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Table 1.-Salient statistics of carbon black produced from natural gas and liquid hydrocarbons in the United States [ ]

Jan 1, 1967

By Thomas V. Falkie, R. Venkataramani

Table

Jan 1, 1972

By M. M. Wong

A brief investigation was made to determine the feasibility of electro-refining beryllium in a KCI-LiCI-BeC12 bath. Thin, platelike crystals of beryllium metal were produced by electrolyzing technical-grade beryllium metal beads (about 94-percent purity) as the soluble anode. Operating cell conditions were: Temperatures of 450° to 600° C.; an inert atmosphere; bath compositions of (1) 38.1 mol. percent KC1, 54.8 mol. percent LiCl, and 7.1 mol. percent BeC12 and (2) 36.7 mol. percent KC1, 52.7 mol. percent LiCl, and 10.6 mol. percent BeC12; cell voltages of 0.30 to 0.80; and initial cathode current densities of 50 to 435 a./sq, ft. Current efficiencies ranging from 87 to 96 percent were obtained. Qualitative spectrographic analyses of the metal products indicated that impurities were reduced. This technique offers the possibility of producing a grade of beryllium purer than that now generally available, which may have better mechanical properties.

Jan 1, 1960

By J. B. Stephenson

The Bureau of Mines, under an interagency agreement with the Department of Energy (DOE), investigated the feasibility of hardfacing the critical surfaces of valves and similar devices by chemical vapor deposition. The purpose of this research was to increase the wear resistance of these components for use in the abrasive and erosive environment of coal gasification units. Tungsten and molybdenum coatings were produced on nickel-plated carbon steels and stain-less steels by hydrogen reduction of the metal hexafluoride at 325° to 600° C. Titanium nitride coatings were produced on low-carbon steels by the reaction of titanium tetrachloride, hydrogen, and nitrogen at 1,000° C. Titanium carbonitride coatings were produced on low-carbon steels by the reaction of nitrogen, hydrogen, and methane at 900° C. Tungsten, molybdenum and titanium nitride coatings were formed on 6-, 10-, and l2-inch (0.15-, 0.25-, and 0.30-meter) ball valve seats for evaluation in the low-Btu coal gasification pilot plant at the Morgantown Energy Research Center, Morgantown, W. Va.

Jan 1, 1979

By K. K. Kelley, L. B. Pankratz, W. W. Weller

The heat capacity of columbium (niobium) carbide (CbC ) was measured over the temperature range from 51 ° to 298 ° K, and the entropy at 298.15° K was evaluated . Also , the heat content above 298.15 ° K of columbium carbide was measured to 1,800 ° K. The results were combined with the known heat of formation at 298.15 ° K to obtain values of the heat and free energy of formation over the temperature range from 298.15 ° K to 2,000 ° K.

Jan 1, 1964

By C. Özgen Karacan

Degasification and methane control in underground coal mining is an important area augmenting conventional ventilation in order to prevent possible fires and explosions due to excessive methane emissions. Coal bed reservoir engineering has been applied for many years to coalbed methane production. In recent years, modeling the flow and draining methane, not only from coal bed itself but also from the overlying strata, have been recognized as important areas of expertise for supplementing underground ventilation. This paper demonstrates the applications of coal bed reservoir engineering and modeling techniques for optimizing and controlling methane emissions in longwall and continuous miner sections. Practical applications and some considerations are presented for reservoir modeling, borehole performances, and face emission predictions for various coal bed and borehole configurations. A section on field reservoir studies and well bore log analyses for methane control are also presented as a complementary way of controlling methane and optimizing ventilation.

