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By S. Helgen, C. Byrns, A. Davis

The 4000 acre historic Robinson Mining District outside Ely, Nevada hosts a continuum of oxidelsulfide waste rock dumps of different ages. In an effort to develop a paradigm to explain past, existing, and future conditions at the site profiles of oxygen, pH, temperature, and specific conductivity were collected from various waste rock dumps using a hand-driven soil gas probe and a down-hole sampling device. The resulting data are useful in interpreting the fate and manner of pyrite oxidation within the dumps and in identifying waste rock dumps that may require remedial measures compared to those that require only minimal action prior to closure.

Jan 1, 2000

By T. Malterer, R. Adams

Peat has unique physical, chemical and biological properties. These include high porosity and water retention, high absorption and adsorption properties, and high buffering capacity. In addition, peat is a rich medium for microorganism activity. Peat has traditionally been used for horticultural purposes. However, in recent years, peat is increasingly being used for waste- treatment purposes. This paper reviews North American literature on the use of peat for waste-treatment applications. The literature indicated that peat has potential for use in the treatment of municipal and on-site effluents, for the removal of low concentrations of heavy metals and for the adsorption of liquid and gaseous hydrocarbon pollutants.

Jan 1, 1997

By S. K. Kawatra, M. T. Rusesky, T. C. Eisele, D. X. Zhang

It has been observed in some mineral processing plants that grinding circuit efficiency varies seasonally, such as in some plants which are located in the northern US and Canada and undergo large seasonal temperature changes, with the grinding circuit efficiency different between summer and winter. This indicates that the temperature of grinding circuit slurry has a noticeable effect on grinding performance. The effect has rarely been studied. To this end, an investigation to examine the effect of changing temperature on efficiency and determination of the mechanism responsible has been carried out. Plant investigations and laboratory experiments have been conducted in order to study hydrocyclones. It was demonstrated that when the pressure drop is held constant, the d50(c) size decreased approximately linearly with increasing temperature, while the shape of the reduced efficiency curve remained nearly constant. This effect was determined to be due to changes in slurry viscosity with temperature.

Jan 1, 1990

By R. L. Lewis

A simple method for estimating the steady-state water quality of a pit lake is presented. The steady-state concentration of a conservative chemical constituent in a pit lake is shown to be a simple function of the inflow rate, the evaporation rate and the inflow concentration. An analytical method is presented for estimating the equilibrium ground water-inflow rate for use in water-quality predictions. The time required to reach chemical steady state is estimated using an iterative mass-balance model. Mine operators should find the methodology useful for planning and screening regulatory applications where conservative estimates of pit lake water quality are desirable.

Jan 1, 2000

By G. F. Revey

All underground operations have limiting factors that influence overall profitability. Hoisting, hauling, available headings, labor, milling capacity and other factors limit how much material can be removed from an underground mine. Consequently, when mines use limited labor to handle the additional rock from overbreak and to perform extra ground support tasks, productive activity is replaced by nonproductive work. Mining economics are further penalized when overbreak causes dilution of ore grades. This paper reviews the organizational systems that mines have been using to create environments that foster the creation of successful overbreak-control programs. Actual case histories document the various quality-improvement techniques, worker incentives and practical project-management systems used by these mines. A brief review of controlled-blasting technology sources and overbreak-measurement tools is also included.

Jan 1, 1999

By K. N. Han

A kinetic model for the batch leaching of various metals using different lixiviants was developed. The overall material balances for the reactants and products at the solid/ liquid interface were formulated for various types of heterogeneous reactions at the interface. The solutions to these mass balances are identified analytically, as well as numerically. Applications of these numerical solutions to various leaching systems using rotating discs or powders are discussed. The metal-dissolution systems addressed include cobalt, nickel and copper in acid, cyanide and ammoniacal solutions.

Jan 1, 1996

By C. R. Euston, B. T. Field, W. E. Lindquist

Pyroprocessing applications in the minerals industry range from low-temperature drying to high-temperature reactions. Material characteristics and process requirements range over a very broad spectrum and can confuse plant engineers trying to select a pyroprocessirtg system for their plant. This paper examines the important process variables and offers empirical guidelines to assist in a user's overall process evaluation.

