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In this study, the flotation performances of ethoxycarbonyl thionocarbamate (ECTC), dialkyl thionocarbamate (DATC) and xanthate copper sulfide collectors are compared by the structure-reactivity relationship using generalized perturbation theory and density functional calculation at the B3PW91/6-31G(D) level. The electron-donating power of xanthates is strong and, therefore, xanthates can strongly react with metal cation on the surfaces of copper and iron sulfide minerals through the formation of normal covalent bonds. This explains the poor selectivity of xanthates and also the high pH levels (above 13) required for the flotation separation of copper/iron sulfide minerals. DATCs are more selective for copper sulfide flotation, particularly against gangue iron sulfides. Although less powerful than xanthates, DATCs can perform copper/iron flotation separation at lower operating pH (commonly at pH levels below 11.5). ECTCs use an ethoxycarbonyl replacing an alkyl N-substituent in DATCs. The presence of the ethoxycarbonyl group effectively changes the functional group of collector from -C(=S)NH- to -C(=S)NHC(=O)-. The strong electron-withdrawing ethoxycarbonyl group adjacent to the C=S group decreases the electron density of the sulfur atom, which improves ECTC?s selectivity against iron sulfide minerals at slightly alkaline conditions. The lowest unoccupied molecular orbit (LUMO) of ECTC, which is constituted by the pz-orbit of every atoms in the conjugate -O-C(=O)-N-C(=S)-O- group and which is pleased with accepting richly d-orbital electrons (feedback electrons) from the (t2g)6(eg)3Cu(II) or t6e4Cu(I) configuration of copper cation on the surfaces of copper sulfide minerals, resulted in the formation of dative p-bond. The iron atom, which has a (t2g)6Fe(II) or (t2ga)3(ega)2 Fe(III) configuration on the surfaces of iron sulfide minerals (Fe(III) is the predominant composition at alkaline conditions), has difficulty in offering its d-orbital electrons (feedback electrons) to ECTC?s LUMO. ECTC collectors are powerful for copper sulfide minerals and very selective against iron sulfides, which has been further confirmed by UV spectra and bench-scale and industrial-scale flotation tests.

Jan 1, 2008

By Clay Haynes

In 2005, Black & Veatch Corporation began designing a raw water conveyance system for San Luis Obispo County from Lake Nacimiento to the city of San Luis Obispo. The first element of the water transfer system will be a raw water pump station and lake tap. The wet well of the pump station will consist of a concrete lined shaft approximately 180 feet deep constructed in the very incompetent sandstone of the Vacqueros Formation. The lake will be wet tapped at approximately 172 feet below grade using a slurry earth pressure balance tunnel boring machine. The 48 to 72-inch finished diameter microtunnel will be approximately 500 feet in length. Construction is scheduled to begin in the winter of 2007.

Jan 1, 2008

By Jurgen te Kook

State-of-the-art for subsidence calculation are stochastical models. Although these models were successfully used all over the world they have their limitations due to the fact that they are not based on mechanical laws. For example the models did not take the rock mass structure and the rock mass characteristics into account. Therefore in a research program the skills of geomechanical numerical models for subsidence calculation were investigated. A case study shows that numerical models which are in principle based on the elastic theory are suitable for subsidence prediction. Due to the principles of these models the results are not sufficient in the case of multiple seam extraction. More extended geomechanical numerical models like FLAC and UDEC were investigated in further steps of the research work. Up to now large area geomechanical models require unrealistic long calculation times if the level of detail is similar to that of small scale calculations. Due to this it was necessary to implement a simplified description of the rock mass structure and characteristics. Different case studies show that this approach is successfull for subsidence calculation by numerical geomechanical models even for multiple seam extraction.

