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By Fred N. Kissell

In This Chapter [Measuring the gas emission from the coal Methane at the top of the silo Methane at the load-out area and Actions taken after a silo explosion] Methane accumulations in coal silos have resulted in the occasional silo explosion. These can be quite violent and dangerous because coal dust adds to the strength of the blast. However, with the appropriate precautionary measures, methane accumulations in silos can be greatly reduced. Mine Safety and Health Administration (MSHA) regulations at 30 CFR2 77.201 require that the methane content in the air of any coal silo be maintained below 1.0 vol %.3 Also, MSHA requires that methane tests be conducted before any electrical equipment is energized, unless a continuous monitor capable of deenergizing the electrical equipment is used.4 Measuring the gas emission from the coal. The first necessary step in dealing with silo methane issues is to measure the gas emission from the coal going into the silo. Such measure-ments allow one to estimate the silo ventilation needs and permit a comparison with the methane controls used at other mines that have similar gas levels. The gassiness of the coal can be measured by taking conveyor belt grab samples.5 Matta et al. [1978] measured the gas emission from conveyor belt grab samples using a simple desorption test. To conduct the test, they collected several grab samples of coal, weighing a few pounds each, from the conveyor belt entering the silo.6 They then sealed the coal into an airtight sample container that was equipped with a valve and short hose along with a pressure gauge. Every few hours they opened the valve and bled the emitted gas into a water-filled graduated cylinder that had been inverted and placed in a pan of water (Figure 11–1). The results are shown in Figure 11–2.

Jan 6, 2006

By B. J. Scheiner

The Federal Bureau of Mines investigated an electrolytic oxidation procedure for extracting lead, zinc, copper, and silver from lead-zinc concentrates. Concentrates slurried in brine were pumped through the anode compartment of electrolytic cells equipped with selective ion diaphragms. Hydrochloric and hypochlorous acids generated in the anode compartment converted the metal sulfides in the concentrates to soluble metal chlorides, sulfate ion, and elemental sulfur. Metal extractions of 92 to 100 pct were obtained from lead-zinc concentrates at an energy consumption ranging from 1.5 to 5.0 kW-hr/lb metal extracted. Sodium hydroxide was formed in the cathode compartment at a current efficiency of >99 pet. Silver and copper were extracted from refractory tetrahedrite minerals, but the process entailed a relatively high energy consumption. Sealing the top of the diaphragm cell utilized the chlorine more effectively, thereby reducing energy consumption 10 to 50 pct.

Jan 1, 1975

By W. W. Fowkes

The Federal Bureau of Mines examined a low-temperature tar obtained from a small-scale commercial unit for carbonizing North Dakota lignite for products that might be important to the economic processing of the tar. Tie tar may be divided into three distinct parts: (1) Tar acids, 45 volume-percent; (2) tar bases, 1 volume percent; and (3) neutral compounds, 54 volume-percent. It has a boiling range of approximately 150° to 380° C. (the decomposition temperature) and yields 18 weight-percent as hard pitch. The tar distillate up to 365° C. may be separated as: (1) Tar acids, 48 volume-percent; (2) tar bases, 1 volume-percent; and (3) hydrocarbons, 51 volume-percent. The tar-acid distillate, boiling to approximately 265° C., was characterized in some detail; the neutral fractions and the tar bases were less thoroughly examined. In general, as might be expected of a primary low-temperature tar, the lower boiling fractions are less in quantity compared with the usual high-temperature tar. The homologous series of each major class appears to be rather complete, although some components are present in very small amounts. The tar is quite unstable thermally, and might be more conveniently processed by extraction methods rather than by distillation procedures. The neutral fraction of the tar is highly aromatic, and might be considered as base stock for the production of liquid fuels.

