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By J. D. McAuliffe

The Homer-Wauseca Mine is operated by the Hanna Mining Company, three miles north of Iron River, Michigan on the Menominee Iron Range. The mine produces 5,300 tons of direct shipping iron ore daily. The present main producing level is at a depth of 1,500 feet below the collar. The ore body continues to a depth of 2,700 feet below the collar, to which depth the modern circular concrete shaft has been completed. A view of the property is shown in Figure #1. This paper is a report on the development of large underground boreholes used initially to conduct stope filling material into inaccessible, mined-out stopes. Later holes were drilled for ventilation raises, for mine drainage, for passageway for power cable, also for the primary breaking point for long hole stoping. Some, which were drilled as ventilation raises, were later stripped to a suitable size for a manway or ladder road. The holes varied in size from 6" to 30" with the present popular, economical working size being 16 1/4", used as a stope fill passage in mined out areas and for ventilation in deeper development. Foremost has been the desire to develop equipment suitable for drilling raises large enough for manways.

Jan 1, 1963

By R B. Wanty

Historically, most investigations of biogeochemical cycling in acid rock drainage systems involved synoptic sampling over longer time periods (one sample per week or month) or intensive time series studies over a few hours or days. However, many important episodic loading events, such as seasonal meltwater and storm events occur on timescales that are rarely observed by these traditional sampling approaches. Monitoring these transient processes, which may contribute the bulk of the annual metal loading, is essential for accurate assessment in acid rock drainage areas. Recent work also has demonstrated dramatic diel (24 hour cycle) variations in trace metal concentrations in response to diel changes in temperature, pH, oxygen, and photochemical cycling (Brick and Moore, 1996; Nimick et al, in prep). To characterise a system that may respond to diel, seasonal, and episodic events, a monitoring program must sample at a frequency that captures the details of these major forcing events. We developed two novel instruments, the Zn-DigiScan and the DigiSampler to examine low and high frequency temporal changes in acid rock drainage areas. The Zn-DigiScan is a battery powered real time in situ chemical analyser designed for long-term deployments with hourly analyses of Zn. Stream physical parameters (temperature, conductivity, dissolved oxygen, pH, turbidity, etc) were measured every 15 minutes with a water quality sonde. The DigiSampler was developed for the long-term daily sampling of biogeochemically active elements and can take either discrete samples or samples integrated over 24 hours. The DigiSampler collects 2 ml samples in a Teflon coil which are separated by 0.2 ml nitrogen bubbles. The sample coil is returned to lab and the 2 ml samples are diluted 1:10 and analysed for trace metals by ICP-MS. Initial results from a three-day deployment at Fisher Creek, MT, USA have successfully demonstrated the ability of the Zn-DigiScan to record Zn concentrations at levels below 100 ¦g/L. Zinc concentrations measured at 30 minute intervals in Fisher Creek showed a diel cycle with low values of ~25 ¦g/L in the late afternoon and increasing to ~60 ¦g/L by early morning. Zn concentrations were inversely related to temperature and pH, suggesting that temperature and pH dependent adsorption was the main factor controlling diel Zn fluctuations. Initial deployment of the DigiSampler also was successful, revealing diel cycles in Zn, Cu, and Mn. Comparison of trace metal samples collected by the DigiSampler showed good agreement with samples collected by an Isco automated water sampler, demonstrating that the DigiSampler can collect clean samples for trace metal analysis at the low ¦g/L range.

Jan 1, 2003

By W. P. Arnott, P. Nascimento, X. L. Wang, K. C. Kocsis, S. J. Taylor, H. Firouzkouhi

We report the first spectral photoacoustic measurements of silica, coal, and kaolinite dust absorption coefficients from 11 to 13 μm at 5 nm resolution made with a tunable quantum cascade laser. This is important because airborne silica dust and coal dust within mining environments continue to be a problem for mine workers and staff due to their severe health effects on the respiratory system, while other dust types are potentially interferents to their detection. Our real-time spectra compare favorably with the non-real-time filter-based Fourier transform infrared spectrometer (FTIR) spectra obtained using the sampling system developed by NIOSH for their end-of-shift method to determine silica dust concentrations using a portable FTIR. We discuss our new dust generation system and instrument testing chamber. We also show that our PM4 silica mass concentration measurements by a low-cost air quality sensor (SPS30) are in good agreement with the TSI Aerosol Particle Sizer instrument, the NIOSH end of shift method, gravimetric mass, and correlate well with photoacoustic light absorption measurements at a wavelength where silica absorbs strongly.