Jan 1, 2008

By Günther M. Volkmann

Continuous developments in tunneling require knowledge transfer between designers and suppliers to optimize the application of support systems. This collaboration allows the designer access to the latest research results, technical innovations, and support specific measurement techniques as well as the supplier?s experiences on recent projects. Project specific requirements determine the information that can be used to increase support system efficiency, advance rate, degree of safety, or decrease costs. This cooperative effort results in not only an unambiguous tender document, but also an optimized design with reduced risk that is coordinated with safe and high performance construction techniques. This paper will address the benefits of an early collaboration to both the design and the specifications in the tender document by using the A3 Hindhead project (UK) as an example.

Jan 1, 2008

By I. Ocak

The modulus of elasticity of rock material (Ei) is an important rock property that is used as an input parameter in the design stage of engineering projects such as dam and tunnel constructions, mining excavations, and so forth. However, determination of the modulus of elasticity is sometimes difficult to obtain by laboratory tests because high-quality cores are required. For this reason, empirical methods for predicting the modulus of elasticity of rock material have been popular research topics in recently published literature. In this study, the relationships between the uniaxial compressive strength (UCS), unit weight (?) and modulus of elasticity for different types of rocks were analysed by using 177 data obtained from laboratory tests carried out on cores obtained from drill holes within the area of the Kadiköy-Kartal Metro line (Istanbul, Turkey). Keywords: Kadikoy?Kartal Metro, uniaxial compressive strength, unit weight, estimating the modulus of elasticity.

Jan 1, 2008

By J Elsen, R Snellings, K Van Balen

This research concerns the mineralogical study of the physico-chemical reactions taking place at the pozzolan-binder interface. Lime binder/ pozzolan mixtures have been prepared for different natural zeolites. Analcime, phillipsite, chabazite, erionite, mordenite and clinoptilolite were mixed with portlandite and water, after which the progress in the reaction was quantitatively determined by thermogravimetrical analyses from three to 180 days. A first and important step was the thorough characterisation of the raw materials by quantitative X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscope energy- dispersive X-ray (SEM-EDX) measurements of the zeolite minerals, Brunauer-Emmet-Teller (BET) specific surface area measurements, grain-size analyses and cation exchange capacity measurements. Beside these zeolite samples with varying Si/Al ratios, two clinoptilolite samples exchanged to the calcium, potassium and sodium form were studied and the difference in their short- and long-term reactivity was assessed. Also the difference in reactivity between identical clinoptilolite samples ground to different grain sizes, obviously having different specific surface areas, was determined experimentally. The results indicate that the external surface area only influences the short-term reactivity, whereas the cation content has effect on both long- and short-term. Na-exchanged samples combine clearly more portlandite in the first few days, whereas the reaction slows down afterwards compared to K- and Ca-exchanged samples. The early reactivity of the unexchanged zeolite samples could be explained by these two parameters, but their long-term reactivity seemed to be related to their Si/Al ratio. Samples with zeolites rich in Si reacted faster then their Al-rich counterparts.

Jan 1, 2008

By Trevor Rangasamy

Technically based guidelines for managing rock related risks associated with strip mines in South African collieries are currently vague and are to a large extent based on experience and trial and error. To date, no mine specific or universal design charts exist within the South African industry. Quantification is done on a reactive basis i.e. following reported instabilities. The conditions under which, proactive tools to manage instabilities would be practically applicable are: The design of simple easy to use charts. Designing the charts for a target audience that is primarily production management. Well organized, logical set-up of the charts that will allow for easy future refinements. Allowing for variations in rock and soil properties within the charts that would account for colliery specific and region specific variability. The factors selected for in depth investigation that were deemed to have either individually or in combination, a primary influence on the stability of strip mines are (in no order of priority): Appropriate batter angles for ?soft? materials. Surcharge loading (spoils, dumps, topographical highs) on the highwall side. Influence of the thickness of stratification on stability. Influence of moisture content on stability. Influence of the changes to the coal seam dip angle on stability. Influence of persistent ?strip long axis? parallel faults/joints on stability. Spoil stability for variations in material type. This paper provides details of the work undertaken, using principally numerical modelling techniques, to produce design charts that will allow for proactive management of rock-related instabilities on strip mines.

