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By W. C. Lilliendahl, G. Meister

Uranium metal with a purity of about 99.9 pct was produced on a large scale by fused salt electrolysis with a material efficiency of about 90 pct. The material efficiency depends mainly on bath composition, electrolysis temperature, electrode smothering, and elutriation during washing of the powder. RESEARCH and development work on fused salt electrolysis carried on by the Westinghouse Lamp Div. Bloomfield, N. J., was done under the Manhattan District Corps of Engineers and later under the Atomic Energy Commission for the commercialization of uranium production for the first atomic pile at the University of Chicago in 1942. From the conception of the atomic bomb project it was recognized that metals with impurity levels having little metallurgical significance would be required. Permissible impurity levels were based on neutron absorption. Of particular significance was boron, which could not be present in amounts exceeding 1 ppm. The electrolytic method as developed in 1930 by Driggs and Lilliendahl,1,2 and later improved, yielded uranium of very low boron and other deleterious impurity content. No other method was capable at that time of producing uranium metal of the required purity.' The low boron content of uranium produced by the electrolytic process resulted from the availability of the reactants which were low in boron content, and from the inherent elimination of boron in the fused salt bath. Since the heart of any electrolytic process is the electrolysis cell, this paper will deal with the development of the original bath composition for the efficient production of uranium from a batch process to one of continuous operation. Emphasis also will be placed on other factors which will affect the material efficiency of the process. With the laboratory cell the material efficiency of uranium powder recovery in the early electrolysis was relatively low, about 35 pct based on the ratio of uranium recovered to uranium added. This early process also had other defects. The electro- lytic bath could not be used continuously. After three runs from a freshly charged crucible, the deposit showed a tendency to slip off the electrode as it was raised from the bath. This condition necessitated pouring the charge every fourth run and preparing a new bath. It was assumed at that time that this condition was caused by the increasing fluoride concentration with each addition of uranium salt, which adected the mobility of the uranium ions. Experimental The electrolysis cells differed in size only. They were of the floating cathode type. The laboratory cells were 21/2 in. ID and 6 in. deep and operated at 30 amp and 5 volts. Production was about 150 g metal powder per 8 hr. The plant cells (5 units) were 9 in. ID x 21 in. deep and operated at 1800 amp at 12 volts. The total production unit was designed to produce 250 lb of uranium powder per 8 hr day. Because of the tendency of uranium fines toward spontaneous combustion, material efficiencies were based only on the recovery of useful coarser metal which could be safely handled. The reported efficiencies are of particular significance only as related to the same group of experimental procedures. At the start of the project no changes were contemplated until previous data could be definitely confirmed. Therefore, the first experiments were with the 50 pct CaCl2-50 pct NaCl mixture. The material efficiency of uranium deposition as a function of the number of electrolyses is shown in Table I. In Table I, the decrease in efficiency at 800°C with number of runs is apparent and confirmed the earlier data. Operating at 900°C enabled the number of runs to be doubled, but before pouring the charge the efficiency of recovery became poor. This test indicated that the improved efficiency might have been caused by an increase in the fluidity of the bath.

