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By D. M. Muir

The mineralogy of residues formed during the pressure acid leaching of arid region nickel laterite ore varies according to the salinity of the process water, alkali cation additives and the overall acid loading. In fresh water, hematite is the main iron-bearing leach residue component, together with amorphous silica and hydronium or sodium alunite/jarosite [(H3O,Na)(Fe,Al)3(SO4)2(OH)6]. As the process water salinity increases, or as NH4+ or K salts are added, alunite/jarosite is the kinetically favoured iron-bearing phase accompanied by an increase in acid consumption. The alunite/jarosite appears as two XRD distinct phases with different Fe:Al molar ratios. In weakly saline water, iron-rich alunite/jarosite slowly transforms to hematite and an aluminium-rich alunite/jarosite together with the release of acid. The addition of potassium salts forms a more stable alunite/jarosite whilst the addition of ammonium salts leads to greater transformation of alunite/jarosite at 250°C. Weakly saline process water gives enhanced nickel recoveries, whilst strongly saline process water gives lower nickel recoveries but higher soluble iron because of chloro-complexation. SEM and microprobe analysis shows very little nickel is associated with the alunite/jarosite and hematite phases. Nickel losses to the residues are attributed to adsorption on amorphous silica and to a lesser extent on alunite/jarosite.

Jan 1, 2006

When overburden depth exceeds economical recovery in openpit coal mines, the use of highwall mining systems has increasingly come into play. However, stability in the highwalls is always a major safety concern during such mining. The U.S. Mine Safety and Health Administration requires that highwall mining operators follow ground control plans that specify the pillar sizes necessary to prevent collapse that would threaten highwall stability.

Jan 1, 2006

At present, discounted cash flow analysis is generally accepted as the preferred method of valuation of mine projects in surface coal mining. One of the major reasons for that is its ability to take into account the time effect of money over the life-of-mine. As a looking-forward method, it requires forecasts be made with regard to economic, technological, technical, geological, and environmental conditions that will prevail in the future. All forecasts are inherently uncertain as they are a function of the uncertainty of all variables of the discounted cash flows analysis. This indicates that the only alternative for modeling the uncertainty in the project evaluation is the development of adequate risk models to serve the decision-making process. The paper offers a model of project cash flows at risk in strip coal mining, which is an integrated corporate risk management solution. The model is based on a stochastic approach that provides the answer to the question about how large is the deviation between stochastic cash flows and the planned value (or that used in the budget) at each time step of the discounted cash flows analysis, that is due to the uncertainty in the model variables. A solution is worked out for the allowable range of the stochastic cash flows variation that determines the probability of achieving the planned value of a mine project. The Monte Carlo simulation technique is used to model the stochastic behavior of the project variables. A case study of an opencast coal mine project is provided to illustrate the applicability of the risk model. The results obtained provide a new understanding of the mine project risk as a component of the project discount rate.

Jan 1, 2006

Gas-liquid contacting in the packed bed is a common operation in metallurgical reactors. Research has shown that, unlike wetting flow, non-wetting liquid flows in the form of discrete droplets or rivulets. Thus, modeling of the liquid phase as a continuum is in contradiction to the observations. Also, for the non-wetting case, continuum models have failed to describe liquid flow path when the liquid source is a point source. The aim of the current work is to put forward a combined Lagrangian-Eulerian approach to model the liquid and gas flow in the packed bed. Liquid is assumed discrete and modeled using a force balance approach. Gas is assumed to be interpenetrating continua and modeled using k-emodel for turbulent flow. Structured packing is assumed and x- ray imaging technique is used to visualize liquid flow lines in the bed. Simulation results for liquid flow path compared with the experiments.

Jan 1, 2006

By Pinakin C. Chaubal

Today?s steel industry is in a vibrant and resurgent mode. This transformation has been in the making for some time now. Over the last few decades, the industry was steadily transforming itself into becoming a high tech industry. New technology was adopted, efficiencies were enhanced, lean manufacturing concepts were brought in and a strong customer focus was developed. Today?s mills employ sophisticated instrumentation, computerized monitoring, on-line smart systems etc. driving processes that are producing at rates of many tons/minute. All this is not possible without judiciously using the latest available technologies in various fields and developing a more sophisticated work force. Prof. Sohn has been a pioneer in driving the concept of process engineering in process metallurgy. In this paper the focus is on some aspects of process engineering ? primarily process modeling - as applied to iron and steelmaking processes. Examples are shown to demonstrate how problems have been addressed. Some thoughts on future directions are presented.

