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By H. Arima

The Akita Zinc Company is the only refinery which produces hematite from the iron content in the zinc leach residue. The Akita Hematite Process consists of five stages, which are SO2 pressure leaching, the first neutralization stage, the de-arsenic process, the second neutralization stage and pressure hematite precipitation. In order to strengthen its cost competitiveness and stabilize its operation, the Akita Hematite Process has been modified continuously. Most recently, two process modifications were carried out. The first was an improved ability to maintain a lower arsenic concentration in the de-arsenic process, and the second was an increased throughput in the hematite precipitation autoclave. The details of these recent changes in the Akita Hematite Process are presented in this paper.

Jan 1, 2006

By K. Vanbroekhoven

An industrial site near the centre of a historical town in Flanders is characterized by chromium(VI) contamination of the groundwater. Since the potential for natural attenuation was not sufficient to control the groundwater plume as observed from different analyses like pH, Eh, soil oxidation and reduction capacity, the feasibility of site remediation based on in-situ bioprecipitation of chromium was examined in lab microcosm studies. By creating reducing conditions by addition of a carbon source in the groundwater, chromium(VI) can be biologically reduced to chromium(III), which can form an insoluble precipitate of chromium(III) hydroxide. Microcosms contained contaminated groundwater and aquifer samples that were collected and manipulated under anaerobic conditions. Three different carbon sources were screened for their effectiveness: molasses from sugar beet production, molasses form starch production (protamylasses) based on potato juice and lactate. The different concentrations of sugar molasses were used to determine the optimal conditions. A range of parameters was monitored at regular time intervals for a period of six months such as chromium(VI) and chromium(III), DOC, methane, pH, Eh. A rapid conversion of chromium(VI) to chromium(III) was observed for all conditions tested. However, extensive removal of chromium from the groundwater by precipitation was only achieved for a limited number of conditions. In general, lactate was found to be the most effective carbon source, slightly better than the lowest concentration of sugar molasses that was tested, which itself was more effective than molasses based on potato. Higher concentrations of molasses, although causing a steeper decline in redox potential, resulted in less effective Cr removal. Typically, the fermentation of molasses results in acidification and this drop in pH may hinder the formation of insoluble chromium(III)hydroxides. It may also be possible that certain components of the molasses form soluble complexes with chromium(III). For lactate, no significant drop in pH was observed. Following the laboratory microcosm tests, the stability of the chromium precipitates was examined by performing a sequential extraction on the microcosm materials. These were performed under redox conditions which were similar to the ones observed in the field. Since the outcome of these tests was positive, a pilot scale test was implemented in the field in April 2005. Two different substrates, the cheap waste product sugar molasses and lactate are being injected creating two different impact zones and typical parameters are monitored. Frequent re-injections were important to maintain reduced conditions and are carried out three-weekly up to now. To study the stability of precipitates formed, mesocosm socks containing aquifer material were installed in the monitoring wells and harvested at regular intervals. Results of this pilot test will be presented and compared to the laboratory results. Based on the success of this field test, a full scale process will be designed and implemented as remediation strategy.

Jan 1, 2006

This paper reports the advances made during the development of underground mine fill technology from circa 1960 to the present and, in particular, indicates where increased input from process plant metallurgists û mainly milling, but also smelting û can contribute to further advances. Fill types pertinent to the discussion are partially deslimed, partially dewatered mill tailings fill (uncemented, cemented) and paste fill. Pertinent process plant includes hydrocyclones, thickeners, filters, elutriation tanks, holding tanks, mixing mills, pumps and pipes. Control instrumentation is a critical component of each of the process plant units. The impact of smelter practice on filling is not considered in this paper, except to note that some smelter slags are, or have the potential to be, active pozzolans and when ground to the specific surface area of Portland cement can act as partial Portland cement replacements, a factor of economic and operating significance when Portland cement supply lines are considerable and/or tenuous. The important role of process plant metallurgists has long been recognised, with Thomas, Nantel and Notley (1979) including them as one of the many categories of professionals with contributions to make. With the ever increasing sophistication of mine fill practice and its ever increasing acceptance as an essential component of the mining/ milling/waste disposal process, the scope for contributions by the modern breed of highly educated, specifically trained process plant metallurgists is becoming ever increasingly obvious.

