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By E. L. Garton

The Bureau of Mines for a number of years has been conducting an investigation of crude petroleum from producing fields in the United States and the Western Hemisphere and has published a series of reports on these fields. Analyses of crude-oil samples from many oil fields of Oklahoma are given in Bulletin 2913. Analyses of 21 representative crude oils from various producing zones of the Oklahoma City field are given in this report. A close study of the analyses reveals very few differences in the general characteristics and chemical properties of these oils.

Jan 1, 1932

By N. A. Gokcen

This Bureau of Mines report reviews and summarizes recent studies of the rates of chlorination of aluminous resources with CO and C12 mixtures with and without COC12. No reaction mechanism could be obtained from the existing results; however, diffusional barriers in the gas and solid layers probably control the chlorination rate in thermogravimetric experiments. Fluidized beds of particles smaller than 0.1 mm appeared to show very little solid layer diffusional barrier. For optimum chlorination the particle size should probably be less than 8 mm, the calcination temperature approximately 700° C, and the chlorination temperature from 650° to 750° C. Relatively rapid chlorination with COC12 in thermogravimetric experiments was attributed partly to the simultaneous supply of reductant and chlorinator by one gas to the sample reaction site. Comparable results for chlorination of fluidized beds with COC12 are not available. Equimolar mixtures of CO and C12 produced the optimum rate of reaction. Addition to the calcine of 10 to 20 wt-pct NaCl accelerated the rate of chlorination, and addition of SiC14 to the gas mixture decreased the rate of chlorination of SiO2 drastically, but at the expense of chlorination of significant fractions of Al2O3. Further research in various areas is suggested.

Jan 1, 1983

By Raymond P. Maloney

The Bureau of Mines investigated the White Mountain mercury deposit, in the Kuskokwim River Basin, to better determine the extent of mercury mineralization and to encourage its development by private industry. A program of diamond drilling, augering, bulldozer trenching, and sampling was carried on during four field seasons, from 1960 to 1963, inclusive. Significant amounts of cinnabar, with only trace amounts of arsenic and antimony, occur in dolomite over an area about 4,000 feet long and 1,500 feet wide. The deposit differs from other mercury deposits in the Kuskokwim River Basin by the absence of silica-carbonate and rhyolite intrusives. Small-scale mining was started in 1963 as the result of Bureau investigation and continued during the summers of 1964 and 1965. The investigations indicate that open pit mining might be the most feasible method of working this deposit.

Jan 1, 1967

By W. T. Benson

The Bureau of Mines has examined selected deposits of titanium minerals throughout the United States. The titaniferous magnetite deposits in the western San Gabriel Mountains, Los Angeles County, Calif., were among those selected for study, and in 1956-58 field work was conducted to determine the extent and character of the titaniferous magnetite deposits occurring in the area. This report describes this work and summarizes earlier work in the area by the Bureau and others. The titaniferous magnetite occurs disseminated as seams and lenticular pods in an anorthosite belt 4 to 6 miles wide that trends about. N. 80° W., extending from sec. 13, T. 3 N., R. 12 W., to the west boundary of R. 14 W., at which point the titaniferous magnetite-bearing rocks disappear beneath the sediments in the Santa Clara River Valley.

Jan 1, 1962

By L. Nahai

COAL, salt, lapis lazuli, and construction materials such as lime, gypsum, slate and stone were the only mineral commodities produced in Afghanistan during 1963. Beryl has been produced sporadically. Small deposits of chromite and lead-zinc are known but remained unexploited because there were no domestic markets for the two commodities and transportation costs from Afghanistan to world markets were too high. Oil fields of sufficient magnitude to justify exploitation have not been discovered, but known natural gas reserves are substantial and have potential significance. There is evidence of large high-grade iron ore resources, but these are in an unfavorable location. The contribution of the mineral industry to the economy was small, although precise figures are not available. The reported value of mineral production in 1963 (excluding barite) was 181.6 million afghanis (about US$4 million). Employment in the industry, including cement plants and quarries, was estimated to be no more than about 2,000.