Jan 1, 2006

By C. Taschereau, G. A. Vickell, A. R. Laplante

Evidence in support of an iron-gold corrosion cell during the high-temperature/highpressure elution of loaded carbon is presented herein including, but not limited to, its discovery, mode of genesis, and confirmatory laboratory testwork. A discussion of metallurgical and economic impacts, remedial investigations, plant design considerations, and future work including mitigative possibilities is presented.

Jan 1, 2006

By Brian H. Greene

The U.S. Army Corps of Engineers, Pittsburgh District, is in the final phases of modernizing the locks and dams on the Monongahela River. One facet of this modernization is to replace the existing Locks 4 located on the Monongahela River approximately 40 river miles upstream from Pittsburgh, Pennsylvania. The existing locks consist of a 56-foot x 720-foot main chamber and a riverside 56-foot x 360-foot auxiliary chamber built in the 1930s. Two new lock chambers, each 84-foot wide by 720-foot long, will be constructed at the location of existing Locks 4 and will be named Charleroi Locks. The purpose of the new project is to facilitate navigation on the lower Monongahela River. Pittsburgh is currently the second largest inland waterway port in the nation, and the new locks will be an important component of the navigational infrastructure. The existing lock walls are of mass concrete construction and are founded on wooden timber piles driven to rock through alluvial sands and gravels. The new lock walls were designed to be supported by approximately 300 reinforced concrete drilled shafts, varying in diameter from 4 to 6 feet. To handle axial loads, the drilled shafts were designed for end bearing, with some skin friction. The tips of the shafts will be founded within competent rock. Since the walls will undergo lateral loads, the drilled shaft design also had to consider this loading condition. Some of the drilled shafts will be installed within coffer boxes, which will incorporate a tremie concrete seal down to top of rock. Complicating the design even further was the fact that some portions of the new walls will be supported by shafts that extend some 9 feet above top of rock through alluvial soils, producing a cantilever effect. The first phase of the new lock construction was initiated in the summer of 2005 with a contract awarded to replace the river wall. This required shutting down the existing riverside lock chamber and diverting all river traffic to the longer existing land chamber. The foundation of the new river wall will use 144 drilled shafts. To optimize the design embedment of drilled shafts in rock for the river wall, an exploratory drilling program was conducted by the contractor in July and August, 2005. Based on the quality of the sedimentary bedrock, the shafts will be embedded in rock from 31 to 38 feet. To achieve adequate end bearing resistance, the tips of each shaft will extend through predominantly claystones into a more competent siltstone unit for a minimum embedment of one foot. The contractor also performed an exploratory pile driving program to aid in the construction of the drilled shaft casing and the cut off walls that will encapsulate the river wall. Two demonstration drilled shafts located outside the footprint of the new river wall, will be constructed prior to the drilling of any production shafts. The demonstration drilled shafts will verify that the contractor is able to meet the design criteria and quality requirements of the contract. The river wall contract is currently underway and is scheduled to be completed in 2010.

Jan 1, 2006

By D. Markwart, B. Volk

Anode effects are a phenomenon of the aluminium electrolysis process which produce potent greenhouse gases called PFCs (CF4, C2F6). With concerns surrounding global warming, and increasing regulation of GHG emissions, anode effects have become a significant sustainability issue for aluminium producers. In modem smelters, sophisticated computer control and automated alumina feeding systems allow for very tight control of the alumina concentration in the electrolyte and thus very low anode effect frequencies. Older smelters, however, do not have these systems and must either invest heavily to obtain them, or find other, innovative ways to reduce anode effect frequency. This paper will present the integrated approach to anode effect reduction used in the Vertical Stud Soderberg (VSS) potlines at Kitimat Works. Through an innovative combination of simplified signal analysis, modified alumina feed control logic, anode effect prediction, and anode effect prevention using a pager based communication system, Kitimat W arks has been able to make significant reductions to its anode effect frequency.