Jan 1, 2000

By Kal V. S. Sastry

Mineral processing simulation has come a long way since its beginning about thirty years ago. With our increased understanding of mineral process systems and the advent of new software and hardware technologies, we can visualize an ideal mineral processing simulator. This paper attempts to identify a number of desirable features of an ideal mineral process simulator and to describe the exciting trends in making such an ideal simulator a reality.

Jan 1, 1992

By D. Ince

Flotation of dolomite from apatite was investigated, using dodecylamine hydrochloride or sodium oleate as the collector, with and without inorganic modifiers such as sodium chloride. Separation of dolomite from apatite was anticipated from the single mineral experiments under various pH and collector concentration conditions. Flotation selectivity in the mixtures, however, was found to be limited. Attempts to control the flotation response of these minerals by addition of salts such as NaCl and KCI indicated that selectivity is possible. The presence of sodium chloride was determined to depress apatite flotation using sodium oleate, leaving dolomite flotation unaffected (Moudgil and Ince, 1989). In this paper, conditions for optimum separation and the effect of major parameters on the desired selectivity are discussed.

Jan 1, 1992

By M. Polat, S. Chander

Many models have been suggested in the past to obtain a satisfactory fit to flotation data. Of these, first-order kinetics models with a distribution of flotation rate constants are most common. A serious limitation of these models is that type of the distribution must be pre-supposed. Methods to overcome this limitation are discussed and a procedure is suggested for estimating the 'actual' distribution of flotation rate constants. It is demonstrated that the classical first-order model fits the data well when applied to coal flotation in narrow size-specific gravity intervals. When applied to material which is fractionated on the basis of size alone, the use of three parameter models, which were modified from their two parameter analogs such as rectangular, sinusoidal, and triangular, gave most reliable results.

Jan 1, 1995

By Vanessa M. Torres, Lafayette C. L. Freitas, Evandeo C. Silva

This paper shows two applications of artificial intelligence models in process development. In the first application, a heuristic fuzzy correlation can predict flotation behavior in bench scale based on feed characteristics for a high variability copper ore, as well as to predict plant performance for a feasibility project evaluation, minimizing its risk. The second case study shows the use of neural networks to model the iron ore sintering, correlating ore characteristics and operational parameters with sinter properties. With this application, CVRD aims to establish a new step on iron ore product evaluation and customer support.

Jan 1, 1998

By R. K. Rajamani, R. Verma

In ball milling the rates of breakage vary primarily with the size distribution of powder in the mill. Using an approximate solution to the batch-grinding equation, the acceleration and deceleration of breakage rates of all individual size classes are determined when the grinding environment is varied. Experimental results with limestone and copper ore show time-dependent breakage rates under both dry and wet grinding conditions. The effect of grinding additives on breakage rates is also studied. In general, breakage rates increase for coarse sizes and decrease for fine sizes with an increase in the fines present in the mill. Such variations have strong implications in closed-circuit grinding.

Jan 1, 1992

By V. I. Ryaboy, V. A. Luknitsky, V. V. Zuyev

The action has been studied of three types of reagents used as intensifiers in grinding copper-molybdenum, sulphide-sheelite, polymetallic and other types of ores, namely N-donor, dispersant, and surface-acting agents. It has been proved that, depending on the type of ore treated, the C (N-donor) and C-170 (dispersant) reagents increase the yield of the principal size fraction of 0.074mm by 8-16% (relative). Consequently, the specific mill capacity improves by 13-21 %. The C and C-170 reagents activate the subsequent flotation stage and are thus beneficial to the mineral recovery. The surface-acting reagents affect the mineral grinding process to a lesser extent. The intensifying action of the reagents is attributed to the effective crushing energy decrease (lower crack-resistance factor) or else to the slime-dispersing effect of the reagents. The pilot-plant test results for the C reagents are given. Both C and C170 reagents are commercially produced and recommended for use at a number of concentrators in Russia, Uzbekistan and Kazakhstan.

Jan 1, 1995

By E. Robert Kiehl

In the early days of the United States, gypsum was most commonly used for the manufacture of plasters with energy being used for quarrying, grinding, and calcining of gypsum rock. With the dramatic switch to gypsum-drywall construction after World War II, the energy usage per ton of rock processed increased more than threefold, and with the rapid growth of the construction industry, the total energy consumption in gypsum-board production alone increased eightfold during the period from 1940 to 1973. The gypsum industry was one of the first to recognize the need for energy conservation and has voluntarily reported its progress to the Federal Energy Administration for the past several years. Efficiencies in the use of energy have resulted in decreasing the unit consumption an estimated 10 percent during the past six years. Improved combustion efficiencies, optimum operating conditions, more liberal use of insulation, and heat recovery will all contribute to the gypsum industry's goal of using less energy. Gypsum products today are vital to over 85 percent of new housing construction in the United States.