Jan 1, 1964

By James P. Ulery, Jon C. Volkwein

The U.S. Bureau of Mines investigated a method of using inert gas to prevent the formation of explosive gas mixtures in auger highwall mining of coal. A combination of gasoline and diesel engine exhaust gases was introduced into the auger drill hole using a short section of pipe located at the collar. Gas samples were taken and analyzed on-site with infrared detectors for oxygen, carbon dioxide, methane, and carbon monoxide. Evacuated bottle samples were also taken and analyzed by gas chromatography in the laboratory. These gas results were analyzed for explosibility. Coal samples from various depths were used to obtain the gas content of the coal using the modified direct method. Personal expo- sure to carbon monoxide was also monitored. The highest methane level observed was 9.55%. The levels of inert gas (carbon dioxide and nitrogen) were sufficiently high to prevent any ignition of the methane. Results showed that for all conditions during mining, gas concentrations were nonexplosive. The gas content of the coal was about 0.30 cm3/g. The maximum personal time-weighted average sample for carbon monoxide was 20 ppm. This system provides a safe, inexpensive, simple method for pre- venting explosions during auger mining.

Jan 1, 1993

By Boyd Guthrie

The current use of Mid - Continent crude oil for the manufacture of war products , such as aviation gasoline and lubricating cil , has caused an acute shortage of available supply from established sources . Therefore , refiners who heretofore have had no reason to use West Texas crude oils now are considering them as charging stock and need more information concerning their characteristics . The Bureau of Mines has published several reports3/ giving analyses of the most important of these crude oils . However, to make the applicable data in these publications readily available to refiners , the present compilation of analyses of West Texas crude oils has been prepared . Data showing the effect of catalytic desulfurization of naphthas from West Texas crude oils have been presented in a restricted Bureau of Mines Report of Investigations . These analyses were made under the general supervision of R. A. Cattell , chief, Petroleum and Natural Gas Division, Bureau of Mines , Washington, D. C. , and N. A. C. Smith, supervising engineer , Fetroleum Experiment Station, Bureau of Mines , Bartlesville, Okla . , and under the direct supervision of Harold M. Smith, senior petroleum chemist, Bartlesville , Okla .

Jan 1, 1944

By J. E. Zeilinger

This Bureau of Mines report describes the preparation characteristics of the significant coalbeds of Clay, Gilmer, and Lewis Counties, W. Va. In 1966, almost 1.3 million tons of coal was mined in these counties, of which more than one-half was from the Pittsburgh coalbed. Washability analyses were made of 16 coalbed samples. Of these, only 11 samples could be upgraded to metallurgical quality. For steam or power generation five of the coals were of low sulfur content as received. The remaining samples were generally of medium sulfur content even after upgrading.

Jan 1, 1969

By C. E. Augustine, B. A. Landry, P. Nicholls

"Wien bituminous coal is burned in a hand-fired up-draft boiler used for heating purposes it has a decided tendency to produce smoke. A design of furnace and a method of firing and attendance that are satisfactory for fuels low in volatile matter, as anthracite or coke, are not necessarily Satisfactory for bituminous coals. It is therefore becoming common practice to use a special design of furnace for bituminous coals, in order to facilitate the combustion of the volatile matter and soot. This is done by (1) providing a larger combustion space to give more time for the combustion, (2) construction that will produce a better mixing of the gases and secondary air supplied over the fuel bed, or (3) keeping the gases at a higher temperature by preheating the secondary air, as may be done by surrounding them with refractory surfaces, or causing them to pass through a fuel bed of hot coke. A furnace may be built to use any or all of these methods of smoke prevention.In Bureau of Mines Technical Paper 303, Blizard5 and others give tests on a large heating boiler when burning coke, anthracite, and bituminous coal. Certair alternative furnace arrangements were used, but there was no material change in the furnace design for the various fuels. Since that time the manufacturer has made modifications in design to adapt it for use of bituminous coal, and additional tests have been made to determine how this change affected the production of smoke and the efficiency of the boiler."