Jan 1, 2008

By L. Dornelles, M. H. Prediger, R. de C. de S. Schneider, D. A. R. Lopez

In this work it was evaluated the environmental impact of sunflower plantation for biodiesel production. It was considered, for life cycle analysis (LCA) of sunflower in familiar agriculture in the South of Brazil, data collected in 23 experimental farmings with sowing in the period from August to November (2006 -2007). The LCA has considered the plantation conditions, energetic efficiency, man power, diesel volume, type of machines, fertilizers and pesticides used. From the analysis carried through it was evidenced that the sunflower produced in small scale does not need the use of tractors to have an excellent productivity and low impact. Therefore, the sunflower can be cultivated, with the necessary cares, in periods that do not compromise the man power for other cultures and the sunflower is an alternative so that the familiar property can produce biodiesel.

Jan 1, 2008

By M. J. Sapko

From 2001 to 2007, the Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) conducted studies to develop alternative methodologies to full-scale explosion testing for deter-mining the ultimate strength of mine seals. As a result, the PRL developed and proposes an alternative seal-strength evaluation method based on a hydrostatic pressure-loading concept. The researchers suggest pressure loading a seal using water to twice the expected dynamic design load. The hydrostatic chamber test offers a means of validating seal designs, establishing appropriate resistance functions and determining the ultimate strength of seals through testing to failure. This article contrasts the full-scale explosion and hydrostatic testing of mine seals using a simple dynamic system model and principles.

Jan 1, 2008

By B Besa

Australia is a world leader in the design and operation of mines accessed by the decline method. Literature indicates that a number of metalliferous underground mines using the decline system are also increasing steadily. This increase has generated a great deal of interest in underground haulage systems in future due to the huge costs involved in the development of declines. Studies have also shown that the current method of accessing orebodies by the conventional decline method has proved to be expensive, especially for narrow vein deposits. This is because decline development costs are influenced by mine planning and design parameters as well as available haulage systems that the mining engineer can choose from. The current access method suggests that more waste material is being extracted because of the size of decline openings adopted (5.5 mW and 5.5 mH). Also the conventional 1:7 decline gradient and turning radius of 20 m makes decline lengths, as well as the duration of development, excessively longer. This paper discusses results of a mine design case study with monorail technology as a method of accessing and developing the decline. The proposed system is economical, has high advance rates and offers a significant reduction in capital expenditure. The study compares costs, development metres and the duration of decline development using the monorail system with the conventional (truck haulage) access method. Results obtained indicate that the monorail technology has the potential to reduce the decline length by over 62.6 per cent and decline costs by 63 per cent for the case study. The monorail system also reduces the total capital development costs by 22 per cent for the same case study. Due to rapid development resulting from increased advance rates and the shorter decline length coupled with smaller decline openings, the time to access the deposit reduced by 71.8 per cent. This case study demonstrates that the economics of narrow vein deposits can be improved significantly by using the monorail system of decline development.

Jan 1, 2008

By F. Hassani, R. Mikaeil, B. Ferdowsi

Two analytical solutions for estimating the ovaling deformation and forces in circular tunnels are widely used in engineering practice, due to soil-structure interaction under seismic loading. This paper discusses the discrepancy between the two analytical and finite difference methods. A comparison of the two analytical methods shows that the calculated forces and displacements are identical for the condition of full-slip between the tunnel lining and ground. However, the calculated lining thrusts differ by an order of magnitude when considering no-slip between the tunnel lining and the ground. The analytical solutions are compared to numerical analyses of the no-slip condition using the finite difference method to validate which of the two methods provide the correct method. To achieve the goal, numerical modelling, field data of the Kuhin railway tunnel and Manjil earthquake characteristics are used. Numerical analysis results agree with one of the analytical solutions that provides a higher estimate of the thrust on the tunnel lining, thus highlighting the limitation of the other analytical solution.

