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By Alexander V. Suvorin, Vladyslav M. Sokolov

"The traditional technologies for production of the coprecipitated and deposited catalysts are analyzed from the standpoint of diversion of application of the feedstock and increase of efficiency for its usage. The options for return of the metals of spent catalysts to the catalysts production are described. The novel environmentally friendly and cost efficient approach for reutilization of the spent catalysts is realized in practice. It anticipates application along with spent catalysts of the waste generated in the catalytic productions. Reutilization of the Ni-containing catalysts is referred as an illustration. Introduction The recent development of large catalytic manufacturing for organic and inorganic synthesis, and petroleum refinery as well as for applied environmental catalysis has brought about increase and diversification of catalysts production. The generation of spent catalysts has been increased correspondently. The feedstock for production of catalysts is mostly metals in a form of nitrates, carbonates, hydroxides, hydroxydcarbonates. Sometimes salts of organic acids, of ammoniates, of chlorides and of sulphates occur. All these materials are scarce and expensive. So their repeated use by reutilization of spent catalysts is very actual issue. The traditional recycling the Fe-, Cr-, Ni-, Cu- or Zn-containing spent catalysts are carried out by pyrometallurgical reclamation of pure metals or alloys. They can not be used directly in production of catalysts [1, 2]. The hydrometallurgical approach is used for recycling spent catalysts with PGM, W, Mo, Co, Ni or Cu. It provides production of salts of these metals in a form of sulphates, chlorides, carbonates, hydroxydcarbonates and sometimes nitrates or ammoniates. Only a limited number of these salts can be used directly in production of catalysts. Material losses during catalysts production The basic feedstock for manufacturing coprecipitated and deposited catalysts that may be produced from the spent catalysts is aqueous solutions of metals nitrates. Their production is based on application of nitric acid as a dissolvent. About half of it is lost with the flue gases in a form of nitrates vapor and nitrogen oxides (II, IV). The last compound is generated by reaction:"

Jan 1, 2008

By D. E. Martin, K. J. Hamill, H. J. Miller

1. INTRODUCTION In April 1979, the U. S. Nuclear Regulatory Commission issued the Draft Generic Environmental Impact Statement (GEIS) on Uranium Milling (NUREG-0511) for public comment. While the GEIS is a broad environmental impact assessment of the U.S. uranium milling industry as a whole, its primary focus is on the issue of uranium mill tailings disposal and long term isolation. In August of 1979, proposed regulations (U.S. Federal Register Notice 44FR50012), incorporating both conclusions of the GEIS and provisions of recent U.S. legislation on uranium mill tailings (Uranium Mill Tailings Radiation Control Act of 1978--UMTRCA), were also issued for public comment. This paper (1) briefly reviews the major conclusions of the draft GEIS, (2) summarizes the major elements and rationale of the associated, proposed regulations, and (3) reviews some of the major issues raised during the public comment period and changes which the NRC staff expects will be made in finalizing the GEIS and regulations. The risk in summarizing a document of such broad scope and complexity as the GEIS is that the depth of evaluation and the full technical bases for conclusions reached may not be adequately conveyed. Recognizing this, those Sections of the draft GEIS where a more complete discussion of the issues is presented are parenthetically noted in this paper in order to facilitate location of additional background and supporting material. 2. GENERAL CONCLUSIONS In the GEIS, a full range of tailings disposal alternatives was considered. These alternatives ranged from the past practice of doing little or nothing to control tailings, to advanced treatment alternatives such as nitric acid leaching to increase removal of radioactive elements and fixation of tailings in cement or asphalt. Our broad conclusions were: -Any alternative which results in the need for ongoing, active maintenance to assure long term containment, is unacceptable. (12.3.2.1) -Advanced treatment alternatives are unwarranted since they offer uncertain incremental benefits yet involve costs which may be as much as an order of magnitude greater than costs associated with acceptable alternatives. In addition, the advanced treatment