Jan 1, 2006

By James A. Finch, Jason S. Doucet, Cesar O. Gomez

"Exercising control over the physical environment of flotation as a step towards process optimization is the driving force for characterizing gas dispersion in flotation cells, a subject of considerable research and still not fully understood. From an operational standpoint, however, there are just a few variables that can be manipulated to manage gas dispersion on a cell-to-cell basis, the most important being gas rate (superficial gas velocity Jg). Measurements in eight plants demonstrate there is often no strategy for distribution of gas to cells in a bank, i.e., there is no particular Jg profile. Two exercises where Jg profiles were set allowed metallurgical performance to be manipulated and an optimum Jg profile to be selected. To facilitate setting Jg profiles, a multi-unit device based on McGill Jg sensor technology is introduced. Possible directions for gas dispersion management are discussed.INTRODUCTIONThe earliest patents regarding the flotation process ignored the importance of air and in certain cases, steps were taken to eliminate bubbles from the system (Nelson and Smit, 2005). Rickard (1916) described a keen metallurgist who observed better than expected performance and hypothesized that entrained air was enhancing the process. Within a few years of this observation, the basic concept of modern froth flotation was developed whereby air is dispersed into slurry to induce bubble particle contact.As research into flotation advanced, the link between performance and the flow-rate of air entering the cell was established. In the first volume of the International Journal of Mineral Processing, Harris (1974) described the importance of airflow-rate and derived parameters such as the superficial gas velocity (then called the superficial airflow velocity) as being important parameters for cell design and scale-up. Mehrotra and Kapur (1974) presented research suggesting that the rate of flotation was strongly correlated to the aeration rate. McKee et al. (1976) continued to demonstrate the importance of airflow-rate linking it to the entrainment rate of hydrophilic gangue material."

Jan 1, 2006

By Pengfu Tan

Lead blast-furnace bullion cools to near its freezing point in an operation known as copper drossing or hot drossing usually contains 0.02-0.06% copper. The removal of this copper is usually carried out in a batch operation known as sulfur drossing. Sulfur is stirred into the bullion at temperatures near its freezing point, and the dross of copper and lead sulfides that floats to the surface is skimmed off manually. A thermodynamic model has been developed to simulate the copper drossing. The phase diagram of Pb-Cu-S system has been calculated, and the effects of the process parameters, such as temperature, copper content, and sulfur content, on the drossing process have been simulated and discussed.

Jan 1, 2006

By Pratheesh George

Solid state galvanic cell with CaF2 as the electrolyte was employed for determining the thermodynamic properties of Nb-Al binary alloys in the temperature range of 973-1073 K. The activities and activity coefficients of Al in NbAl3 were determined. The experimental procedure and the design and construction of the experimental setup have been also explained in detail. Aluminum activity in NbAl3 increased with increase in temperature and shows a strong negative deviation from ideality. The activities of aluminum in NbAl3 were determined to be 0.0165 and 0.0289 at 973 and 1073 K respectively. The stability of NbAl3 has been compared with other available intermetallic systems.

Jan 1, 2006

By Anthony T. Iannacchione

The Roof Fall Risk Index (RFRI) is a new method introduced by the National Institute for Occupational Safety and Health (NIOSH) to assist the underground stone mine operator in 1) assessing defects the mine strata and 2) rating the relative roof fall risk these defects pose. The RFRI utilizes observational techniques to identify defects in the roof strata caused by local geologic, stress, and mining conditions. Assessment values for ten defined defect categories provides the foundation for estimating a range of risk conditions between 0 and 100 that define the potential for a roof fall. This paper examines how the defect information is collected using two field verification sites and proposes methods to analyze the RFRI data. These examples provide information on how well the method replicates observed conditions and how it might be applied in practice.