Jan 1, 1961

By Robert F. Chaiken

More than 500 fires are now burning in abandoned coal waste banks and coal deposits in the United States. Once established, such fires can burn for decades, and extinguishing them by conventional methods such as surface sealing to exclude air, excavation to remove fuel, or flushing to cool the fire zone is usually difficult and always expensive. Burnout Control, a technique developed by the Bureau of Mines for the control of abandoned fires, involves the accelerated combustion of coal in place with total management of the heat and fumes produced. A burning waste bank or mine is placed under negative pressure relative to the atmosphere, and heat and combustion products are drawn from the combustion zone through an exhaust ventilation system. Heat produced appears as sensible heat in the exhaust, at temperatures as high as 1,000° C (1,832° F), and can be recovered for the production of steam, hot water, process heat, or electricity. The Bureau's first field demonstration of Burnout Control was at Calamity Hollow in Allegheny County, PA (near Pittsburgh). Calamity Hollow was the site of an underground mine in the 1900's and was surface mined in the 1940's. In the winter of 1961-62, a fire of undetermined origin was discovered in the exposed coal. In 1963, the Bureau constructed a trench barrier around the fire and a surface seal over the affected area. The fire was isolated, but not completely extinguished. In 1979, when the Bureau began work on the Calamity Hollow Mine Fire Project, to demonstrate controlled burnout, the fire was still smoldering on the hot side of the trench barrier. The project, which was begun in December 1979 and ended in July 1982, consisted of the design, construction, operation, and subsequent dismantling of a Burnout Control ventilation system. This report is the fourth in a five-part series that describes the Calamity Hollow Mine Fire Project. The first report, part 1, describes the design and construction of the field installation. Part 2 will present the results of a continuous 4-month burnout operation. (Because part 2 involves the analysis of a substantial body of data, it will not be published until after publication of parts 3, 4, and 5). Part 3 describes the instrumentation used to control and monitor the progress of the burnout operation. This part (part 4) and part 5 both deal with the closeout phase of the field demonstration. The quenching of the fire is described in this report, and part 5 will describe the final excavation and backfilling of the heated zones. The reports in this series document the Calamity Hollow controlled burnout demonstration, which showed that (1) controlled in situ combustion is a feasible method for controlling underground fires in abandoned mines, (2) the resultant thermal exhaust output is sufficient for energy utilization, and (3) water injection with fume exhaustion is a potentially effective method for cooling large underground fire zones. Further trials of both Burnout Control and water injection with fume exhaustion are planned.

Jan 1, 1984

By James C. Barker

Yttrium and rare-earth element. pegmatite dikes are associated with a peralkaline granitic and nephelene syenite complex near Dora Bay on southern Prince of Wales Island. Mineralized dikes were mapped and sampled during USBM investigations in 1987 and 1988. Coarse-grained pegmatite dikes, which emanated as late-stage magmatic fluids from the intrusion, further evolved into vein-dikes and ultimately silica-rich veins. The dikes can be traced up to two miles along a north-south zone. Lithophile elements exhibit a pronounced zonation in vein-dikes and veins that are distal to the Dora Bay complex with increasing values correlating with increasing distance from the complex. The pattern of mineralization suggests very late stage magmatic fluids containing the incompatable lithophile elements were injected into a preexisting north-south fracture zone. REE mineralogy exhibit fine-grained intergrowths of principally thalenite and bastnaesite with lessor monazite and eudialyte. Euxenite contains most of the columbium values and zircon is commonly associated with the dikes. Estimates of inferred and hypothetical resource tonnage range from 1.7 X 1C6 to 8.5 X 106 st for two deposits. Contained RED (including yttrium) averages 0.5 pct and ranges up to 2.0 pct. Deposits are of polymineralic composition and about half of this resource comprises the heavy yttrium subgroup.

Jan 1, 2011

By L. L. Oden

The purpose of this research was to develop a method to remove copper and tin from the magnetic fraction of incinerated municipal refuse, as recovered by the Bureau of Mines pilot plant in College Park, Md. Copper, present in the scrap in a metallic form bonded to ferrous objects, was amenable to leaching in cupric ammonium carbonate solution. Copper levels in small 5-to 10-lb lots of treated scrap were reduced from the initial level, 0.5 to 0.6 pct, to 0.1 to 0.2 pct. Larger lots of scrap (100 lb) were treated less effectively because of poor contact of solution and scrap. Oxidation in the air or in aerated aqueous solution was applied to liberate tin from the dilute solid solution present on the surface of incinerated tinplate. Shredding of air-oxidized scrap or caustic leaching of scrap oxidized in solution reduced tin levels from the initial 0.25-pct level to about 0.1 pct.