Jan 1, 2008

With unprecedented worldwide growth and increasing global demand for energy expected to swell by 60 per-cent in the next two decades, mining matters as much now, if not more, than it ever has. This was the consensus at the 110th Annual National Western Mining Conference presented by the Colorado Mining Association, Feb. 12-14 at the Westin Hotel in Denver, CO. The role of coal ? America?s most abundant energy source ? the future of uranium and its possible resurgence in the energy marketplace, the skyrocketing value of gold as well as the issues of health, safety, climate change, legislation and government?s role in mining were all discussed during the three-day conference that operated under the banner of ?Mining Matters.? Barbara Filas, chairperson of the 110th National Western Mining Conference, president of Knight Piesold Co. and former SME president, welcomed the record crowd with an inspiring speech in which she pointed out that although ?most normal folks don?t know what role mining plays in their everyday life, mining does matter. ?Our industry,? she said, ?matters to Colorado. It matters to Colorado because it is a $3-billion industry. It matters to the 13,000 people who are employed directly or indirectly by the industry and it matters to schools that receive more than half of the royalties that are generated by mining.? During discussions of mining?s place in Colorado, the western United States and the world, special attention was paid to coal, uranium and the future of energy. ?It is time to rethink our perceptions about coal,? said Mark A. Smith, president and chief executive officer of Chevron Mining Inc. He spoke during the opening reception in a presentation titled, ?Coal to Liquids: Bridging America?s Energy Gap.? Although coal is America?s most abundant, and cheapest energy source, it is also one of the most scrutinized because of the pollution it causes and recent, and heavily publicized, tragedies that have claimed the lives of some who mine it.

Jan 1, 2008

By I M. Platten, Y Xie

Sampling protocols that are designed to suit the mineralisation style will result in a reduction of the nugget effect and hence resource risk. The a priori need for all sampling programs is the effective characterisation of the mineralisation type(s) to support optimisation. This requires a program of sampling for sampling followed by holistic characterisation. At each end of the coarse-gold to fine-gold spectrum, the samplability of a deposit ranges from relatively simple for fine-grained disseminated gold particles, through to extremely difficult for coarse nuggety mineralisation. Many deposits contain a proportion of both particle size types. The proportion and size of coarse gold particles has a direct impact on the effectiveness of sampling, where coarser particles will require larger samples and more specialised protocols. The nature of mineralisation geology/mineralogy and associated gold particle sizing can only be determined by sampling to facilitate optimised protocols. Mineralogical studies, focusing on particle size, particle clustering and distribution in host minerals, are required as part of wider paragenetic and metallurgical investigations. This paper discusses the role of mineralogical studies in the characterisation of gold ores for sampling optimisation through a series of case studies.

Jan 1, 2008

By Jeff Whyatt

Deformation of underground salt, trona and potash mines is generally time dependent, providing for gradual adjustment of strata to mining induced stresses. Time dependence can allow for higher extraction ratios provided eventual failure can be tolerated. However, this eventual failure can be violent if creep deformation can shift stress and potential energy to strong, brittle geologic units. The mine failure case studies reviewed here illustrate this process. Yield pillars and defects in bridging strata figure prominently in these cases. Yield pillars provide local and temporary support to the roof, temporarily delaying the cave; and allowing extraction ratios and overburden spans to increase beyond the long term capacity of overlying strata. Defects (faults, voids, thinning) of strong overburden strata reduce the critical span, sometimes to less than panel width. Analyses of many of these cases have focused on a cascading pillar failure mechanism, but recent work and this review point to failure of strong overburden strata as the essential element. The suddenness of failure and attendant seismic events pose hazards to miners and, in some cases, to those on the surface. Characterizing these failures is a first step towards recognizing and managing the risk of catastrophic collapse in underground mines.