Jan 1, 2006

By Alysson Tadeu Pereira Almeida

Steels with low concentrations of nitrogen, hydrogen and carbon have been in large demand lately. The RH process is a secondary refining process that can simultaneously attain significant levels of removal of these interstitial elements from liquid steel. In the RH process, the melt circulation rate plays a very important role in determining the productivity of the equipment, since it affects the decarburization rate. In the present work, a physical model of a RH degasser in a 1:5 scale of an industrial reactor has been built and used in the study of the circulation rate and of the kinetics of decarburization. The effects of the gas flow rate and of the configurations of the nozzles used in the injection of the gas have been analyzed. The decarburization reaction of liquid steel was simulated using a reaction involving CO2 and caustic solutions. The concentration of CO2 in the solution was evaluated using pH measurements. The experimental results indicated that the kinetics of decarburization can be described by a first order equation. Based on the results, it was possible to determine the contributions of the decarburization in the upleg snorkel and in the vacuum vessel.

Jan 1, 2006

Young professionals are riding the current wave of high demand for their services and relatively little competition for placements. The attraction and retention of quality incumbents has therefore become a significant strategic issue for companies in our industry. Money is important, but poorly structured career development and lack of learning opportunities can discourage the highest paid professionals from being enthusiastic and striving for excellence. This will inevitably lead to the search for a new position. Important factors at play include the young professionalÆs lack of understanding of career pathways and poor quality, or lack of, structured on-the-job training and professional development. Too often young and not so young professionals are faced with the reality that fabulous looking (and paying) jobs can be quickly reduced to the monotony of repetitive tasks in an isolating environment. While it is the responsibility of the incumbent to manage their own career and professional development, without experience, how is anyone meant to understand the importance of their roles and the options for career development? Mentoring is therefore essential to the strategic plans of every organisation and the strategic plans of every professional. Mentors will accelerate learning, guide decision making and develop both competency and confidence as they share their experience, both technical and regarding the machinations of a particular discipline, within our industry. Mentors need not be from the same organisation as the mentee and in some cases this may be a distinct advantage. This paper discusses mentoring as an opportunity for young professionals and mentors to initiate and maintain a supportive relationship, the responsibility of management to get mentoring right and the responsibility of young professionals to demand the opportunity for professional development through mentoring.

Jan 1, 2006

By D Craw, N Newman

Previously published stream quality data and AMD (acid mine drainage) analyses have been collated into a database (DAME û Database for Assessment of Mine Environments) and additional samples including NMD (neutral mine drainage) have been collected from coal mine drainages on the West Coast. Variations in the chemistry of mine drainage samples can be related to four factors: 1.       regional geology (Brunner Coal Measures or Paparoa Coal Measures) 2.       mine type (open cast or underground) 3.       hydrogeology 4.       local geology   In general mines hosted in Paparoa Coal Measures produce NMD whereas mines hosted in Brunner Coal Measures produce AMD with highly variable chemistry. Differences in coal mine drainage chemistry between mines hosted in Brunner and Paparoa Coal Measure sequences can be measured with acid-base accounting geochemistry. Correlation of ANC (acid neutralising capacity) and MPA (maximum potential acidity) analysis of rocks with mine drainage samples is substantially better than correlation of NAG (net acid generation) analysis with mine drainage chemistry.   It is likely that NAG analysis over estimates acid generation potential of some samples due to release of organic acids that are not released under environmental conditions. In general, differences in mine drainage chemistry between Brunner and Paparoa hosted mines are attributed to the effect depositional environment and diagenesis on coal measure composition. Exceptions to generalisations relating mine drainage to Paparoa or Brunner host rocks are likely where local geological conditions cause increased deposition of pyrite in Paparoa rocks and additional analyses are required to confirm interpretations.   Based on the interpretation of these results a mine drainage chemistry hazard model has been constructed. The hazard model predicts likely variations in mine drainage chemistry based on the four factors listed above. The hazard model has implications for mine related water quality risks. For example, ecotoxicity, human health affects and selection of remediation techniques are all sensitive to mine drainage chemistry.

Jan 1, 2006

By Bowen Li

Andalusite is an excellent raw material for refractory applications due to its high aluminum oxide content and phase transformation to mullite at high temperature. Granular andalusite in particle sizes of about 1 to 2 mm was traditionally utilized for the manufacturing of refractory brick. However, if powder andalusite in micron particle size is utilized in high-alumina refractory products, reinforcement on the refractory brick can be obtained and the sintering temperature can be decreased. The phase transformation of powder andalusite plays a key role for the difference.