Jan 1, 1980

By Sven Petersen, Iain J. Stobbs, Bramley J. Murton, Paul A. J. Lusty

"INTRODUCTIONIt is widely thought that seafloor massive sulphide (SMS) deposits, the modern analogue of volcanogenic massive sulphide (VMS) deposits, present a potential global resource for base (Cu, Zn) and precious metals (Au, Ag). In addition, SMS deposits can be enriched in ‘critical metals’ including Se, Te, Tl [1], which are essential for use in the construction of modern and green technologies. Globally over 340 high temperature hydrothermal sites have been identified at a range of ocean spreading centres [2], significant massive sulphide deposit formation has been recorded at 165 of these sites [3].To date only 13 deep sea sulphide deposits have undergone intrusive investigation (drilling or coring) and of these, only 6 sites have published tonnage estimates [2]. Almost all research and drilling of SMS deposits has been focused on active systems, the investigation of the morphology, subsurface structure and mineralogy of hydrothermally extinct seafloor massive sulphide (eSMS) deposits is almost non-existent.As such, little is known about the mechanisms that operate post-SMS formation and which have an impact on the preservation and hence resource value of SMS. Identifying these generic processes and mechanisms, and the extent to which they impact the resource grade, is critical in evaluating the global potential of SMS."

Jan 1, 2017

By Raja V. Ramani, Robert L. Frantz

"The House/Senate Joint Conference Committee has instructed the Bureau of Mines to have the Advisory Committee on Mining and Mineral Resources Research review on an annual and simultaneous basis each generic mineral technology research center (GMTC). In order to accomplish that review promptly and uniformly, committee members have revised and approved an in-depth questionnaire. That document formed the basis of their review. The information provided by that questionnaire was an important factor in their recommendations concerning the future direction of the program; a presentation was made at the last National Plan Update.The comprehensive nature of the questionnaire and the scope of the information contained therein make it an excellent retrospective of the Center. Having a clear vision of where the Center has been and knowing where it is now will help guide it into the future. It is felt that such a detailed view of the Center's facilities and research program will be of value to Center personnel and Advisory Committee members.Each aspect of the questionnaire has been examined, answered in detail, and documented throughly. With the completed questionnaire as a guide, this volume examines the research program, Center personnel presently active on GMTC projects, number of graduate degrees granted with GMTC support, GMTC publications, degree of individual interaction, technology transfer, the reference center, GMTC equipment and facilities, and any envisioned plans for future research. It is hoped that this volume will serve as a review of the years 1984-1988, the first four years of the Center's operation."

Aug 31, 1989

"The mission of the Respirable Dust Center is to enhance the health, safety and productivity of the miners 'through advancing the fundamental .understanding of all aspects of respirable dust associated with mining and milling and the interaction of dus.t and lungs for reducing the incidence and severity of respirable dust disease. All Dust Center activities are focussed to be responsive to this mission which is shared by several federal agencies closely associated with the Generic Mineral Technology Center for Respirable Dust such as USBM, M,SHA, and NIOSH, and the mining industry. While significant progress has been achieved in making mine atmospheres cleaner and healthier, respirable dust disease remains the nations worst industrial hazard. GOALSThe goals of the Respirable Dust Center have been formulated to recognize the diverse scientific, engineering and medical aspects of respirable dust as well as the need to enhance the interaction, education and technology transfer in the respirable dust area.The Center goals are to:1. Enhance the understanding of the scientific, engineering and biological characteristics of fine and respirable mineral particles, fibers, organic aerosols, and complex particles found in the mining and milling atmospheres.2. Advance the understanding of the physical behavior of airborne respirable dust particles in flowing streams under different. stimuli during mining and milling.3. Advance fundamental understanding of the causative mechanisms for the occupationally related lung impairments and the airway diseases of mine and mill workers.4. Establish the relationship between natural and cultural factors (mine geology, mineralogy, mining and milling methods, equipment and control measures) in the generation, exposures, and pathogenic properties of fine particles.5. Contribute to the development of control mechanisms for reducing ambient respirable dust concentrations, worker exposure, the incidence and severity of dust related lung disorders and disease prevention in mining and milling atmospheres.6. Enhance functional integration among the various research personnel in the Center, as well as, with other groups, such as MSHA, NIOSH and USBM involved in respirable dust research and control.7. Develop technically trained personnel for employment in the mineral industry for respirable dust research and control.8. Enhance the availability of respirable dust-related information utilizing several technology transfer avenues."

