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By Barry Hunsaker

I cannot help but be reminded, as I stand here today, of my boyhood years and heritage, both of which are inextricably tied to this very valley and are, in a: bay, apropos of the theme of this Keynote Session. I remember the scarcity of people. For example, 48, 000 in Phoenix and 436, 000 in the State in 1930 and 65,000 in Phoenix and 499, 000 in the State in 1940. Today Phoenix boasts a population of over 500, 000 and the State a population of 1, 500,000. I remember the' lack of facilities, goods and services, including gas and electric power. I recall stories of my grandfather who had the freighting or teaming contract to haul all the supplies and generating equipment, by wagon mind you, up the old Apache Trail to Roosevelt Dam. . .a three day trip from the nearest railhead which, by the way, was not Phoenix, for it did not merit a railhead on those days, but the village of Maricopa approximately 25 miles south of Phoenix. I remember chopping firewood, heating wash water on an open fire in a No. 3 wash tub at the rear of the house and doing my school homework by the light of a kerosene lamp just 25 to 35 years ago within what is now a large metropolitan area

Jan 1, 1965

Natural gas from the south west Queensland gas fields is now available in north west Queensland to fuel the development of many Carpentaria Mineral Province projects. Like these projects, the south west Queensland gas project, developed under the operatorship of Santos Ltd, has its own æMining CycleÆ. While the project is entering its third expansion phase, it is at the same time actively extending its discovery phase, with large programs of gas exploration and reserves definition. This paper outlines the history of the south west Queensland gas project, with particular emphasis on the relationship of the project to north west Queensland.

Jan 1, 1998

By K. C. Sclater

GAS as a factor in the efficiency of oil production, might be a better title for this paper as it deals in general with the significance of the gas-oil ratio as an index of the efficiency of oil production and briefly discusses oil production methods with reference to the gas-oil ratio in wells, particularly during the early life of a field. In the recent hearings held at Washington before the Federal Oil Conservation Board the fuller utilization of the energy contained in the gas occluded in or associated with the oil underground was stressed by some of the speakers when referring to greater ultimate recovery of oil. One speaker commenting on this point said in part, "There is ample evidence indicative that if the gas associated with the petroleum in our fields were conserved and elevated gas pressure maintained in the oil sands during their productive life, the ultimate production of oil could be greatly increased."

Jan 1, 1926

By Italo Onederra, Miguel Araos

Most of the current explosives for mining blasting activities rely on voids to become sensitive to initiation, then detonating and finally, sustaining that detonation. The use of voids is known as hot spot sensitisation. Various forms of voids serve as hot spots – gas bubbles (predominantly in bulk explosives), glass (or plastic microballoons, for packaged products), or expanded polystyrene (bulk explosives). Gas bubble sensitisation uses the decomposition of sodium nitrite to produce nitrogen gas bubbles, which are dispersed throughout the bulk explosion. These gas bubbles, when hit by a shock wave (such as from a booster), compress and heat up, subsequently decomposing the explosive and releasing energy to sustain the detonation. It has been suggested that the use of different types of gases to create voids in non-ideal explosives could offer some alternatives to the sensitisation process, which could be reflected in the change of the detonation properties of the explosive. The reason would be that each gas has a different ratio of specific heats (=/), and when these gas bubbles are compressed, they will heat up to different temperature, affecting the decomposition of the explosive and thus, the VOD.

Jan 26, 2026

By C. A. C. Sequeira, G. N. Anastassakis

Electrochemical processes occur on nano-, micro- and macro- scale in numerous applications such as fuel cells, batteries, hydrogen production, mineral extraction, water treatment, electrotherapy, sensors and many others. In most of these applications, gases evolve either at one or both electrodes due to electrolysis. These gases form bubbles play a crucial role in electrochemical systems. For example, in electrowinning (EW) that is used to extract and refine metals such as Cu, Zn, Ni, Mn, and Cd from their solutions, in most cases the solution is acidic and oxidation of water molecules at the anode is the common counter reaction, which results in the liberation of oxygen bubbles. This generally requires a high overpotential and accounts for a considerable percentage of the energy consumed in metal EW electrolytic cells, apart from producing acid mist that is very corrosive for other cell equipment and building structures. The behaviour of bubbles in electrochemical systems is still a complex challenging topic which requires a better understanding of gas bubbles hydrodynamics and their interactions with electrode surface and bulk liquid, as well as between the bubbles themselves. The objective of the current paper is to briefly review the fundamental hydrodynamics of both gas bubbles on the electrode surface and gas bubbles interaction with the liquid bulk solution. The current work also investigates the impact of gas bubbling and some operating parameters in copper EW, such as current density (100-500 A/m2), temperature (25-75ºC), acidity (50-300 g/L) and a typical chemical mist suppressant (<50 ppm). The results clearly show that both suppressant and temperature reduced the overall surface tension of the solution. Also, chloride concentration and applied current improved electrolyte flow and copper quality at higher current densities. The current paper contributes to the development of mineral processing (specifically to copper hydrometallurgy), as it deals with fundamental hydrodynamics and interactions of gas bubbles that formed during copper EW and play a crucial role in copper electrochemical systems.