Jan 1, 1958

By Ramin Motamed, Joseph A. W. Toth

Evaluation of the capacity of large-diameter drilled shafts using current load test methods present challenges when considering the magnitude of loads required to fully mobilize their capacities. Often, these full scale tests do not fully mobilize the capacity through side resistance. Therefore, the need for innovative solutions to extrapolate side resistance and interpret nominal capacity are of key interest. In this study, we evaluate three methodologies for extrapolating unit side resistance based on bi-directional load test data. Fellenius (2001) presented these methods for interpretation of pile capacity using static load tests. Our interpretations are based on the evaluation of 116 load tests. Unit side resistance was calculated and reviewed for each load test and categorized using three criteria of mobilization; (A) full, (B) partial and (C) linear. This study specifically focuses on load tests that showed fully mobilized unit side resistance behavior (Criteria A). The three methodologies were applied assuming Criteria (A) load tests were mobilized to 50% of their measured values. Subsequent comparisons of each extrapolation were then compared against the full measured values for each test and generally showed good agreement. INTRODUCTION It is widely accepted that conducting load tests such as standard top-down tests or bi-directional (i.e. O- cell) tests can help designers understand load-settlement behavior and the nominal resistance of drilled shaft foundations. These load testing methods provide the advantage of confirming design assumptions as well as improving the reliability of the foundation design. The potential cost savings from the application of these methods for mid to large size projects is self-evident. For example, in a recent project in Northern Nevada, an O-cell test on a 6.9 ft diameter, 114.8 ft length drilled shaft imposed an initial cost of $125k to the project, resulting in a 15% reduction on the total foundation cost; equivalent to $1.3 million in overall savings (Pease, 2014). However, the costs of implementing such methods on smaller projects can be prohibitively expensive (Hagerty et al, 2016). Despite the clear advantages of drilled shaft load testing, the current practice is not without limitations. Performing load tests on large-diameter drilled shafts with high capacities is a challenge considering the significant loads required to fully mobilize the capacity of such foundations. In some cases, the feasibility of these tests is impractical because the associated initial cost is not guaranteed to outweigh the final savings. As a result, large scale load tests are sometimes ruled out from the design phase of projects. Furthermore, in the majority of load tests the magnitude of loads applied are specifically selected to not approach failure, so the shafts can be used in the future foundation system (i.e. production shafts). This practice of field testing restricts our knowledge of the true capacity of the drilled shaft at failure; hence the nominal resistance remains unknown.

Jan 1, 2018

By J. Drimmer

The past several decades have seen the rapid expansion of multinational mining companies? exploration and production activities around the globe. This trend has resulted from a number of factors, including increased demand for resources as a result of worldwide economic growth, the diminishment of known and proven reserves, rising commodity prices, technology improvements, and the liberalization of investment regimes in developing countries with significant natural resources. With those opportunities, however, come associated risks and significantly increased legal compliance obligations that may be imposed by various bodies. That includes domestic regulations, as well as foreign civil and criminal laws with extraterritorial reach. A failure to adhere to those laws can have dire consequences, including substantial monetary fines and penalties, severe damage to a company?s reputation, and even jail time for individual company employees.

Jan 1, 2010

By Gabrielle Luana Jimenez

Aparelhos eletroeletrônicos como computadores e televisões são constituídos por telas de cristal líquido, que ao se tornarem obsoletos são classificados como resíduos, e dispostos em aterros sanitários. Entretanto, na composição das telas de cristal líquido há metais de valor agregado, como o índio (In). Com a fundamentação no processo de reciclagem de telas de LCD, este estudo propõe a recuperação e quantificação desse metal que é encontrado na forma de ITO (óxido de índio e estanho). Para tal feito, foram empregadas rotas hidrometalúrgicas, tendo como principal etapa a lixiviação. Como parâmetros de controle, os ensaios de extração sólido-líquido foram realizados em temperaturas que variam de 50 a 80°C. Com isso, foi obtido resultado de extração do índio em cerca de 60% em massa, nas condições de 60°C e após 4 horas de lixiviação.

Aug 17, 2017

By Alexandre Silva Guimarães

A extração por solventes sinérgica dos metais cálcio, magnésio e níquel, presentes em soluções aquosas sulfúricas em níveis de concentração similares aos dos licores industriais HPAL (High Pressure Acid Leaching), foi avaliada neste trabalho empregando-se os extratantes comerciais Cyanex 272 e Cyanex 301. O uso de Cyanex 301 (10%v/v) sozinho não se mostrou eficiente, em decorrência do baixo percentual de extração e da baixa seletividade entre os metais. Quando misturado ao Cyanex 272, porém, observou-se a possibilidade de remoção seletiva de magnésio, deixando cálcio e níquel em solução. A melhor condição operacional foi obtida utilizando-se 5-10%v/v de Cyanex 301 e 20% de Cyanex 272, na faixa de pH entre 5,4-5,7, na qual se extraiu aproximadamente 70-80% de magnésio, 15-35% de cálcio e 10-15% de níquel.