Jan 1, 1990

"The Generic Mineral Technology Center on Respirable Dust was established in August 1983, at the request of the Bureau of Mines, to conduct research that affords ""...each miner the opportunity to work underground during the period of (his/her) adult working life without incurring any disability from pneumoconiosis or any other occupational disease"". The Center consists of the Mining and Mineral Resources Research Institutes (MRI) of The Pennsylvania State University (PSU) and West Virginia University (WVU) in association with the MRIs of the Massachusetts Institute of Technology (MIT) and the University of Minnesota (UMN). (FIGURE 34) Michigan Technological University (MTU) is also affiliated with the Center in the area of diesel particulates.The Center brings together experts concerned with particles causing potentially disabling or fatal diseases including pneumoconiosis (""black-lung""), silicosis, and asbestosis. The latter is of deep concern not just to workers in the mineral sector of the economy but also to the general populace. The primary goal of the Center is to reduce the incidence and severity of respirable dust disease through advancing fundamental understanding of all aspects of respirable dust associated with mining and milling, and the interaction of dust and lungs. The research program of the Generic Mineral Technology Center explores these scientific, engineering or medical concerns with the objective of refining existing strategies and developing new respirable dust control techniquesand technology that are consistent with the fundamental dust-lung interaction processes that lead to mine worker disability. The work concentrates on five areas (FIGURE 35):"

Nov 1, 1988

By Diego Berti Salvaro

A morfologia, dimensões e composição química de tribocamadas são fortemente dependentes das pressões e temperaturas existentes no contato e oriundas das reações das superfícies entre si, com a atmosfera, com os lubrificantes e contaminantes presentes no contato. No presente artigo foi analisada a formação de tribocamadas em pares DLCaço inoxidável testados por 180, 500, 1000 e 2500 horas em atmosfera de gás refrigerante R134a sem a presença de óleo lubrificante. A caracterização foi realizada por microscopia eletrônica de varredura espectroscopia de energia dispersiva (MEV-EDS) (morfologia e composição química) e interferometria ótica de luz branca (dimensões). Nas análises por MEV-EDS foram identificadas tribocamadas que se apresentaram mais pronunciadas nas superfícies do aço inoxidável sendo as mesmas oriundas de transferências mútuas entre os pares tribológicos bem como oxidação. A espessura das tribocamadas, por sua vez variou de 100 a 500 nm. Os resultados revelam que as tribocamadas são quimicamente estáveis e que suas espessuras não variam significativamente após mil horas de ensaio.

Aug 16, 2017

By J. P. Sims

Abstract - Ultramafic to mafic igneous intrusions of the Las Aguilas district form part of a belt of generally mafic plutonic bodies within medium- and high-grade early Paleozoic metamorphic rocks in the southern Sierras Pampeanas region, Province of San Luis. The intrusions host the largest known nickel sulfide resource in Argentina and contain significant Cu, Co and PGE mineralization (2.2 Mt at 0.5% Ni, 0.5% Cu, 0.035% Co). Sulfides at Las Aguilas Este, one of two principal mineralized zones, are hosted by a body comprising subvertically dipping units of predominantly orthopyroxenite and melanorite cumulate, with lesser dunite, harzburgite, norite, leuconorite, and amphibolite. The units are zoned horizontally from ultramafic to mafic compositions, representing primary magmatic zonation away from an original base or side of the intrusion. Intercumulus nettextured and disseminated aggregates of pyrrhotite-chalcopyrite-pentlandite are concentrated in the peridotitic zones and extend into melanorite. Whole rock major and trace element compositions, and olivine chemistry, indicate that the parent magma was gabbroic/basaltic with 100 (Mg/Mg+Fe) near 59, and resembles tholeiitic magmas generated in subduction-related arc, or back-arc settings. Unusually aluminous Cr-bearing spinel is compositionally similar to those in some synorogenic mafic/ultramafic plutons in magmatic arc settings. Relatively Ni-depleted olivines and low Cu/Pd ratios are indicative of magmatic sulfide segregation early in the crystallization of the magma. Early orthopyroxene saturation and virtual lack of clinopyroxene, in conjunction with sulfur isotope values up to +6.6 ‰, spinel compositions, and presence of graphite, phlogopite and magmatic hornblende, all attest to probable crustal contamination of the parent magma. Assimilation of crustal sulfur may have been crucial in the early attainment of sulfide saturation and resultant formation of magmatic Ni-Cu sulfide mineralization. Fabrics, textures and mineralogy of the intrusions and country rocks and U-Pb zircon dating indicate syntectonic-synmetamorphic emplacement at 478±6 Ma during the Famatinian (Ordovician) orogeny. Minor to locally significant recrystallization and deformation of mafic-ultramafic rocks and redistribution of sulfides and PGE occurred during and following the Famatinian orogeny. The Las Aguilas intrusion is one of several tholeiitic mafic-ultramafic intrusive complexes within an Ordovician arc - back-arc system in the Sierras Pampeanas. Aeromagnetic datasets and regional mapping suggest there is further potential for intrusion-hosted Ni-Cu mineralization along this eroded magmatic arc.

