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By Patrick Pelletier, Pierre-Alexandre Bossé, Julie Fournier, Gianni Bartolacci, Jayson Tessier, Ahmed Bouajila, Carl Duchesne

"This paper summarizes research into the study of the control of flotation processes based on froth images. The use of numerical image analysis techniques for the extraction of significant patterns (froth structure and colour) from industrial flotation froths is discussed.First, the froth was analysed by the use of the Multivariate Image Analysis (MIA) method to extract the spectral variation contained in a RBG image. The Partial Least Squares (PLS) was applied to develop the empirical model for the prediction of froth grade. The results of this application are illustrated using one industrial case study.Second, the froth was also analysed by Gray Level Co-occurrence Matrix (GLCM) and Wavelet Transform Analysis (WTA) to extract features related more to morphological aspects. Since there is useful information hidden in froth texture, these methods are used as texture descriptor to classify different types of froths.Third, a control strategy based on a froth structure indicator was developed and implemented on an industrial zinc flotation circuit. The feedback controller uses a reagent flow-rate in order to maintain the froth structure at its set point. Process improvements obtained with the implemented control strategy are highlighted.Finally, the feasibility to implement a hybrid control strategy consisting in a froth structure supervision controller based on the froth concentrate grade estimated by MIA and recovery inferred by image analysis is discussed.INTRODUCTIONThe development of control strategies to achieve satisfactory control performance has always been a great challenge for engineers and the need for improved process diagnosis, control and optimization has become more and more evident for the mineral processing industry in the last decades. That is why new process variables need to be measured particularly in highly multivariable processes such as flotation. This industrial process is subject to a wide variety of disturbances mainly generated by frequent and sometimes abrupt changes in physical and/or chemical ore characteristics and also, due to some irregularities in manual process operating procedures. A flotation circuit scheme is always a complex network of more than two dozens slurry streams. Information about those streams (% solid, metal content analysis and flow rates) is important for process diagnosis performance evaluation and control. Also, because of the grade decrease and increasing complexity of the new processed ores, more instrumentation outputs and more powerful and significant pr"

Jan 1, 2005

By C Smith, J Cilliers, K Hadler

Unstable flotation froths, that burst before they overflow, produce no concentrate. Increasing the froth stability to improve recovery is therefore an obvious control strategy. Froth stability can be measured readily as the fraction of air entering the flotation cell that overflows as froth, rather than bursting on the surface; the ‘air recovery.’ Air rate is one of the most significant variables affecting froth stability. It is interesting that froth stability (air recovery) is maximised at a specific air rate, above or below which it decreases. It is important for metallurgists to realise that this maximum froth stability also produces the maximum mineral recovery, without compromising concentrate grade. Flotation cells must be operated at the air rate that produces the highest air recovery. The peak air recovery (PAR) to maximum mineral recovery relationship was first demonstrated by Hadler and Cilliers in 2009. Since then, the relationship between PAR and flotation performance has been widely explored; varying air rate, froth depth and particle size. Industrially, reducing the flotation bank air rate to achieve PAR yielded better mineral recoveries than other down-the-bank air rate profiles. In this paper, we present an overview of these key developments and findings in flotation optimisation based on PAR. Furthermore, using new industrial data, we show that PAR is not just applicable to rougher-scavenger cells, but also to flotation columns. Finally, we consider the future application of such an optimising control concept. CITATION:Smith, C, Hadler, K and Cilliers, J, 2018. Flotation control using froth stability: past, present and future, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 441–454 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By A. Eslami