Aug 16, 2017

By Alexandre Silva Guimarães

Investigou-se a extração seletiva de Ca e Mg do licor sulfúrico concentrado de Ni visando sua purificação. Observou-se que a mistura sinérgica dos extratantes D2EHPA + ácido naftênico apresenta maior afinidade na extração de Ca em pH = 5. Comportamento oposto foi verificado pelo extratante Cyanex 272, cuja preferência de extração é pelo Mg para 5 = pH = 6. A cinética de extração de Ca e Mg é rápida atingindo o equilíbrio em menos de 6 minutos. A purificação do licor de Ni requer a utilização de 2 circuitos de extração em operações estagiadas. No primeiro circuito, Ca pode ser removido do licor empregando-se o sistema orgânico D2EHPA (10% v/v) + ácido naftênico (20% v/v). O pH ótimo é 3,5, no qual foram extraídos 72% de Ca (ßCa/Ni = 40) em uma contatação. No segundo circuito, o licor deve ser submetido a uma extração de Mg pelo Cyanex 272 (20% v/v). O pH operacional propício é 5,5 com extração de 66% de Mg (ßMg/Ni = 16, uma contatação). O licor purificado de Ni pode ser encaminhado à etapa de eletrorrecuperação almejando-se a obtenção de Ni metálico.

Oct 30, 2017

By Carlos de F. Gontijo

The flotation of quartz particles was studied over the particle size range from 0.5 µm to 1000 µm and for advancing water contact angles between 0º and 83º. Flotation was performed in a column and in a Rushton turbine cell. Particle contact angle threshold values, below which the particles could not be floated, were identified for the particle size range 0.5~1000 µm, under different hydrodynamic conditions. The flotation response of the particles, either in a column or in a mechanically agitated cell with a similar bubble size, was comparable. Turbulence plays a role, as does bubble-particle aggregate velocity and bubble size. The stability of the bubble-particle aggregate controls the maximum floatable particle size of coarse particles. For fine particles, the flotation limit is dictated by the energy required to rupture the intervening liquid film between the particle and bubble. Flotation of very fine and large particles is facilitated with small bubbles and high contact angles. These results greatly extend our earlier observations and theoretical predictions.

Jan 1, 2014

Coal has been mined in the central Appalachian coalfields of southern West Virginia, western Virginia, and eastern Kentucky for more than a century. The dwindling reserve base consists in large part of coal that would have been considered unmineable by earlier generations. Nearly every current operation is working on a property where coal has been extracted in the past, from seams either above, below, or both. NIOSH is conducting research aimed at helping mine planners prevent hazardous conditions due to multiple seam interactions. To-date, more than 300 case histories have been collected from underground mines, mainly from central Appalachia. This paper focuses on several of the more challenging situations that have been encountered, including: • Room-and-pillar development 20 ft (6 m) beneath full extraction workings at a depth of 1,000 ft (300m) of cover (Virginia) • Pillar recovery 45 ft above full extraction workings at 900 ft (270 m) of cover (Virginia) • Near-simultaneous room-and-pillar mining with pillar recovery with 40 ft (12 m) of interburden and 1,500-2,000 ft (450-600 m) of cover (Kentucky) • Longwall mining directly beneath main entries in overlying seams (West Virginia) • Some of these operations have been highly successful in overcoming the challenges, others less so. The lessons learned from their experience will help ensure that these and similar difficult reserves can be mined safely.

Coal has been mined in the central Appalachian coalfields of southern West Virginia, western Virginia, and eastern Kentucky for more than a century. The dwindling reserve base consists in large part of coal that would have been considered unmineable by earlier generations. Nearly every current operation is working on a property where coal has been extracted in the past, from seams either above, below, or both. NIOSH is conducting research aimed at helping mine planners prevent hazardous conditions due to multiple seam interactions. To-date, more than 300 case histories have been collected from underground mines, mainly from central Appalachia. This paper focuses on several of the more challenging situations that have been encountered, including: • Room-and-pillar development 20 ft (6 m) beneath full extraction workings at a depth of 1,000 ft (300m) of cover (Virginia) • Pillar recovery 45 ft above full extraction workings at 900 ft (270 m) of cover (Virginia) • Near-simultaneous room-and-pillar mining with pillar recovery with 40 ft (12 m) of interburden and 1,500-2,000 ft (450-600 m) of cover (Kentucky) • Longwall mining directly beneath main entries in overlying seams (West Virginia) • Some of these operations have been highly successful in overcoming the challenges, others less so. The lessons learned from their experience will help ensure that these and similar difficult reserves can be mined safely.