Jan 1, 1978

By J. Brinen, D. R. Nagaraj

Secondary Ion Mass Spectroscopy (SIMS) was used to study copper ion adsorption, and its effect on subsequent sulfide collector adsorption, on pyrite and pyroxene minerals under flotation related conditions. Copper was found to adsorb on both of these minerals and cause enhanced sulfide collector adsorption. The distribution and depth profile of copper and collector on these mineral surfaces were obtained by using SIMS in the imaging mode. The results of this study have provided a valuable insight to understanding pyrite and gangue flotation observed frequently in operating plants.

Jan 1, 1995

By C. L. Schneider, R. P. King

Size distributions and liberation spectra were measured in samples taken from 10 streams in a taconite milling circuit under normal operating conditions. The size distributions were deter- mined by sieving and the liberation spectra by image analysis using the linear-intercept method with proper stereological correction. The measured data were used to validate a simulation of the milling circuit using MODSIM which included the calculation of both size distributions and liberation spectra. Both the measured data and the simulator showed that liberated magnetite was returned to the mill in the cyclone underflow. The simulation will be used to improve the economic performance of the plant.

Jan 1, 1995

By Fred V. Carrillo

California was the leading state in industrial mineral production value with an estimated value of nearly $2 billion. In total value of U.S. non-fuel mineral production estimated for 1992 by the U.S; Bureau of Mines, California ranked second; 81 % of California's total production value was derived from industrial minerals. California led all other states in the production of boron minerals, portland cement, diatomite, calcined gypsum and construction sand and gravel, and ranked second in potash and soda ash production. California's five leading industrial minerals in terms of value were portland cement, construction sand and gravel, boron, crushed stone, and soda ash. California had 13 additional industrial minerals production with reported sales of over $1 million including; industrial sand and gravel, magnesium compounds, lime, salt, potash, natural sodium sulfate, clay, feldspar, crude gypsum, pumice, dimension stone, calcium chloride and perlite.

Jan 1, 1995

By N. Rajmohan, K. T. Jacob

Presented is a thermodynamic feasibility analysis of extracting base metal chlorides from low-grade, multi-metallic oxide ores using CaC[1]2 as a chlorinating agent in the presence of SO2 and O2. The oxides react to form corresponding chlorides, while CaC[1]2 is converted to CaSO4. The Ellingham diagram is used for comparing the standard Gibbs' free energy change for the sulfation-chlorination reaction of a large number of oxides. Except for alumina, silica and chromia, most of the other metal oxides will be converted to their respective chlorides. The volatile chlorides can be condensed, and the chlorides present in the condensed state can be leached. A process is proposed that uses a nontoxic chlorinating agent and gives an efficient separation of the metallic values from the gangue.

Jan 1, 1993

By B. H. Richard, P. J. Wolfe, T. G. Holdeman

Guided seismic wave propagation was studied in the Lower Freeport (6A) coal seam in the Oak Park No. 7 mine near Cadiz, OH. Three component geophones were implanted in the coal at distances ranging from 72 m to 183 m from the seismic source. Both Love- and Rayleigh-type modes were observed but the Love-type mode produced the best data. Detailed analysis was performed on the best Love data and a Dziewonski map of group velocity vs. frequency was constructed. This map was in excellent agreement with a theoretical dispersion curve calculated for a model of the coal seam. The Love wave group velocity was found to have a minimum value of 510 m/sec at 275 Hz. Only the fundamental mode contributed significantly to the observed signal and it was observed up to the maximum distance available.