Jan 1, 1973

By Robert S. Hedin

Passive methods of treating mine water use chemical and biological processes that decrease metal concentrations and neutralize acidity. Compared with conventional chemical treatment, passive methods generally require more land area, but use less costly reagents and require less operational attention and maintenance. Currently, three types of passive technologies exist: aerobic wetlands, organic substrate wetlands, and anoxic limestone drains. Aerobic wetlands promote mixed oxidation and hydrolysis reactions, and are most effective when the raw mine water is net alkaline. Organic substrate wetlands promote anaerobic bacterial activity that results in the precipitation of metal sulfides and the generation of bicarbonate alkalinity. Anoxic limestone drains generate bicarbonate alkalinity and can be useful for the pretreatment of mine water before it flows into a wetland. Rates of metal and acidity removal for passive systems have been developed empirically by the U.S. Bureau of Mines. Aerobic wetlands remove Fe and Mn from alkaline water at rates of 10-20 and 0.5- 1.0 g. m-2? d-1, respectively. Wetlands with a composted organic substrate remove acidity from mine water at rates of 3-9 g. m-2? d-1?. A model for the design and sizing of passive treatment systems is presented in this report.

Jan 1, 1994

By F. W. Wessel

This report summarizes Bureau of Mines laboratory tests of four tungsten¬-bearing materials of various grades, The test work has demonstrated that the dry reaction between sodium carbonate and scheelite is best conducted at 900° C. or a few degrees less. The sodium carbonate requirement, in addition to the stoichiometric equivalent of the scheelite, is in some inverse relationship to the grade of tungsten in the ore. Residence time and particle size exert a definite but minor control on the reaction. Pressure-digestion tests on an impure concentrate indicate the technical feasibility of extraction by this process. INTRDUCTION Over 100 years ago Oxland discovered that tungstic oxide could be removed from wolframite and converted to a soluble form by reacting the mineral with a soluble alkaline salt at elevated temperatures. He patented this discovery, and this patent 4/ since has been the basis for most tungsten extraction. Much literature exists on this process and its modifications, and the characteristics and possibilities of the reaction are quite well defined.

Jan 1, 1956

By Leroy Dockter

The grinding characteristics of lignite in a ball mill were investigated. The variables studied were initial lignite moisture content, degree of in-the-mill drying, and lignite source. The mill tested was a pilot-p1ant-size conical ball mill which had a maximum output of from 80 to 180 lb/hr pulverized product depending on the lignite and test conditions. The capacity of the test mill ranged from 82 to 103 lb/hr depending upon mine source, in pulverization of as-mined lignite with minimum drying, The capabilities of the ball mill could not be correlated to Hardgrove index of the individual lignites or other observed physical properties. Predrying lignite from its 35 to 40 percent raw moisture content to about 10 percent moisture before grinding improved the mill capacity 87 percent, compared to an increase in capacity of 74 percent with in-the-mi11 drying to the same product moisture.

Jan 1, 1967

By Chas. G. Maier

The bright annealing of copper is an industrial practice of considerable importance. In connection with this process, equilibrium concentrations of carbon monoxide and dioxide, which may exist in contact with copper and cuprous oxide at elevated temperatures, are of interest. Data obtained at the Pacific Experiment Station of the U. S. Bureau of Mines enable estimates of these equilibrium concentrations to be made in two independent ways. Although the publication of final data on one method can not take place until certain further experimental work is accomplished, repeated requests which the Bureau of Minus has had for data relative to the annealing and deoxidation of copper justify the present preliminary report. This paper deals with the calculation of gas concentrations in the reduction of cuprous oxide, using more scientific data which will be published later, and refers especially to those conditions of temperature and concentration of practical implication, and from which critical limits ensue.