When producing high grade mattes in smelter plants, copper losses in the slag are inevitable. Hence, the recovery of copper from slag has been the focus of many research projects, copper flotation being a widely used process. In the Khatoonabad converter, 200 t/d of slag are presently produced with a grade of 2.3% Cu. Assuming a 85% recovery by flotation, about 3.9 t/d copper could be produced, which is of prime importance economically. In the present work, a sample of this slag was crushed and ground in the laboratory to liberate the copper-bearing minerals. Following mineralogical studies, optimum laboratory flotation parameters were obtained, resulting in 90.27 % recovery and 9.42% of copper grade for the rougher stage. At pilot scale, a pulp of 28% solids was floated at ph 10.5 using 40 git of Z6, 25 git of R407 and 20 git of MIBC and A65. A recovery of 83.52% was obtained for a concentrate grade of 28.36% Cu. In the rougher cells, the feed consisted of particles 94% finer than 74 microns whereas in the cleaning stage, particles were 95% finer than 44 microns. Based on the obtained results, the Sarcheshmeh Khatoonabad converter slag is presently being fed to the Chargonbad flotation plant, where a concentrate of 32% copper at 86% recovery is being produced.

Jan 1, 2007

By Grano S. R, Ralston J

It is the perennial problem most metallurgists face when examining data collected from laboratory float tests and plant surveys - there are more numbers than we know what to do with! The objective of this paper is to analyse and interpret a set

Jan 1, 1994

By B. Yu, Y. O. Oyediran, M. Robart

"This paper presents the latest flotation development testwork conducted in 2015 on the ‘B Zone’ samples from the Strange Lake Alkalic Complex (SLAC). Since the discovery by Iron Ore Company of Canada (IOC), metallurgical development has been under taken by a number of mining companies targeting various value metals, including yttrium, zirconium, niobium, and rare earths.Most recent, Quest Rare Minerals Ltd. (Quest) completed a Pre-Feasibility Study (PFS) in 2013 where the flowsheet was relatively complex and led Quest to explore alternative options. In 2014, the PFS flowsheet was simplified and one of the features introduced was pre-concentration by rougher flotation. The combined rougher flotation concentrate and slimes successfully recovered >90% TREE in 60% mass thus reducing capital cost and technical risks of the downstream hydrometallurgical processes. The latest flotation development testwork focused on achieving a pre-concentrate in which >80% TREE are recovered in 20% mass. Two separate reagent schemes, based on an ester phosphate collector (Clariant 1682) and a benzoylhydroxamic acid collector (Florrea 7510), were developed. Parameters evaluated in the development testwork included desliming, secondary yttrium and zircon collectors, depressants, temperature, conditioning temperature, time, and density, pH, sodium silicate type, cleaning, and flowsheet configuration. Both developed reagent schemes achieved the targeted metallurgy.INTRODUCTIONThe Strange Lake Alkalic Complex (SLAC) was discovered after geological survey and mapping studies by Geological Survey of Canada and Newfoundland and Labrador Department of Natural Resources between 1967 and 1980. Subsequent exploratory drilling programs by Iron Ore Company (IOC) in the 1980s found that the REE and high field strength element (HFSE) mineralization were within the central region of the SLAC which was named A Zone by IOC and later renamed Main Zone by Quest Rare Minerals Ltd. (Quest). Additional exploratory drilling outside the Main Zone by IOC and later by Quest, led to the discovery of B Zone, which was recognized as the most significant deposit of rare earth elements, yttrium, and zirconium in the SLAC. The B Zone Indicated Resources are estimated at 278.13 Mt at 0.93% total rare earth oxide (TREO) and Inferred Mineral Resources are estimated at 214.35 Mt at 0.85% TREO (Oyediran et al., 2014)."