Aug 20, 2022

By David Bigby

A remote reading dual height telltale system has been developed to provide mine management with early warning of impending roof failure. This system is a logical development from the visual dual height and triple height telltales which are increasingly being used worldwide for routine monitoring of mine roof. The paper describes the principles and history of telltales from their origins in France, their refinement and routine use in the UK and their subsequent spread around the world. They are now being used in various forms in USA, Canada, Germany, Spitzbergen (Norway), Poland, Ukraine, Russia, Australia, South Africa, Mexico, India, Egypt and China. The remote reading telltale system has coal mine intrinsic safety approval in Europe and the United States (MSHA) and the first commercial system was installed in a German colliery at the beginning of the year. Up to 100 dual height telltales can be connected, in a simple "daisy chain" configuration, to each of 4 underground interrogation units. These are connected through a twisted pair link to a surface computer which displays the readings, updates the database, generates warnings and provides the user interface. The paper describes the features and principles of operation of the system which differs considerably from conventional mine-wide monitoring systems. A European Community funded research programme is currently underway with the aim of developing improved alarm generating algorithms including evaluation of interfacing a neural network to the system. The paper concludes by exploring other potential applications of the system for ground control monitoring currently in development, including extensometry, stope closure monitoring and support load measurement.

Jan 1, 2001

By J. A. Hillier

The staff of the Hudson Bay Mining and Smelting concentrator have developed a new type of reagent feeder. Several factors encouraged the development of such a system: varying heads caused by the mixing of ores from several mines, the increasing number of flotation circuits operated and reagent feeding stations remote from the flotation operator's work area. The reagent feeders also had to be compatible with future plans for reagent control from an on-stream X-ray analyzer and computer system. The new feeder is a positive-displacement pump set to deliver a constant volume per stroke. At a remote panel, the feed rate is altered by changing the time between strokes. The feeders have been found to be reasonably trouble-free and accurate to less than 2 per cent error.

Jan 1, 1973

By H Lemos, E Nunes, D Jacobson, R Costa, L Ono, A Alves, H Delboni Jr

Oversize rock breaking and metal tramp removal are key issues for reducing primary crusher downtime, as well as improving the safety associated with its operation. Remote operation of such tasks would thus not only increase productivity, but also reduce the risks related to work in confined spaces, fall risks, and overhead hazards. These issues are particularly relevant in high-capacity operations such as iron ore mining, where large machines are in continuous operation. This article describes the architecture, construction and advanced testing of a novel remotely operated robotic mechanism for assessment and removal of metal tramp from primary crusher chambers. The system essentially includes a robotic-arm equipped with a hydraulic clamp tool for handling oversize material, as well as an oxy-flame module for cutting metal pieces entrapped within the primary crusher cavity. The first industrial unit was delivered to a large iron ore mine in Brazil, where the installation and testing is scheduled within the coming months.

Nov 8, 2021

By Richard R. Wilding

The United States Coal Mining Indus- try had the opportunity to greatly improve their roof control techniques during the nineteen seventies by the use of fully grouted resin roof bolts. This new tool was first approved for underground coal mines by M.S.H.A. ten years ago and during the next decade has been perfected to meet many problems previously thought to be unsolveable. The initial approved cartridge was very similar to the ones used in Europe in the nineteen sixties and since then has undergone a great deal of modification for our mines. These refinements in cartridge construction have been obtained by the close cooperation of resin manufacturers with mining personnel in perfecting pro- ducts customized to particular needs. This type of continuing program naturally necessitates a responsibility upon the resin anchor manufacturer to maintain a competant technical department. These roof control technicians by constant exposure to many of the most demanding underground problems, have developed through the years into leaders in successful applications. Today, Celtite has over twenty technically trained underground technicians with an accumulation of over one hundred years experience in resin anchors. Our documented technical reports are in excess of five thousand, involving over six hundred mines representing every major coal mining area in most mineable seams. This department has been the implement used to work with our research and development people in perfecting a continual line of improved resin anchors. This program has been a significant factor in leading the resin anchor industry into a position where approximately one third of the 1980 under- ground coal production used the fully grouted system. However, as gratifying as this accomplishment is, our experience has lead us to believe that there is an additional demand for a roof control system capable of combining the mechanical bolts ability to apply tension with resins proven superiority in anchoring. A significant number mines visited during the last decade had problems that we believed could be better answered by applying tension rather than the fully grouted approach. In most in- stances, their current mechanical installations were doing an adequate job until anchor slippage occured. Fully grouted systems solved this bleed-off problem. However, an acceptable number of falls still occured. In these some- what unique areas which we believe may amount to as much as fifteen percent of the total bolt installations, the need for improved anchors was a necessity. In developing this program we listed the ultimate requirements necessary for both the bolt and the anchor. These are for the bolt: A. Have one end manufactured so it can be grouted to the mine roof with polyester resin, obtaining a variable length from 12" to 36". B. Have a mechanism which allows the operator to tension the roof from zero to 10,000 psi. This mechanism should indicate if the roof is in compression and the bolt in tension. C. Have a mechanism which allows the operator to thoroughly mix the resin. D. The head of the bolt should not extend below the roof line any more than a normal mechanical bolt. E. Not require any extra tools for installation. F. Be bendable for use in low seam coal. G. Be durable and inexpensive. The ultimate point anchor resin should have the following characteristics: A. Have a mix and gel cycle which would compete with a mechanical bolt for speed of installation. B. Have a pull out strength in excess of a normal 5/8" mechanical bolt.