Jan 1, 2006

PIP is regularly engaged in businesses where Greenfield Capital Projects are under- delivering on the expected business case. In most of these projects, we can identify that rigorous review has been carried out on the design and financial cost elements and substantial reporting is maintained to Boards on progress versus plan of project completion and cost. However, in all sites of this nature that we have worked at, the planning, design and execution of the operational elements or æwiringÆ of the organisation have fallen short and resulted in significant extra cost or opportunity cost (lost tonnage or quality) during start-up. When compared to the amount of planning and resources that have been poured into the capital side, the ledger on the æwiringÆ side is typically fairly sparse. This presentation outlines the importance of running a disciplined, rigorous process to prepare the human and wiring side of a start-up to ensure rapid start-ups and put the site on the pathway to high performance. It gives an outline of the rigorous process PIP has used with projects to ensure excellent start-ups.

Jan 1, 2006

Brunswick Mine, one of the largest underground zinc mines in the world, is scheduled to close in 2010 after almost half a century of production. All mines eventually close; some suddenly as a result of unsustainable economic or technical conditions and others, as in our case, as a result of the depletion of the orebody. When the mine is the most significant employer and an economic driver in the region, it is key that the closure is handled in a planned, communicated, well-executed fashion. The following paper documents strategies, plans and activities that are currently taking place in order to ensure a seamless closure that satisfies all stakeholders including employees, management, regulatory bodies and the public. It is an important deliverable for the company that the good will, credibility and reputation that has been built up over the years is sustained throughout the closure process and beyond. A life of mine labour agreement with the unionised workforce, staff retention and recruiting programs, regulatory closure plans, communications and transition adjustment activities will be discussed. The use of a stage-gate style project management tool analysing the risks and key deliverables will be highlighted. It is hoped that the concepts and approaches discussed here may be of value to other operations that will be faced with closure, and its inherent challenges, in the not too distant future.

Jan 1, 2006

By D. A. Beattie

Three novel dextrin polymers of varying functional group chemistry but similar molecular weight have been used to depress talc in single and mixed mineral studies. The mixed mineral system was a model sulphide ore consisting of talc, pentlandite, and chalcopyrite. Adsorption isotherms for the three polymers on both valuable and gangue mineral phases were determined to give initial clues as to the ability of the polymers to depress talc. Flotation testing revealed a distinct hierarchy of effectiveness of the polymers in the depression of talc in the single mineral system (MP Dextrin > CM Dextrin > Dextrin TYM), reflecting the observed adsorption affinity and adsorbed amount of the polymers on talc. However, a different order of effectiveness was observed for talc depression in the mixed mineral system (CM Dextrin > MP Dextrin > Dextrin TYM). Competition between the valuable and gangue mineral phases for uptake of MP Dextrin is responsible for its observed decrease in efficiency in mixed mineral flotation. All three polymers were found to be reasonably selective in their action, although at high dosages the polymers began to affect the flotation of the valuable minerals.

Jan 1, 2006

By S Harris, A Bossilkov

The Kwinana (Western Australia) and Gladstone (Queensland) industrial areas are among the few dozens of heavy industrial areas globally that demonstrate significant levels of regional resource synergies. Such synergies are also referred to as æindustrial ecologyÆ or æindustrial symbiosisÆ. Fundamentally they involve the exchange of by-products or sharing of utilities between companies in close geographic proximity to achieve competitive advantage and environmental benefit. A concerted research effort is currently underway to foster greater realisation of regional resource synergies in minerals processing intensive regions, in Australia and internationally. This paper summarises current insights from the foundation research into engineering tools and technologies and enabling mechanisms for regional resource synergy developments. Regional resource synergy developments were reviewed for 16 international and two Australian regions. It was found that Kwinana and Gladstone compare favourably with the well-regarded international examples of regional synergy development. Given the fairly strong evidence that self-organisation is critical for regional synergy developments, an implementation model has been proposed that captures entry points for synergy developments at the level of platform (industry collaboration), process (developing synergy opportunities) and project (assessing and implementing specific synergies). It was also found that regional synergies have so far developed in the absence of specific methods for identification and screening of synergy opportunities. Moreover, very limited attention has been paid to the associated technological and engineering challenges. The current technical research effort therefore targets: the development of a toolset for the identification and development of potential synergy opportunities; and assessment of technology needs and opportunities for regional synergies involving water, energy and materials recovery and reuse.