Jan 1, 2006

By Siegmund Babendererde, Jan O. Babendererde

Extruded Concrete Lining combines technological and financial advantages. The tunnel lining is reliably embedded in the surrounding ground as the fluid concrete is extruded at constant pressure directly behind the TBM supporting the exposed surface. Ground deformation from the TBM passage can be compensated and the ground will be pre-stressed by the extrusion process. Developments in concrete technology permit high speed tunneling by use of a slip formwork attached to the TBM. Realised projects in Milano (Italy), Lyon (France), Frankfurt (Germany) and Akima (Japan) will be demonstrated.

Jan 1, 2001

By G. E. Wasson

Consolidation Coal Co. tested the agglomeration of fine coal using a laboratory pellet mill. The principal operating variables examined were feed coal moisture, coal size distribution, and additives to the feed coal. The moisture of the feed coal was found to be critical to both the pellet mill operability and the product strength. Coals, with feed moistures too high to pelletize, could be pelletized if mixed with lime or a water absorbent material. The addition of dry starch binder improved the product strength.

Jan 1, 1991

By D. Letzig

Wrought magnesium alloys are of special interest as lightweight structural components as a result of their more homogeneous microstructures and improved mechanical properties compared to cast components. Extrusion as a shaping technology offers the possibility to produce a wide variety of magnesium alloy profiles. In this contribution we describe the role of extrusion parameters such as extrusion speed, ratio and temperature as well as the type of extrusion process on the microstructural development of AZ-series magnesium alloys and the resulting mechanical properties. The effect of microstructure on the tensile/compression deformation behavior of the alloys has also been investigated. Aspects of process optimization designed to overcome technical and economic limitations and thus establish magnesium alloy profiles for industrial applications will also be discussed.

Jan 1, 2006

By Gerhard Derge

EXTRUSION processes are used in the commercial production of a wide variety of products, as indicated by the review presented a few years ago by D. K. Crampton.1 Most writers have confined themselves to a general description of the equipment and products and the engineer-ing aspects of the process. The few studies that have dealt with the metallurgical side of extrusion have been concerned primarily with an examination of the mode of flow of the metal during extrusion. This has been accomplished by the use of composite billets, by scribing grids on symmetrical sections of billets and observing the change of dimensions in the gridwork, or by examining microstructures in extruded sections.2-8 Another limitation of these original studies is that they were confined to the extrusion of very simple shapes, usually rods having a diameter of about one-fourth that of the billet. Tin is particularly well suited to the extrusion of collapsible tubes and similar shapes in which the extruded section is very small in comparison to the diameter of the billet or slug. In modern production, impact extrusion methods are generally employed, therefore the thickness of the slug is small compared to its diameter. Under these conditions the process differs considerably from the processes that have been most fully described in the literature, and it is known that the quality of the product is very sensitive to slight variations in any one of the many variable factors involved, such as composition and structure of the alloy, rate of extrusion, temperature, shape of punch and die. An exhaustive examination of all of the above-mentioned problems promises to produce so many data that it seems advisable to initiate the reports at this time, even though all of the factors outlined have not been examined fully, and to confine this paper to a description of the apparatus and method. Only tin and its alloys with small amounts of copper have been considered. These are the alloys most commonly used in this country for the production of the type of articles already described.

Jan 1, 1939

By D. S. Salonine

Aluminum alloys are widely used in modern industry. Tubes and hollow shapes give great opportunities for structural purposes as well as fluid transport due to their stiffness and lightness, Extrusions on a mandrel or through a bridge die, that requires splitting of the billet with re-welding, produce hollow shapes with varied contours, fins and multiple cavities. Moving and stationary mandrels, mandrel lubrication, tooling for ribbed-tube heat exchangers, and for drilling pipes are considered. Bridge dies can be classified by the bridge position relative to the die face, by mandrel support structure, and by assembly type, The main parameters influencing the quality of the die-welded seams are considered, The difficulties of extruding various alloys through bridge dies are discussed in terms of metallurgical factors, Some approaches to the calculation of the stresses in a bridge are presented.

