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By F. X. McCawley

The Bureau of Mines, in pursuing its goal of extending the life span of strategic materials, conducted field corrosion studies at the East Mesa Known Geothermal Resources Area (KGRA) in the Imperial Valley, Calif., to determine the optimum materials of construction for use in geothermal mineral energy resource recovery plants. These studies included characterization of geothermal environments and in situ corrosion testing. The corrosion resistance of 10 alloys exposed to 5 brine and steam process environments was evaluated using the low-salinity, high-temperature brine from geothermal well Mesa 6-1. Of these alloys, Hastelloy C-276, Hastelloy S, Incone1 625, titanium-2nickel, and 316 L stainless steel had excellent resistance to corrosion in all of the process environments; E-Brite 26-1 and 430 stainless steel had fair resistance. Although general corrosion rates for 4130 steel and 1020 carbon steel were substantially higher than those of the other iron-base alloys, these two alloys could prove useful in low-salinity process environments because of their low cost. Aluminum alloy 5005 was the least corrosion resistant alloy and pitted severely. Scales formed on all of the alloys in every process environment. Calcite, aragonite, and an amorphous silicate were the major components of the scales.

Jan 1, 1980

By Paul L. Michael

Roof warring signals from eleven underground coal mines (principally in the Pittsburgh seam) were studied and analyzed. The character of individual acoustic warning signals is shown to be dependent on spectral distribution of energy. Reverberation tires (pulse decay rates) were found to be usually between 0.1 and 0.5 seconds. Listening tests were conducted to assess the miner's ability to discriminate speech and roof talk signals in noise and in quiet, with and without ear protectors and with various levels of hearing loss. The ability to detect roof talk is shown to be generally degraded while wearing car protection in quiet, although, if car protectors are worn only when required by high noise levels, the ability to detect roof talk will be preserved at its maximum.

Jan 1, 1972

By Wilton Johnson

The Bureau of Mines study indicates that land utilized by the mining industry for mineral extraction and processing from 1930 through 1980 amounted to 5.7 million acres, or 0.25 percent of the land mass in the United States. Land reclaimed by the industry during the same period was 2.7 million acres, or 47 percent of the land utilized. Land use by the mining industry includes surface land used for excavation or mining, for waste from underground mining, and for wastes from milling or processing operations. Data on land use for disposal of overburden waste from surface coal mines and on areas affected by subsidence associated with underground mining are included for the period 1930-71 only. The 10 leading States in total land used for mining over the 51-year period were, in decreasing order, Pennsylvania, Kentucky, Ohio, Illinois, West Virginia, Florida, Indiana, California, Alabama, and Missouri. Seven mineral commodities accounting for 92 percent of land use are, in decreasing order, bituminous coal, sand and gravel, stone, phosphate rock, clay, copper, and iron ore, all predominately surface mined. Bituminous coal production was responsible for nearly half of the total area utilized. Reclamation of mined lands and waste disposal sites over the reporting period was largely on lands utilized in mining bituminous coal; 75 percent of the land used for bituminous coal production was reclaimed.

Jan 1, 1981

By Donald W. Mitchell

Research shows that water neutralizes the explosion hazard of coal dust when present in sufficient quantity and when intimately mixed with the dust. The quantity of water required to neutralize coal dust and coal-rock dust mixtures is about equal to the limiting moisture adsorptive capacity of the dust; the adsorptive capacity increases with increase in the fineness and volatile content of the coal. Pools of water or high atmospheric humidity do not reduce the explosion hazard. Although wetted dust is less dispersible than dry dust, poor dispersibility cannot be relied on as the sole safeguard against explosion. Dust mixtures that contain water in excess of their limiting adsorptive capacity are dispersed and ignited by severe initiation sources. Pure coal dust adsorbs water with difficulty and retains water poorly; adsorption and retention is increased by the addition of rock dust the coal; the rock dust agglutinates wetted coal and assures that incombustible is present should drying occur. Therefore, it is advantageous to rock-dust wet areas in bituminous coal and lignite mines. When coal-rock dust mixtures are wetted and subsequently dried, the explosion hazard is about the same as for dust which was not wetted.

Jan 1, 1962

By Robert L. Jones

The Boston Consolidated mine is situated in the Bingham mining district, Salt Lake County; Utah (fig. 1). The property has had a noteworthy production of cupriferous, gold-bearing, pyritic ore in addition to lead ore. The Bureau of Mines established a diamond-drilling development project on the property in September 1943 with the primary objective of determining the continuity of a mineralized zone in the Commercial limestone below and to the northeast of the 800-foot level (fig.2). Examination of the geologic feature at the property previous to drilling indicated that the mineralized limestone horizon would continue belay the 800-foot level, but with a flatter dip than disclosed above this level. During the project period, 36 holes totaling 4,001 feet were drilled from underground stations outlining the zone below the 800-foot level (figs. 2 and 3).