Jan 1, 2006

By Yuanbo Zhang

Zinc leach residues produced by hydrometallurgical zinc plants contain many valuable elements (zinc, iron, lead, gallium, indium silver, etc), while they have not been utilized effectively hitherto. In this paper, a new process of flotation-reduction roasting-magnetic separation to recover these valuable elements from zinc leach residues is developed on a basis of mineralogy investigations of them. The results show that silver concentrate with grade of 4321.6 g/t and recovery of 80.69% have been obtained, using 1750 g/t Na2S as conditioner, 750 g/t ammonium dibutyl dithiophosphate and SN-9 (assistant collector) as combined collector and 100 g/t terpenic oil as frother, if zinc leach residues with 523 g/t silver are floated at pH = 5.0. When the flotation tailings are subjected to reduction roasting at 1100? for 2 h, the volatilizations of zinc, lead and indium are over 96%. After roasted products are treated by wet-grinding and magnetic separation, the grade of gallium and gallium in the concentrates achieved respectively reaches 1805 g/t and 1536g/t, and the recovery of them is high to 94.67% and 93.20%, respectively.

Jan 1, 2006

By F. H. Samuel, J. E. Gruzleski, S. Valtierra, H. W. Doty, N. Andrade

In this work, the age-hardening behavior of cast Al-Si base alloys was investigated. It was found that multiple aging peaks are present in the age-hardening curves of Al-Si-Cu-Mg alloys. TEM observations reveal that the age-hardening behavior is related to the precipitation sequence of the alloy. For the Al-Si-Cu-Mg alloy, the first aging peak is the result from the high-density GP zones, while the subsequent are from metastable phases. The transition from GP zones to metastable phases may be the main reason of the formation of multiple aging peaks.

Jan 1, 2006

By D. Panias

Alumina hydroxides such as gibbsite (Al(OH)3) and boehmite (AlOOH) are precursors of many types of alumina that find important industrial applications. The thermal decomposition of AlOOH, which is a more energy saving precursor compared to gibbsite, gives rise to the formation of ?-, d-, ?- and a-aluminas that are used for the production of catalysts. The applications of the aluminas are governed by their properties that are a function of the precursor material and its microstructure. The microstructure in turn is a factor of the method and conditions applied, as well as, in the case of soft chemical processes, on the anions present. Towards these ends, this study was focused on the effect of different anions on the physicochemical characteristics of the alumina hydroxides precipitated in the first 5 minutes after the perturbation of the stability of a supersaturated sodium aluminate solution (Bayer liquor).

Jan 1, 2006

By Valerio Viti

In High Pressure Die Casting a molten metal is injected through a thin gate into the cast cavity. High injection pressures and high gate velocities create atomization phenomena which can negatively affect the final quality of the cast. In order to control atomization process it is essential to understand the atomization patterns and the two-phase flowfield that exist at the gate exit. In the present work, 2D numerical simulations of the flow of molten Magnesium through a high aspect-ratio rectangular gate are performed using a water analogue for an open and closed cavity. The numerical simulations made use of VOF-type (Eulerian) physical models and Lagrangian models. Further, a sub-grid scale model was implemented that, in conjunction with VOF-type equations can efficiently predict the general atomization pattern without the need for high-resolution grids. The numerical results were compared to experimental data for validation.

Jan 1, 2006

By Jana Dobrovska

The paper deals with new approach for measurement and evaluation of chemical microheterogeneity of elements in polycomponent metallic systems (i. e. steels, Ni-alloys). The method is based on the original mathematical model for determination of distribution curves of dendritic segregation of selected elements and on the original mathematical model for determination of the effective partition coefficients of these elements in the structure of analyzed alloy. Application of the method at research of chemical heterogeneity of continuously cast steel slab is also presented. The original results of measurement of dendritic microheterogeneity of eight elements (Al, Si, P, S, Ti, Cr, Mn and Fe) in structure of nine zones of a transversal section of slab are given.

Jan 1, 2006