Jan 1, 1999

By Diego Berti Salvaro

The morphology, dimensions and chemical composition of tribolayers strongly depend on the pressures and temperatures acting on the contact. They are formed by reactions between the surfaces in contact with each other as well as with the atmosphere, lubricants and possible contaminants. In this paper the influence of test time (180, 500, 1000 and 2500 h) into the formation and characteristics of tribolayers in pairs DLC-stainless steel tested under refrigerant gas R134a atmosphere without presence of lubricating oil was analyzed. The characterization was performed using scanning electron microscopy, energy dispersive spectroscopy (SEM-EDS) (morphology and chemical composition) and white light interferometry (dimensions). The tribolayers thicknesses ranged from 100 to 500 nm and they were composed by elements originated from mutual transfers between the tribological pairs as well as oxides, being more pronounced on the stainless steel surface. The results show that the tribolayers are chemically stable (maintained the same composition over time) and the thickness remained stable after a thousand hours of testing.

Jul 31, 2018

Nickel-iron sulphide mineralization at Nepean, Western Australia occurs within a small Archaean greenstone outlier in granite south of the main Coolgardie greenstone belt. Individual sulphide ore bodies are situated near the foot- wall contact of simply-differentiated en echelon ultramafic sills that have intruded a sequence of sulphide-bearing metasediments and amphibo- lites. The paper describes a detailed section through the No. 2 ultramafic sill and its associated sulphide ore zone, which gave Metals Exploration N.L. the first significant nickel discovery in the Nepean area in 1968. The sill is variable in thickness up to 30 m along a strike length of 600 m, and is truncated to the north by pegmatite intrusion and pinches out to the south. The body has border zones of pyroxenetic composition, now represented by felted aggregates of chlorite and amphibole, and a central peridotitic core in which olivine and orthopyroxene are concentrated towards the base. Textures within the peridotite are dominated by large lath-shaped olivine grains and their serpentine pseudomorphs, which delineate triangular areas composed of talc, chlorite, and amphibole. Orthopyroxene occurs in large ovoid patches and is often replaced by Talc.

Jan 1, 1973

By R W. Hutchinson

Cupreous pyrite deposits in Cyprus have many geologic similarities to Canadian massive sulphide copper-zinc ores as well as certain significant differences. A comparison of the Cyprus and Canadian deposits indicates a complex genetic history for the latter and suggests that their origin should be re-examined. The Cyprus ores occur in subaqueous extrusive rocks near and at the top of a Cretaceous volcanic pile or igneous complex. The rocks have not been deformed, nor have they been deeply buried or deeply eroded. Apparently the ores formed near or at surface in the top of the volcanic pile by a volcanic-exhalative process and from an ore-fluid of volcanic derivation. The Canadian deposits are of comparable composition and have similar geologic set-tings, but occur in the most ancient Precambrian rocks. Their enclosing Keewatin greenstones have, in most places, been deformed, regionally metamorphosed and invaded by granitic intrusions. Comparison suggests that the Canadian ores also formed initially near surface in ancient Keewatin volcanic complexes by a syngenetic, volcanic-exhalative process. Subsequently, during orogenesis, they were deformed, remobilized under conditions of elevated pressure-temperature and re-emplaced as epigenetic bodies into