Jan 1, 2016

By M. Kerr

Background- History The most significant change in mining since the late 1970?s has been the emergence of very large scale mining operations , which have been developed to ensure profitability with relatively low grade ores. These large tonnage operations have resulted in the development of larger unit sized machines in all operations of beneficiation, solid-liquid separation and dewatering. Often only a few flotation lines are installed and tonnages up to 25 ktpd and beyond are not uncommon. The increased throughputs have led to the development of circular, reactor type tank designs. The reactor cell system is the most up to date flotation cell design to utilise the principles of circular cell design. The Svedala DV mechanism was specially developed to suit the RCS machine giving good solids handling characteristics and excellent metallurgical performance. Development of UG2 ore type flotation equipment The equipment was developed and optimised by Svedala process from 1995. A higher energy specification was requested by industry. This amounted to 3kW/m3 for installed volume. Existing designs were at 1.5kW/m3. Hence various modifications were required to achieve the required power input. The first 50m3 machines were installed and developed at Impala Platinum?s UG2 circuit over a one year period. Once reliability and performance was achieved, over 300 large volume flotation cells were installed at Anglo Platinum and Lonmin operations as well. Pilot Plant Development The Impala Platinum High Energy pilot plant was commissioned in 2002 and had an installed power exceeding 5kW/m3. It was operated for over a year at the tailings dam booster station and was fundamental to the large scale scavenging plant design. All experience in overcoming mechanical and operational problems was applied in scale up design principles. A very robust mechanism was designed to accommodate the additional power input from installed motors, as well as the high SG (>1.5) of the feed source. The pilot plant flowsheet is shown in the figure below.

Jan 1, 2007

By Stanley D. Michaelson, Norman Weisis

The purpose of beneficiation is to increase the economic value of an ore by elimination of waste rock or by separation of minerals that require separate reduction, without destroying the physical and chemical identity of the minerals. Flotation has replaced older methods of beneficiation to a very great ex- tent, nearly entirely in the case of the copper, lead, and zinc minerals and less completely in the case of such other minerals as iron, coal, and titanium. Flotation is also used to recover barite, fluorspar, feldspar, cement rock, spodumene, vermiculite, silica, beryl, and potash in the nonmetallic field, and cobalt, vanadium, germanium, antimony, mercury, molybdenum, manganese, nickel, gold and silver, cadmium, and bismuth for metals. The rapid growth of flotation to pre-eminence cannot be attributed to its low cost, because gravity, magnetic, and electrical methods may in some cases cost only half as much. But for ores containing finely disseminated minerals, these other methods are successful only in exceptional cases, for example the magnetic taconites or titanium-bearing sands. For low grade ores with coarse texture or spotty mineralization the advantages of low-cost gravity methods and highly efficient flotation are often combined, as in the beneficiation of coal and some ores of lead and zinc, phosphate, tungsten, and manganese. When an ore is responsive to either flotation or non-flotation concentration, or to combinations of the two, the choice depends upon cost of the process only when dealing with ores of low value; in other cases it is dictated by either the process efficiency or the product specification. Generally speaking, flotatio.1 is so efficient as compared with other methods of concentration that process cost is rarely an important factor in its selection. It is said, "The metal in the mill tailing has already been mined." Once the mining cost has been paid it doesn't increase total costs very much to do a thorough job of milling. With the exception of the few types of ores that are not amenable to flotation, the chief reason for preferring electrical and gravity methods to flotation may lie in the specification of the product. Flotation demands fine grinding, and specifications may not permit this with many nonmetallic ores or coal. Another reason is the size of investment-where capital is hard to obtain or the life of the property is short, the justification for a flotation plant may not exist, and one must be content to skim off the cream. y not exist, and one must be content to skim off the cream. Gravity processes often cost less than flotation because a large part of the waste rockcan be rejected without costly grinding, no chemicals are required,

Jan 1, 1962

By B Murphy

Traditionally comminution optimisation has been focused on energy minimisation, whereas flotation optimisation has been focused on recovery improvement. One of the largest, if not the largest, operating cost over the life of a flotation circuit is electrical energy. With increasing pressure on operators to lower production costs and the cost of energy increasing, reducing the energy consumption of the flotation circuit can be beneficial to site economics. This paper reviews the use of energy by mechanically agitated flotation machines and discusses the measurement and benchmarking of energy consumption in modern flotation concentrators. Opportunities for improving flotation energy efficiency are also identified.CITATION:Murphy, B, 2013. Flotation energy consumption and opportunities for improvement, in Proceedings MetPlant 2013 , pp 399-412 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