Jan 1, 2008

By Norberto Benitez, Christian Ludwig, Simona Regenspurg, Fabian Mendez

"Navarro is the main garbage dump in the city of Cali (Colombia). Operated since the late 1960s it collects about 1.600 tons of waste daily. The environment surrounding Navarro is highly contaminated and the pollutants released by the dump threaten human health in the adjoining neighborhoods. The goal of our project is to identify major pollutants released from the dump and their distribution in the surrounding ecosystem. In a first phase of the sampling and analysis program landfill leachate was collected and screened for heavy metals and for the most common persistent organic pollutants. This allowed us to identify the most relevant compounds on which we focused in a more detailed second phase investigation. These compounds were quantified in the vicinity of the landfill (groundwater, surface water, drinking water and soil) to get information on their mobility and possible pathways into the human body.IntroductionThe usual technique of waste disposal in most developing countries is by landfilling on not -, or not well controlled sites, where people live close by or even on the waste itself. A typical example for this practice is Navarro, the main garbage dump in the city of Cali (Colombia). Operated since the late 1960s it now consists of about 23 million tons of household and industrial waste. The dump is located on a wetland in the riverbed of the Cauca River, the main drinking water source for Cali. Two ponds of unknown permeability located next to the landfill collect a fraction of the waste leachate. During the rainy season, the ponds frequently overflow and drain into the soil (alluvial, loamy sediments) of surrounding sugar cane fields. The environment of Navarro is assumed to be highly polluted and there is evidence that it affects the health of nearby inhabitants. Specifically, the incidence of respiratory diseases was higher among vulnerable individuals (<3 and >50 years old) living in a <3 km perimeter of Navarro as compared with a control group (Solano et al., 2006). Further, a clustering of extremely rare congenital malformations (sirenomelias and cyclops) was observed in a small area during a short time period (<6 months) (Filigrana et al., 2008)."

Jan 1, 2008

By P. J. Bethell

Background Increasingly complex geological conditions, with the presence of high ash binders in the mining horizon were encountered at the A.C. I. Dugout Mine near Price, Utah. This led to the production of high ash coal from the Dugout Mine during 2003 and 2004. This material had poor marketability and posed operating issues for the utilities burning the coal. Ash levels increased from typical levels in the 9-12% range to between 15 and 25%. etween 15 and 25%. Reviews of the mine plan and expected geological conditions indicated that further periods of high ash production could be expected. Action Plan Detailed sampling of the mine high ash production was carried out. The majority of the coal from the Dugout Mine is trucked to the Savage Coal Terminal (SCT) at Wellington, Utah where it is stored in multiple piles by quality. Coal at the mine is segregated by a CoalScan 2600, on-line analyzer into high ash, low ash and rock chute (waste material). From these piles, the material is crushed prior to shipment to SCT. The samples obtained from the various high ash piles were subjected to detailed sizing and washability analysis. Once this information was obtained, alternative circuit configurations were evaluated to process this material into a salable product. Water supplies in the arid terrain where the plant is located are scarce. This factor played a part in the final circuit design.

Jan 1, 2008

By Z. Yang, M. J. Collins, N. E. Tuffrey, R. J. Kalanchey, I. M. Masters

The high elevation of China Western Mining Company (WMC)&apos; s Ganhe refinery, and the high iron content of concentrates produced by the WMC mines, were key factors in the selection of pressure leaching by WMC for their new zinc refinery. This paper describes the results of pressure leaching test work conducted by Sherritt in Fort Saskatchewan with a sample of WMC concentrate from Qinghai Province in China. Results from batch pressure leach tests and a four-day pilot plant campaign are reported. The pilot plant campaign included continuous operation of a two-stage pressure leach circuit, as well as neutralization and iron removal steps, resulting in the production of iron-free zinc sulphate solution. Greater than 98% zinc extraction was achieved in pressure leaching, while producing solution containing about 9 g/L H2SO4 and 2 g/L Fe. Following neutralization and iron removal, the solution contained about 170 g/L Zn and less than 10 mg/L Fe. Overall recovery of sulphur in the zinc concentrate feed to elemental sulphur byproduct was about 85%, while 75 to 80% of the indium in the feed was recoverable from the neutralization residue. The test results highlighted the technical and economic advantages offered by the Sherritt Zinc Pressure Leach Process and provided the required data for the engineering design.