Jan 1, 1929

By H. R. Shell

To obtain a better understanding of the crystallization of fluoride containing amphiboles from melts, an investigation of the range of stability between fluoramphi-boles and other minerals was conducted by the Bureau of Mines. This study has shown that the stability of fluoramphiboles is strongly influenced by both fluoride concentration and isomorphic replacement. Over 150 reactions were made with different compositions and reaction conditions. substitutions attempted and the phases that formed when the composition was crystallized by cooling from the melt are discussed. The attainment of equilibrium in these multicomponent systems is not claimed. Many ions that would be expected to enter the amphibole structure instead resulted in crystallization of phases other than amphibole. Those compositions that resulted in a high yield of acicular fluoramphibole by crystallization from the melts are shown in table 2. The fluoramphiboles obtained from melts typically had an acicular crystal habit and a hardness of 6 to 7 on the Mohs' scale. Although many had relatively high length to cross section ratios, none were fibrous; it was concluded that the possibility of synthesizing a fibrous fluoramphibole from a melt was low. However, many compositions can be crystallized into a tough, hard, impact-resistant mass of interlocking acicular crystals.

Jan 1, 1958

By Matthew N. Plis

This U.S. Bureau of Mines report presents the documentation for COALVAL, a coal property evaluation software package developed on Lotus 1-2-3,4 version 2.2, spreadsheets. The software is compatible with version 3.1 as well, and may provisionally be run on the earlier 2.01 version. COALVAL is a menu-driven program that produces a prefeasibility-level cost analysis of mine-planned coal resources. The package contains cost models for each of five coal mining methods commonly employed in Appalachia: auger, contour strip, mountain top removal, continuous miner, and longwall. Other models, such as a dragline cost model, will be incorporated as the Bureau's Coal Recoverability Program matures. COALVAL allows mine operators, evaluators, consultants, and Government entities to input resource data and the various production, operating, and cost variables that pertain to their property. The program can evaluate up to 25 seams, each to be mined with up to five different mining methods, within a given area. Summary spreadsheets listing the cost per clean ton to mine the resources, f.o.b. the tipple, are produced for each property, seam, and mining method/seam combination.

Jan 1, 1993

By J. W. Thompson

A contract stipUlating for the delivery of quantities of phosphate rock" f. o. b. mines," and stipUlating that" while this contract is in form an absolute sale for a fixed quantity in each year, it is mutually understood and agreed that the purchase is for the buyer's consumption and not for a sale; the buyer agreeing to give to seller the refusal of any surplus over and above the actual consumption. Buyer is at liberty to increase or diminish the quantity called for in any year, to the extent of not exceeding 10 per cent; provided that the quantity to be taken shall not be less than buyer's consumption; provided further that notice of such increased or diminished demand be given seller 12 months in advance of such change," is to be construed as a contract for the sale of stated quantities of rock, deliverable in approximately equal quantities during each year for the specified series of years, subject only to be increased or diminished after specified notice in any year, where the amount taken would not be les<; than the buyer's consumption, not exceeding 10 per cent, and the contract indicating that the rock was intended by both parties for consumption in the fertilizer plant of the buyer. but the quantity to be taken was not limited by the necessities of' the plant.

Jan 1, 1916

By K. J. Liles

This Bureau of Mines paper describes the composition and properties of drilling fluids for use in high-temperature geothermal wells, and summarizes the problems encountered with fluid use at the known major geothermal sites throughout the world. These include the western continental United States, Hawaii, Italy, Iceland, Japan, New Zealand, and Turkey. Water-base drilling fluids of 9- to 10-lb/gal weights are relied on primarily for geothermal well use, although air drilling is sometimes used. Bentonite-lignite-water systems have been used most often, and additives such as polyacrylates, lignosulfonates, and chromates are employed to improve the properties of the basic system.

Jan 1, 1976

By D. E. Sullivan

The Bureau of Mines investigated the availability of potash from 68 mines and deposits in 12 market economy countries (MEC&apos;s) containing, at the demonstrated resource level, approximately 11.7 billion metric tons (mt) of potash in assay terms of contained K2O; K2O as used by industry as a standard of comparison for the different forms of potash. These resources include almost 190 million mt in the United States, 9.63 billion mt in Canada, approximately 430 million mt in Western Europe (France, Federal Republic of Germany, Italy, Spain, and the United Kingdom), 1.24 billion mt in the Middle East (Israel and Jordan) and over 220 million mt in other countries (Brazil, Chile, and the Congo). This analysis his determined that future production of potash in MEC?s will most likely continue to be from the large resources associated with producing operations in Canada. Based solely on the demonstrated resources included in this study, potash mining in the United States would decline while overseas production from MEC&apos;s can continue into the next century at near current production levels. However, timely development of new or inferred resources would offset any such decline. Producing mines in Canada have the resources to increase and maintain increased production well into the next century. For U.S. potash users, Canada is a long-term stable and secure source.