By Claude Bazin

"Laboratory semi-batch flotation tests were conducted using two different sulphide ore samples. The size reduction was adjusted to cover a wide range of flotation feed size distributions. Results show that similar recoveries can be achieved independently of the fineness of grind. This result suggests that possible energy savings could be achieved by a redistribution of the power between the grinding and regrinding mills. The behaviour of the selectivity curves shows that some gangue minerals are more sensitive to particle size than other ones, implying the existence of preferential associations between minerals in the ore.INTRODUCTIONInteractions between grinding and flotation have been studied for many years, and still a robust model to link the two processes lacks to be developed (Girard et al., 2005; Bazin et al., 2001). The ore size reduction liberates mineral grains, while flotation separates them into valuable minerals and gangue. The more size reduction that is applied to the ore the more important is the mineral liberation but also the production of fine particles that can pose problems during flotation (Trahar and Warren, 1976). The definition of the grinding requirement for flotation is a complex problem (Rickelton and Dell, 1977; Sosa Blanca et al., 2000; Morrison, 1993; Wei and Gay, 1999).This paper analyzes the effect of the fineness of grind using semi-batch flotation test results. The first two sections describe the test procedure and the results. The third section analyzes the results in terms of liberation and selectivity, and proposes a possible redistribution of power between grinding and regrinding mills."

Jan 1, 2006

By Q. Cui, B. Z. Zhou, Z. G. Song, Y. G. Zhu, G. B. Zheng

The complex refractory Cu-Pb-Zn polymetallic ore in Xinjiang, China is a massive sulphide ore with complex mineral components. In the past two years, the ore mineralogy has changed, resulting in a decline in metallurgy, with too much zinc reporting to the lead and copper concentrates. A detailed mineralogical study indicating the presence of secondary copper minerals, which could be activating the sphalerite early in the present circuit, was used to develop a novel reagent and flotation flowsheet termed “Pb-Cu co-flotation, Cu intensified flotation, Zn flotation”. It was tested and found to significantly contribute to improving the flotation performance of the ore. In the Pb-Cu co-flotation circuit, successful depression of pyrite and sphalerite was achieved using a BK612- Na2S based depressant system. Most of the galena and some of the Cu bearing minerals with excellent floatability were collected with the use of the selective collector BK906. The rest of Cu bearing minerals were floated in a copper Z200 circuit using a BK537-lime-zinc sulphate based depressant scheme. Zinc flotation from the copper tailing was performed in a SIBX circuit using lime as a pyrite depressant. Using the proposed flowsheet, overall Pb, Cu, and Zn recovery increased significantly to 88%, 87%, and 90% respectively. Keywords: Complex polymetallic ore, Cu-Pb-Zn, Pb-Cu co-flotation, particle size

Jan 1, 2020

By Priyanka Dhar, Kurt Aasly, Hanumantha Rao Kota, Hassan Bouzahzah, Maria Thornhill

The interest in investigating the processing characteristics of mineral deposits in Norway has seen an upsurge in the last decade. One of the major areas of interest is a huge copper deposit, operated by NUSSIR ASA located in the Repparfjord Tectonic Window in the caledonides of west Finnmark. This study reports analysis of ore from the deposit for development and modifications in the flotation flowsheet for the NUSSIR ASA copper ore. The mineralogical characterization for the ore sample was achived by optical microscopy and Zeiss automated mineralogy while grinding characteristics were tested using Bond Index tests. The results confirmed the presence of Cu minerals in the form of chalcocite, chalcopyrite and bornite in the samples, which are mainly liberated in the – 105 µm size range. The majority of non-liberated copper sulphides associated with silica and the carbonates varies from 3 to 28 percent in the –250 µm samples . It is also observed that the copper minerals are uniformly distributed in all size ranges. Selective flotation of NUSSIR copper ore was performed in different size fractions with a motive to identify the correct liberation size and thus to obtain a copper concentrate meeting the quality requirements. The flotation experiments are essentially performed in two stages: the rougher and the cleaner stage. Mass balance calculations were performed showing that approximately 88 percent of copper can be obtained at the end of the process. Ultimately, overall circuit copper recoveries ranged between 83.5 to 88.1 % with a concentrate grade of 35 to 48 % Cu.