Jan 1, 2008

By Juan Daniel Martínez, Janaina Accordi Junkes, Dachamir Hotza, Tatiana Pineda

"The rice husk combustion in a bubbling and atmospheric fluidized bed reactor was investigated. The results showed the technical viability of producing both heat and amorphous silica from a renewable energy source. This paper presents the characterization of rice husk ash (RHA) obtained under varying fluidization velocities (0.13-0.15 m/s) and rice husk feed (4.5-7.2 kg/h). Characterization techniques include X-ray fluorescence, X-ray diffraction, particle size distribution and scanning electron microscopy. For the employed range of fluidization velocities of rice husk feed no noticeable influence on the chemical composition of produced RHA was observed. After combustion, RHA containing ~93% amorphous silica and <3% unburned char was obtained. RHA primary particles presented sizes from 90 to 100 µm and a tendency for agglomeration in aqueous media. Thus, the potential of this type of reactors with respect to speed, continuity and self-sufficiency energy of the process was shown.IntroductionDue to the increase of the agroindustrial production, the concern with processing by-products, such as rice husk (RH), is growing. For a better material and energy use, allowing a cleaner production and a more maintainable development, RH can be used as renewable fuel in the production plant, for instance, in steam generators. The adequate combustion of RH generates hot gases with low levels of pollutants, as carbon monoxide and particulate material.RH is the protecting coating formed during the growth of the rice grain, composed by four structural layers.1 The main components of the husk are cellulose and hemicelulose (50%) besides lignine (26%) and organic components (4%), as oils and proteins. The remaining amount includes inorganic materials (SiO2, Al2O3, K2O, Na2O, MgO, CaO, Fe2O3, MnO, P2O5).1The rice husk ash (RHA) is the product of the termochemical transformation of RH. The conditions of the different conversion processes (pyrolysis, gasification and/or combustion) determine the physical-chemical characteristics of the final product. RHA corresponds to 14 to 25% RH, depending on the variety of the rice, climate and soil of the producing area.2-4 The main component of RHA, which is generated at moderate combustion temperatures, is amorphous silica (SiO2) in the range from 80 to 97%.4,5"

Jan 1, 2008

By D. Mohapatra

Extraction of Al(III) from aqueous sulfuric acid solutions into organic Cyanex 272®-carbon tetrachloride systems was investigated from a multi-component mixture containing aluminum, cobalt and nickel. Al(III) extraction efficiency was quantitative with 1.0 M Cyanex 272® in two stages at an aqueous: organic (A:O) phase ratio of 1:1 and an equilibrium pH of 3.2. The stripping of Al(III) from the loaded organic (LO) with different acids indicated sulfuric acid to be the best stripping agent. More than 99% stripping of Al(III) from the LO was achieved using 2 M H2SO4 at an A:O phase ratio of 1:1 in a single stage. The stoichiometry of the extracted species of Al(III) was determined by the slope analysis method. The extraction reaction proceeded via the cation exchange mechanism and the extracted species was assumed to be AlA3?3HA, where HA refers to the dimeric and A the anionic form of the extractant, Cyanex 272®. The extraction of Al(III) was studied in the presence of various ions to ascertain the tolerance limit of individual ions.

Jan 1, 2008

By K. L. Morton

Groundwater and associated pore pressure represent elements that can have a negative impact on surface mining and slope stability. Groundwater flow and deformation within a slope influence each other. An increase in pore pressure will result in a decrease of effective stress; and conversely, if the pore pressure decreases, the effective stress increases. Slope analysis and slope design calculations require good information on pore pressure distribution around an open pit excavation. Until recently very little pore pressure data were available and assumptions had to be used. Location and design of measuring points depend on geological and structural setting, geotechnical domains and practicality. Good planning and the use of sensitive point piezometers to measure in situ pore pressures means that real-time data can be collected and used for the construction of flow nets, the determination of pore pressure distribution around an open pit mine, the validation of the dewatering/depressurization requirements, the calculation of the efficiency of the dewatering system and finally the use of pore pressure data in slope stability analysis. The recommended layout for a monitoring system, types and design of piezometers, data collection and use of the pore pressure data are presented.

Jan 1, 2008