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By C. A. Young

Previous experimental results have shown that an increase in temperature and/or oxygen concentration leads to an increase in the hydrophobicity of fluorite (CaF2) with adsorbed oleate. Subsequently, ex-situ Fourier transform infrared (FT-IR) transmission studies suggested that this increase in hydrophobicity was the result of double-bond reactions between adjacent oleate species adsorbed at the fluorite surface. Now an in-situ FT-IR study on single crystals of fluorite has been used to monitor this phenomenon using internal reflection spectroscopy (IRS) with the crystals serving as reactive internal reflection elements. The double-bond reaction has been correlated with in-situ adsorption density measurements. These results demonstrate that only the first chemisorbed oleate layer undergoes the double-bond reaction at an appreciable rate. However, multilayers of precipitated calcium oleate in the case of fluorite appear to react minimally even for oxygen saturated solutions at elevated temperatures.

Jan 1, 1991

By I. K. Choi

In a recent paper by Smith and Wen(1) the adsorption of sodium dodecylsulfate and trimethyldodecylammonium chloride on kaolinite was studied. As would be expected considering the general negative character of kaolinite, except perhaps at quite' acid pH values (2,3,4), it was found that trimethyldodecylammonium chloride adsorbed strongly on kaolinite at basic pH values. Furthermore, it was found that sodium dodecylsulfate adsorbed strongly on kaolinite at acid pH values, particularly at initial 1H values below pH 3 (final pH values near pH 4). It is interesting to note that adsorption of the anionic surfactant was strong under conditions where the kaolinite was apparently slightly negatively charged (2). The present paper reports on an extension of the work by Smith and Wen. In this paper the effects of the presence of dodecyl alcohol and sodium hexametaphosphate on adsorption of sodium dodecylsulfate and trimethyldodecylammonium chloride on kaolinite are considered.

Jan 1, 1967

By K Timtner

As shown in former publications there are problems in load sharing of backstops in multiple drives of conveyors. Therefore, detailed calculation methods and design recommendations are required. In this paper various designs of load sharing methods are described and a dynamic torque calculation method will be presented. With this method the loadsharing properties for low and high speed backstops are calculated and compared. These properties depend on the spring characteristic of the drive train between backstop and load. Furthermore, the properties depend on the method of torquearm support and shock absorber configuration. Remarkable differences for external and internal backstops are shown

Jan 1, 1998

By P. I. Prescott

Ground calcium carbonate (GCC) is used in the paper, plastics, paint, rubber, caulks, and sealants industries. The favorable properties of GCC include high whiteness and brightness, low hardness, and outstanding rheology in water systems. The quality of calcitic GCC ores, which include chalk, limestone, and marble, is dependent on calcite purity and the nature and quantity of ancillary minerals. Wet and dry grinding is used in the manufacture of GCC. Ore processed by optical sorting, flotation, and/or particle size classification has higher brightness and lower abrasion. GCC markets are a function of the product's properties, purity, and cost.

Jan 1, 1995

By J. Gauntt

Calcium carbonate is one of the most widely used industrial minerals in applications like cement, lime, agriculture, power plant fluegas desulfurization (FGD) and construction aggregates. Most applications are generally high-volume and low value ($9/t or $10/st) or less free-on-board (f.o.b.) mine site) uses of this material. Specialty uses of ground calcium carbonate (GCC) are typically referred to as ?performance mineral? or ?extender and ?ller? applications. Primary specialty markets for GCC include paper and plastics as well as a number of construction applications including joint compounds, carpet backing, paint, and adhesives, caulks and sealants (ACS). Other important specialty applications for GCC include rubber, food and personal care products. A new and growing application for GCC is in nonwoven fabrics, where this mineral replaces a small percentage of the polymer. Typical specialty applications for GCC are color sensitive and require extremely white/bright materials. Although deposits of limestone are located in most states, high brightness resources are relatively rare and controlled by a limited group of suppliers.

By Z. Zhongwei

The leaching kinetic of mechanically activated sphalerite with acid FeCl3 solution was investigated. The result has shown that mechanical pre-treatment has greatly enhanced the leaching process. Comparing with the original concentrate, the activated one can be leached more completely at relatively lower temperature with diluter FeCl3 concentration within a shorter leaching time. The activation energy for the activated concentrate is 27 KJ/mol, while for the original one is 52 KJ/mol.