Jan 1, 2005

By W. B. Price

AT the New York meeting of the American Institute of Mining-and Metallurgical Engineers held in February, 1926, W. H. Bassett and J. C. Bradley presented a paper entitled "Exudations on Copper Castings."§ The purpose of the present paper, as the title suggests, is to call attention to somewhat similar phenomena which the authors have encountered in brass and bronze. From a study of the examples given, a more-or-less speculative theory of "inverse segregation" is advanced. PROTUBERANCES ON ADMIRALTY BRASS In the rolling mill of the Scovill Manufacturing Co., there have been found quite commonly bars of certain alloys which had a sort of shaggy roughness on the surface due to slight metallic protuberances. No special attention was paid to these until some bars were found on which these protuberances were heavy enough at the bottom of the bars to produce a blistered appearance. A sample of the protuberances was milled off the surface of the bar illustrated (Fig.. 1a) and upon analysis was found to contain 66.66 percent. copper, 4.02 per cent. tin and .03 . per cent. lead, whereas the average composition of the bar was 70.21 per cent. copper, 1.21 per cent. tin, and .01 per cent. lead. A sample of the shaggy-rough protuberances at the -very top of a bar was also analyzed and was found to contain 2.45 per cent. tin, indicating that it was probably of the same origin as the blistered areas. These results were not entirely unexpected for previous analyses of this alloy had -revealed that the surface was richer in tin than the rest of the bar. This, of course, is contrary to what we would expect from a consideration of the equilibrium diagram and has been called "inverse segregation."

Jan 10, 1926

By W. B. Price

AT the New York meeting of the American Institute of Mining and Metallurgical Engineers held in February, 1926, W. H. Bassett and J. C. Bradley presented a paper entitled "Exudations on Copper Castings."' The purpose of the present paper, as the title suggests, is to call attention to somewhat similar phenomena which the authors have encountered in brass and bronze. From a study of the examples given, a more-or-less speculative theory of "inverse segregation" is advanced. Protuberances on Admiralty Brass In the rolling mill of the Scovill Manufacturing Co., there have been found quite commonly bars of certain alloys which had a sort of shaggy roughness on the surface due to slight metallic protuberances. No special attention was paid to these until some bars were found on which these protuberances were heavy enough at the bottom of the bars to produce a blistered appearance. A sample of the protuberances was milled off the surface of the bar illustrated (Fig. la) and upon analysis was found to contain 66.66 per cent. copper, 4.02 per cent. tin and 0.03 per cent. lead, whereas the average composition of the bar was 70.21 per cent. copper, 1.21 per cent. tin, and 0.01 per cent. lead. A sample of the shaggy-rough protuberances at the very top of a bar was also analyzed and was found to contain 2.45 per cent. tin, indicating that it was probably of the same origin as the blistered areas. These results were not entirely unexpected for previous analyses of this alloy had revealed that the surface was richer in tin than the rest of the bar. This, of course, is contrary to what we would expect from a consideration of the equilibrium diagram and has been called "inverse segregation." Fig. 16 is a cross-section of a bar through the protuberances on the surface. It reveals that there is a decidedly different structure through the raised areas and seems to indicate that the bar originally solidified

Jan 1, 1927

By W. H. Bassett

Beads of metal frequently appear at the ends of cast-copper wire bars and on the sides of wedge cakes near the top. These are richer in cuprous-oxide than the rest of the casting. A micrographical study of these exudations has been made. It is suggested that the material is forced through the surface while the copper is solidifying. If not eliminated in process of manufacture, it shows on the finished polished sheet copper in patches differing in color from the main body of the sheet. FIGURES 1 to 4 show the copper exudations, at different magnifications, as they appear on the ends of cast wire bars, and on the sides, usually near the top, of wedge cakes. Sometimes the exudations are in fine "drops;" at other times, large masses of the material are found. Microscopic examination of the copper exudation indicates that it is high in oxide and of eutectic proportions. Because of the difficulty of securing a suitable sample, the protuberances have not been analyzed chemically; but the spectroscope shows no indication that there are any more metallic impurities present than in the balance of the copper. The lowest copper plus silver content of the coppers studied for this? paper was 99.914 per cent.; the highest, 99.966 per cent.; so the oxygen content of the whole casting would be well under 0.07 per cent.