Jan 1, 2006

By C. Liu

Zeta potentials and settling rates of an oil sands tailings sample taken from Syncrude Canada Ltd's Aurora Stacker Pilot Operation were studied. Two clay minerals, kaolinite and illite, were also studied since these are the major constituent minerals in the fine oil sands tailings. Process water, decanted water as well as distilled water were used. It was observed that the zeta potentials of the tailings solids showed maximum negative values in process water at pH 8-10, which coincides with the pH of commercial hot water bitumen extraction process. The settling rates of the tailings sample were very low, at 0.008 m/hr in decanted water and 0.04 m/hr in process water. The rates were increased to 1.0 m/hr in decanted water and 0.13 m/hr in process water at an addition of 50 g/t Ciba AF1235. Although the settling rate was higher the supernatant was cloudier in decanted water than in process water. Further increase in the dosages of Ciba AF1235 did not increase the settling rates in decanted water but gradually increased it in process water, reaching 0.46 m/hr at 100 g/t. The results indicated that lower concentrations of Ca2+ and Mg2 (in decanted water) benefited settling rates but did not benefit supernatant clarity. Test results also indicated that Ciba AF1235 caused selective flocculation of the tailings sample, since the top sediments had higher illite and lower quartz contents than the bottom sediments.

Jan 1, 2006

By M McLean

This paper deals with change strategies on brownfield and greenfield sites in extractive industries. It draws upon contemporary experiences across Australian, Indonesia and Papua New Guinea (PNG). Change strategies can be used when owners of an extractive industry operation want to optimise their resource. This paper draws upon many tried and proven theories and practices, including the findings of the Tavistock Institute (Trist, Emmery, Bamford, Jaques), as well as the concepts of Adult Learning espoused by Malcolm Knowles and is supported by learnings of Australian based management consultants. This paper reviews a range of approaches that have succeeded in the integration of systems, machines and people, with the key corporate objectives of: increasing productivity; decreasing cost; improving on-time delivery performance and achieving long-term survival. Such integration needs to be measured to show the outcomes from the change strategies and the authors have worked within many measurement regimes and metrics but for the most part, found that JaquesÆ set of metrics being æquality, quantity, resources and timeÆ has gained currency across many Australian operations. This paper contends that investing money in machines alone without a commensurate investment into the people side is counter-productive. Further, if there is not an understanding of processes, ie stable and capable, core and support processes, then all that new technologies will do, is to make what is done badly, only quicker. Recent interventions for the most part, have been cognisant of this balanced approach towards change management. The change strategies described are across extractive industry implementations, using a number of tools and techniques drawn from Continuous Improvement and Six SigmaÖ (registered trade and service mark of Motorola Corporation, USA).

Jan 1, 2006

Pyrometallurgy has played a very important role in southern Africa for at least four centuries. It continues to do so, and recent years have seen many exciting developments in pyrometallurgical technology. The wonderfully diverse rich mineral deposits in this area of the world have provided some unique opportunities for industrial processes to be established. The ?Southern African Pyrometallurgy 2006? conference was set up to showcase southern African pyrometallurgical operations, and to provide a forum for the exchange of ideas between people working at various types of smelters. Papers have been obtained from a wide variety of pyrometallurgical plants in southern Africa. These descriptions of plant operations (as well as some history, and highlights of current work) will provide useful reference information for some time to come. Contributions are also included from universities, research organizations, and engineering companies, so that the full spectrum of pyrometallurgical activities can be covered. The plant descriptions will be published on a website, where they can be updated as and when required, with the eventual goal of having a description of every smelter in the region. The conference venue was selected to be the 'Cradle of Humankind' world heritage area, about 40 km from Johannesburg. Not only does this keep the conference within easy reach of the city and yet far enough out into the countryside to allow people to focus on the conference, it is also within easy reach of many pyrometallurgical plants. There is a particular significance to the choice of location, in that the Swartkrans area close to the Sterkfontein Caves is the site of the earliest evidence of the deliberate controlled use of fire by human beings (about 1.3 million years ago), and this is obviously a necessary precursor to pyrometallurgy. The area also lends itself to a very wide range of outdoor, social, and cultural activities to supplement the technical content of the programme. It is hoped that activities such as a hot air balloon safari and visits to the world-renowned Sterkfontein Caves and Wonder Cave will help to make the conference a memorable one for those able to attend. I trust that the ongoing value of the papers and presentations will make all the hard work of the many contributors most worthwhile.