Jan 1, 1981

By J A. Rabe, PAP Fouche, K O?Neill

Two of the most important issues mines have to deal with are tracking the ore mined from pit to plant and to test the efficiency of beneficiation equipment. Kumba Resources and Saco Systems are working together at moment to develop a RFID tracer system to help address these issues. This paper will focus on the tracking of ore from pit to plant. The main advantages for ore tracking is to ensure plant feed blending and dilution according to plan. The RFID tracer system works on the basis of a tracer that physically simulates the ore properties and radio frequency technology that facilitates communication with the tracer and allowing information to be stored on the tracer. This paper tends to indicate the progress on the application of RFID tracer technology in the minerals processing environment as tested at Kumba Resources so far. It is concluded that the system has great potential, but some important problems remain

Jan 1, 2005

By Johann van Wjk

Mandatory Codes of Practice to Combat Rock Fall Accidents came into force on South African Collieries in 1997. These were drawn up in accordance with guidelines issued by the Chief Inspector of Mines, The Codes of Practice (CoP's) are legal documents in terms of the South African Mine Health and Safety Act 1996. One of the main results Of the introduction of the COP'S from a practitioner's point of view is that they formalized much of what would have constituted a typical visit to an underground section previously. Other important requirements were as Billows: Support rules and Strata Control Standard Procedures were to be drawn tip. Identification of Special Areas (areas requiring a higher level of rock engineering input and with, typically, higher order of support and restrictions on mining geometries), Changing conditions underground to he identified timeously. Implementation of the CoP to he monitored. To comply with these requirements on Ingwe Collieries (a division of BHPO Billiton Energy Coal) it was decided to produce too separate forms to be used in conjunction with each other. The first of these, the "Underground Section Physical Risk Rating" measures the physical conditions in each section whereas the second form, the "Section Perfomance Rating" determines how well the section personnel are Coping with the conditions. This form also pleasures compliance with the Support Rules and Strata Control Standards. Both forms are essentially risk matrices but with various scenarios described, each with a certain weighting. The "Risk and Performance Form" system for bord and pillar operations has by now been used for five years in the Ingwe and Eyesizwe Mining Collieries and has achieved a great deal of acceptance. This system has enabled the quantification of previously subjective observations and has improved the strata control awareness and management of underground mining sections. Amongst other initiatives it has assisted ill reducing the severity and frequency of fall of-ground accidents.

Jan 1, 2002

By S. Boisvert

Risk-based Inspection (RBI) addresses the challenges associated with ageing plants by focusing the inspection effort on the process equipments with the highest risk, thereby improving plant safety and reducing inspection costs. The RBI methodology is commonly used in the oil industry through the API 581 standard. Since no such standard exists in the mining and metals industry, BPR-Bechtel has developed one using inspection data from process equipments in CEZinc. Models were developed for various damage mechanisms, such as uniform corrosion and stress corrosion cracking. The equations were organized into a user friendly software that facilitates the implementation process.