Jan 1, 1965

By Ernst A. Hauser

IN a paper published three years ago,' the term "silicic chemistry" was used for the first time to emphasize the increasing importance of the chemistry of silicon in science and technology. The development through which the colloid chemistry of siliceous matter has gone since then is in itself ample proof that the coining of this new term for this branch of colloid science was not presumptuous. Until quite recently, however, silicic chemistry concerned itself only with the composition and colloidal properties of natural and synthetic siliceous matter, but had not paid much attention to the genesis of this matter, particularly to that of the clay minerals. What is even more disturbing, particularly from an educational point of view, is the fact that neither mineralogy, geology, nor metallurgy has fully realized the important role colloidal phenomena must have played in the genesis of our planet and the formation of minerals generally speaking. Considering the importance of colloid chemistry today in the fields just mentioned, it is not surprising that the theories most agreed upon by geologists and mineralogists for the origin of clay minerals are not acceptable from a strictly colloid chemical point of view for the genesis of these most important and most abundant components of the earth. Of all the theories pertaining to the origin of clay minerals, those still most accepted by geologists and mineralogists are the "residual clay" and the "transported clay" theories.15 The former is based primarily on the assumption that the formation of clay minerals is the result of surface weathering of fresh rocks, or is due to the action of solutions. Taking the action of water on orthoclase as an example, the most recent ideas have been summarized by H. Jenny13 as follows:

Jan 1, 1952

"The Archaean komatiite-associated nickel sulphide deposits at Kambalda, Western Australia, exhibit a number of stratigraphic features that are indicative of a strong volcanic control on ore localization, including (1) a restriction to specific basal cumulate metakomatiite host units, (2) confinement within distinctive synvolcanic embayments in the footwall and (3) variations in the internal structure and composition of overlying and adjacent barren metakomatiite flow's and the distribution of interflow metasediments with proximity to the ore zones.The high magnesium content of the host units (up to 45% MgO volatile-free) in comparison with that of aphyric or spinifex- textured lavas (16-32% MgO) has been considered previously to indicate either magmas/lavas rich in intratelluric olivine or selective accumulation of olivine phenocrysts. The marked linear trend of the oreshoots, basal host units, footwall embayments and the volcanic stratigraphic relationships have been used as evidence for local linear feeding fissures. Rare relict igneous olivine in some host units is, however, demonstrably not intratelluric, and there is no direct or indirect evidence of a proximal eruptive site (e.g. footwall feeders, pyroclastic breccias, ultramafic intrusives) at Kambalda such as at some other deposits of this type. Kambalda is interpreted as a distal rather than proximal volcanic environment.Emplacement of the komatiite sequence at Kambalda was probably controlled by the locations of a few specific eruptive sites relative to regional topographic gradients and influenced by the topography of the pre-existing volcanic surface. Olivine enrichment in the basal host units occurred by in-situ fractionation and cumulus crystallization of olivine during longitudinal lava flow within linear lava conduits, possibly centralized on depressions between non-overlapping footwall basalt flows. The distinctive stratigraphic relationships are attributed to localization of lava conduits along the volcanic pitchline, flanked by more slowly moving parts of the flows. There are analogies with the physical volcanology of Modern basaltic and Proterozoic komatiitic lava flows.A corollary of this model is that the lava conduits thermally eroded and assimilated sulphidic sediments, contributing additional sulphur to sulphur-saturated komatiites or possibly inducing sulphide separation in originally sulphur-undersaturated komatiites. The latter would account for the restriction of ores to linear cumulate komatiite host units (thermally active lava conduits) and the locally mutually exclusive, but stratigraphically equivalent, relationship between the ores and sulphidic metasediments at Kambalda."