Jan 1, 2006

By S. Frimpong, N. Demirel

Overburden excavation is an integral component of the surface mine production chain. The walking dragline is the most economic production equipment for overburden excavation in strip mining. Draglines are capital intensive, and thus, investments in multiple units severely impact the economic viability of projects. The use of few dragline units results in highly concentrated production focus, which must be efficiently managed to derive the potential economic benefits. Efficient use of draglines requires a thorough knowledge of the powered functions, the 3D rotational and translational motions and machine-formation interactions within the operating environment. Dragline kinematics and dynamics are required to understand and characterize machine performance and efficiency. In order to sustain the high productivity in difficult operating conditions, the dynamics of the dragline must be modeled and analyzed based on comprehensive kinematics. This paper investigates the planar kinematics of the front-end assembly and its interactions with the formation during excavation using the “Vector Loop Analysis” formulation with comprehensive simulation modeling in MATLAB Simulink. The kinematic models are used to examine the translational, rotational and angular displacement, velocity and acceleration components of the dragline front-end assembly along defined bucket trajectories during excavation. The results are the precursors for comprehensive modeling to examine the load deformation, torque requirements and dragline stress loading profiles for improving machine health and longevity.

Jan 1, 2006

By Mike Rogers

Platinum production in Southern Africa amounted to 80% of world production in 2005with a small increase from 5 117 000 ounces to 5 275 000 ounces. For the seventh consecutive year the platinum market is on course to record a moderate deficit in supply. This is reflected in the price increase from a trading range US$860 to US$880 in June 2005 to an excess of US$1 200 in September 2006. Southern Africa, with its extensive platinum reserves, will continue to be the dominant platinum producer and has a number of new mines in an advanced stage of planning. The slogan ?Platinum Surges Ahead? was selected to describe the exciting and vibrantnature of all aspects of platinum mining, beneficiation and marketing. This conference will cover these aspects from exploration and orebody delineation, through mine design, development and operation to mine closure; mineral beneficiation, marketing and compliance with the Mining Charter will also be subjects for discussion and debate. It is also anticipated that the issue of overall increases in productivity, through the introduction of technology, will demonstrate Southern Africa?s status as a premier mining district. It is my pleasure to welcome delegates from abroad and locally, on behalf of the SAIMM, to the Second International Platinum Conference ?Platinum Surges Ahead?. I trust that you will find the proceedings informative and value adding and will participate in the discussions and debate in order to obtain maximum benefit from the conference. I am sure that the post-conference tours will be interesting and of great benefit to participants. Finally, a big word of thanks to the members of the Organising Committee, the management and staff of the SAIMM, and to our willing sponsors, without all of whom this conference would not have been possible.

Jan 1, 2006

The mining industry is an important economical factor in Vietnam. Mining is presently being conducted at about 60 locations and at over 1000 mines. Petroleum extraction and coal mining are the most important parts of industry though metals such as zinc, tin, chromites, iron are also extracted. Last year the sector produced 20 million tons of crude oil, 26 million tons of coal and 500,000 tons of apatite. In particular, Vietnam is one of the world?s largest producers of anthracite, and it is one of the top producers of ilmenite and zircon in the Asia-Pacific region. The government intends to increase the mining production on all levels, however, at present one can observe adverse impacts of the mining activities on the natural environment such as insufficient waste dump rehabilitation, occurrence of acid mine drainage, mining subsidence and emissions as well as lack of appropriate water treatment facilities. This paper describes the current mining situation, future perspectives, the major environmental challenges of the country and approaches to solve these problems. Particular emphasis will be given to the research project ?RAME ? Research Association on Mining and Environment in Vietnam?, a venture carried out by universities, research centres and industry. This project is worked out in collaboration with the national Vietnamese coal and industrial minerals company VINACOMIN.