Jan 1, 2018

By T P. Fischer, S N. Williams, N C. Sturchio

Chemical and isotopic analyses of fumarole gases from Galeras Volcano, Colombia provide significant insights into the origin of volatile components in the magma. Water comprises a mixture of magmatic (rock-equilibrated at high temperature) and meteoric, with the relative proportions varying through time. Carbon isotopes are most consistent with a mantle source, although other contributions to the system cannot be ruled out. Nitrogen most likely originated from organic matter in subducted oceanic sediments. All of these &apos;primary&apos; components have been modified somewhat by interaction or exchange with other reservoirs during ascent to the surface. In addition to information on the origin of the gases, these data show significant temporal variations precursory to eruptive events. Chemical ratios change and water becomes more meteoric in character prior to eruptions.

Jan 1, 1995

By Sturchio NC, Williams SN, Fischer TP

Chemical and isotopic analyses of fumarole gases from Galeras Volcano, Colombia provide significant insights into the origin of volatile components in the magma.. Water comprises a mixture of magmatic (rock-equilibrated at high temperature) and meteoric, with the relative proportions varying through time. Carbon isotopes are most consistent with a mantle source, although other contributions to the system cannot be ruled out. Nitrogen most likely originated from organic matter in subducted oceanic sediments. All of these "primary" components have been modified somewhat by interaction or exchange with other reservoirs during ascent to the surface. In addition to information on the origin of the gases, these data show significant temporal variations precursory to eruptive events. Chemical ratios change and water becomes more meteoric in character prior to eruptions.

Jan 1, 1995

By Manuel Gutierrez, Roberto Gomez, Juan Aravena, Johan Gjoevad

The use of explosives in mining operations is a process that involves the search for an ideal explosive for the type of geological condition of the mineral to be extracted. For the explosives present on the market the majority are based on Ammonium Nitrate. This as it is an ideal balance of high energy efficiency achieved with low development of gas emission. The manufacturing and loading operation of the explosive requires multiple process stages and different raw materials, which, if is not correctly supervised and controlled may cause the development of harmful gases or, in the worst case, even toxic gases. The majority of mining operations are located at remote locations without the presence of communities, and hence individuals, which could be affected by emission of the harmful or even toxic gases. In these operations the protection is mainly to protect the employees of the operation. However, if the operation is located near communities, the effect of these gases becomes a serious problem. The communities' perception of post-blasting gases, according to interviews carried out in this project, describes these as smells of black gunpowder, damp soil with a volatile permanence and medium intensity, sometimes a stinking tone is added. The legislation in Chile that controls the exposure of “workers” to different gases is Supreme Decree 594, 2019 (Decreto Supremo 594). Currently the Chilean Ministry of Environment and Sernageomin (Servicio Nacional de Geología y Minería) are taking actions to reform and strengthen oversight, seeking through a short law to provide more tools to the government to decentralize decisions in case of non-compliance with the decree. This paper describes the development and implementation of a permanent and remote gas monitoring system, considering the reasons for choosing the gases to be included in the equipment, the types of sensors and their capabilities, the way to verify in the field the correct functioning of the technology throughout the project, and finally how the data collected in the field is meeting the government's expectations in terms of permanent and online reportability. Additionally, it addresses the continuity of gas monitoring in the community that will disappear in the short term due to the expansion of mining operations, thereby ensuring the protection of both workers and affected communities.

Jan 21, 2025

By Baisheng Nie

The process of gas diffusion through coal particles and the mathematical physical model under the third kind boundary condition was determined to obtain the rules of gas diffusion through coal particles of different sizes. The analytical solution of the equation was obtained by the Method of Mathematical Physics. The parameters of analytical solutions and the implications of parameters were analyzed. The Biot criterion (Bi) and the Fourier criterion (F0) of mass transfer can represent and reflect the features of gas diffusion field of coal particles. Moreover, the measurement method of gas diffusion coefficient and surface mass transfer coefficient is introduced and an example of measurement is given. The achievement can provide the support to prevent disasters related to methane in coal mines.

