnCl4(g) or SnCl2(g) in the presence of chlorides and can be easily volatilized from the ores.

Jan 1, 2005

By D. Song

In this paper, the differential equations governing the mass transport and the electrochemical reaction in a cathode catalyst layer of polymer electrolyte membrane fuel cells are solved based on the polynomial series expansion method. Explicit expressions for the polarization curve as well as for the distributions of oxygen, current density and overpotential are obtained when a quadratic, cubic or quartic polynomial is employed to approximate the oxygen concentration distribution. These kinds of explicit solutions are desirable for MEA design and diagnosis purposes. The comparison between the conventional numerical approach and the explicit solution approach proposed here shows that satisfactory accuracy can be reached by the first four terms of the polynomial series. The effect of the catalyst layer thickness on the accuracy of the obtained explicit polynomial solutions is also discussed.

Jan 1, 2005

By Bill Cain, David F. Tsztoo, R. John Caulfield, D. Scott Kieffer

In 1994, the East Bay Municipal Utility District (EBMUD) commenced a system-wide Seismic Improvement Program to protect their facilities from catastrophic damage. A primary focus of this program has been on retrofitting the 75-year old Claremont Tunnel, which crosses the active Hayward Fault zone. A large earthquake on the Hayward Fault could generate enough right-lateral fault slip to effectively sever this important lifeline. The retrofit project involves construction of a new bypass tunnel through the Hayward Fault zone, together with systematic contact grouting and localized structural repair of the existing concrete liner. Several innovative design measures have been incorporated into the seismic retrofit design, including an oversized tunnel cross section, backfill concrete side drifts, seismic isolation of an internal structural pipe, and shear fuses in the final lining.

Jan 1, 2005

By T. Gerritsen, C. Martinez, F. Stober, T Ma, J. R. Frias, M. Sedighy, J. Janzen

Electrode control systems regulate power by physically positioning electrodes. Due to the weight and inertia of the electrodes and hoist equipment, this is a relatively slow process where power fluctuations of less than a few seconds are not fully corrected. Nickel laterite AC furnaces operating in high voltage, shielded arc mode typically incur frequent power variations of approximately +/- 20% or more around the power set point. To provide enhanced power control, Hatch has recently supplied, at commercial scale, a thyristor-switched reactance system called an SPLC. The SPLC incorporates predictive control software to operate furnaces at the maximum transformer rating by reducing the large power swings experienced without the SPLC. The resulting higher average power enables higher production, without increasing transformer or power plant capacity. A 60 MW production version of the SPLC has been commissioned on Falconbridge Dominicana's laterite nickel furnace, yielding excellent results with a 3 to 1 reduction in power fluctuations.

Jan 1, 2005