Jan 1, 2010

By A. du Plessis

The study summarized in this paper focused on expanding existing South African mine closure cost calculation models to provide a new model that incorporates risks, which could have an effect on the closure costs during the life cycle of the mine. This research is important because currently there are a number of mines that do not have sufficient financial provision to close and rehabilitate the mines. The magnitude of the lack of funds could be reduced or eliminated if the closure cost calculation is done in a more risk-orientated manner. The model consists of an expansion of existing closure cost calculation models, by applying the Monte Carlo risk simulation technique to model influences of external and internal changes affecting closure costs. It is shown that the proposed risk-based model provides a way to understand better the implications of uncertainty on the closure costs.

Jan 1, 2006

By RALPH BALTES, AMIR EHSAN KIANFAR, FABIAN UTH, ELISABETH CLAUSEN

As indoor positioning provides particular challenges due to the unavailability of GPS signals, various systems such as ultrawideband (UWB), radio frequency identification (RFID), ultrasound, and wireless local area network (WLAN) have been proposed in recent years. Some of these technologies are currently being marketed and some are still being developed. UWB technology allows for higher precision while also reducing power consumption. Hence, the underground automation and localization systems can use this technology for more accuracy and robustness. This article discusses new robust UWB modules used for underground positioning and collision avoidance with regard to human safety in underground mining operations.

Jul 31, 2020

By RALPH BALTES, AMIR EHSAN KIANFAR, FABIAN UTH, ELISABETH CLAUSEN

  Underground positioning and communication are essential technologies for the future of underground mining operations. In contrast to other positioning and communication technologies such as wireless local area network (WLAN) or radio frequency identification (RFID), ultra-wideband (UWB) radio technology provides significant benefits like accurate and robust positioning of mobile machine equipment, which is indispensable for future autonomous systems in underground mining processes, such as production, transportation and auxiliary operations. Among these technologies, UWB offers many advantages, including higher accuracy, robustness, resistance against noise and multipath effects, and low power consumption [1,2]. Underground automation and localization systems benefit from these advantages and use the technology to improve efficiency and safety. There are many studies being carried out on this technology to increase the results’ accuracy, energy sufficiency and more. Two robust UWB modules that were developed for underground positioning and collision avoidance with regard to human safety in underground mining operations are introduced. The measurement results of tests carried out in an underground mine are discussed as well to confirm the functionality of the system.

By Lloyd B. Underwood

In the event of a sudden nuclear attack upon the United States, it is imperative that vital command and control centers have a high probability of survival. One such vital facility is the North American Air Defense Command Combat Operations Center at Colorado Springs, Colorado. Known briefly as NOW, this installation when completed will be housed in large chambers excavated out of granite beneath the eastern slope of Cheyenne Mountain (Figure 1). The NORAD COC, a U. S. Air Force sponsored project, will serve as the primary collection and evaluation center for data concerning unknown aircraft, missiles, or space vehicles, which might bring destruction to North America. The data will be fed into high-speed computers and electronic equipment from outpost sources - radar, ballistic missile early warning stations and picket ships throughout the world. Electronically controlled display boards will make it possible to evaluate the tracking data instantaneously and to take appropriate defensive action1.

Jan 1, 1965

By W. R. Reed, G. J. Joy, B. Kendall, A. Bailey

"Testing of the NIOSH-designed roof bolter canopy air curtain (CAC) has gone through many iterations demonstrating successful dust control performance under controlled conditions. J.H. Fletcher & Co. (Fletcher), an original equipment manufacturer of mining equipment, has further developed the CAC concept by incorporating it into the design of its roof bolting machines. A new CAC design has been developed incorporating the results of testing of the NIOSH design and the recent Fletcher design. Observations from smoke testing conducted on this new CAC design in a laboratory setting show promise for improved performance. INTRODUCTION Exposure to respirable coal mine dust can cause coal workers’ pneumoconiosis (CWP) otherwise known as black lung. If silica is present in the dust, the miner may develop silicosis in addition to CWP. CWP and silicosis are occupational respiratory diseases that are ultimately fatal and have no cure. The only method of prevention is through elimination of exposure to respirable coal mine dust and crystalline silica (quartz). The current occupational exposure limit (on an MRE basis) for respirable coal mine dust is 2.0 mg/m3 during each shift that a miner is exposed in the active workings of the mine or in mine facilities [30 CFR 70.100 2015]. Recently enacted legislation changes this standard beginning in August 2016 to 1.5 mg/m3 for a full working shift [Federal Register, 2014]. If the respirable coal mine dust contains more than 5% silica, the applicable respirable dust standard is reduced; calculated as 10 divided by the percent quartz present [30 CFR 70.101] so that the effective exposure limit for respirable quartz is 0.1 mg/m3 for a full working shift. Sources of exposure to respirable coal mine dust for the roof bolting occupations include infrequent maintenance and cleaning of the vacuum dust collection system and operating the bolter downwind (in the return air) of the continuous miner [Goodman and Organiscak, 2003]. Recent studies have demonstrated that vacuum dust collection systems are effective in capturing bolter-generated dust, if maintained and operated correctly and if proper face ventilation techniques are used. However, most exposure to respirable coal mine dust for the roof bolter occurs when the roof bolter machine is operated downwind of the continuous miner [Potts et al., 2011; Colinet et al., 2013]. Because of this higher exposure downwind of the continuous miner, the roof bolter is generally limited to working downwind of the miner only once during a production shift"