Jan 1, 1995

By C. RAMADINI, F. NURJAMAN, A. SHOFI, B. SUHARNO

Nickel demand is increasing along with the rising need for stainless steel and other alloy steel/iron. The small addition of nickel in such materials can improve impact strength, ductility and corrosion resistance. Nickel is generally obtained from nickel sulfide ores (nickel associated with sulfur) and nickel laterite ores (nickel associated with iron and magnesium silicate). Almost 60 percent of nickel is now produced from sulfide ores, despite its existence in sulfide ores being less than in laterite ores. However, the depletion of sulfide ore reserves makes the mastery of nickel laterite ore processing of important and immediate concern. Selective reduction followed by magnetic separation has been in development in lateritic nickel ore processing to overcome the issues of high energy consumption and pollution associated with conventional pyrometallurgy methods such as blast furnace and rotary kiln electric arc furnace (RKEF).

By Lawrence A. Browning

In recent years, there has been a growing realization of the importance of ground water as a national resource and increasing concern that this resource be properly managed and protected from a variety of pervasive practices that endanger it. Aquifers have been adversely affected in every region of the country. In dealing w.ith the underground water program, EPA will have the following objectives: to protect human health, and to protect and conserve an important national resource. In pursuing these objectives, EPA will take economic consequences and other national objectives (e.g., energy) into account. EPA intends to pursue these objectives in full partnership with the States. Generally the States should retain the lead in protecting ground water.

Jan 1, 1978

By Norris E. Brooks

MAPCO Inc. is an integrated energy company involved in oil, gas, gas liquids, pipelines, and coal. The Coal Segment has installed a simple incentive program based on profit, tons produced, and hours worked at each operation. The plan has two segments-production bonus and profit sharing. Each segment is described and the results, which include high productivity, good safety, and high morale are discussed.

Jan 1, 1983

By Manuel Pérez-Tello, María M. Salazar-Campoy, Óscar Rodríguez-Hoyos

The Kaldo furnace is a type of top-blown, rotary reactor that is widely used for the production of precious metals. During the production of doré, a gas jet of compressed air is injected through a water-cooled lance to impinge upon the molten bath surface in the presence of molten metal and a slag phase. A common problem during operation is the difficulty in controlling the distance that the injection lance can penetrate through the reactor mouth without being splashed by the molten phases. Splashing may produce accretions on the lance surface as well as plugging of the nozzle at the lance tip. An additional problem may occur when the gas jet impinges upon the furnace wall and causes rapid wearing of the refractory linings. Because the conditions prevailing in the Kaldo furnace offers poor visibility to the human eye, its operation mostly relies on the empirical knowledge of plant operators and process engineers. A systematic study in a scale model of the Kaldo furnace under controlled laboratory conditions may be valuable to estimate the maximum penetration distance of the injection lance, and thus help improve the operation of an industrial reactor. From a fundamental perspective, the observation of the basic features of the flow patterns in the scale model may help elucidate the relevant phenomena governing the hydrodynamics in this type of system.

By YONGQIONG YANG, Ning Wang, CHONGGUANG LUO, LI ZHU, Hanjie Wen, SHENGJIANG DU, Hannian Gu

Kaolin clay from Late Permian sequences has been considered a potential resource for niobium (Nb) due to high concentrations reported at several hundred micrograms per gram and large areal distribution. A previous case study identified titanium (Ti)-bearing minerals associated with kaolin clay as the main host phases for niobium. Correlation between the Nb and Ti concentrations was poor, however, and the types of Ti-bearing minerals and modes of Nb occurrence were unclear. To investigate this, typical kaolin clay samples from Late Permian sequences in southwest China were characterized, and final products derived from them were investigated using X-ray fluorescence (XRF), inductively coupled plasma-mass spectrometry (ICP-MS), X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM) and energy-dispersive X-ray spectroscopy (EDS). The results revealed three types of titanium dioxide (TiO2) mineral phases in the clay samples: (1) massive TiO2 minerals, (2) aggregates of nano TiO2 minerals and (3) granular TiO2 minerals. The first two did not contain niobium. From the EDS analysis, the granular TiO2 minerals, including anatase and rutile, were the source of Nb in the kaolin clay samples. 