Jun 1, 1929

By M. E. Tyrrell

Mixtures of zirconium diboride and iron, cobalt, and nickel were resistance sintered to high-density compacts using modified electric welding equipment. To evaluate the use of iron, cobalt, or nickel as binders for zirconium diboride, the sintered compacts were examined in polished section and tested for crushing strength, hardness, microhardness, oxidation rate, and resistance to mechanical shock. Each of the zirconium diboride-metal mixtures produced brittle cermets, but the hardness was generally satisfactory. The iron- and cobalt-bonded cermets exhibited rather poor oxidation resistance. Cobalt provided the least brittle bond, and nickel, the hardest and most resistant to oxidation. Iron tended to form chalky compacts with low resistance to mechanical shock.

Jan 1, 1963

By Cheryl Hill, Michael Keane, Pamela Mike, Raghoottma Pandurangi, William Wallace, Mohindar Seebra, Val Vallyathan

"Dipalmitoyl glycerophosphorylcholine (lecithin) dispersed in physiologic saline, a model of the primary component of pulmonary surfactant, is adsorbed by respirable quartz and aluminosilicate dusts. Dust cytotoxicity as measured by erythrocyte bemolysis and pulmonary macrophage enzyme release is suppressed by this adsorption. The degree of suppression of hemolytic potential versus specific adsorption of lecithin from dispersion in saline by respirable quartz and kaolin dusts are compared with dusts' BET specific surface areas to interpret the prophylactic effect of lecithin adsorption. Dust hemolytic potential versus medium pH is presented. Fourier transform infrared spectroscopy and photo-acoustic spectroscopy of lecithin on quartz and of lecithin on kaolin are presented and reviewed with results of studies of the time course of removal of lecithin adsorbed on mineral surfaces by digestion by phospholipase enzyme. Results are discussed in terms of a model of prompt neutralization of respired mineral dusts by pulmonary surfactant, and a gradual re-toxification by digestive processes acting on the adsorbed prophylactic surfactant coating following phagocytosis. INTRODUCTIONQuartz dust of respirable size is well known to cause fibrotic lung disease, but numerous questions persist in the understanding of the initiation and progression of this disease. Our approach concentrates on physical and chemical aspects of mineral dusts early-on in their interactions with living organisms, and we have chosen simplified models to investigate that interaction.In the alveolar ·spaces of the lung, tissue is coated with a surface-active material (pulmonary surfactant), which, among other functions, mechanically stabilizes the lung from collapse by reducing the surface tension of water in the alveolar sacs.1 This surfactant is also the material that is first contacted by a mineral particle that is transported to an alveolus and is impacted there. This surfactant material has been studied extensively. The primary components are known to be proteins (about 11 % in dog lavage fluid), and phospholipids (about 88%).2 Pbosphatidyl cholines constitute roughly 80% of the phospholipid fraction; about 70% of the phosphatidyl choline fraction is dipalmitoyl lecithin (DPL).2 Respirable aluminosilicate particles are capable of adsorbing dipalmitoyl lecithin from dispersion in physiologic saline, a model for a possible initial event occurring upon deposition of a particle in a pulmonary alveolus. As may be seen from Figure 1, the DPL molecule has several fixed charges at neutral pH; a positive charge on the trimethylamine (choline) moiety, and a negative charge on the phosphate group. Also evident are the two fatty acid residues of palmitic acid, which are bonded through ester likages to the glycerol segment of the molecule. The fatty acid moieties of phosphatidyl choline make the molecule inso1uble in aqueous solutions under normal conditions, but a colloidal unit of aggregated molecules called a micelle is usually formed spontaneously above a certain minimum concentration. Small micellar vesicles are generally formed in the laboratory by using ultrasonic agitation or by solvent evaporation methods."