Jan 1, 2018

By L. A. Cisternas, A. Lopez-Valdivieso, Y. L. Botero, L. Cortes

In the processing of sulfidic ores, pyrite is usually depressed and ends up in the tailings. However, pyrite is the most common species responsible for acid mine drainage (AMD) due to its spontaneous oxidation. This AMD affects the tailing chemical stability by dissolving some toxic or heavy metals species such as As, Cd, Co, Pb, and Zn, which can migrate into the surrounding ecosystems. Therefore, the strategies to reduce pyrite’s environmental impacts are a crucial point to produce more chemically stable tailings. Consequently, numerous studies have been made to find procedures that could inhibit or restrain AMD. This work aims to develop a procedure for designing conceptual flotation circuits that can produce tailings with low content of pyrite and to assess this type of circuit with traditional flotation circuits. The method consists of applying optimal flotation design where three products are considered: metal concentrate, pyrite concentrate, and tailing with low content of pyrite. Two approaches are considered; in the first, a flotation circuit is designed to generate a concentrate rich in all sulfide minerals and to obtain a tail with low pyrite content. Then, a second flotation circuit is designed for the selective separation of the bulk into metal concentrate and pyrite concentrate. This is called fractional separation design. In the second approach, a flotation circuit design is realised that generate the three products simultaneously. This is called integrated separation design. Both fractional separation design and integrated separation design are assessed in this paper. This methodology is focused on cleaner production (waste prevention and resource minimisation) rather than end-of-pipe technology (treat existing waste). The methodology was applied to a copper sulfide ore from a local company in the Antofagasta region (Chile). This ore contains chalcocite, covellite, iron oxides, and pyrite. Keywords: Flotation, tailing, pyrite, cleaner production

Jan 1, 2020

By Wen Tao Liu, Tong Tian, Fu Sheng Niu, Xiu Man Liang

The level of automation employed in flotation production is relatively low. In an actual concentrator, operators use their judgment to adjust the production state based on the visual characteristics of the flotation froth surface. There are shortcomings, such as strong subjectivity and lagging process operation, that easily cause the waste of manpower and material resources. Machine vision technology is introduced to replace human visualization, achieving a quantitative description of the visual characteristics of the froth surface. The state variable parameters are provided for the identification of the flotation conditions.

By Wen Tao Liu, Tong Tian, Fu Sheng Niu, Xiu Man Liang

In order to address the difficulty of accurate segmentation of froth images of different sizes, a method of froth image segmentation based on highlight correction and parameter adaptation is proposed. First, a machine vision system on a single-cell flotation machine is built to collect froth images. Homomorphic filtering is used to improve the uneven brightness and shadow of the images. Fuzzy c-means (FCM) clustering is then utilized to classify similar highlights that belong to the same froth. After Otsu threshold segmentation, a parameter-adaptive morphological operation is used to extract the marker points and edge bands and correct the froth edges in the original image. Finally, the modified image is filtered by morphological reconstruction, and the highlight mark is used as the local minimum point for watershed segmentation. Three sizes of froth images are segmented in comparative experiments. The results show that the proposed method is suitable for the segmentation of froth images of different sizes. The position of the extracted segmentation line is close to reality, with average over-segmentation and under-segmentation rates for froth images of 2.6% and 6.8%, respectively. The froth image segmentation performance is stronger than that of the other methods examined.