By Chee Theng

"So many talks, so little time.One of the toughest challenges associated with attending the SME Annual Conference and Expo is deciding how to allocate one’s resources. After accounting for keynote and plenary sessions, committee meetings, networking events, luncheons and exhibits, attending even one of the 109 technical sessions and more than 600 technical paper presentations can be a labor of love. Many, however, managed to make it to many of the sessions, including the mineral and metallurgical processing technical session on solvent extraction, ion exchange and electrowinning.At one point, that room was seated to near capacity, with a considerable number of the audience members standing by the walls at the back. Brittany Valera of Freeport-McMoRan Inc. was one who came early and enjoyed the session in its entirety. "Everything was pretty exciting," she said. "I really liked the modular plants. I think the future of mining, just like what we talked about in there, lies in thinking about things like remote locations, lifetimes of plants, anything that would be reusable and sustainable; and lower-cost and user-friendly would be really beneficial."Michael Moats, associate professor of metallurgical engineering at Missouri University of Science and Technology, started off the session by presenting on behalf of post-doctoral student Alex Luyima, who, like many before him, had been snapped up by industry and is now working for a secondary-metals refining company in Texas. Their team studied the nucleation and growth mechanism of copper on stainless steel from synthetic acidified copper sulfate in the absence and presence of chloride ions and three commercial organic additives: Hydrostar 4208, DXG-F7 and Cyquest N-900. Currenttime data were analyzed using known models, with reference to scanning electron microscope images. Good agreement was achieved between the models and SEM micrographs of deposits at a commercially relevant current density of 30 mA/ cm2. The addition of 20 mg/L chloride was found to increase the size and reduce the number of nuclei. The addition of 2.5 mg/L of each additive did not change the mechanism, but all three reduced the size and increased the number of nuclei, leading to more uniform coverage of the substrate with smoother deposits produced in twohour electrowinning experiments. N-900 had the best deposition coverage while DXG-7 was the easiest to dissolve."

Jan 1, 2014

By RICKARD HANSEN

Vehicle fires in underground mines pose a certain risk for which measures to prevent or mitigate the fires are highly important. Fire protection measures can be divided into active and passive measures, where active measures require an external power to work in the event of a fire, and passive measures could include an existing partition preventing fire spread. As passive fire protection does not rely on activation, it is expected to provide high reliability and a robust solution, and should be considered during the design process. This paper investigates passive fire protection measures that could be implemented in the design of mining vehicles. It was found that passive fire protection should include the use of several measures simultaneously to ensure fire protection throughout the different phases of a fire. Threshold distances for fuel components were calculated, and it was found that combining hydraulic hoses and electrical cables resulted in larger threshold distances. A pool fire along the underside of a vehicle will pose a certain risk, and passive measures should be focused on ignition prevention, making high demands on the insulation/shielding along the underside. Any occurring tire fire may pose a challenge, and the priority should be on preventing ignition. Potential measures include shielding the wheelhouse and applying fire-resistant sealings.

By H. O. Harju

In July 1968, P.T. Inco Indonesia was granted a Contract of Work to explore and develop the nickel laterite resources on the southeastern peninsula of the island of Sulawesi. Since 1970, exploration has centred on the deposits at Soroako as the site for initial project development. This paper describes the exploration methods used to evaluate these rather unique laterite deposits, the geology of which is described in the first section of this volume.

Jan 1, 1979

By Tom L. Enos

Increased production through the plant was limited due to thickener circuit constraints. To overcome these constraints and maximize plant throughput to match grinding circuit capability, two options were considered: A. Adding 2000 TPD CIL circuit to operate in parallel with the existing CCD circuit. B. Adding a CIL circuit to treat the entire 4600 TPD while retaining some thickeners for tailings thickening. Option B was selected based on simplified plant operations, reduced operating costs, minimal capital requirements, reduced solution losses, and bullion grade improvement.