Jan 1, 1949

By E. G. King

As low-temperature heat-capacity and entropy data were available for only one sesquisulfide (cerium sesquisulfide), it appeared desirable to augment the information for this class of compounds by measuring the sulfides of antimony and indium. In addition a pressing need existed for data on indium sulfide to supplement vaporization studies in progress in the Department of Mineral Technology, University of California. This Bureau of Mines paper reports low-temperature heat-capacity measurements and entropy evaluations at 298.15° R. of antimony sesquisulfide of stoiehiometric composition (Sb2S3) and of indium sesquisulfide which was somewhat deficient in sulfur (In2S2.93). The data for the latter substance were adjusted to correspond to the stoichiome tric composition (In2S3 ) . Indium sesquisulfide has a lower entropy at 298.15' K, than either antimony sesquisulfide or cerium sesquisulfide, in line with the higher atomic density of the indium compound.

Jan 1, 1962

By W. A. Calhoun

This investigation of low-grade bauxites as potential sources of aluminum by caustic desilication and alumina extraction was undertaken by the Bureau of Mines to develop extractive methods for winning alumina from domestic deposits of low-grade bauxites. This report is the second of a series covering the work by the Bureau of Mines' Rolla, Mo., and Bauxite, Ark., laboratories. The first report published in the Journal of Metals, December 1951,3/ and dealt with kaolin and halloysite. The present investigation is concerned with low-grade bauxites only. The purpose of these investigations is to increase the domestic supply of aluminum ores. With eventual depletion of high-grade deposits, aluminous materials, such as low-grade bauxite, clays, shales, and high-iron laterites, will become our principal domestic sources of aluminum. The development of extractive processes for winning alumina from these low-grade materials is one of the many national security measures undertaken by the Bureau of Mines. A method has-been developed in the laboratory for successfully treating high-silica bauxites from domestic deposits. In this process the bauxite was calcined at 980° C. to form amorphous silica and alumina. The calcine was then leached by percolation with 15-percent sodium hydroxide solution at 940 to 96° C., removing 67 to 77 percent of the silica with a loss of 4.1 to 5.0 percent of the alumina. The sodium hydroxide in the spent liquor used in desilication was 95 percent recoverable, and comparable desilication results were obtained with 100-percent reclaimed liquor, The indicated cost of reagents, for sodium hydroxide and lime used in the desilication and regenera¬tion of spent liquor, was about $4.00 per ton of calcine treated.

Jan 1, 1954

By J. R. Thoenen

In Progress Report 1,4/ a number of facto mere demonstrated and conclusions drawn from experimental tests and records made during commercial blasting operations at a number of quarries. For example, the tests showed (1) that vibrations received on outcrops were of comparatively

Jan 1, 1938

By G. M. Kintz, Charles B. Carpenter, G. W. Jones

"INTRODUCTION At 9:12 a. m. on April 16, 1947, the ammonium nitrate cargo in hold 4 of the S. S. Grandcamp, a 7,176 gross-ton Liberty ship owned by the French Government, detonated at pier 0 of the Texas City Terminal Railway Co., Texas City, Galveston County, Tex.This detonation was the first of a series of explosions and fires that took the lives of approximately 600 persons, injured 3,000 other persons, and caused a property damage and business loss that will exceed $58,800,000. It has been estimated that the life, accident, and workmen's compensation insurance loss will be $8,200,000.At 1:10 a. m. on April 17, 1947, the ammonium nitrate cargo in hold 5 of the S.S. High Flyer, a 6,214-gross-ton Liberty ship owned and operated by the Lykes Bros. Steamship Co., Inc., detonated at pier L. This explosion materially increased the property damage caused by the first explosion, in between 50 and 100 persons, and is believed to have taken the life of only one person.The exact number of casualties resulting from the Texas City disaster may never be known. On June 22, 1947, 65 days after the explosions, the red Cross and the Texas Department of Public safety repoted:,""Identified dead, 405; unidentified dead, 63; believed missing, 100; injured, 3,000; hospital¬ized, 600; still in hospitals, 37."""