Aug 1, 2013

By Cesar Gomez, Jaime Álvarez, Lisette Wen

Laboratory mechanical flotation cells are extensively used in mineral processing for running batch flotation tests with a variety of purposes, for example assessing feed characteristics, determining flotation kinetics, or testing of new reagents and procedures. It is known that the results obtained depend on the operation mode, self-aerated or forced-air, and on the operating conditions selected for the test, in particular impeller speed and gas flow rate. These different results are a consequence of changes in size distribution of the generated bubble population and its remarkable evolution when frother is added; variations in bubble size affect the bubble surface area flux (BSAF), a variable which correlates with particle collection. Results of a two-phase (air-water) test program designed to measure bubble size for a variety of combinations of impeller type and speed, gas flow rate, frother type and concentration, and cell volume, demonstrated the wide range of BSAF with which the cell can be operated. The results obtained in this work demonstrated that gas dispersion in a forced-air lab flotation machine is significantly affected by the characteristics of the impeller/cell geometry combination in use, and the operating conditions selected. Operating conditions must be carefully selected and maintained during the test to ensure consistent results, in particular when frother concentrations below 20 ppm are used, because frother concentration in the cell will decrease as flotation progresses as a consequence of frother partitioning to the concentrate.

Jan 1, 2014

By Finch. J. A., C. Perez, J. M. Ortiz, G. Cortes, A. B. Yañiez, F. Coddou, P. Morales, H. Elgueta

A campaign to perform characterization tests in a TankCell®-300 flotation cell installed at Chuquicamata Codelco&apos;s concentrator was conducted. The campaign included integrated gas dispersion measurements (gas velocity radial mapping and single point gas holdup and bubble size) and determination of frother concentration. Cell streams were sampled to assess metallurgical performance at the same time. The experimental program was designed to establish the bubble surface area flux operating range and its effect on performance, and the effect of using longer residence times and of a device designed to enhance mixing in the collection zone (FlowBooster(TM)). The gas dispersion results and their relationship to metallurgical performance are discussed.

Jan 1, 2009

The effect of superficial gas rate distribution (Jg profile) on down-the-bank metallurgical response was tested in the rougher-scavenger bank (eight 10-m3 tank cells, 4 roughers and 4 scavengers) at Highland Valley Copper Mine&apos;s Cu/Mo separation circuit. Three Jg profiles were tested: (a) as found (i.e., typical practice), (b) increasing decreasing (i.e., increasing from cell 1 to 4 and decreasing from cell 5 to 8), and (c) decreasing-increasing (i.e., decreasing from cell 1 to 4 and increasing from cell 5 to 8). The Jg profile approach proved to be of considerable value. Profile (b) gave the best metallurgical results, i.e., the highest down-the-bank grade/recovery (increase in grade at constant recovery was approx. 3-4% compared to the as found case) and the most efficient Cu/Mo separation (cumulative Cu recovery was reduced by almost half - approx. from 20% to 12%, at 99% Mo recovery). The success of the evaluation prompted the implementation of profile (b). Detailed gas dispersion characterization tests (Jg and Db (bubble size)) showed significant discrepancies between the Jg measured directly (using the McGill University sensor) and the Jg calculated from field instrument readings (volumetric gas flowmeter) and machine dimensions (cell cross-sectional area). Tests were designed to reveal the source of disagreement. It was observed that a significant number of bubbles were not able to float (i.e., they were entrained with the tailings), the evidence appearing to be a significant number of very small bubbles (approx. 200-300 µm) which did not have sufficient buoyancy to rise. Consequently, rather than relying on the field instrument, the evaluation depended on the McGill University Jg sensor, which collects bubbles in a tube near the pulp-froth interface, thus providing significance to the data as the measurements were obtained from bubbles that almost certainly floated.