Jan 1, 1990

By W. W. Agey

As a result of a field examination made during the Bureau of Mines intensive manganese program, three lots of ore were procured from the famous old Paymaster District, 7 miles from Midway Wells, Imperial County, Calif. This district is an old producer and shipped approximately 10,000 tons of 45-percent manganese ore during World War I. A 2-ton lot of ore was taken of a Bureau engineer from the exposure of a small fissure vein in conglomerate on the Turtle Group of claims; 1 mile east of the Pacific Coast Manganese Corp. claims. The vein material consisted of manganese oxides, calcite, and quartz in fairly coarse association.

Jan 1, 1949

By Frank L. Hess

Vanadium, although widely spread in minute quantities through the crust of the earth, is found in few places sufficiently concentrated to be economically mined and prepared for use. Most rocks carry from a trace to a few hundredths of a per cent of vanadium oxide, and coal ash may carry about as much as the rocks, Much of the "coal" quoted in the literature as carrying vanadium has been asphaltite, and in other ccal the vanadium is of late introduction. The ash of the petroleums, though usually present in very small quantity, may carry a large percentage of vanadiun, so that production of vanadium from it has been seriously considered. Naturally the ashes of soze asphaltites similarly carry vanadium.' The great deposit at Minasragra, Peru, to which further reference will be made, is probably an altered asphaltite. Ilmenite and cther iron minerals usually carry vanadium 10 and some has been saved from the minette ores of France. 11 Many veins that carry lead copper and zinc minerals also carry a little vanadium, which, especially if the veins are in a comparatively dry region, such as the southwestern United States, northern Mexico, Northern Rhodesia, Southwest Africa, or Spain, collects in the oxidized parts of the veins as vanadinite,

Apr 1, 1932

By Richard L. Rains

The Bureau of Mines conducted a mineral investigation of the 29,000-acre Dixie Summit area near Elk City, Idaho, during the summer of 1989. At the Petsite mine a marginally economic, identified resource of 4.9 million tons with an average grade of 0.023 ounces gold per ton was delineated. Possible resources of gold, along with silver, copper, lead, and zinc, occur in at least eight other lode deposits. Placer gold may be recoverable by recreational-sized suction dredges in some stream drainages, Five lode mines in the study area have produced over 5,516 ounces of gold (placer gold production was not recorded), 4,757 troy ounces of sliver, 36,746 pounds of lead, and 3,800 pounds of copper. Current mining claims in or adjacent to the study area total 460 lode and 70 placer claims. There are two patented lode claims within the Dixie Summit study area.

Jan 1, 1991

By Joseph S. Coffman

The Bureau of Mines investigated the availability of barite (BaSO4) from 35 U.S. and 41 non-U.S. mines and deposits in 17 market economy countries (MEC's). This evaluation assesses the availability of mud-grade barite, and concentrates consumed by the chemicals and fillers industries. The demonstrated resources defined in this analysis totaled 130 million metric tons (Mmt) of barite (contained BaSO4), yielding a potential 115 Mmt of recoverable barite concentrates. At the 1984 MEC production rate, the evaluated resources would last about 30 yr; however, this would include production costs of up to $100/mt concentrate. An average price needed to cover all costs of production over the life of each operation was determined for both mud-grade and chemical- and filler-grade barite products. Including a 0-pct discounted-cash-flow rate of return (DCFROR), regional weighted- average total production cost ranged from $38/mt for barite concentrates in Asia to $71/mt for U.S. operations. Transportation costs have the greatest impact, contributing up to 60 pct of the total cost of production. Rail transportation costs from the mines to U.S. markets are generally significantly higher than ocean shipping rates on imports.