Jan 1, 1986

By K. C. Dean

A flotation method was developed by the Bureau of Mines for concentrating pollucite, a cesium-aluminum-silicate mineral that may contain from 20 to 40 percent cesium oxide. Separation of the pollucite from three typical ores was achieved by froth flotation of the associated micas, feldspars, and other gangue minerals, using sulfuric and hydrofluoric acids and a cationic-type collector. A low-tenor, 8 percent cesium ore from Maine was upgraded to 20 percent cesium with recovery of 87 percent of the cesium. Relatively high- grade ores from Canada and Southern Rhodesia were beneficiated at lower ratios of concentration to 28 and 29 percent cesium content respectively with recovery of over 92 percent of the cesium. In addition to concentrating the cesium content of ores, the method also effectively separates cesium from sodium, potassium, and lithium, and in certain ores from rubidium. This is accomplished by selective froth flotation of the alkali metal-bearing gangue minerals such as lepidolite, other micas, and feldspars. Since the alkali metals, especially potassium and rubidium, are difficult to separate chemically or thermally from cesium to prepare high- purity cesium products, separation by physical mans is important.

Jan 1, 1962

By Albert W. Deurbrouck

This report describes the preparation characteristics of the significant, presently producing coalbeds in Mercer County, W. Va. Approximately 650,000 tons of coal was produced in Mercer County, W. Va., in 1960, of which over 630,000 tons was cleaned in four preparation plants. In 1960 the Pocahontas Nos. 3, 6, and 11 coalbeds supplied 99.5 percent of the total coal mined in the county. Because the number of working mines In this county was small, only six samples were collected; four of which were of metallurgical quality as mined. The remaining two samples could be upgraded by washing at suitable specific gravities. Many of the samples taken were of metallurgical quality as mined; however, the float-and-sink analysis on these coals has been included to point out their amenability to the production of premium quality, special purpose coals. In general the coals were low-volatile bituminous in rank with low ash and sulfur contents.

Jan 1, 1963

By Perry G. Cotter

The borides of the transition metals in Groups IV and VI exhibit, in addition to a certain degree of hardness, considerable resistance to heat and oxidation. They have high melting points (1,850°-3,060° C.) and low coefftcients of thermal expansion and can be bonded with other materials and hot-pressed to desired shape (cermets). Suggested uses for the borides include use in rockets and jet engines, as thermocouple protection tubes, as containers for molten metals in die casting, as flame-plated coatings on less refractory compositions to prevent erosion by hot gases, and as control rods and neutron shielding material in nuclear engineering, The Federal Bureau of Mines investigation of zirconium diboride started in 1950 at the Boulder City Nev,, Metallurgy Research Laboratory, Its purpose was to reduce the cost of raw materials for the production of zirconium diboride.

Jan 1, 1961

By Robert L. Anderson

A shaft or slope bottom is that portion of a mine that is contiguous to the bottom of the main hoisting shaft or slope. It includes the terminal tracks for loaded-and empty-car storage, locomotive run-arounds, locomotive shops, charging stalls, supply rooms, pump rooms, waiting rooms, and offices for dispatcher, weighmen, and foremen. This paper will deal principally with the arrangement of tracks and the handling of cars on the bottom, but includes other data that may be affected, directly or indirectly, by the bottom lay-out. All of the mines discussed are being operated in comparatively level coal seams.

Jan 1, 1937

This publication contains eight papers presented at a Bureau of Mines Technology Transfer Symposium in Charleston, W, on June 22, 1983, Five of the papers describe the results of Bureau-sponsored research on cabs and canopies for low-coal underground mining equipment. The other papers describe the efforts of three underground coal mining equipment manufacturers (FMC, Joy, and Lee-Norse) in the area of cab and canopy design.

Jan 1, 1985