By Wen Tao Liu, Tong Tian, Fu Sheng Niu, Xiu Man Liang

In order to address the difficulty of accurate segmentation of froth images of different sizes, a method of froth image segmentation based on highlight correction and parameter adaptation is proposed. First, a machine vision system on a single-cell flotation machine is built to collect froth images. Homomorphic filtering is used to improve the uneven brightness and shadow of the images. Fuzzy c-means (FCM) clustering is then utilized to classify similar highlights that belong to the same froth. After Otsu threshold segmentation, a parameter-adaptive morphological operation is used to extract the marker points and edge bands and correct the froth edges in the original image. Finally, the modified image is filtered by morphological reconstruction, and the highlight mark is used as the local minimum point for watershed segmentation. Three sizes of froth images are segmented in comparative experiments. The results show that the proposed method is suitable for the segmentation of froth images of different sizes. The position of the extracted segmentation line is close to reality, with average over-segmentation and under-segmentation rates for froth images of 2.6% and 6.8%, respectively. The froth image segmentation performance is stronger than that of the other methods examined.

By J. A. Folinsbee, Andre Robitaille, Tony Y. Chong

"Conventional crushing and grinding is followed by gravity concentration to recover free milling gold. Refractory gold, finely disseminated within the pyrite and arsenopyrite matrix, is recovered by flotation followed by pressure oxidation, cyanidation, and cementation. Non-refractory gold is recovered by cyanidation/CIP processing.A comprehensive test program aimed at improving flotation recovery was initiated in June 1995. Plant testing indicated that flotation tails value could be significantly reduced using mechanical flotation cells. Based on these test results, a flotation circuit that incorporates one of the three existing flotation columns followed by mechanical scavenging and cleaning was developed. Detailed engineering was completed in September 1996. Construction started in February 1997 and was completed in 3 months at a cost of $3.2 million. An on-stream X-ray analyzer was installed to provide real-time arsenic and iron analyses and inferred sulphur value on some of the flotation streams.The new flotation circuit proved to be an instant success. Flotation tails values were reduced by 27%. Final tails solids and solution was reduced from 0.035 to 0 023, and 0.0014 to 0.0006 oz/ton Au, respectively. Based on a mill throughput of 1,620 stpd this decrease in tails value will result in an increased gold production of 7,500 ounces per year. The payback for the project is estimated to be around one year.This paper describes the evolution of the project from bench scale testing to commissioning. Also, the operational and economic impacts on down stream processing are highlighted"

Jan 1, 1998

By Ross Byron, Ken Roberts

"During the fall of 2001 a program was initiated to determine the feasibility of improving the metallurgy in the flotation circuit at the Penhorwood Talc Concentrator located near Timmins, Ontario. Bench scale testwork led Plant staff to believe that opportunities existed to improve the flotation performance. Pilot scale testing was then conducted using two vendors and their respective cylindrical type flotation cells to indicate where these opportunities existed.The results of the test program determined that the replacement of the existing flotation circuit (roughers, scavengers and cleaners) with new flotation cells could be economically viable. Justification was due to a reduction in installed horsepower, maintenance costs and a subsequent increase in recovery and throughput while maintaining product quality. Unforeseen benefits included reagent and air reduction, accurate level control as well as improved working conditions due to the removal of the antiquated equipment and ancillaries.This paper will detail the justification, installation and implementation of the new flotation circuit. A special emphasis will explain the hurdles encountered while trying to install and commission the circuit in an operating Concentrator with minimal interruptions to production.INTRODUCTIONThe Penhorwood mine and Concentrator is 28 yrs old and has gone through many ups and downs with different owners, Johns Manville, Steetley Talc and now Luzenac. It has also been expanded twice, with flotation and grinding capacity being added in recent years.All of the concentration is completed at the mine site while the fine grinding takes place in the Timmins micronizing plant.Luzenac’s Philosophy is to be the world leader in Talc production, technology and sales, having about 70% of the current world High Grade talc market."