Jan 1, 1986

By Foster Fraas

Almost all minerals show irreversible changes in electrical conductivity after heating in the temperature range 100° to 800° C. This effect can be detected with only a limited number of minerals with the standard ionizing-electrode-type separator, which differentiates between nonconductors and conductors in the single-particle resistivity range of 1011 to 1013 ohms. Tests outside this range with other type separators, such as the static field type, increase the number of minerals with which the effect can be detected to almost all that were tested. Irreversibility may be the result of an alteration of adsorption layers, volatilization of surface cations or anions, or an oxidation or reduction. One example is limonite, which decomposes to hematite and passes through two minima and two maxima in conductivity in the temperature range 100° to 900° C.

Jan 1, 1959

By Jerry G. Craig

The Bureau of Mines has developed a computerized oil and gas well data retrieval system from studies of the waterflood potential of a producing reservoir. This system stores pertinent information about each well completed in a reservoir and facilitates selection and manipulation of large volumes of data. Use of the system enables reservoir information to be supplied rapidly, accurately, and at less expense.

Jan 1, 1971

By W. A. Cole

This report covers the preliminary phase of an investigation of clays, shales, and certain rocks in Wisconsin to determine the feasibility of processing lightweight aggregate in the State. The study was extended to include rotary-kiln testing of a limited number of shale samples, and to an appraisal of the Maquoketa shale resources in eastern Wisconsin. A total of 45 samples of clays, shales, and other argillaceous rocks of Wisconsin were tested. The lower Maquoketa shale is the only material found to date that offers possibilities as a source of material that can be processed in a rotary kiln for lightweight aggregate. Bedrock occurrences of the Maquoketa shale are found in the eastern and southwestern parts of the State. The populous southeastern region of Wisconsin presents a large potential marketing area for lightweight aggregate. For this reason special study was directed to the Maquoketa shale in the eastern district.

Jan 1, 1961

By Gerrit V. R. Goodman

Future coal mining systems will be able to cut from crosscut to crosscut where advances could exceed 100 ft. However, limitations arise when ventilating such mining systems. In deep advance mining, there would be no workers at the face to advance ventilation tubing or curtain manually. Traditional methods also provide no means for maintaining face ventilation after the miner backs away from the face. U.S. Bureau of Mines research is studying means to provide effective ventilation at cut depths beyond the current limit of 4D ft. Several innovative ventilation schemes are currently being considered. One such method is the use of a jet fan to ventilate a deep cut. A jet fan is simply a freestanding fan using little or no ducting to direct the ventilation flow. Jet fan testing in a 90-ft entry revealed that higher exit velocities and greater penetration depth occurred when various configurations were used to confine and direct the air flow. Additional testing also indicated that 2,200 cfm of fresh air was delivered to the face? 90 ft distant when a check curtain was used to limit entrainment around the fan. Without this curtain, this quantity dropped to only 1,000 cfm. This testing indicated that a jet fan was capable of providing ventilation to a distant face area. It also highlighted potential problems, such as recirculation at the fan and reentrainment in the jet flow. Despite these potential problems, jet fans may be adequate for ventilating cuts exceeding 4D ft.

Jan 1, 2010

By John J. Sammarco

This U.S. Bureau of Mines report describes the research effort and results for a computer-assisted appendage control system of a Joy 14CM continuous mining machine. The cutter head (shear), gathering head, conveyor, and stabilizer jack are the appendages. Positional control of each appendage is accomplished by specifying the desired position to the appendage control computer, which uses appendage position sensor data. Appendage movement is actuated until the desired position is attained as determined by control algorithms. A description of the sensors, mechanical and electrical interfaces, data acquisition and control (DAC) system, experimental method to determine appendage response characteristics (range of motion, start and stop delay times, and movement rates), and their application to the position control loop algorithms are presented. Also, the test results for the shear in an unloaded (free space) and loaded (cutting) condition of the shear are presented.

Jan 1, 1991