Jan 1, 1984

By Peter E. Price

Salt dome hosted metallic sulfide deposits are the product of a complex evolutionary system involving halokinesis, cap rock development and diagenesis, and the generation, migration, and accumulation of basinal brines and hydrocarbons. Hydrocarbons play an important role in: (1) the production of calcite cap rock which hosts some of the metallic sulfide and sulfur concentrations, and (2) the generation of the reduced sulfur available for metallic sulfide precipitation and sulfur formation. Hydrocarbons and related fluids also are involved in the transporta¬tion and remobilization of the metals. Hydrocarbon consumption, in the course of cap rock development and sulfide mineralization at Hockley dome, is estimated to have been 6.4 million barrels of oil or 114 million cubic feet of methane. Mineral textures, including cap-rock banding, sulfide bands in anhydrite, and fine sulfide mineral banding indicate both episodic fluid influx and fluid compositional differences through time. Features such as pyrite "shells" and sphalerite and marcasite hemispheres may have been localized by hydrocarbon droplets and /or bacterial colonies. Marcasite mineralization in shallow strata above and flanking Hockley dome is best developed over the western and southern parts of the dome. This pattern mimics the known distribution of sulfide mineralization, which is dominantly marcasite, in the underlying cap rock. The iron sulfide paragenetic sequence in the sediments is pyritohedral and cubic + pyrithohedral pyrite followed by marcasite which is encrusted by cubic pyrite. Sulfur isotopic averages for the three stages are +20.8, -20.2, and +6.4 per mil, respectively. These values generally coincide with cap rock sulfate (+20 per mil), cap rock hosted metallic sulfides (-20 to +4 per mil), and sulfur in hydrocarbons (+5.8 per mil). Hydrocarbon compositions indicate provincial variations in oil composition and generation history. Long Point and Boling domes, which have an intergrown sulfide-sulfate-sulfur mineral assemblage indicative of mixed reducing-oxidizing environment, contain oils that are less mature than Hockley dome which appears to be more mineralogically segregated. Sterane biomarker compositions of the oils at Hockley, Long Point and Boling domes indicate a local, dominantly terrestrial source. An oil sample from supracap sandstones on the northeast flank of Hockley dome contained over 750 ppm combined Fe, Zn, Pb, and Co, indicating that hydrocarbons are carrying or remobilizing metals. Cap rock calcite and anhydrite also exhibit provincial variations in strontium isotopic ratios. Calcite and anhydrite cap rocks from several sulfide mineralized domes in the Houston diapir province have strontium isotopic ratios that are more radiogenic than Jurassic sea water (>0.7078). A calcite sample within massive sulfides at Winnfield dome also has a high 87Sr/86Sr ratio (0.7085). Variations in strontium isotopic ratios with strontium content indicate the mixing of at least three Sr-bearing fluids in the cap rock environment, one of which may have been the metal carrier. Anhydrite residues from diapiric salt have strontium ratios up to 0.7100, considerably more radiogenic than Jurassic seawater. These high ratios indicate either that salt and anhydrite recrystallized sometime post-Jurassic in the presence of a fluid with a high 87Sr/86Sr ratio, or that they precipitated in the Jurassic from a fluid with a higher 87Sr/86Sr ratio than Jurassic seawater. Salt domes with cap rocks containing metallic sulfides have only been found in basins that have geopressured zones. Waters from geopressured zones in the vicinity of mineralized salt domes have salinities that are two or more times higher and iron and base metal concentrations that are three to one thousand times higher, than geopressured fluids from other parts of the basin.

Jan 1, 2013

By Charles R. Keyes

Continued discussion of the paper of Charles R. Keyes, Trans., xxxix., pp. 139 to 169, 850 to 856, and Bulletin Ho. 34, October, 1909, pp. 945 to 947. CHARLES R. KEYES, Des Moines, Iowa (communication to the Secretary*):-It is with pleasure that I acknowledge the value and interest of the historical notes on early mining at Lake Valley, contributed by Messrs. MacDonald and Courtis. In my own paper there was no attempt to enter into this phase of the subject; partly for reason that the intention was to take up this in detail in another connection, partly because there was not space enough to. devote to it in a brief geologic paper, and partly on account of the fact that the strictly mining features are quite distinct from the purely geologic characteristics. As may be inferred from its perusal, the brief historical paragraph prefacing my paper was in reality geologic in its bearing. The events referred to therein relate to the published information concerning the geologic structure. The personages principally mentioned were noted merely to show how the names of several of our most distinguished scientists came to be closely associated with that of Lake Valley. Far from my intentions was it to slight the memory of any , of that brave band who, with lives in their hands, took so active a part in the early development of the mines. The value of their records is perhaps much greater than that of any published notes. The narratives of Messrs. MacDonald and Courtis are as thrilling as many other experiences related of that time and place. Few of us at the present time can appreciate the dangers of that early day, when the fierce Apache all but swept the. white man from that part of the country, when renegades from Texas overran the land, and when the outlaws of the nations took their last stand before advancing civilization. In marked contrast do we to-day reach Lake Valley by means of the 11 iron horse"; and out of a luxurious Pullman