Jan 2, 1926

By F. P. Jung

This presentation will be a general overview of the Cerrejon Coal Project being developed jointly by Carbocol, an entity of the Colombian government, and Intercor, an Exxon affiliate. The word "Cerrajon", by the way, is simply Spanish for a small hill. There is a distinctive hill near the mine site, and it's the only landmark of any significance. It's shown in Figure 1. So the locals call this area "El Cerrejon", "the little hill." Let me start with some of the highlights of the project, summarized in Figure 2, and then go into more detail later. A four-year feasibility study covered the geology, quality, engineering, construction operation and marketing of coal from this region. This study led Exxon to declare the project as commercial in July of 1980. Then in September of 1980 the president of Colombia gave the government's okay to proceed.

Jan 1, 1982

By Stephen Hall

Introduction Marine Autonomous Systems are making rapid progress from their early years as research tools for university departments & government institutes into having a growing number of real-world applications for industry, academia, statutory inspection, data acquisition and defence. Deep sea mining offers a distinct set of challenges that are very well suited to autonomous underwater vehicles (AUVs) and to a lesser extent for autonomous surface vehicles. Deeper, smarter, more capable Global demand for rare earth metals and high-grade ore will inevitably lead to exploitation of deep ocean resources as terrestrial reserves become depleted or remain unavailable for political or environmental reasons. Winning production licenses from the international seabed authority and especially gaining public trust to undertake deep sea mining activities and licenses will depend upon high quality pre-exploitation scientific surveys of the sea floor ecosystem, and subsequent monitoring of the impact of mining activity and remediation work. The actual area covered by the seabed mining operation may be quite small in terms of square kilometres, but still larger than can be patrolled by tethered ‘eyeball’ class Remote Operated Vehicles, so multi-spectral inspection, assessment and monitoring will be more effective when carried out by untethered AUVs. By using seabed recharging stations and data upload points the AUV can stay in situ in the deep ocean, rather than be repeatedly brought back to the surface.

Jan 1, 2018

By S. Afrouz, C. Keles, W. R. Reed, E. Sarver, T. Akinseye, A. Greth, L. Pan, F. Animah

Among underground coal miners, roof bolter operators are generally considered to have some of the highest risks for hazardous respirable dust exposure. This is because bolting requires drilling into roof strata that can often be a source of silica and silicate dust, which are associated with occupational lung diseases. However, little is known about the variability of dust characteristics (e.g., mineralogy constituents, particle size) in the vicinity of the bolter—or when specific dust controls are applied. As part of a prior NIOSH study, respirable dust samples were collected during several different events in standardized locations around an active roof bolter, and personal samples were also collected from the operator during the cleanout of the bolter’s dust collection system when it was equipped with a novel wet dust box versus a traditional dry box. Those samples were made available for follow-up analysis by scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM–EDX), as well as direct-on-filter Fourier transform infrared spectroscopy (FTIR). Results showed variability in dust constituents and particle sizes at locations around the roof bolter, and indicated some event-to-event differences in dust sources. Additionally, compared to the dry dust box, the wet dust box appeared to reduce (by 41–82%) the relative silica and silicate content in the respirable dust to which the operator was exposed during cleanout. Furthermore, an inter-laboratory comparison demonstrated the reproducibility of a standardized direct-on-filter FTIR method for estimating quartz mass (i.e., the predominant form of crystalline silica) in respirable coal mine dust samples. However, for constituent analysis by SEM–EDX, differences observed between results from two independent labs indicate that standardization of the analytical protocol is necessary to enable comparability of results.

Jan 5, 2024