Jan 1, 1989

By Desiree Willis

At 6 percent downgrade to a low point beneath California?s Sacramento River, the Lower Northwest Interceptor Sewer was a difficult project from the outset. Project owner Sacramento County Regional Sanitation District (SRC-SD) planned to excavate the V-shaped tunnel in two sections using an earth pressure balance (EPB) machine in soft ground. Muck removal, due to the steep downgrade, was a tricky proposition. ?We did look at muck cars, but determined they were not the best option due to the relatively steep slope of the tunnel alignment. The safety benefits of conveyors on this job were obvious, as there were not the potential hazards associated with muck cars traveling on an incline or derailing,? said Steve Norris, senior civil engineer for SRCSD The successful project represented one of the first instances of a conveyor system being used for a soft ground tunnel boring machine (TBM) application. Several projects in California, including a recent tunnel completed in 2009, have highlighted a growing acceptance of conveyor muck removal in a variety of ground conditions. Conveyors offer higher system availability than more common methods, such as muck cars, as they allow for continual operation of the TBM. The design of conveyor systems must, however, take into account the differences in material between soft ground and hard rock, including belt cleaning features, sealed transfer points and other elements.

Jun 1, 2010

By J. Sohn

The most promising near-term alternative to fuel cell driven vehicles is probably Hybrid Electric Vehicle (HEV or EV) technology. HEV technology combines the best characteristics of fuel-driven engines, electric motor drives, and energy storage components. It is designed with a combustion engine that functions as the primary power source, and an electric power storage system that functions as the secondary power source. The presence of the secondary power source allows designers to size the combustion engine for cruising power requirements. A new energy source for HEV or EV market will become lithium ion batteries (LIBs) in the near future. LIBs for HEV or EV has large scale about more 10,000 times than small size one for IT devices in order to achieve high electric density/capacity and high efficiency, etc. In those reasons, physical treatment of the batteries is more difficult for stable dismantling in comparison with the smaller one. Hybrid vehicle sales will grow by nearly 400 percent during the next seven years, according to a new report from analyst firm ABI Research. By 2013 hybrids will make up 6 percent of annual U.S. auto sales. The traction battery pack will become air-cooled LIBs which consists of several modules of Li ion battery and connected in series/parallel configuration to provide about >450 VDC, >150 kW peak power, and >80 Ah capacity. As the use of these batteries tends to increase significantly for the next years, it is relevant issues that development of new recycling methods as well as optimization of existing processes to treat spent LIBs for HEV have being addressed in order to obtain sustainability. In this study, physical treatment containing stable electrical discharge of spent LIBs for HEV was carried out for recovery of valuable metals from the batteries. Also In order to increase the yield of valuable metals through physical treatments such as electric discharge of spent batteries, crushing, and classification, we also focused on the recovery of cobalt from +8 mesh fraction due to its large portion in crushed intermediates.

Jan 1, 2010

By John W. Stevenson

At the No. 4 Mine of Jim Walter Resources in Tuscaloosa County in the North Central part of the State of Alabama, the Mary Lee and Blue Creek coal beds lay 2000 feet below the surface. The quantity of methane gas stored within the coal bed reservoir at this depth and released during development mining necessitates that each coal producing section be ventilated using large air quantities approaching 100,000 cfm. In order to meet coal contractural commitments in the early stages of mine development by installing the necessary number of continuous mining machine units and to develop the mine to projected air shaft sites, high pressure, large volume mine ventilating fans were required. This presentation discusses the installation start-up and changeover procedures when two size GAF 31.5-28-1 TLT-Babcock 3500 Horsepower fans with adjustable pitch in flight blades were put on line while phasing out two Jeffrey Mining Machine Company 8HUA 117 Fans. A graph will be presented to depict the most economic diameter shaft size under 2000 feet of cover with different air quantity requirements.

Jan 1, 1982

By Douglas J. Lacke

1974 marked the start of a new era for Climax Molybdenum Co., a division of AMAX, with the initiation of an open pit operation above the existing successful underground block panel caving mine. A number of problems posed a challenge to the Climax open pit. Highly fractured rock, old mine workings, permafrost, and more than 7.6 m/a (300") of snowfall forced changes in normal operations. Final pit wall design was altered. Production bench heights were lessened due to old workings. These and other modifications contribute to a highly successful open pit operation.

Jan 1, 1981

By R. Miller

Lowering our globe’s emissions is a major effort as we move toward a future net-zero carbon environment requiring significant investment in a new, low-carbon infrastructure, along with key market incentives to change. Industry will play a key part in this transformation, requiring expertise in both energy and emissions. Key elements of the de-carbonization strategy are: energy data, emissions reporting method, governance, de-carbonization project generation and drivers, the MACC, electrification, and the de-carbonization checklist. For a zero carbon future, it will be key for business leaders to understand decarbonization, anticipate technological changes, and implement new business me

Mar 2, 2022