Jan 1, 2009

By Richard H. Spencer, Thomas E. Doerfler, Robert L. Lagace, James M. Dobbie, William S. Hawes

This report assesses the expected detectability, on the surface above mines, of electromagnetic signals produced in the frequency band of 630 to 3030 Hz by a rescue transmitter activated by miners trapped underground. This assessment is based on a statistical analysis of experimental signal and noise data taken at a representative sample of coal mine sites well distributed over the United States underground coal fields. Regression analyses are performed to characterize the signal transmission behavior of overburdens as a function of depth and frequency. The predicted signal behavior is then combined with experimentally based distributions of the background noise, and aural detection characteristics of signals in noise, to generate curves of the expected probability of detection for trapped miner signals versus overburden depth and operating frequency. The implications of these results, and associated recommendations, are presented regarding the detectability of trapped miners, sensitivity analyses and confirmatory tests, and operational utilization considerations for the trapped miners and the search and rescue team on the surface.

Jan 7, 1980

By Joseph J. Wallace

1. From the standpoint of known recoverable reserves, the following is the order of importance of the beds: Upper Kittaoning, Lower Kittanning, Upper Freeport, Lower Freeport, Middle Kittaning, Clarion, Pittsburgh, and Redstone. 2. mown measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and on 1,800 tons per acre-foot of coal in place, me estimated at 1,859 million short tons as of January 1, 1952. Of this, 1,351 million short tons me in beds 28 inches and more thick. Areas in each bed were omitted from the estimates because available data relative to the bed characteristics are too meager to make an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1953

By Mary F. Koehler

Interoxidic compounds, such as vanadates, have not been studied extensively in the field of thermodynamics. This is a report of three vanadates of sodium--metavanadate, pyrovanadate, and orthovanadate. Vanadates of other metals will be considered in future reports. The heats of formation at 298.15° K. of the three sodium vanadates (both from the oxides and from the elements) were derived from the results of sodium hydroxide solution calorimetry. Free energies of formation were obtained by combining heat and entropy values. The results support the conclusion that the three sodium vanadates were stable with respect to all possible decompositions in which vanadium retains its pentavalency.

Jan 1, 1960

By N. S. Dalal, X. Shi

"Electron spin resonance (ESR) spin trapping methodology has been used to study the reactions of manganese dusts with glutathione, employing a-{4-pyridyl-1-oxide)·N-tert-butyl-nitrone (PBN) and 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) as spin traps. The results show evidence for the glutathionyl radical formation in the reactions of both MnO2 and manganese (Ill) acetate with glutathione. Based on these experimental observations, we hypothesise that the mechanism of neurotoxic effects of manganese might be due to the fact that the generation of glutathionyl radicals depletes the glutathione pool and reduces the glutathione shield against free radical products of dopamine metabolism and manganese induced reactive oxygenated species. IntroductionExposure to manganese compounds often occurs as the result of foundries and mining operations (1. 2). Other significant sources of environmental manganese include coal-fired power plants and burning of residual and crude oil (3, 4). Lately gasoline combustion has also started to contribute since manganese (methyl cyclopentadienyl manganese tricarbonyl. 0. 125 g/gallon) is being used instead of lead as an antiknock ingredient in automobile fuels (5. 6). Although manganese is an essential element in certain biological processes it is toxic in excessive amounts. The manganese toxicity is mainly associated with the nervous system (7-9). Symptoms frequently observed in manganese poisoning or manganism are disorientation, memory loss, anxiety, compulsive laughing and crying, mask-like faces, akincsia rigidity and tremor (10). In spite of numerous investigations to understand the mechanism of manganese induced injury. it has not been possible to localize the initial chemical lesion responsible for altered physiology and ultimate cell death. This may perhaps he the reason for failure in developing a successful therapy for manganese intoxication."

Jan 1, 1990

By C. Gary Reiness

A safety glass eyepiece which had been repeatedly exposed to mine environment over a number of years was studied to determine some of its optical properties. In the regions from 385 to 400 mµ and from 625 to 760 mµ, the transmittance was less than the 89 percent required by the American Standard Safety Code for Head, Eye, and Respiratory Protection. From 200 to 320 mµ the relative transmittance of two parts of the eyepiece was found to vary widely, having a maximum of 38 percent difference at 315 mµ. Irradiation of the glass by ultraviolet light caused enhanced absorption in the range from 200 to 1,200 mµ. There was a time-dependent increase of 1016 color centers per cubic centimeter throughout this range after 36.5 hours of irradiation. The rate-of-growth curve for the optical density, at 243.5 mµ and 23° C, was resolved into linear and saturable components, indicating zero order and first order