Jan 1, 2004

By Sergio Castro, Janusz Laskowski

In the flotation in highly concentrated electrolyte solutions not only ionic strength but also chemical composition, flotation pH and mineral properties play an important role. As a result an improvement or depression may be observed. A strong improvement in the floatability of hydrophobic bituminous coals and other inherently hydrophobic minerals is characteristic for the "salt flotation process", which is carried out in concentrated electrolyte solutions at natural pH and without addition of any flotation reagents. However, pH is a key factor when saline and hipersaline waters with hydrolyzing metallic ions are used as process water. In the case of flotation of Cu-Mo sulfide ores in seawater, molybdenite is strongly depressed by the Mg2+ hydrolysis products when pH is raised to depress pyrite. Process water with a high content of Mg2+ and Ca2+ ions, and this also includes seawater, have deleterious effect on the anionic flotation of industrial minerals with fatty acids. The flotation of potash ores is carried out in NaCl-KCl saturated brine (6-7 mole/L of NaCl and KCl) with the use of long-chain amines. Such a high electrolyte concentration changes dramatically the amine Krafft point making the collector insoluble in brine; its mode of action entirely differs from that in conventional flotation processes.

Jan 1, 2014

By Sergio Castro, Janusz Laskowski

In the flotation in highly concentrated electrolyte solutions not only ionic strength but also chemical composition, flotation pH and mineral properties play an important role. As a result an improvement or depression may be observed. A strong improvement in the floatability of hydrophobic bituminous coals and other inherently hydrophobic minerals is characteristic for the "salt flotation process", which is carried out in concentrated electrolyte solutions at natural pH and without addition of any flotation reagents. However, pH is a key factor when saline and hipersaline waters with hydrolyzing metallic ions are used as process water. In the case of flotation of Cu-Mo sulfide ores in seawater, molybdenite is strongly depressed by the Mg2+ hydrolysis products when pH is raised to depress pyrite. Process water with a high content of Mg2+ and Ca2+ ions, and this also includes seawater, have deleterious effect on the anionic flotation of industrial minerals with fatty acids. The flotation of potash ores is carried out in NaCl-KCl saturated brine (6-7 mole/L of NaCl and KCl) with the use of long-chain amines. Such a high electrolyte concentration changes dramatically the amine Krafft point making the collector insoluble in brine; its mode of action entirely differs from that in conventional flotation processes.

Jan 1, 2014

By S. Castro, L. Gutierrez

"Mining operations are often located in remote arid environments with limited access to fresh water. Shortage of fresh water in such cases makes it necessary to use seawater in mineral processing plants. Such plants treating Cu- Mo sulfide ores in seawater have been fully operational in Chile (e.g. Las Luces, Centinela). In many cases process waters used in commercial flotation plants (e.g. Mt Keith in Western Australia) are even more concentrated electrolyte solutions than seawater. This paper is an attempt at classification of the flotation operations carried out in process waters that are concentrated electrolyte solutions.INTRODUCTIONAccording to Gleick (1966), of the total Earth’ water resources 97.5% is in the oceans and ice caps, and thus only about 2.5% is fresh water. Shortage of fresh water in many parts of the world makes it necessary to use seawater in mineral processing operations. The existing commercial operations using seawater as well as recent research projects that deal not only with sulfide ores but also with apatite ores provide a lot of information that can now be generalized. The progress that has been made in this area is reviewed and based on this information an attempt is being made at classifying the flotation operations carried out in highly concentrated electrolyte process waters.SALT FLOTATIONFlotation in highly concentrated electrolyte solutions was studied by Klassen (Klassen, 1963). He reported that hydrophobic, bituminous coals, could float in salt solutions without addition of any other flotation agents. The process is referred to as salt flotation. Other inherently hyhrophobic minerals (e.g. talc, graphite, sulfur, etc.) were shown to behave similarly (Klassen and Mokrousov, 1963)As Figure 1 shows, some coals float quite well in solutions of Na2SO4, NaCl and NaNO3 (Klassen, 1963). While there are differences between the tested salts (explained by different foamabilities of these solutions) all the tests indicate that only bituminous coals float well in concentrated electrolyte solutions. 0.3 M solutions are quite sufficient to initiate a good and very fast flotation. If wettability of various coals is compared it becomes obvious that these well floating coals are very hydrophobic bituminous coals (Figure 2)."

Jan 1, 2018