Jan 1, 2007

By J. A. Finch

"Gas dispersion in flotation defines the efficiency of the process once the chemistry has been established. There are three measurements, superficial gas velocity, gas holdup, and bubble size, which along with the derived quantity bubble surface area flux, are used to define “gas dispersion.” Sensors for measuring gas dispersion in industrial machines have been developed. This communication describes the working principle of the techniques and illustrates their potential to detect problems and to improve the operation of individual cells, banks and circuits. IntroductionFlotation is the most widely used process to separate minerals and is finding increasing application in other chemical and environmental fields. The process exploits natural and induced hydrophobicity to collect selected particles on the surface of a bubble. Once the process chemistry to control hydrophobicity has been established, the efficiency depends on dispersion of air to generate the necessary bubble surface area. Bubble surface area flux, Sb, the interfacial area generated per unit time and unit area of the machine, is emerging as one of the most useful variables to quantify gas dispersion (Gorain et al., 1997, 1998) although not without its critics (Heiskenan et al., 2001).For a bubble population of mean size db at a superficial gas velocity (or rate) Jg, the bubble surface area flux can be derived from geometric considerations (Finch et al., 1999):"

Jan 1, 2002

By Alejandro Yañez, Martta Nousiainen, Rodrigo Grau

"Gas dispersion plays a fundamental role in froth flotation. Gas dispersion in flotation is quantified by using four properties: gas velocity, bubble size, gas hold-up and bubble surface area flux. Gas dispersion measurements were conducted in three flotation cells: TankCell 1, TankCell e300 and TankCell e500. The measurements reported in this paper were carried out exclusively in two-phase systems using only water and air at frother dosages exceeding the Critical Coalescence Concentration (CCC) in order to prevent bubbles from coalescing. The measurements conducted in TankCell 1 and TankCell e500 were conducted by Outotec specialists, whereas the characterization of TankCell e300 had been conducted earlier in 2008 by a team from McGill University. When working in two-phase systems and under non-coalescing conditions, gas dispersion characteristics measured in different scales can be compared directly. The measurements conducted in TankCell e300 are taken as a base line in order to compare the performance of TankCell e500, whereas TankCell 1 is a pilot-scale flotation cell which is used in rotor testing. The gas dispersion properties in TankCells were found to be affected by the air flow rate and rotor tip speed. Bubble sizes (d32) measured on the three-size scale seem to be within the same range of 0.6 mm to 1.6 mm. It was noted that the bubble size was influenced by rotor tip speed and gas velocity. In general, as the rotor tip speed increased, the bubble size decreased and as the gas velocity increased, so did the bubble size. The rotor tip speed also has an impact on the hold-up; in general, as the rotor tip speed increased the gas hold-up also increased but the influence of air flow rate on gas hold-up was greater. Bubble surface area flux was found to vary between 40 and 85 1/s. As the gas velocity increased, the bubble surface area flux also increased."

Jan 1, 2014

By Avishan Atrafi, Marek Pawlik

"Gas dispersion properties of sodium salts of 6, 12 and 18-carbon fatty acids (hexanoic, lauric and oleic acid) were investigated as a function of pH. A strong effect of pH was observed on gas dispersion properties of fatty acids. At high pH for 12 and 18 carbon fatty acids, at which these surfactants formed a true solution, the gas dispersion properties were similar to those of MIBC. In the case of sodium hexanoate, which has a much higher solubility than the longer chain fatty acids and therefore does not form precipitates, the gas dispersion properties of this surfactant were strongly enhanced in the acidic pH range, where hexanoic acid was fully associated. This result is an indication that undissociated hexanoic acid is much more surface-active than anionic hexanoate. Only a small effect of the surfactant chain length on gas dispersion properties of the tested reagents was observed. The measured critical coalescence concentration (CCC95) values increase slightly by decreasing chain length and range from 5.8 x 10-5 mol/L (17.7 mg/L) for sodium oleate to 7.2 x 10-5 mol/L (16 mg/L) for sodium laurate at pH 10 and 1.9 x 10-4 mol/L (26 mg/L) for sodium hexanoate at pH 3.7. These are compared to CCC95 of MIBC, which is measured to be 8 x 10-5 mol/L (8 mg/L). The soluble molecular species were recognized as the most effective species in preventing bubble coalescence."