Jan 1, 1968

By B. J. Dalton

Several relationships between coexisting phases for analytical binary solutions near the critical point are given. These relationships were developed from a consideration of a (G u, P) surface at constant temperature and a (G u, T) surface at constant pressure, where G is the molal Gibbs free energy, u is the concentration of component 1 expressed as a mole fraction, G is the pressure, and T is the temperature. These formulas should facilitate the calculation of some of the quantities useful in making thermodynamic consistency checks on phase equilibria data about the critical point.

Jan 1, 1970

By L. B. Pankratz

High-temperature heat-content values of gallium and scandium sesquioxides were measured over the temperature range from 298° to 1,800° K. The results fill gaps in the thermodynamic information for these compounds; no previous similar data existed. The heat-content values were combined with heats and entropies of formation to obtain free energies of formation of gallium and scandium sesquioxides to 2,000° K. The thermodynamic stabilities of the sesquioxides of aluminum, gallium, scandim, and yttrium were compared.

Jan 1, 1963

By L. E. Schultze

[The Bureau of Mines conducted bench-scale studies to develop techniques for stripping tetravalent cerium from tri-n-butyl phosphate solutions. Experiments were conducted in a constant-temperature bath using beakers and mechanical stirring. Ninety-five pct of the cerium was stripped from a 50-pct tri-n-butyl phosphate 50-pct kerosene solution containing 0.18 M cerium in 15 minutes at 50° C using 0.11 M aqueous formaldehyde.]

Jan 1, 1974

By G. A. Apell

The presence of considerable mineralization at the surface together with other favorable conditions suggested inclusion of the Nigger Jim diggings area in a comprehensive study of shallow lead deposits in southwestern Wisconsin. The area, which was the site of considerable shallow development some 60 to 70 years ago, offered the possibility of substantial quantities of lead at near-surface horizons. The investigation included completion of 30 churn-drill holes totaling 1,808 feet of drilling, 2 diamond-drill holes totaling 164.5 feet of drilling, and 25 feet of test pitting in two excavations. The degree of mineralization was determined in an area l,500 feet long and 150 to 300 feet wide along a mineralized trend that has not been investigated beyond the limits of the zone drilled by the Bureau of Mines.

Jan 1, 1948

PURPOSE: Evaluate practical technological advances in hearing protective devices for use in different mining environments RESEARCH SUMMARY: Previous NIOSH research shows that miners develop hearing loss much more quickly than nonoccupationally noise-exposed individuals and that miners experience a greater severity of hearing loss than would be expected for nonoccupational noise-exposed persons of the same age and sex. As described in the National Occupation-al Research Agenda, problems created by occupational hearing loss include(1) reduced quality of life due to social isolation and unrelenting tinnitus,(2) impaired communication with family members, the public, and coworkers, (3) diminished ability to monitor the work environment (i.e., warning signals, equipment sounds, etc.), (4) lost productivity and increased accidents resulting from impaired communication and isolation, and (5) expenses for workers? compensation and hearing aids.

Jan 1, 2001

By C. J. Chindgren

A refractory-lined, garage-type automobile incinerator with a natural gas afterburner for air pollution control was cooperatively constructed and tested by the Bureau of Mines and the Wasatch Metal & Salvage Co. in Salt Lake City, Utah. The incinerator is capable of relatively smokeless burning of 32 to 60 cars per day, dependent on the degree to which the cars are stripped prior to incineration. Preliminary burning campaigns indicate the cost of incineration to be approximately $2.75 per car.