Jan 1, 1987

By Ronald P. Geitgey

Pumice and volcanic cinder are volcanic rocks characterized by a cellular structure. They are formed as gases (primarily water) dissolved in molten rock, or magma, exsolve to generate a froth that cools and solidifies into rigid foam. The cells or bubbles are referred to as vesicles and they range in size from a few thousandth of a millimeter to several centimeters. Due to their vesicular character, both pumice and cinder have lower density and higher porosity than most other rock types, and, as the vesicle walls are broken, sharp cutting edges are continually generated. These properties are the basis for their commercial value as lightweight aggregates, insulators, absorbents, and abrasives. There is a certain imprecision in the terminology applied to volcanic products, reflecting to varying degrees the diversity of volcanic rocks, the relative youth of volcanology as a distinct field of study, and customs and practices of commercial trade. In general terms, pumice is light colored (white, gray, pink, pale yellow, or brown) and highly vesicular, usually with vesicle walls that are visibly glassy. Many pumice fragments are light enough to float on water. Pumice is readily cut by steel tools and some can be crushed by hand. Individual pumice fragments may range from 1 or 2 m in one dimension to c1 mm. Commercially, finer fragments are called pumicite or volcanic ash. In volcanology the term ash refers to any fragment c2 mm in size regardless of its composition. Cinder, or scoria, is dark colored (black, red, brown) with thick vesicle walls that appear dull or stony and that may exhibit iridescence. Cinder typically is heavier than pumice and has a higher crushing strength. In volcanology the term scoria refers to dark vesicular material throughout a wide size range while it is common commercial practice to use scoria for larger fragments (usually greater than 2.5 cm) and cinder for smaller fragments. GEOLOGY Composition and Physical Characteristics Most pumice is silicic ranging from 60 to 70% SiO2, that is, dacitic to rhyolitic in composition. Pumice of less silicic composition, including basaltic, occurs but it is less common and does not have extensive commercial use. Scoria and cinder are typically basaltic to andesitic with approximately 50 to 60% SiO2. Pumice and cinder may contain phenocrysts of feldspars and various ferromagnesian minerals that crystallized in the magma prior to eruption. Fragments of rock through which the magma has passed may be entrained in the melt and wall rock may be fragmented and admixed during an explosive eruption. Some scoria particles have lithic fragment cores. Phenocrysts and lithic fragments are relatively unimportant in cinder end uses but their presence may be detrimental in certain pumice products. Pumice typically has vesicles <1 mm in size separated by thin walls. Vesicle shapes include irregular, spherical, elliptical, and elongate to the point of being tubular with a silky appearance (Fig. 1). In some pumices, the vesicles are interconnected making the fragments permeable and highly absorbent; in others the vesicles are isolated forming a highly porous but very impermeable pumice. Floating masses of pumice fragments from the eruption of Krakatoa in 1883 were reported in the Indian Ocean for up to two years after the eruption. Vesicles in cinder are larger and range from spherical to highly irregular in shape with much thicker walls and abundant interconnections. Scoria and cinder are typically heavier, porous, and do not float. Density and hardness of pumice must be expressed precisely to avoid confusion. Density may refer to the glass itself, the apparent density of the vesicular pumice particle, or the bulk density of pumice in a deposit or in a product. Pumice glass has a specific gravity of 2.5 or more depending on its composition. Pumice fragments typically have a specific gravity of 4.0 and so will float on water, at least until enough vesicles are saturated to cause them to sink. Expressed as density, pumice fragments typically weigh less than 1 g/cm3. Depending on moisture content, particle density, and particle size distribution, the bulk density of pumice typically ranges from 500 to 700 kg/m3. Typical bulk densities of cinder range from 700 to 900 kg/m3 for material used as lightweight aggregate while the bulk density of cinder used for highways and railroad ballast may be considerably higher. Hardness in pumice may refer to the glass vesicle walls, possibly including crystals or lithic fragments, or to the apparent hardness of the particle as a whole, which is more a measure of the strength of the vesicle structure. Pumice glass typically has a Mohs hardness of 5 to 5.5. A pumice particle may have a much lower apparent hardness and be easily cut with a knife or steel saw because the vesicle walls break readily. Pumice and cinder are primarily pyroclastic deposits formed as fragmental products of volcanic eruptions. Several classification - systems differing in various details have been proposed for pyroclasts and pyroclastic deposits based on particle size (Fisher, 1961, Schmid, 1981, Cas and Wright, 1988). Generally, particles >64 mm are referred to as blocks or bombs depending on their shape. Particles between 64 mm and 2 mm (4 mm in some schemes) are called lapilli and smaller particles are called ash. These names may be modified by compositional terms, for example pumice lapilli or scoria lapilli. Most commercial deposits are composed of fragments in the lapilli size range. In the United States, pumice fragments having one dimension of 5 cm or more are legally defined as block pumice. The procedures for acquiring pumice from federal land are determined in part by this definition and are described in a later section.

Jan 1, 1994