Jan 1, 2016

By W. R. Reed, G. J. Joy, B. Kendall, A. Bailey

"Testing of the roof bolter canopy air curtain (CAC) designed by the U.S. National Institute for Occupational Safety and Health (NIOSH) has gone through many iterations, demonstrating successful dust control performance under controlled laboratory conditions. J.H. Fletcher & Co., an original equipment manufacturer of mining equipment, further developed the concept by incorporating it into the design of its roof bolting machines. In the present work, laboratory testing was conducted, showing dust control efficiencies ranging from 17.2 to 24.5 percent. Subsequent computational fluid dynamics (CFD) analysis revealed limitations in the design, and a potential improvement was analyzed and recommended. As a result, a new CAC design is being developed, incorporating the results of the testing and CFD analysis.IntroductionExposure to respirable coal mine dust can cause coal workers’ pneumo-coniosis (CWP), also known as black lung. If silica is present in the dust, the miner may develop silicosis in addition to CWP. CWP and silicosis are occupational respiratory diseases that are ultimately fatal and have no cure. The only method of prevention is to eliminate exposure to respirable coal mine dust and crystalline silica, or quartz. The occupational exposure limit on a Mining Research Establishment (MRE) basis for respirable coal mine dust had been 2 mg/m3 during each shift that a miner is exposed in the active workings of the mine or in mine facilities. Under recently enacted legislation, this standard was changed in August 2016 to 1.5 mg/m3 for a full working shift (The Office of the Federal Register, 30 CFR 70.100, 2015). When respirable quartz is present, the mine must maintain its average concentration at or below 0.1 mg/m3. If the mine exceeds the 0.1 mg/m3 respirable quartz dust concentration, then the applicable respirable dust standard is reduced, calculated as 10 divided by the percentage of quartz present (The Office of the Federal Register, 30 CFR 70.101, 2015).The sources of exposure to respirable coal mine dust for roof bolting occupations include infrequent maintenance and cleaning of the vacuum dust collection system and operating the bolter downwind — in the return air — of the continuous miner (Good-man and Organiscak, 2003). Recent studies have demonstrated that vacu-um dust collection systems are effective in capturing bolter-generated dust if maintained and operated correctly and if proper face ventilation techniques are used. However, most expo-sure to respirable coal mine dust for a roof bolter occurs when the roof bolter machine is operated downwind of the continuous miner (Potts, Reed and Colinet, 2011; Colinet, Reed and Potts, 2013). Because of this higher exposure downwind of the continuous miner, the roof bolter is often limited to working downwind of the miner only once during a production shift."

Jan 1, 2017

By Y. Ichihara, H. Matsumoto, K. Itakura, H. Eguchi, G. Deguchi, K. Sato

Mechanical data from a rockbolt drilling machine, such as torque, thrust, revolution and stroke, are useful for understanding the geological and geomechanical conditions around roadways and hence selecting the optimum bolt type and density. Laboratory experiments showed that the level of torque or thrust reflects differences in rock type, with separation of strata and cracks appearing as a specific pattern. Algorithms of neural networks based on adaptive resonance theory and back-propagation were used to extract the pattern and estimate the location of discontinuities. For field testing in an underground coal mine, a prototype data acquisition system was attached to a portable drilling machine. Several sets of logging data from one locality were combined to construct a two-dimensional model of the strata, from which the slope angles of discontinuity faces could be estimated