Feb 1, 1948

By Joseph M. Kuchta

The limits of flammability and minimum autoignition temperature of a fuel are important elements in assessing fire and explosion hazards that may exist when using or handling the fuel. The limits of flammability define the range of compositions of the fuel gas or vapor mixed with an oxidant through which a flame, initiated by an outside energy source such as an electrical spark, can propagate. The minimum autoignition temperature (M.A.I.T.) is the lowest temperature at which the fuel vapors ignite spontaneously in a specified medium; in this case the ignition energy is supplied by the heat content of tae environment. This temperature is also referred to as S.I.T. value by some authors. Because the autoignition of a fuel also depends on the time interval during which the fuel is subjected to heat, ignition delays are significant. Ignition delay is defined here as the total time elapsed between the introduction of the liquid fuel into the oxidizing atmosphere and the appearance of a flame. This time interval includes both the physical and chemical processes leading to ignition. The ignition delay is usually maximum at the M.A.I.T, and decreases as the temperature of the system is increased. The flash point and the fire point are also useful in assessing the fire and explosion hazards of a fuel. The flash point is the lowest temperature at which saturated, flammable fuel vapor-air mixtures are formed at atmospheric pressure and, therefore, it is essentially the lower limit of flammability

Jan 1, 1962

By C. F. Winquist

The Bureau of Mines is engaged in research to evaluate the effects of cutter bit wear at coal mine faces. This paper addresses one element of conical bit wear, bit rotation. A discussion on mounting configura-tion and bit forces and their effects on rotation is presented. The effects on rotation and bit forces of bit attack angle, cutting depth, and skew are determined for two types of conical bits during linear cutting of sandstone-inclusive rock. The results indicate that a 10° negative skew angle and 35° attack angle produce the maximum rotation of 17.5° for each foot of cutting. Data on bit rotation and bit forces are presented in an appendix.

Jan 1, 1985

By C. S. Tout

While investigating methods for determining the best temperatures for hot-working experimental stainless steels, the Bureau of Mines Albany Metallurgy Research Center developed a machine in which hot-twist tests could be made in a few minutes. This machine is similar to some used previously except that specimens are heated by induction instead of by radiation, and their temperature is measured by a calibrated radiation-detection unit instead of by a thermocouple. In. developing the technique for using the new machine, tests were made on specimens of medium-carbon steel, mild steel, and AISI (American Iron and Steel Institute) type 304 stainless steel. Tests also were made on as-cast specimens and preworked specimens of experimental AISI type 202, low austenitic stainless steel, and as-cast specimens of AISI type 301 experimental stainless steel. The optimum hot-working temperatures were determined for all types of steel tested. Also, data were gathered on the effects of test speed and temperature on torsional strength and the effect of twisting on tensile stress in the specimen.

Jan 1, 1962

By A. C. Smith

The U.S. Bureau of Mines constructed a large-scaJe facility to study the self-heating of a large coal mass under conditions that simulate a gob area of a mine. The insulated coal chamber can hold up to 13 short tons (st) of coal and is provided with a forced ventilation system and computer-controlled temperature and gas measurement systems to monitor the heat and mass transfer phenomena that occur in the coalbed. Three experiments were completed with high-volatile C bituminous coals that exhibited high spontaneous combustion potentials in laboratory-scale tests. In the first two tests, a sustained heating was not achieved. In the third test, temperatures throughout the coalbed increased steadily from the start, with thermal runaway occurring near the center of the coalbed after 23 days. The thermal reaction wne then moved toward the front of the coalbed. The results of these tests showed that the self-heating of a large coal mass depends not just on the reactivity of the coal, but also on the particle size of the coal, the freshness of the coal surfaces, the heat-of-wetting effect, and the availability of O2 at optimum ventilation rates.

Jan 1, 1991

By E. E. Ungar

The ways in which noise is generated and radiated by chutes and screens are described and corresponding noise control concepts are discussed. The amounts of noise reduction produced by applicable noise control means are delineated and generally cost-effective means are recommended. Available noise control materials and their applications are discussed. The results of field measurements, laboratory experiments, theoretical analyses, and studies of data provided by suppliers are summarized.

Jan 1, 1975

This report presents production and delivered costs for coal exports from the five major Western coal-exporting countries: Australia, Canada. Colombia, South Africa, and the United States. Cost data were compiled from visits to 43 mines by U.S. Bureau of Mines engineers between 1985 and 1990. All report costs are in January 1989 U.S. dollars per short ton. Production costs for raw coal are divided into mining and regulatory categories. Costs are broken down by type of cost, type of mine. and country. Scheduled operating and capital costs for raw coal were processed by the Bureau's MINSIM discounted cash flow program to determine total production costs calculated at 0% and 15% discounted cash flow rates of return (DCFROR). Delivered costs are for salable coal delivered to various markets. Costs are broken down by supply country, market, and type of cost. Scheduled operating and capital costs for salable coal were processed by the Bureau's MINSIM discounted cash-flow program to determine total salable coal costs at 0% DCFROR. Added to total salable coal costs were transportation and port costs to get delivered costs. Comparative overview information on the coal industries of the five study countries are appended. This appendix includes information on industry economics and exports, production and reserves, and coal industry issues.