Apr 1, 1910

By CHARLES R. KETES

I. INTRODUCTORY. Lake Valley, New Mexico, has long been one of the most widely known mining districts of southwestern United States. For many years its silver-mines have been among the most famous of the country, visited by many mining men and geologists; yet little information regarding the origin of the ore-deposits and the influencing geologic conditions has found its way into print. With the recent revival of public attention, after a decade and a half of utter stagnation, to the mining of silver in the Southwest, special interest attaches to the genesis and geologic disposition of the ore-bodies which are so finely open to inspection in the Lake Valley district. Moreover, the local features here described are typical of the conditions existing over a much larger field. The fact that the ores are chiefly the chloride and the chloro-bromide of silver adds further interest. Data bearing upon the genesis of haloid ore-deposits are, at the present time, very much sought. Arid regions offer particularly favorable conditions for the formation of such ores. This New Mexican district appears to supply solutions to many problems concerning this class of ores, which have long vexed the student of ore-deposits. II. LOCATION AND HISTORY. The town of Lake Valley is situated in Sierra county, in the southwestern part of New Mexico, and 100 miles northwest of El Paso, as the crow flies.From a mining standpoint, the location of the place is itself suggestive, as it lies on the southeastern slope of the great quaquaversal arch of the Colorado plateau. The center of this vast dome is in north-central Arizona, and radii about 150 miles in length reach its foot in all directions. Around its basal margins runs the broad mineralized belt containing most of the great mines of the Southwest, which extends from south-central Colorado southward and southwestward through New Mexico, thence westward through Arizona, northwestward and northward through southeastern California and western Nevada, and, finally, eastward through Nevada and Utah into Colorado again. This great mineralized belt is important as geographically limiting profitable mining over the greater part of five States.

Jan 1, 1908

By Charles R. Keyes

Discussion of the paper of Charles R. Keyes, Bi-Monthly Bulletin, No. 19, January, 1908, pp. 1 to 31. BERNARD MACDONALD, Guanajuato, Mexico (communication to the Secretary*) :-Mr. Keyes's paper is very interesting to me because of my personal experience with the development of the ore-deposits of Lake Valley. Seeing that many of the important facts connected with the early history of the development of these mines are either now unknown, or have become more or less distorted, and thinking that it would be interesting as well as valuable to have these recorded as a historical supplement to Mr. Keyes's elaborate paper, I present the following narrative: In February, 1881, soon after the Atchison, Topeka & Santa Fé railroad made connection with the Southern Pacific at Denting, N. M., the Lake Valley properties were brought to the attention of New York and Philadelphia capitalists by John A. Miller, of Silver City, N. M. At that time silver was $1.10 all ounce and silver-mining was very attractive. Vast fortunes were being made in Leadville and other Colorado camps, and Tombstone was pouring out its millions. Lake Valley, like all' other mining-camps in their early history, had its drawbacks, but the railroad, then passing within 14 miles of it, mitigated many of these. The camp lay in the foot-hills of the Black range, in which the Apaches had their stronghold, and raided, when it suited their convenience, the surrounding country, killing the prospectors and pioneer settlers and stealing their cattle. This band of Indians was joined by the outlaws and desperadoes from the frontiers of Texas, Arizona, and Mexico, who collectively defied the United States soldiers, restrained, as the latter were, by the mollycoddles from the East. The brutality of the Indian raids through Arizona and New Mexico in those days would scarcely be believed now, but they stain in deep