Jan 1, 1970

By H. Polat, Q. Hu, M. Polat, S. Chander

"The electrostatic charge on spray droplets of ionic surfactant solutions and coal particles was measured and the results were correlated with the dust collection efficiency. When various surfactant were added, the magnitude of the droplet charge increased significantly and it was observed to be a function of surfactant type and concentration. The concentration of maximum droplet charge coincided with surfactant concentration where maximum collection efficiency was observed for these surfactants. Particles of coal also carried substantial amount of charge magnitude of which seemed to be a function of coal rank.Based on the results presented in this paper, it was concluded that ionic surfactant primarily act as a strong electrostatic charge inducer for droplets. Due to interactions between these highly charged droplets and naturally charged particles, the efficiency of droplet-particle collisions play a primary role when compared to the wetting and engulfment phenomenon which could only follow a successful collision. INTRODUCTIONWater spray are widely used to suppress airborne dust in mine atmospheres (Walton and Woolcock, 1960; Kobrick, 1970; Hamilton, 1974; Jayaraman et al., 1986). Several investigators have considered the use of surfactants to enhance the effectiveness of water sprays especially for difficult to wet particles such as those of coal (Glanville and Wightman, 1979). The capture of dust particles by water droplets involves droplet-particle collisions, adhesion of particles to droplets, and engulfment of particles into droplets. Surfactants affect these sub processes through their influence on droplet charge, surface tension, and wetting. The last two mechanism have been thoroughly studied in recent years (Walker et al., 1952; Cohen and Rosen, 1981; Glenville and Haley, 1982; Chander et al., 1988; 1991). However, little attention has been paid to the role of electrical charge on particles and droplets on the collision and adhesion of spray droplets and dust particles."

Nov 1, 1995

By R. R. Wells

This report summarizes the results of laboratory testing of copper-bearing magnetite ore from the Poorman, Bush & Brown, and Copper Center deposits, Kasaan Peninsula, Prince of Wales Island, southeastern Alaska. The ores contain minor amounts of chalcopyrite and pyrite. Intimate association of these sulfides with magnetite necessitates fine grinding for adequate liberation and rejection of copper and sulfur and for the production of high-grade iron concentrate low in objectionable impurities. Laboratory tests indicated that the optimum results can be obtained by flotation of ore ground to minus-100-mesh, with subsequent wet magnetic separation treatment of the flotation tailing. A summary of results obtained by this treatment of the three samples tested is shown in table 1.

Jan 1, 1957

By David C. Byrne

PURPOSE: Evaluate practical technological advances in hearing protective devices for use in different mining environments. RESEARCH SUMMARY: Previous NIOSH research shows that miners develop hearing loss much more quickly than nonoccupationally noise-exposed individuals and that miners experience a greater severity of hearing loss than would be expected for nonoccupational noise-exposed persons of the same age and sex. As described in the National Occupation-al Research Agenda, problems created by occupational hearing loss include(1) reduced quality of life due to social isolation and unrelenting tinnitus,(2) impaired communication with family members, the public, and coworkers, (3) diminished ability to monitor the work environment (i.e., warning signals, equipment sounds, etc.), (4) lost productivity and increased accidents resulting from impaired communication and isolation, and (5) expenses for workers’ compensation and hearing aids. Although eliminating hazardous noise is the long-term solution to the noise problem, miners will likely need to rely on personal hearing protection in certain situations for quite some time. However, it is well known that noise attenuation provided by hearing protectors as they are worn during everyday use is usually quite different (i.e., worse) than when tested under lab conditions. In addition, workers may refuse to wear their hearing protection for any number of reasons. This project was initiated to evaluate practical technological advances in hearing protectors, with an emphasis on optimizing the balance between effectiveness, comfort, over protection, and communication ability. The recently completed auditory research facility is now under-going the accreditation process conducted by the National Institute of Standards and Technology under the National Voluntary Laboratory Accreditation Program. Experiments are planned to investigate the factors that affect a miner’s ability to hear hazard and warning sounds (e.g., roof working, alarm signals, spoken communications, etc.). A service contract has been initiated to record and digitally store samples of typical warning sounds heard in an underground coal mine. This information will be analyzed in the lab to develop recommendations that can be offered to the mining community regarding correct earplug/earmuff usage to maximize there cognition of hazard and warning sounds while adequately protecting the miners’ hearing.

Jan 12, 2001