Jun 19, 1905

By M. Gonzalez Fernandez

"Commercially introduced in 2004, the SAGDesign™ test has today proved its efficiency for sizing SAG mills for a wide variety of ores, from very soft to very hard ones. The interest of building a model using the SAGDesign™ test specific energy is the introduction of such a model into a complete process simulator making it possible to predict a complete material balance. The developed model compares the required specific energy with the energy provided by the mill. This energy calculation is derived from the Austin Power Formula. The specific energy provided by the test is corrected, using various parameters, such as the Ball Mill Work Index, to take into account the true operating conditions, the feed and product sizes. The core of this model allows the determination of the product d80 using the mill geometry, its operating conditions and of course the SAGDesign™ test results. To be included in a simulator, the model must also predict the overall size distribution of the SAG mill discharge. Assumptions to answer this point are presented here. The model has been implemented in the USIM PAC simulator. It is used either to predict the product size distribution for a given SAG mill, but also to size a SAG mill for getting a required reduction ratio. INTRODUCTION Over the last few years several types of new comminution machines have been introduced in the market. The most notable newcomer was the HPGR (Morley, 2006). But, even when these machines have some advantages, they have not earned the trust of the mining industry. That is why the established technologies still being the first choice. And, in comminution, that first choice are SAG and ball mills. The design of ball mills has been well understood for a long time. The Bond Ball Mill Work Index is the standard test which helps to describe the ore in terms of energy requirements for milling. Unfortunately, the development of an equivalent test to characterize the ore subject to SAG milling has taken some time. As of today, several tests are available in the market, like the MacPherson test, the MinnovEX SAG Power Index (SPI™), the JK Drop Weight Test, the SMC Test® and the SAGDesign™ test (Verret et al., 2011). The SAGDesign™ test, developed by John Starkey in Canada in the early 2000s (Starkey et al., 2008, 2015), has become one of the standards to assess the grindability of an ore in a SAG mill. One of its advantages is the reduced sample mass needed to perform it, hence, the reduced cost. The second one is that the output of the test is straightforward, it is the energy required to grind the ore between two sizes. Because of this energetic approach, the results provided by the test can be directly applied to size a new mill or to assess the performance of an existing mill."

Jan 1, 2018

By S Kost, R Nievergelt, F Cortes

In recent years, the use of steel fibre-reinforced concrete (SFRC) for segmental tunnel linings has become increasingly popular due to numerous advantages including durability, resistance to spalling, reduced cracking at corners and edges and significant cost-saving potential. One of the key parameters for measuring the performance of SFRC is the residual (post crack) flexural strength. A problem often faced in design and quality control of SFRC is the high variability of results obtained by standard beam test methods, with reported coefficients of variability (CoV) in the order of 25 per cent. The high test variability results in a relatively low permissible design strength relative to the average flexural strength of the material and commonly leads to non-conformances with respect to residual flexural strength during production testing.This paper presents the implementation of an alternative testing method using large round determinate panels (RDPs) for quality control testing of the SFRC used in the segmental lining of the City East Cable Tunnel (CECT) in Sydney. The alternative RDP test method was found to correlate well with standard beam tests and significantly reduce the variability of test results, minimising the risk of outlying residual flexural strength results, with zero non-compliant test results reported during the production period.This successful implementation of an alternative test for post-crack flexural strength with lower variability in results constitutes a relevant precedent to demonstrate the feasibility of this approach which contributes to the development of more cost-effective concrete mixes and minimises the risk for non-compliant results and the contractual disputes that commonly arise from these.CITATION:Cortes, F, Nievergelt, R and Kost, S, 2014. Development of a segmental lining specification for steel fibre reinforced concrete flexural strength testing using round panel tests, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 461–468 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By A. J. Davidson

A Cu-conducting solid electrolyte was used to develop the sensor. Instead of measuring the potential across the electrolyte from the reference material to the Cu-containing phase, a potential was applied and the stable current measured. This gave reasonable readings for copper-tin alloys, which agreed with the theoretical calculations, but was less satisfactory in the case of mattes because the surface area of electrolyte presented to the matte phase varied from sensor to sensor. To overcome this problem the potential was applied, the current was measured and then reversed and remeasured and the ratio of the currents was calculated. The current ratio is shown to be independent of the resistance of the electrolyte and the surface area of the electrolyte offered to the melt, but strongly dependent on the activity of the copper

Jun 21, 1905