Jan 1, 2006

By Xiang Sun

Microwave heating has been used in numerous industrial processes due to its great advantages when compared with conventional heating methods. However, microwave heated products can be affected by non-uniform temperature distribution resulting from the mechanisms of microwave heating. To overcome this problem, a critical step is to have a temperature-time profile. In order to characterize and evaluate microwave heating effects, an accurate temperature measurement is needed. This paper discusses the possibility of applying several temperature measurement techniques in microwave processing. Both contact and non-contact methods are introduced and compared.

Jan 1, 2006

By Jason Graetz

Aluminum hydride is a covalent, binary hydride that has been known for more than 60 years and is an attractive medium for on-board automotive hydrogen storage, since it contains 10.1 % by wt. hydrogen with a density of 1.48 g/ml. There are at least 7 non-solvated AlH3 phases, namely a, a', a, ?, d, e and ?. The properties of a-AlH3, obtained from the Dow Chemical Co. in 1980, have been previously reported. Here we present a description of the thermodynamic and kinetic properties of freshly prepared a, 0 and y phases of AlH3. In all cases the decomposition kinetics are appreciable below 100" C and all will meet the DOE 2010 gravimetric and volumetric vehicular system targets (6 wt% H2 and 0.045 kg/L). However, further research will be required to develop an efficient and economical process to regenerate AlH3 from the spent A1 powder.

Jan 1, 2006

By A. Zarei-Hanzaki, S. M. Fatemi-Varzaneh, M. Haghshenas

The microstructure in modified semi-solid ALTHIX (A356) alloy consists of aAl phase with Al/Si eutectic structure. Silicon phase in eutectic structure is coral like with fine fibers. The lack of good ductility in this alloy is related to the presence of silicon fibers. Accordingly many investigations have been recently conducted to modify the Si morphology through Thermomechanical processing on this alloy. In the present work an ALTHIX (A356) alloy was deformed at 450°C, 500°C and 540°C through different strain rates. Consequently the silicon fibers were broken into small particles. The results indicated that the Si particles may coarsen according to Ostwald ripening mechanism at 540°C deformed by rate of0.0005 sec-1 & 0.0001 sec-1-

Jan 1, 2006

By Florian König

It is well known that the bearing capacity and stiffness of displacement piles may increase significantly with time, a phenomenon usually referred to as set-up. In cohesive soils the set-up is commonly explained by consolidation processes in which the dissipation of the excess pore pressures around the pile leads to an increase in effective radial stresses. Recent case histories show that set-up may also occur in sand over a period which exceeds by far the consolidation process. Therefore, other effects apart from the dissipation of excess pore pressures must contribute to this long-term set-up effect. This paper presents the results of a series of multiple pile load tests on prefabricated concrete piles which capture the effect of pile set-up empirically. The main characteristics of the set-up trend are shown with respect to soil type, pile dimensions and distribution over the pile length. Possible reasons for pile set-up like consolidation and stress relaxation after the end of driving are examined using a finite element model which simulates the pile installation process.

Jan 1, 2006

By J. Kirsch

Keywords: Pyrometallurgy, pneumatic transport, pneumatic transport Dense-phase pneumatic injection has begun to replace more traditional furnace-feeding systems. The paper describes the technology as it is applied to processes where the back pressure at the point of injection is greater than 50 kPaG. It reviews earlier systems of injection and more recent developments that address concerns for instantaneous control in modern smelters. The new technologies fall into two groups, (1) modified pressure-difference control (sub-divided into simple and complex) and (2) mechanical-feeder-based control. Features of current injection systems include feed splitting in two forms, passive and active, and co-current injection.

Jan 1, 2006

Ceremonies for the induction of four mining industry pioneers into the National Mining Hall of Fame will be held Saturday, Sept.9, 2006 at the Museum Convention Center in Leadville, CO. The four inductees are Earl H. Beistline (1916 to present), R.A.F. Penrose (1863-1931), Robert M. Reininger (1912-2006) and John Stanton (1830-1906). The inductions will bring to 193 the number of mining “greats” whose engraved photographs and biographical sketches are installed in the National Mining Hall of Fame.

Jan 1, 2006