Jan 1, 2014

This paper discusses three case studies conducted at Highland Valley Copper mine (HVC) that illustrate operational improvements and insights which resulted from using the McGill University gas dispersion sensors. In the first study, the superficial gas velocity (Jg) sensor was used to implement a gas profiling control strategy for the rougher, scavenger and first cleaner cells in the Cu/Mo separation circuit. The data showed a 40% reduction of down-the-bank Cu recovery at constant Mo recovery which resulted from operating the cells at the target profiles. In the second study, the bubble size analyzer was used to better understand two mechanisms of bubble formation in the two flotation columns that make up the final Mo cleaning stage: the conventional rubber-sleeve sparger and the Microcel(TM) system. The data showed a considerable reduction of bubble size in the Microcel column which resulted in a significant increase in concentrate quality (1-2% Mo absolute) and a dramatic (4-5 fold) increase in concentrate production rate compared to the typical operation. The estimated economic benefit resulting from the improved column flotation operation was an overall 4% increase in Mo circuit recovery. In the third study, real-time measurements obtained from the gas holdup and bulk density sensors were used to infer the pulp density (% solids) in a rougher cell of the bulk flotation circuit. Validation tests demonstrated that this approach provides reliable pulp density measurements. Although promising, more work is required before implementing this approach at HVC.

Jan 1, 2009

By J. A. Finch

The metallurgical performance of a flotation cell is strongly influenced by the features of the bubble population, characterized by the gas dispersion properties, a collective term including bubble size, superficial gas velocity and gas holdup. It is required that gas be well distributed throughout the cell. Gas distribution is estimated here by simultaneous measurement of gas velocity (Jg) at different distances from the center (radial Jg mapping). This communication describes a technique to perform radial Jg mapping together with fundamentals for the interpretation of the data.

Jan 1, 2009

By Y. F. Bulgakov, Y. V. Melnikova, V. S. Zakharov

A new technology of atmosphere in inertization of fire section with the help of gazeous nitrogen is presented in the report. This technology is based on membrane air subdivision into two streams, concentrated with nitrogen (up to 99%) and with oxygen correspondently with subsequent giving them into the place of fire. This technology belongs to environmentally friendly ones and it has a great number of technical, mobile and economic advantages comparing with the rest of well-known methods of fire extinguishing. This technology application in Ukrainian coal mines allowed to reduce the member of isolated places of fire at the expense of their extinguishing efficiency.

Jan 1, 2003

By Michael L. Ogilvie

The proportion of underground coal production as a percentage of overall Australian production has fallen in the last 10 years, with underground production remaining more or less static at about 53 Mt (58 million st). However, underground coal mining remains a viable industry in Australia, due to use of modern longwall mining systems. In 1993-1994, 26 longwalls were in operation, with total production exceeding 39 Mt/a (43 million stpy). Some of these longwalls achieve productivity levels approaching efficient opencut operations, and in some cases, they exceed them. These high-production longwall mines are not without problems when depth and distances from outcrop increase and the gas content of the seams approaches or exceeds critical limits. When gas content of a coal seam exceeds 6 m3/t (233 cu ft/st), gas flows into the mine may be sufficient to interrupt production from time to time.

Jan 1, 1995

By J Sargeant, T Levi, J Theiler, B Beamish

Two coal samples (810 Panel and Area 900) collected from Clarence Colliery have been tested under a controlled heating procedure to evaluate the gas evolution trends corresponding to increasing temperature. Gas evolution data are normally used to identify key gas indicators and validate the trigger action response plan settings for the mine as part of the Principal Hazard Management Plan for Spontaneous Combustion. The samples were located some 6 km apart and there is a significant coal-type difference between them. At low temperatures (&lt;100&#176;C), the Graham’s ratio (GR) values for the two samples are almost identical. However, at elevated temperatures, there is a significant difference, with the 810 Panel coal having higher GR values than the Area 900 coal. This is most likely due to a difference in the coal reactivity. The 810 Panel coal does not evolve ethylene until temperatures in excess of 140&#176;C are reached, whereas Area 900 coal evolves ethylene once temperatures in excess of 120&#176;C are reached. The 810 Panel coal also produces significant ethane evolution (200 ppm) at low temperatures (50&#176;C) due to the presence of retained ethane seam gas, which decreases as the temperature increases due to desorption from the coal. Once the coal temperature exceeds 130&#176;C, the ethane evolution increases again due to coal oxidation reactions, reaching levels of 50 ppm. In contrast, the Area 900 coal has no significant low-temperature ethane evolution, and ethane evolution only increases once the coal temperature exceeds 120&#176;C. There are also noticeable differences in the trends of other gases evolved from the coal. These findings have implications for the interpretation of gas monitoring results from the two different areas of the mine. They also illustrate the need for obtaining results from each new area of a mine as it develops so that changing gas evolution trends can be identified in advance of mining.CITATION:Beamish, B, Sargeant, J, Levi, T and Theiler, J, 2015. Gas evolution trends for coal from two different areas at Clarence Colliery, in Proceedings The Australian Mine Ventilation Conference, pp 273–278 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015