Jan 1, 1993

By D. Harry Chambers

The Bureau of Mines, through a memorandum of agreement with the Department of Defense, conducted research to recover silver from aircraft scrap. Silver was recovered by an electrolytic method from stainless steel honeycomb sections separated from the aircraft. These sections had been constructed by sandwiching a stainless steel honeycomb core between stainless steel sheets and then brazing the assembly with a silver alloy. Over 300 pounds of silver was used in the B-58 bomber, concentrated in certain honeycomb sections of the aircraft. Following shredding of the aircraft parts, an average of 95 percent (ranging 67 to 100 percent) of the silver was recovered in a single electro-refining step. After the electrorefined product was magnetically cleaned, purity of the recovered silver was greater than 99.3 percent.

Jan 1, 1980

By J. B. Rosenbaum

Prolonged laboratory and limited pilot plant tests have shown that the Bureau of Mines buffered S02 -H2S process is capable of removing 95 to 99 percent of the S02 from industrial waste gases. Most of the S02 is converted to elemental sulfur; only about I percent converted to sulfate The process comprises (1) washing the flue gas to remove particulates and S03, (2) absorption of the S02 in citric acid or other carboxylate solution, (3) reaction of the loaded solution with H2S in a closed vessel to precipitate the absorbed S02 as elemental sulfur, and (4) separation of the sulfur from the regenerated solution by oil flotation and melting. Two-thirds of the molten sulfur is converted to H2S for use in the sulfur precipitation step by reacting sulfur vapor with natural gas and steam in the presence of an alumina catalyst. The chemistry and mechanism of the process are described, initial laboratory and pilot plant data are summarized, and second-generation laboratory operation and pilot plant design are reviewed. Preliminary cost estimates are presented for recovering sulfur from copper smelter gas, powerplant flue gas, and Claus plant tail gas.

Jan 1, 1973

By G. W. Birge, D. E. Wolfson, J. G. Walters

An investigation was conducted to determine the relationship between ASTM and Micum tumbler data and to develop equations that would enable the conversion of data from one test method for comparison with those determined by the other , and thereby facilitate the international exchange of data . Relative strengths of 18 commercially produced cokes were determined by ASTM and Micum tumblers and ASTM shatter test . Two of the samples were coke produced for foundry use , and two were produced in beehive ovens . The remaining 14 samples were produced for blast furnace consumption and had ASTM tumbler stabilities of 36 to 58. Statistical procedures were used to relate the three test methods and also to evaluate the effect of charge weights , top sizes of coke , and types of screens specified by the two standard tumbler procedures , square - hole wire mesh for the ASTM tumbler and punched round - hole for the Micum . A significant result was that the data obtained with like screens have a higher degree of correlation with a smaller standard deviation than data from the screens specified for each tumbler .

Jan 1, 1964

By L. D. Tracy

Many bituminous coal-mining companies have inaugurated extensive safety programs, but the failure to have approved or permissible equipment or safe practice in only one part of a mine has resulted in disaster. The necessity of using only equipment bearing the U. S. Bureau of Mines approval plate is emphasized by the fact that many accidents are the direct result of carelessness on the part of trusted employees using non-permissible equipment. A concrete example is found in the case of an explosion on October 26, 1926, in a mine in the Pittsburgh district, Pennsylvania. Story of the Explosion At about 10 o'clock on the night of the explosion an examination was made in No. 2 butt left and parallel off No. 14 north, and was found to be clear of dangerous accumulations of gas. (See figure). Several hours later a crew of two men brought a self-propelling rock-dusting machine within 50 feet of the face of No. 2 butt parallel before they examined for gas. The machine operator found an accumulation of explosive gas about 13 inches from the roof. He began to wave his arms thoroughly mixing the gas and air. Undoubtedly a highly explosive mixture was created, and as the men attempted to run the machine back to fresh air as explosion occurred.

Jan 1, 1927

Reliably measure stress chan¬ges in order to assess stability of mine openings. Approach: A durable, permissible, sensor and readout system have been developed and tested. How It Works: The stress sensing element is a taut steel wire which is, vibrated at its natural frequency, If the tension on the wire is changed because of deformation of the sensor housing, the natural frequency of the wire changes. This effect is similar to decreasing or increasing the pitch of a violin string by loosening or tightening it. Because the stress sensor electrical output is a frequency signal, rather than an amplitude signal, its accuracy is unaffected by the resistance of the signal wire, or other attenuation. Signal wires can be a mile or longer without affecting accuracy. When a button is pushed on the readout box, the sensor wire is electromagnetically excited and vibrates at its natural frequency. That signal causes a readout in illuminated digits. (By referring to calibration chart and the previous reading, the user knows the change in stress.) This system is permissible. To install the sensor, a slightly oversize hole is drilled into the mine pillar. Next, a special tool is used to both position the sensor and wedge it in place. Figure 1, shows the sensor and its integral wedge and hole-fitting piece.

Jan 1, 1976