Feb 1, 1909

By H Q. Zhang, M C Chai, W Fu, H Y Chen, L M. Wei, Q J. Yang

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Fozichong deposit – located in the south-western segment of the giant Qinhang metallogenic belt, South China – is a large-sized lead-zinc polymetallic deposit. This deposit contains two main ore districts, termed as the Guyi ore district in the north and the Hesan ore district in the south respectively. We present an integrated data set on sulfide minerals, fluid inclusions and stable isotope (H-O-S-Pb) geochemistry to better understand the features and genesis of the Fozichong deposit.Field and paragenetic relationships indicate three mineralisation stages forming the early (Po+Sp+Gn+Ccp+Py+Di+Ep+Qtz), middle (Sp+Gn+Ccp+Py+Ep+Chl+Qtz) and late (Gn+Sp+Py+Qtz+Cal) sulfide assemblages respectively. Mineral chemistry – particularly S/Fe and Co/Ni ratios in pyrite, Zn/Fe, Zn/Mn and Zn/Cd ratios in sphalerite and Pb/Ag ratios in galena – indicates a magmatic association for the sulfide minerals.Quartz and calcite coexisting with the sulfide minerals of various stages host abundant fluid inclusions. Quartz in the early stage contains two- or three-phase CO2-H2O and liquid-rich aqueous inclusions, which have homogenisation temperatures of 162~365°C and salinities of 2.9~17.8 wt per cent NaClequiv, whereas quartz and calcite from the middle and late stages are dominated by two-phase, liquid-rich aqueous inclusions that have slightly lower homogenisation temperatures (153°C~320°C) and much lower salinities (1.0~6.0 wt per cent NaClequiv). Hydrogen isotopes (dD = -59‰~-41‰), analysed using fluid inclusion waters from quartz and calculated oxygen isotopes (d18OH2O = -5.47‰~4.00‰) for the equilibrated ore fluids, indicate that the ore-forming fluids may have been sourced from magma and mixed with groundwater in the late stages. Sulfide minerals have d34S values of 2.3‰~4.3‰, consistent with a magmatic-derived source for sulfur. Lead isotopes (206Pb/204Pb = 18.592~18.794, 207Pb/204Pb = 15.648~15.864, 208Pb/204Pb = 38.909~39.580) confirm that lead and, by inference, zinc were mainly derived from magmatic rocks, with subordinate contributions from sedimentary rocks.Various lines of evidence support that the formation of the Fozichong deposit has close genetic association with the granite porphyry intruded in the late Yanshanian period (106 Ma), and it can be classified as a magmatic hydrothermal type lead-zinc deposit. We propose that the Hesan and Guyi ore districts may represent the proximal and distal products of a magmatic – hydrothermal system respectively.CITATION:Fu, W, Zhang, H Q, Chai, M C, Yang, Q J, Chen, H Y and Wei, L M, 2015. Genesis of the large-sized Fozichong lead-zinc polymetallic deposit, Guangxi, south China – constraints from the sulfide mineralogy, fluid inclusions and isotope geochemistry , in Proceedings PACRIM 2015 Congress, pp 609–614 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By MORTON WEBB

Discussion of the paper of Max Boehmer, presented at the Pittsburg meeting, March, 1910, and printed in Bulletin. No. 38, February, 1910, pp. 119 to 122. W. MORTON WEBB, Germiston, Transvaal, South Africa (communication to the Secretary*):-The experience of Mr. Boehmer in the Leadville district and his reputation as an engineer assure the interest of anything he may write on the ore-bodies of that district; and all engineers who have operated in Leadville will agree that the theory of the origin of the Leadville deposits, as given by Mr. Emmons in his famous monograph, does not adequately explain the genesis of all the deposits. The solution of the problem does not, however, appear to be quite so simple as Mr. Boehmer would make it; and the advance pamphlet issued by the U. S. Geological Survey, pending the completion of the main report, shows that there is still much ground for controversy. No doubt the later eruptives had a greater influence on the deposition of the ore-bodies than was thought at the time of the first investigation by the Survey; but it has always appeared to me that the influence exerted by these dikes was more in the nature of a physical than a chemical one. The weight of evidence in recent years is mostly in the direction of ascension rather than lateral secretion; and one of the strongest evidences is the fact that most of the ore-bodies lie under one of the comparatively impervious layers which help to make up the structure of these hills. On Iron hill I have found a very persistent white porphyry sheet, split off from the overlying porphyry and lying from 30 to 60 ft. below the main white porphyry and blue limestone contact. This sheet varies from a few to 50 ft. in thickness, and where found adds another "contact" to that region ; some of the largest ore-bodies on Iron hill lie immediately under this sheet. Above this is the main white porphyry and * Received Mar. 3, 1910.

Feb 1, 1911

Neither the copper orebodies nor the zinc-lead-silver orebodies at Mount Isa were formed syntectonically as has been claimed for the last 20 and 10 years respectively. Both orebody types were cogenetic, coeval, and formed early during the sedimentation and diagenesis of the host formation. The copper orebodies are interpreted as having formed diagenetically at hand specimen scale, syngenetically at formation scale. The zinc-lead-silver orebodies are interpreted as having formed primarily by sedimentary means at both hand specimen and formation scales.

Jan 1, 2000